Interfacial stress distribution between bovine dentine and resin composite in dentine bonding systems

In finite element stress analysis, the principal interfacial stress at a tensile bond strength of 10 MPa during tensile loading was estimated for the resin composite/dentine material including the bonding area with elastic moduli of 0.03, 0.3, 3.0 and 12.0 GPa assumed in this study. Interfacial stress along the resin composite/bonding area interface or bonding area/dentine interface increased with increasing elastic modulus. The interfacial stress distributed non-uniformly and locally at the most sensitive sites, that is, the edge of the resin composite/bonding area interface with the lowest elastic modulus (0.03 GPa) and the edge of bonding area/dentine interfaces with other elastic modulus values (0.3, 3.0 and 12.0 GPa). The maximum value of interfacial stress increased linearly with increasing elastic modulus of bonding area from 0.03 to 12.0 GPa. This study showed that the distribution of interfacial stress was highly non-uniform along the interfaces of the bonded areas in dentinal adhesives.     

Study of the infiltration and mechanical behavior of C/C composites prepared by ECVI

Three kinds of preforms, chopped fibers/resin carbon, spreading layers of carbon cloth, and needle-pricked long fiber felt, were used in this study. The preforms were densified by using the electrified preform heating CVI method (ECVI), and infiltrated using natural gas. Initial thermal gradients were determined. Resistivity and density evolutions with infiltration time have been recorded. A tensile test was applied to investigate the influence of preform architecture on the tensile properties of the C/C composites. Results show that the architecture of preform strongly influences the uniformity of infiltration and fibers/matrix bonding. The samples prepared from using 1K plain carbon cloth have the smallest density variations with position (about 0.011 g/cm³), and possess the highest tensile strength and modulus, while the samples produced from chopped fibers/resin carbon possess the lowest tensile strength due to their strong interfacial bonding between resin carbon and carbon fibers and poor microstructure.     

Influence of bonding on the tensile creep behavior of paper in a cyclic humidity environment

It has been shown, as paper structure is improved through increased bonding (by increasing relative bonded area or specific bond strength), a fully efficient loaded structure can be achieved. Once fully efficient, further improvements in bonding become redundant and have no effect on some paper deformation behaviors; deformation is dictated only by the characteristics of the fibers. Although previous work had shown this was true for elastic modulus and short time duration stress-strain behavior, it has only recently been shown to be true for constant humidity tensile creep behavior. In this study, the goal was to ascertain if cyclic humidity tensile creep behavior (known as accelerated creep) would follow the same trend. To accomplish this, sheets were made at differing levels of relative bonded area and specific bond strength. This was done by applying two different wet pressing levels (to alter relative bonded area) and using bonder and debonder (to change specific bond strength). It was found that accelerated creep behavior of paper sheets is no different than constant humidity creep behavior; changing bonding does not influence accelerated creep if the sheet has a fully efficient loaded structure. If the sheet structure is inefficiently loaded (there is no redundancy in bonding), accelerated creep will be affected by bonding. However, it is proposed that the only reason accelerated creep is influenced by bonding when inefficiently loaded is because constant humidity creep behavior determines the accelerated behavior and it is influenced, in this case, by bonding.     

新型聚合物水泥胶浆界面剂粘结性能及作用机理研究

采用新型聚合物水泥胶浆作为界面剂以提高新旧混凝土之间的粘结性能,通过拉拔粘结强度与劈裂抗拉粘结强度实验对5种不同类型的聚合物水泥胶浆界面剂的粘结性能进行了测试,并利用扫描电镜(SEM)分析研究了丁苯聚合物水泥胶浆的界面增强机理。实验结果表明,5种聚合物乳液中,丁苯聚合物水泥胶浆具有较好的拉拔粘结性能,当优选m(水泥)∶m(DB-1乳液)=3∶2时,其7d、28d拉拔粘结强度分别达到1.83MPa、2.41MPa,相比水泥净浆空白样分别提高了144%、96%;在劈裂抗拉粘结强度方面,水平方向浇筑时劈裂抗拉粘结强度相对较高,当聚合物水泥胶浆的优选m(水泥)∶m(DB-1乳液)=3∶2,水平浇筑时其28d劈拉粘结强度达到2.96MPa,明显高于不掺界面剂的试样以及掺加其它配比界面剂的混凝土试样;经过微观测试分析,丁苯DB-1聚合物水泥砂浆内部界面过渡区(ITZ)相比空白样明显致密,表明丁苯聚合物的加入有效填充了水泥基材料内部的宏观与微观缺陷,提高了界面过渡区的密实程度。     

