Spatial variation in concentrations of dissolved nitrogen species in an upland blanket peat catchment

The concentration of nitrogen (N), particularly as nitrate (NO3-N), in upland streams, lakes and rivers is frequently used as a diagnostic of the vulnerability of upland ecosystems to increased atmospheric nitrogen deposition and N saturation. The N content of running waters, however, is generally assessed on the basis of sampling at a limited number of points in space and time within the catchment under investigation. The current study was conducted at Trout Beck, an 11.5 km2 blanket peat-dominated catchment in the North Pennine uplands of the UK. Results from sampling at 33 sites within this catchment demonstrated that the concentrations of all dissolved N species were highly variable, even over short distances. Statistical relationships between the concentrations of NO3-N and dissolved organic nitrogen (DON) and percentage catchment cover of Calluna/Eriophorum and Eriophorum vegetation were found. However, it was also noted that in catchments containing limestone outcrops, NO3-N concentration was much higher than in catchments where runoff was sourced directly from the blanket peat surface. It is possible that NH4-N and DON leached from the blanket peat are mineralised and nitrified, providing a source for the NO3-N found in the river channels. Overall, the current study suggests that interpretations of N-saturation based on river water chemistry measurements at a single point must be treated cautiously, and that the influence of catchment-scale physical factors, such as vegetation and geology cover on the concentration of dissolved N species in upland river waters should not be ignored.     

Dissolved and particulate nutrient export from rural catchments: a case study from Luxembourg

Nutrient enrichment of freshwaters continues to be one of the most serious problems facing the management of surface waters. Effective remediation/conservation measures require accurate qualitative and quantitative knowledge of nutrient sources, transport mechanisms, transformations and annual dynamics of different nitrogen (N) and phosphorus (P) forms. In this paper, nitrate (NO3-N), soluble reactive phosphorus (SRP) and total phosphorus (TP) concentrations and loads are presented for two adjacent rural basins of 306 km2 and 424 km2, and for five sub-basins differing in size (between 1 km2 and 33 km2), land use (extent of forest cover between 20% and 93%) and household pressure (from 0 to 40 people/km2) with the aim of studying the influence of land use and catchment size on nutrient exports. The studied catchments are all situated on Devonian schistous substrates in the Ardennes region (Belgium-Luxembourg), and therefore have similar hydrological regimes. As the study period could not be the same for all basins, annual export coefficients were corrected with the 25 years normalized discharge of the Sure River: two regression analyses (for dry and humid periods) relating monthly nutrient loads to monthly runoff were used to determine correction factors to be applied to each parameter and each basin. This procedure allows for the comparing annual export coefficients from basins sampled in different years. Results show a marked seasonal response and a large variability of NO3-N export loads between forested (4 kg N ha-1 year-1), agricultural (27-33 kg N ha-1 year-1) and mixed catchments (17-22 kg N ha-1 year-1). For SRP and TP, no significant agricultural impact was found. Land and bank erosion control the total P massflow in the studied catchments (0.4-1.3 kg P ha-1 year-1), which is mostly in a particulate form, detached and transported during storm events. Soluble reactive P fluxes ranged between 10% and 30% of the TP mass, depending on the importance of point sources in the basins studied. No relation was found between the size of the basins and the export of nitrate, SRP or TP. Nutrient export, specially for NO3-N and TP, shows significant inter-annual variations, closely linked to inter-annual discharge variations. Flow and load frequency data analysis confirm this association for all the basins on an annual basis. Seasonal or storm specific fluxes strongly deviate from their annual values.     

Hydrological controls on nutrient concentrations and fluxes in agricultural catchments

