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随着污水厂出水排放标准日益提高,对排水中粪大肠菌群的控制也越来越严格。现场电解制次氯酸钠发生系统是一种较为理想的环境友好型氯消毒技术,能够有效杀灭城镇污水处理厂出水中的粪大肠杆菌。因原水水质不同,次氯酸钠的杀菌效果会有差异。次氯酸钠对原水中的氨氮有一定的去除作用,但是有可能氧化原水中残留的有机氮,从而使得氨氮含量重新升高。现场连续投加试验中,反应池次氯酸钠浓度为1.2mg/L,出水中的粪大肠菌群始终稳定达到GB18918-2002一级A标准的要求,且其他水质指标(如氨氮、COD等)良好。 相似文献
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氨氮是我国水体环境监测的主要指标,是各级监测站点的必测项目。本研究主要是比较水体中氨氮测定的两种方法(凯氏定氮法与钠氏试剂分光光度法),主要测定了人工污水中氨氮,对全自动定氮仪的条件优化,并与钠氏试剂法进行比较。结果表明:全自动定氮仪测定水体中氨氮时最佳的条件:滴定所用盐酸浓度在0.03 mol/L比较适宜用于测定水体中的氨氮;定氮仪蒸馏氨氮时消化管中加入40%NaOH的体积数为10 mL。利用Foss-2300全自动定氮仪测定水体中的氨氮是一种方便、快捷,数据可靠,环保、新型的方法。 相似文献
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气态膜吸收法脱除水中氨的传质效果 总被引:2,自引:0,他引:2
利用聚丙烯中空纤维气态膜对氨/水分离过程及影响因素进行研究,考察膜两侧液体流速、浓度、温度等工艺条件对传质系数和氨脱除率的影响。研究结果表明:气态膜-化学吸收法对氨/水有很好分离效果;原料液温度和流速的影响较为显著,传质系数随温度升高而升高,而提高原料液的流速,膜通量增加,氨的脱除率却下降,压力降升高;氨的初始浓度对膜通量影响较大,膜通量随初始浓度升高而增大;吸收液中反应物浓度相对于透过氨浓度过量时,吸收液的浓度、流速对传质过程影响较小。 相似文献
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Mashallah Rezakazemi Ali Ghafarinazari Saeed Shirazian Ali Khoshsima 《Polymer Engineering and Science》2013,53(6):1272-1278
A new modeling approach was developed for prediction of ammonia removal from water by means of porous membranes. The model was based on adaptive neuro‐fuzzy interface system (ANFIS) to simulate ammonia stripping from water by means of hollow‐fiber membrane contactors. The predictions aimed to obtain optimum conditions for ammonia stripping using the Taguchi method. The initial concentrations of ammonia, pH of the ammonia solution, velocity of the feed, and the presence of excess ions in the ammonia feed solution were considered as the input properties. On the other hand, mass transfer coefficient was considered as output. The prediction results revealed that the pH of the ammonia feed has a significant effect on the separation of ammonia from water. The results also showed that the prediction of ANFIS model and experimental data match well and that the model can be used for prediction of porous membranes. Furthermore, simulated annealing was also used to determine controllable conditions to find the highest mass transfer coefficient. POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers 相似文献
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将超重力法氨水吹脱制氨技术用于选择性催化还原(SCR)脱硝工艺(需氨5vol%~10vol%),以空气?氨水为实验体系、旋转填料床为吹氨设备,考察了进气温度、超重力因子、气液体积比在装填不同填料时对脱氨率和产氨率的影响规律。结果表明,处理气量为4~10 m3/h时,丝网和乱堆两种不锈钢填料的吹脱率均随进气温度、超重力因子和气液体积比增大而增大;产氨率随进气温度和超重力因子增大而增大,随气液体积比增大而降低,产氨率达10%以上,与SCR法所需浓度一致,表明超重力氨水吹脱所制氨浓度可用于SCR脱硝。处理气量为50?700 m3/h时,吹脱浓度1wt%的氨氮废水,产氨率最大为3.0%。虽不满足SCR脱硝要求,但可将氨氮废水吹脱和氨水吹脱工艺相结合,节约氨水消耗量。 相似文献
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Effects of low temperatures upon fine structures of cotton pretreated with either liquid ammonia or caustic of mercerizing strength were investigated. Temperatures of cotton after impregnation with liquid ammonia were lowered by (1) liquid nitrogen, (2) acetone–Dry Ice, (3) acetone, or (4) simple evaporation. With alkali-impregnated fabrics, temperature was lowered by immersion in liquid nitrogen. Changes in fine structure of ammonia- and alkali-celluloses were evaluated by x-ray diffraction before and after removal of each swelling reagent. After treatment with either ammonia or caustic soda, extent of crystalline modification was increased as temperature was reduced. X-ray diffractograms taken while liquid ammonia was still present indicated that the cellulose I structure of cotton sheeting was converted to cellulose