Effect of welding parameters on diffusion bonding of type 304 stainless steel–copper bimetal

Abstract

Stainless steel AISI type 304 and electrolytic cold rolled copper were joined by diffusion bonding at temperatures ranging from 650 to 950°C, for times from 5 to 45 min, and at pressures from 2 to 12 MPa. After bonding the microstructure of the interface was investigated, including the grain size, and shear and tensile strengths of the bonded specimens were determined. From the results, it was seen that the bond shear strength was dependent on interface grain boundary migration and on grain growth during the bonding process. In addition, attempts were made to find a relationship between grain size and shear strength in the bonding area. Taking into account the results of shear testing and microstructural observation, for a sound bond, optimum bonding conditions were obtained at temperatures of 800–850°C for 15–20 min at 4–6.5 MPa. The fracture behaviour of the diffusion bonded joint was investigated by means of shear and tensile testing under different bonding conditions. It was found that both shear and tensile strengths of the bonds were sensitive to the bonding conditions, and the intermetallic phases did not affect these parameters. Furthermore, the value of shear strength of the bond surface determined by shear testing was higher than the shear strength of the fracture surface determined by tensile testing.     

超声强化氨基化多壁碳纳米管改性环氧黏接接头性能研究

目的 探究超声处理对氨基化多壁碳纳米管(MWCNTs–NH₂)改性环氧黏接接头黏接性能和热稳定性的影响,为强化MWCNTs–NH₂改性环氧胶黏剂与铝合金的黏接提供参考。方法 通过机械搅拌与声波破碎的方法将质量分数为0.75%的MWCNTs–NH₂添加到环氧胶黏剂基体中,使用MWCNTs–NH₂改性环氧胶黏剂制备铝合金黏接接头,基于超声辅助黏接工艺在铝合金黏接过程中进行超声处理。通过傅里叶变换红外光谱仪(FTIR)分析MWCNTs–NH₂改性环氧胶黏剂基体官能团的变化情况。采用单搭接剪切强度试验测定黏接接头的拉伸剪切强度。通过扫描电子显微镜(Scanning Electron Microscope,SEM)观察黏接接头拉伸失效断面以及铝合金与胶黏剂间的黏接界面。通过热失重分析仪(TGA)测试并记录胶黏剂试样质量随温度变化的曲线。结果 经超声处理后,MWCNTs–NH₂与树脂基体间的化学反应增强。与纯环氧黏接接头相比,超声处理后的MWCNTs–NH_2...     

蜂窝夹层结构真空袋共固化工艺过程实验研究

针对蜂窝夹层板的共固化工艺 , 以玻纤/环氧 648复合材料为面板 , 以 Nomex蜂窝为夹芯材料 , 采用真空袋法研究了树脂流动对胶瘤面积和面板孔隙缺陷的影响 , 并通过平拉强度的测试考察了胶接强度与胶瘤面积之间的关系。结果表明: 胶瘤面积随加压时机的推迟先增大后减小 , 并且下面板/芯材胶瘤面积要大于上面板/芯材胶瘤面积 ; 在树脂黏度变化的不同阶段 , 面板中的孔隙消除机制不同 , 并与密封袋内抽气通路的分布有关。力学测试结果发现 , 胶瘤面积的增大有利于平拉强度的提高 , 但当胶接强度超过蜂窝抗拉强度时 , 平拉强度的测试方法存在局限性。      