Like many streams draining intensively farmed parts of lowland Scotland, water quality in the Newmills burn, Aberdeenshire, is characterized by relatively high nutrient levels; mean concentrations of NO3-N and NH3-N are 6.09 mg l(-1) and 0.28 mg l(-1), respectively, whilst average PO4-P concentrations reach 0.06 mg l(-1). Nutrient concentrations vary spatially and temporally with levels being highest under arable farming during the autumn and winter. Annual fluxes from the 14.5 km2 catchment are estimated at 25.67 and 1.26 kg ha(-1) a(-1) for NO3-N and NH3-N, respectively, and 0.26 kg ha(-1) a(-1) for PO4-P. Hydrological controls exert a strong influence on both nutrient concentrations and fluxes. Over short timescales nutrient concentrations and fluxes are greatest during storm events when P04-P and NH3-N are mobilized by overland flow in riparian areas, particularly where the soils have been compacted by livestock or farm machinery. Delivery of deeper soil water in subsurface storm flow, facilitated by agricultural under-drainage, provide large contributions of NO3-N on the recession limb of hydrological events. In contrast, groundwater inputs generally have lower NO3 concentrations implying that denitrification may be a pathway of N loss in the saturated zone. Approximately 75% of the N loss for the catchment occurs during the autumn and early winter when high flows dominate the hydrological regime. The close coupling of hydrological pathways and biogeochemical processes has major implications for catchment management strategies such as Nitrate Vulnerable Zones (NVZs) as it is likely that significant groundwater stores with long residence times will continue to cause N losses before water quality improvements become apparent.     

复合流人工湿地对富营养化河水的脱氮效能研究

采用组合基质复合流人工湿地处理富营养化河水,重点分析了其脱氮效能。结果表明:人工湿地系统对富营养化河水具有较好的处理效果,出水水质基本可达到《地表水环境质量标准》(GB 3838—2002)的Ⅲ类标准,对TN、NH4+-N、NO3--N、COD、TP的去除率分别为50.00%、63.07%、55.30%、53.83%、77.27%。人工湿地系统的脱氮量主要来源于对无机氮的削减;影响脱氮效果的因素主要有HRT、温度、TN面积负荷以及进水硝态氮比例,通过对以上影响因子拟合形成的TN去除率预测模型,预测准确度较高,可用于指导实际工程的设计与调试运行。     

Bioremediation efficiency in the removal of dissolved inorganic nutrients by the red seaweed, Porphyra yezoensis, cultivated in the open sea

The bioremediation capability and efficiency of large-scale Porphyra cultivation in the removal of inorganic nitrogen and phosphorus from open sea area were studied. The study took place in 2002-2004, in a 300 ha nori farm along the Lusi coast, Qidong County, Jiangsu Province, China, where the valuable rhodophyte seaweed Porphyra yezoensis has been extensively cultivated. Nutrient concentrations were significantly reduced by the seaweed cultivation. During the non-cultivation period of P. yezoensis, the concentrations of NH4-N, NO2-N, NO3-N and PO4-P were 43-61, 1-3, 33-44 and 1-3 micromol L(-1), respectively. Within the Porphyra cultivation area, the average nutrient concentrations during the Porphyra cultivation season were 20.5, 1.1, 27.9 and 0.96 micromol L(-1) for NH4-N, NO2-N, NO3-N and PO4-P, respectively, significantly lower than in the non-cultivation season (p<0.05). Compared with the control area, Porphyra farming resulted in the reduction of NH4-N, NO2-N, NO3-N and PO4-P by 50-94%, 42-91%, 21-38% and 42-67%, respectively. Nitrogen and phosphorus contents in dry Porphyra thalli harvested from the Lusi coast averaged 6.3% and 1.0%, respectively. There were significant monthly variations in tissue nitrogen content (p<0.05) but not in tissue phosphorus content (p>0.05). The highest tissue nitrogen content, 7.65% in dry wt, was found in December and the lowest value, 4.85%, in dry wt, in April. The annual biomass production of P. yezoensis was about 800 kg dry wt ha(-1) at the Lusi Coast in 2003-2004. An average of 14708.5 kg of tissue nitrogen and 2373.5 kg of tissue phosphorus in P. yezoensis biomass were harvested annually from 300 ha of cultivation from Lusi coastal water. These results indicated that Porphyra efficiently removed excess nutrient from nearshore eutrophic coastal areas. Therefore, large-scale cultivation of P. yezoensis could alleviate eutrophication in coastal waters economically.     