III at liquid nitrogen temperatures; extent of conversion was approximately that obtained when a looser yarn structure was treated with liquid ammonia and the ammonia was removed by evaporation. When ammonia was removed with water, the cellulose I lattice was regenerated. In the presence of 23% NaOH, diffractograms indicated a significant decrease in order after a similar drop in temperature, but patterns were not of cellulose II until the NaOH was removed with water. Conversion to cellulose III or to cellulose II was achieved instantaneously when ammonia- and alkali-impregnated fabrics were immersed in liquid nitrogen. 相似文献
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《Journal of Adhesion Science and Technology》2013,27(12):1411-1431
Treatment of fluorinated ethylene propylene (FEP) and polytetrafluoroethylene (PTFE) by plasmas established in water vapour or ammonia gas enabled the rapid and facile modification of their surface chemistries. Under comparable plasma conditions, ammonia plasma exposures produced considerably lower air/water contact angles than water vapour plasmas. On storage of samples in air at ambient temperature, contact angles increased markedly within a few days on ammonia plasma-treated samples but remained constant over many weeks on water plasma-treated surfaces. Angle-dependent X-ray photoelectron spectroscopy (XPS) demonstrated a very low depth of modification in the case of ammonia plasma exposure, whereas the oxygen content of water plasma-treated samples was invariant with depth within the XPS analysis region. The long-term stability of water plasma-treated fluorocarbon polymer surfaces is believed to be due to this deep modification which prevents polymer chain reorientation, whereas the shallow modification in ammonia plasmas allows the rapid partial burial of the newly attached chemical groups inside the polymer. When ammonia plasma-treated samples stored in air were immersed in water, the contact angles remained constant, suggesting that the buried groups could not resurface. Contact angle measurements provided a simple and sensitive method for studying the time-dependent reduction in plasma treatment effects and the segmental mobility of modified fluorocarbon polymer surfaces; very shallow reorientation movements can be detected. 相似文献
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氮在水中主要是以有机氮和氨氮的形式存在的,污染受纳水体,影响水环境质量.高浓度氨氮废水可采用吹脱、汽提法去除.中、低浓度氨氮废水可采用MAP法沉氨预处理,除去大部分氨氮后,再经生物处理去除剩余的氨氮.MAP法去除中、低浓度的氨氮处理效果良好,并无二次污染. 相似文献
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采用COSMO-SAC模型研究了不同离子液体存在下氨水溶液的汽液相平衡,探讨了离子液体的亲水性、酸碱性、阴阳离子种类以及功能基团修饰等对氨的相对挥发度的影响。研究发现,不同性质的离子液体均会影响氨水系统的汽液相平衡。一般地,如果水与离子液体相互作用能高于氨与水的相互作用能,离子液体将有利于氨的逸出。当阴离子亲水性和形成氢键的能力越强,或者水与阴离子相互作用能越强,或者氨与阳离子相互作用能越弱,则离子液体越能促进氨水分离。水/离子液体之间的相互作用能与氨/水之间的相互作用能差值越大,离子液体越能提高氨的相对挥发度。当水与离子液体相互作用能低于氨与水的相互作用能时,离子液体也能促进低浓度下的氨水分离。阴离子要比阳离子更能影响氨的相对挥发度,其中氯离子([Cl]-)、醋酸根离子([Ac]-)型离子液体对促进氨水分离的效果更佳。对于甲基咪唑类阳离子([C n mim]+,n=2、4、6、8),烷基链越长,越不利于氨的分离,但在[C2mim]+上嫁接胺基(—NH2)将会改善低浓度下氨水的分离效果。 相似文献
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针对传统焦化蒸氨废水工艺余热未全面回收利用的问题,设计开发了蒸氨废水余热回收利用新技术。通过蒸汽、热水两用型制冷、采暖双工况吸收式热泵机组,可夏季回收蒸氨废水余热制取热水,作为制冷机驱动热源制取工艺冷却水,满足煤气净化回收系统冷却需要,冬季回收蒸氨废水余热并辅以蒸汽为热源生产取暖水,实现了蒸氨废水余热的综合利用,降低了工序能耗,具有较好的经济效益和社会效益。 相似文献
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尿素装置停车实现"零"排放过程分析 总被引:2,自引:0,他引:2
大型尿素装置的生产过程中会产生大量的废水,在正常生产时都较容易回收利用,但在停车过程中将产生大量含氨的废水和废气,因为气相氨较难保存,所以停车时往往会有部分的氨排向空中而造成大气污染和氨的损失.通过对现有装置和停车方法进行改进将气相氨转变为氨水,待再次开车后回收利用,从而使装置停车实现"零"排放. 相似文献