服役低温老化对铝合金-玄武岩纤维增强树脂复合材料粘接接头力学性能的影响及失效预测

为了给铝合金-玄武岩纤维增强树脂(BFRP)复合材料粘接结构在汽车工业中的应用提供参考和指导,加工了铝合金-BFRP复合材料粘接接头。结合汽车服役中的温度区间,选取?10℃和?40℃的低温老化环境,对接头进行0、10、20、30天的老化。对老化后的粘接接头进行准静态拉伸试验和剪切试验,得到不同老化时间下铝合金-BFRP粘接接头的准静态失效强度。结合DSC和FTIR分析低温老化对BFRP复合材料的影响,并对粘接接头的失效断面进行宏观分析和SEM分析。结果表明:在低温老化环境中,胶粘剂与BFRP复合材料的化学性质受低温老化作用影响不大,BFRP中的官能团与玻璃化转变温度(T_g)没有发生明显的变化,接头的失效强度和失效模式主要受胶粘剂与粘接基材的热应力影响。对于拉伸接头,随着低温老化时间的增加,BFRP复合材料纤维与树脂基体间的结合力降低,铝合金-BFRP复合材料接头的失效断面中纤维撕裂的比例逐渐减少,拉伸接头失效强度逐渐下降。老化后剪切接头仍为内聚失效,BFRP复合材料的低温老化对铝合金-BFRP复合材料剪切接头的失效强度几乎没有影响,剪切接头失效强度的下降主要是胶粘剂与粘接基材热膨胀系数不一致引起的热应力的影响。采用二次应力准则公式对?10℃和?40℃低温环境下,拉应力、剪应力值随老化时间的变化规律进行了拟合,在此失效准则的基础上,根据响应面原理,建立接头失效强度随老化时间变化的三维曲面,为粘接技术在车身结构中的工程应用提供参考。      

Mechanical behavior and failure modes of aluminum/bamboo sandwich plates under quasi-static loading

Experimental investigations have been made on the quasi-static mechanical behavior and failure modes of aluminum/bamboo sandwich plates. Thermosetting epoxy resin and thermoplastic Polybond resin were used to bond the aluminum sheets and the bamboo. Tensile, compressive and flexural properties were evaluated. The effects of bond conditions on the mechanical behavior and failure modes were examined. The thermoplastic Polybond resin resulted in a stronger interface bond than the thermosetting epoxy resin. The improvement of the interface bond led to significant increases in compressive and flexural properties. The tensile properties were found to be insensitive to the interface bond. The dominant failure mechanisms affected by the interface bond dictated the mechanical properties of the sandwich plates in individual loading conditions.     

Use of Tablet Tensile Strength Adjusted for Surface Area and Mean Interparticulate Distance to Evaluate Dominating Bonding Mechanisms

In this study, tablet tensile strength has been adjusted for tablet surface area and the average distance between particles in compacts of different materials. The aim of the study was to evaluate the feasibility of using this concept to assess the dominating interparticulate bonding mechanisms. Adjustment of the tensile strength for both tablet surface area and mean pore radius gave similar bonding strength values for materials bonding mainly by weak distance forces (crystalline lactose, sucrose, and microcrystalline cellulose) almost independently of compaction pressure. However, particle size and other factors may still affect the compensated strength values. The bond strength was much higher and more varied for materials bonding also with solid bridges (potassium chloride, sodium chloride, and possibly also sodium bicarbonate and amorphous lactose). For these materials, particle size and compaction pressure had a substantial effect on the bond strength. It is probably the formation of continuous bridges between adjacent particles that is important in these materials rather than the surface properties and the average distance between particles positioned at some distance from each other. Hence, adjusting the tensile strength of compacts does not necessarily reflect all the dominating factors responsible for interparticulate bonding. Nonetheless, adjustment for tablet surface area and mean pore radius allowed discrimination between different dominating interparticulate bonding mechanisms in these compacted materials.     

Use of Tablet Tensile Strength Adjusted for Surface Area and Mean Interparticulate Distance to Evaluate Dominating Bonding Mechanisms

In this study, tablet tensile strength has been adjusted for tablet surface area and the average distance between particles in compacts of different materials. The aim of the study was to evaluate the feasibility of using this concept to assess the dominating interparticulate bonding mechanisms. Adjustment of the tensile strength for both tablet surface area and mean pore radius gave similar bonding strength values for materials bonding mainly by weak distance forces (crystalline lactose, sucrose, and microcrystalline cellulose) almost independently of compaction pressure. However, particle size and other factors may still affect the compensated strength values. The bond strength was much higher and more varied for materials bonding also with solid bridges (potassium chloride, sodium chloride, and possibly also sodium bicarbonate and amorphous lactose). For these materials, particle size and compaction pressure had a substantial effect on the bond strength. It is probably the formation of continuous bridges between adjacent particles that is important in these materials rather than the surface properties and the average distance between particles positioned at some distance from each other. Hence, adjusting the tensile strength of compacts does not necessarily reflect all the dominating factors responsible for interparticulate bonding. Nonetheless, adjustment for tablet surface area and mean pore radius allowed discrimination between different dominating interparticulate bonding mechanisms in these compacted materials.     