Temporal evolution of organic carbon and nitrogen forms in volcanic soils under broom scrub affected by a wildfire

The evolution of total N, total oxidizable C, water-soluble NH(4)(+)-N, exchangeable NH(4)(+)-N and soluble NO(3)(-)-N was studied in Canarian volcanic soils under mountainous legume scrub affected by a wildfire by June 2003. Three systematic soil samplings in the burned area and in neighbouring non-burned sampling points were carried out 3, 7 and 12 months after the fire event. The results showed an important mobilization of N (as total N and soluble and exchangeable NH(4)(+)-N) in the soil within the burned area at short term, with a simultaneous depletion of nitrates. Later on, the water-soluble NH(4)(+)-N levels remained nearly constant along the study period in the burned area, whereas the exchangeable NH(4)(+) decreased progressively. Nitrates were found to increase inside and outside the burned area, but the increase rate was much higher for the burned samples. Total N fluctuated along the year, although its levels were generally higher in the burned area. However, such a response pattern of N to fire in this environment was insufficient to prompt the recovery of the plant cover.     

Nitrous oxide production in high-loading biological nitrogen removal process under low COD/N ratio condition

Effects of influent COD/N ratio on N2O emission from a biological nitrogen removal process with intermittent aeration, supplied with high-strength wastewater, were investigated with laboratory-scale bioreactors. Furthermore, the mechanism of N2O production in the bioreactor supplied with low COD/N ratio wastewater was studied using 15N tracer method, measuring of reduction rates in denitrification pathway, and conducting batch experiments under denitrifying condition. In steady-state operation, 20-30% of influent nitrogen was emitted as N2O in the bioreactors with influent COD/N ratio less than 3.5. A 15N tracer study showed that this N2O originated from denitrification in anoxic phase. However, N2O reduction capacity of denitrifiers was always larger than NO3(-)-N or NO2(-)-N reduction capacity. It was suggested that a high N2O emission rate under low COD/N ratio operations was mainly due to endogenous denitrification with NO2(-)-N in the later part of anoxic phase. This NO2(-)-N build-up was attributed to the difference between NO3(-)-N and NO2(-)-N reduction capacities, which was the feature observed only in low COD/N ratio operations.     

长江与黄河两大流域水生态问题剖析

对流域水生态的研究由传统单一的水质评价逐渐转变为河流生态质量的评价,基于河流健康保障的流域生态保护与发展已成为国际性趋势。长江、黄河两大流域内的生态保护与发展也是重大国家战略。以长江、黄河两大流域为研究对象,对两大流域水生态环境问题进行分区概述,并从河流湖库问题治理的关键是注重流域的整体性的角度,分析为维系两大流域水生态健康可开展的研究工作,最后将生态修复与景观设计结合考虑,提出注重景观价值的流域生态保护策略。     

Nitrogen leaching in a typical agricultural extensively cropped catchment,China: experiments and modelling

Protecting water resources from nitrogen (N) contamination is an important public-health concern and a major national environmental issue in China. Loss of N in soils due to leaching is not only one of the most important problems in agriculture farming, but is also the main factor causing N pollution in aquatic environments. The study area selected is in a typical agricultural extensively cropped land, Fuxianhu Lake catchment in Yunnan Province, China. Three sets of soil columns laboratory experiments were conducted to investigate the migration dynamics and leaching loss of N under different artificial rainfall intensities. One groundwater observation well in agricultural extensively cropped land was built to investigate the groundwater pollution caused by agriculture N loss. Based on the laboratory experiment and field monitoring results, the migration dynamics of ammonia-nitrogen (NH₄-N) and nitrate-nitrogen (NO₃-N) were analysed in detail. The LEACHMN model was used to test against the laboratory and field data to evaluate the drainage water and N leaching loss from the soil. The results indicate that the LEACHMN model is useful to carry out a numerical simulation of the water and N transport both in a laboratory experiment and in field monitoring. The findings of this paper help to demonstrate the distribution and migration of N in agricultural lands, as well as to explore the mechanism of groundwater contamination resulting from agricultural activities. The work presented in this paper is also believed to be useful in formulating management strategies for an extensively cropped catchment to reduce diffusive pollution from agricultural activities.     