Co-Curing of CFRP-Steel Hybrid Joints Using the Vacuum Assisted Resin Infusion Process

This study focuses on the one-step co-curing process of carbon fiber reinforced plastics (CFRP) joined with a steel plate to form a hybrid structure. In this process CFRP laminate and bond to the metal are realized simultaneously by resin infusion, such that the same resin serves for both infusion and adhesion. For comparison, the commonly applied two-step process of adhesive bonding is studied. In this case, the CFRP laminate is fabricated in a first stage through resin infusion of Non Crimp Fabric (NCF) and joined to the steel plate in a further step through adhesive bonding. For this purpose, the commercially available epoxy-based Betamate 1620 is applied. CFRP laminates were fabricated using two different resin systems, namely the epoxy (EP)-based RTM6 and a newly developed fast curing polyurethane (PU) resin. Results show comparable mechanical performance of the PU and EP based CFRP laminates. The strength of the bond of the co-cured samples was in the same order as the samples adhesively bonded with the PU resin and the structural adhesive. The assembly adhesive with higher ductility showed a weaker performance compared to the other tests. It could be shown that the surface roughness had the highest impact on the joint performance under the investigated conditions.     

基于内聚力行为和扩展有限元的砂/树脂复合材料拉伸失效行为的数值计算

基于砂/树脂断裂与砂树脂界面脱粘失效行为的砂/树脂三维微细观单胞模型被构建,用于研究砂/树脂在拉伸载荷作用下的微观应力特征、树脂粘结桥的损伤破坏模式及微观结构（树脂含量、砂粒粒径、砂粒级配及粘结桥有效横截面积比）对其宏观拉伸强度的影响。该三维微细观单胞模型采用内聚力行为方法刻画粘结砂/树脂界面的失效,采用扩展有限元方法（Extented finite element,XFEM）捕捉树脂基体损伤和裂纹扩展。计算结果表明:所构建的三维微细观单胞模型能够显式刻画砂/树脂微细观结构断裂过程,解释微细观结构断裂机制,能够有效地提供树脂含量、砂粒粒径、砂粒级配、粘结桥有效横截面积比等微细观结构对砂/树脂宏观拉伸强度（S_t）影响的信息,可为砂/树脂优化设计提供理论指导。      

板状构件粘结强度的非线性超声导波检测

相较于铆接、螺接、焊接等连接方式,板状粘结构件具有质量轻、应力分布均匀等特点,广泛运用于航空航天、车辆制造等工业领域。板状粘结构件在服役过程中出现的粘结强度退化、弱粘结等会影响其服役可靠性及安全性,因此对粘结强度进行检测十分必要。非线性超声导波对材料微观结构特征变化比较敏感,可用于粘结构件的粘结强度检测。采用非线性超声导波对铝合金-环氧树脂-铝合金板状构件进行检测,通过不同的固化工艺制备粘结结构件模拟不同粘结强度,检测结构件中传播的非线性超声导波,计算超声非线性参量,获得超声非线性参量在不同固化工艺下的变化趋势。通过拉伸实验测得粘结强度,进而构建超声非线性参量与粘结强度的关系。实验结果显示,粘结强度越大,超声导波的非线性参量越小。该研究表明,非线性超声导波可有效检测板状构件的粘结强度,为工业检测板状结构粘结强度提供了有效方法。     

热固性和热塑性硼酚醛树脂的配比对绝热层材料力学、粘接和烧蚀性能的影响

分别将热固性(FB)和热塑性(SFB)两种硼酚醛树脂按照质量比为0 :20,5:15,10:10,15:5 and 20:0的比例添加到EPDM基热绝缘材料中,研究了FB和SFB的质量比对热绝缘材料的力学性能、粘接性能和烧蚀性能的影响.结果显示,随着FB用量增加和SFB用量降低,绝热层材料的应力应变曲线逐渐变陡,交联密度、拉伸强度和粘接强度不断增加,抗烧蚀性能不断增强,但是其断裂伸长率却显著下降;而当FB和SFB树脂的重量比为10:10时,材料的综合性能均比较理想.     