Trends in stream water quality in Environmental Change Network upland catchments: the first 5 years

Hydrochemical data from catchment streams at three Environmental Change Network (ECN) upland catchments in north-east Scotland, south-east Scotland and northern England have been subjected to statistical analysis to separate the components due to long-term trend, season and flow. The relative variances due to each are presented for pH, Ca, SO4-S, NO3-N, DOC and Cl. Long-term trends have been identified with increases in concentration for NO3-N and DOC, decreases in SO4-S concentrations, along with short-term seasonal fluctuations. Application of this trend technique has allowed the detection of changes and contributed to an improved understanding of catchment behaviour.     

Nitrogen in river basins: sources, retention in the surface waters and peatlands, and fluxes to estuaries in Finland

Nitrogen export from diffuse and point sources and its retention in the major river basins of Finland is quantified and discussed. The estimated total export from river-basins in Finland was 119,000 tonnes N a(-1) for the period 1993 to 1998 based on N export from different land use types defined in a GIS-based assessment model, incorporated with estimates of N inputs from atmospheric deposition and point sources. Agriculture contributes 38% of the total export, varying in the range 35-85% in the south-western basins and 0-25% in the northern basins. This estimate of N export from agriculture was based on regional N balances together with data from small agricultural research catchments. Forestry contributes on average 9%, with increasing dominance towards eastern and northern parts of the country: from 2% to 15% in the southern-mid-western Finland basins to 10-30% in the large northern basins. 'Background' N export from forests on both mineral and organic soils contributes 27% on average; in the northern basins it may contribute from 40% up to 90% of the total load. The estimate was calculated based on practically all data available from 42 small, experimental catchments in Finland. Of the total N input to Finnish river-systems, 0% to 68% was retained in surface waters and/or peatlands, with a mean retention of 22%. The highest retention of N (36-61%) was observed in the basins with the highest lake percentages. The lowest retention (0-10%) of N was in the coastal basins with practically no lakes. In the national N mass balance, 38,000 tonnes N a(-1) (32%) was estimated as lake retention and 4,000 tonnes N a(-1) (3%) as retention in peatlands. On the basis of mass balances and sensitivity analysis, retention was in most cases estimated to be in the range of 7.5-12.5 kg ha(-1)a(-1) in lakes and 0-1.5 kg ha(-1)a(-1) in peatlands. The model results were tested using the split-sample technique and uncertainty estimates for different data sources are provided and discussed.     

Organic and minerogenic acidity in Finnish rivers in relation to land use and deposition

The role of organic and minerogenic acidity in controlling pH levels in Finnish rivers was studied by measuring total organic carbon (TOC) and non-marine sulphate (*SO(4)) concentrations in river water of the main river basins and their sub-basins. The basins are located along a latitudinal gradient (60 degrees N to 69 degrees N) and cover 297,322 km(2), 88% of the total area of Finland. The basins are predominately covered by coniferous forests and peatlands, and are located in areas with low sulphate deposition (80-430 mg S m(-2) a(-1)). The proportion of the basin covered by forests on mineral soils ranges from 29 to 64% and the proportion of peatlands from 3 to 60%. The percentage of peatland is highest in northern Finland (28-60%), whereas the proportion of forests on mineral soils increases towards the south. The majority of the agricultural land is located in southern and western Finland. *SO(4) concentrations were positively correlated with the proportion of agricultural land in the basin. Moreover, the percentage of peatlands had a positive correlation with the concentrations of TOC and organic anion. High peatland proportion and high TOC and organic anion concentrations decreased pH values in the river water, whereas no correlation between *SO(4) concentrations and pH was observed. The average organic anion concentration exceeded the average *SO(4) concentration in river water in 17 basins out of the 86 studied basins. The organic anion-dominated areas were situated in northern basins, reflecting the high extent of peatlands in these areas. *SO(4) dominated in southern Finland and in western coastal areas, where the extent of agricultural land, acid sulphate soils and the deposition of sulphate is highest.     