基于蛋白质分散的碳纳米管/环氧树脂粘结剂的粘结性能

碳纳米管/环氧树脂因其优良的力学与粘结性能可广泛应用于航空航天等高端领域结构件的胶结连接。然而如何有效降低碳纳米管的团聚性,保证制备工艺的低成本与绿色环保是该纳米粘结剂能够实际应用的关键。为此,本文提出一种基于蛋白质分散的碳纳米管增强环氧树脂粘接剂并对其粘结性能进行了研究。结果表明：经过酸或碱性环境变性处理的大豆分离蛋白能够有效降低碳纳米管的团聚性并显著提高环氧树脂的粘接性能,当碳纳米管质量分数为0.1wt%时,经酸、碱性处理的大豆分离蛋白-碳纳米管/环氧树脂粘结剂的粘结性能增幅分别为26.6%、26.7%;而当碳纳米管质量分数增加到0.3wt%时,两种处理方法的大豆分离蛋白-碳纳米管/环氧树脂粘结剂的粘结性能增幅分别为10.2%和18.3%,碱处理结果比酸处理提升79%。     

羟基硅油改性酚醛树脂基碳纤维复合材料特性研究

利用FT-IR、SEM、拉伸试验等测试方法分析了羟基硅油改性酚醛树脂基碳纤维复合材料机理，并对羟基硅油改性酚醛树脂基碳纤维复合材料特性进行了研究。实验结果表明：羟基硅油能有效改善界面结合状态，提高酚醛树脂基碳纤维复合材料的拉伸强度，为合理调整原料配比，控制生产工艺参数，获得综合性能优异的复合材料奠定了基础。     

Estimating interface bonding strength in clad sheets based on tensile test results

The bond strengths of the three-layered aluminum/stainless steel/aluminum composite clad sheets produced by cold roll bonding were estimated by the tensile test results. The developed procedure was based on the drops in flow stress after the maximum point of the stress–strain curves, which are related to debonding of interfaces and signify the effect of bond strength on the tensile behavior. The shape of the stress–strain curve of a specimen heat treated at 600 °C to form a brittle intermetallic layer at the roll bonding interface was found to be analogous to those obtained from the tensile test of conventional one-layer specimens, which was considered to be a good evidence of interface debonding during tensile test of roll bonded sheets that show sharp flow stress drops. An important contribution of this work is correlating the tension test to peel test results by simple calculations based on the principles of mechanics of materials.     

氟橡胶与金属粘接用新型环氧树脂胶粘剂

用4,4’-二羟基二苯砜与E-51反应制备的树脂配制了可直接用于氟橡胶与金属粘接的新型环氧树脂胶粘剂,系统研究了胶粘剂的粘接性能及耐久性。结果表明:用于胺类硫化的氟橡胶与金属粘接时的平均拉剪强度大于6MPa,所制备试样在自然环境中放置一年后测试,其拉剪强度仍不低于6MPa。通过差示扫描量热法(DSC)和热失重(TGA)分析表明该胶不仅耐热性好,同时也具有很高的热稳定性。此外,所研制胶粘剂用于双酚AF硫化的氟橡胶与金属粘接时的平均拉剪强度大于4.5MPa,其对硅橡胶也有一定的粘接效果,已试用于汽车同步环中氟橡胶与金属的粘接。     

Effects of surface roughness on the diffusion bonding of Al alloy 6061 in air

The effect of surface roughness on the properties of Al6061 joints fabricated by diffusion bonding in air at 450°C was studied. It was found that rougher surfaces yield superior ultimate tensile strength and linearized bonded ratio. Joints with ultimate tensile strength comparable to that of bulk metal were obtained for holding times of 75 min using rougher surfaces; however, the maximum linearized bonded ratio obtained was only about 75%. Incomplete bonding was attributed to air entrapment along the bond interface. This was due to good bonding occurring at the periphery of the bonded specimens during the early part of the bonding process.