大蒋河排水区排洪方案设计探析

近年来城市洪涝愈发频繁,造成了大量的人员伤亡和财物损失,有必要在城市规划和设计时做好排洪排水设计。本文结合连云港大蒋河排水区的排水设计项目,针对当前的城市发展需求,对原有的防洪和排水规划进行分析和调整,通过在中河入南河口以上建一小型节制闸,可以防止南河洪水对中河排涝产生不利影响。     

The nitrogen composition of streams in upland Scotland: some regional and seasonal differences

The nitrogen (N) composition of streams draining four upland regions of Scotland was compared in samples collected monthly between April 1997 and April 1998. Stream samples were analysed for total N (TN), particulate N (PN), nitrate (NO3), ammonium (NH4), dissolved organic N (DON) and dissolved organic carbon (DOC). Concentrations of TN were small, generally less than 1 mg l(-1) , dominated by dissolved forms of N, and varied significantly between upland regions. Nitrate accounted for most of the variability in TN; largest concentrations were observed in the Southern Uplands and smallest concentrations were observed in the Highlands. Nitrate concentrations were positively correlated with the percentage cover of improved grasslands and brown forest soils and negatively correlated with the percentage cover of peat. Concentrations of DON also varied between regions, but to a lesser extent than those of NO3. Largest concentrations occurred in SW Scotland and smallest concentrations in the Cairngorms. Although a significant positive correlation between DON and DOC was observed, stream water DON content was not related to the percentage cover of peat in the catchment, as was the case for DOC. The average DOC:DON ratio was narrower for streams in the Southern Uplands than for those in the Cairngorms and Highlands. Nitrate and DON displayed contrasting seasonal trends; NO3 concentrations were larger in the winter while DON concentrations were larger in the summer. Only a small proportion, < 8% and < 7%, of TN was PN and NH4, respectively, the majority of N was present as either NO3 or DON. Nitrate was the dominant fraction (58-65%) in all regions except the Highlands where DON accounted for 57% of TN. However, the relative importance of the DON component increased in the summer in all regions. This study has demonstrated that the DON fraction is an important component of the total N transported by streams from upland catchments in Scotland. Thus, assessments of anthropogenic impacts on N losses from upland ecosystems need to consider not only the dissolved inorganic species but also DON.     

Modelling instream nitrogen variability in the Dee catchment, NE Scotland

The Integrated Nitrogen in CAtchments model (INCA) was applied to the River Dee, Aberdeenshire, NE Scotland. To a first approximation the model was able to simulate the annual mean streamwater NO3-N concentrations observed along the length of the main channel. This provided the basis for using INCA to subsequently explore the effects of N deposition and land use management on streamwater NO3-N concentrations and loads. On an annual timescale, the model predictions suggest that NO3-N concentrations will decrease by 5% following a 20% reduction in fertiliser application. Furthermore, model results also suggest that a 50% increase in N deposition will cause a 15% increase in the streamwater NO3-N concentrations. The utility of INCA as a tool for catchment management is discussed, current limitations are highlighted and possible improvements are suggested.     

Atmospheric deposition of nitrogen at five subtropical forested sites in South China

Elevated concentrations of reactive nitrogen (N) in precipitation have been reported for many cities in China. Due to increased use of fossil fuels and expansion in agriculture, further increases in deposition of ammonia (NHx) and reactive N oxides (NOy) are predicted. Increased deposition of reactive N is likely to affect N dynamics and N runoff in forest ecosystems. Yet, in China little work has been done to quantify the levels of atmospheric N deposition in such systems. Here, we assess the deposition of inorganic N (ammonium, NH4+ and nitrate, NO3-) for five subtropical forest ecosystems in remote and urban areas of South China. Annual volume-weighted concentrations in bulk precipitation range from 0.18 to 1.55 mg NH4+ -N L(-1) and from 0.12 to 0.74 mg NO3- -N L(-1). These values are large and several times greater than those reported for remote sites of the world. The fluxes of total inorganic N (TIN) in wet-only deposition range from 0.8 to 2.3 g N m(-2) yr(-1), with NH4+ -N contributing 54% to 77%. Both the tree canopy and the ground vegetation layer are important in determining the net N flux reaching the forest floor, but the net effect varies from site to site. At TieShanPing (TSP), close to Chongqing city, and at CaiJiaTang (CJT), near Shaoshan (Hunan province), the canopy represents a net source of N, probably due to dry deposition. At the other three sites (LiuChongGuan (LCG), LeiGongShan (LGS), both in Guizhou province, and LiuXiHe (LXH) in Guangdong), a net loss of reactive N from precipitation water occurs in the canopy, probably due to uptake processes. The total annual atmospheric TIN load is estimated to range from at least 0.8 g N m(-2) yr(-1) to 4.0 g N m(-2) yr(-1), with a considerable contribution from dry deposition. Concentrations and fluxes of inorganic N in tree canopy throughfall are greater than those in North America. Also the contribution of NH4+ -N to TIN fluxes in throughfall (40% to 70%) is greater than in North America. Our sites have N deposition levels and NH4+ -N contributions similar to those found in Northwest and central Europe. The TIN loads at TSP and CJT far exceed 2.5 g N m(-2) yr(-1), which is the N deposition load above which NO3- leaching is expected in temperate and boreal forests.     

叶尔羌河流域水文分析与桥梁工程设置

分析了叶尔羌河的水系特征、降水洪水特点、主流及各支流的流域特征,结合315国道的工程设置,对喀什和田铁路在叶尔羌河流域的跨河工程进行了合理布设,为该流域同类跨河工程设计提供了科学指导。     

Characterisation of diffuse pollutions from forested watersheds in Japan during storm events - its association with rainfall and watershed features

Forest areas have been identified as important sources of nonpoint pollution in Japan. The managers must estimate stormwater quality and quantities from forested watersheds to develop effective management strategies. Therefore, stormwater runoff loads and concentrations of 10 constituents (total suspended solids, dissolved organic carbon, PO(4)-P, dissolved total phosphorus, total phosphorus, NH(4)-N, NO(2)-N, NO(3)-N, dissolved total nitrogen, and total nitrogen) for 72 events across five regions (Aichi, Kochi, Mie, Nagano, and Tokyo) were characterised. Most loads were significantly and positively correlated with stormwater variables (total event rainfall, event duration, and rainfall intensity), but most discharge-weighted event concentrations (DWECs) showed negative correlations with rainfall intensity. Mean water quality concentration during baseflow was correlated significantly with storm concentrations (r=0.41-0.77). Although all pollutant load equations showed high coefficients of determination (R(2)=0.55-0.80), no models predicted well pollutant concentrations, except those for the three N constituents (R(2)=0.59-0.67). Linear regressions to estimate stormwater concentrations and loads were greatly improved by regional grouping. The lower prediction capability of the concentration models for Mie, compared with the other four regions, indicated that other watershed or storm characteristics should be included in the prediction models. Significant differences among regions were found more frequently in concentrations than in loads for all constituents. Since baseflow conditions implied available pollutant sources for stormwater, the similar spatial characteristics of pollutant concentrations between baseflow and stormflow conditions were an important control for stormwater quality.     

南四湖流域平原区浅层地下水氮污染特征

本文在对浅层地下水"三氮"迁移转化原理和"三氮"污染控制因素进行分析的基础上,阐明了南四湖流域平原区浅层地下水"三氮"含量分布规律,并分析了形成原因。从区域分布看,NO3-N含量呈现湖东山前冲洪积平原区高于湖西冲积湖积平原区的特点;NO2-N含量虽然较低,但含量大于0.01mg/L的地段主要分布于南四湖沿岸和山前冲洪积平原部分地区;NH4-N绝大部分地区未检出。浅层地下水"三氮"含量的上述分布规律与非饱和带的岩性组成、地下水位埋深、农田灌溉方式、土壤含水量等密切相关。最后针对研究区浅层地下水氮污染的特点提出了"三氮"污染防治对策。     

Short- and medium-term effects of three fire fighting chemicals on the properties of a burnt soil

The impact of three fire fighting chemicals (FFC) on 11 chemical soil properties and on soil recovery (0-2 cm depth) was evaluated 1, 30, 90 and 365 days after a prescribed fire. Five treatments were considered: unburnt soil (US) and burnt soil with 2 l m(-2) of water alone (BS) or mixed with the foaming agent Auxquímica RFC-88 at 1% (BS+Fo), Firesorb at 1.5% (BS+Fi) and FR Cross ammonium polyphosphate at 20% (BS+Ap). At t=1 day, soil pH increases in the order US相似文献