共查询到20条相似文献,搜索用时 96 毫秒
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采用微波等离子体化学气相沉积法,以Ar/H2/CH4为气源,通过改变气源流量比例和功率,探究生长低粒径纳米金刚石的最佳条件。利用X射线衍射仪和扫描电子显微镜分别对制备出的薄膜的晶粒尺寸和表面形貌进行了表征,并采用拉曼散射光谱仪对薄膜的质量及残余应力进行了分析。结果表明:氩氢浓度比例相对于功率和甲烷浓度等因素对金刚石粒径影响较大;随着氩氢浓度比例增大,金刚石粒径呈减小趋势;金刚石相对于石墨相的含量先减小后增大,且由拉曼G峰引起的拉应力不断增大;膜表面的团聚体尺寸逐渐减小,平整度随之提升。 相似文献
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纳米粒子粒径的测量研究 总被引:2,自引:0,他引:2
采用X射线衍射法(谢乐法)与透射电子显微镜法(TEM法)对纳米粒子粒径的测量进行了研究。结果表明,该两种方法都可用于纳米粒子粒径的的测量与表征,且两者的测量结果相当一致;纳米粒子实际平均粒径似应在两种方法测定结果之间。 相似文献
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激光蒸凝法制备氧化铜纳米粒子 总被引:6,自引:0,他引:6
以150W CW CO2激光器为光源,Cu(AC)2·H2O为靶材,采用激光蒸凝法制备出了氧化铜纳米粒子.初步研究了反应参数对纳米粒子性能的影响,并用X射线衍射、电子衍射、透射电镜等技术对纳米粒子的性能进行了表征,同时对纳米粒子的形成机理进行了初步的探讨.实验结果表明;激光功率密度、反应压力、载气种类及流量等工艺参数对产品的粒度、晶型等性能均有影响.在惰性气氛下,产物主要是Cu和Cu2O,粒径为10~30nm;在氧气气氛下,产物主要是Cu、Cu2O和CuO的混合物,粒径为10~50nm. 相似文献
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The optical and electrical properties of semiconductor nanoparticles are strongly dependent on their size. A flexible control of the size of the nanoparticles is of interest for tuning their properties for different applications. Here we use a coupled method to control the size of CdS nanoparticles. The method involves the photochemical growth of CdS nanoparticles together with the use of a capping agent as an inhibiting factor. CdS nanoparticles were formed through a photoinduced reaction of CdSO(4) and Na(2)S(2)O(3) in an aqueous solution. Mercaptoethanol (C(2)H(6)OS) was used as the capping agent, and we investigated the effect of illumination time, illumination intensity and the concentration of capping agent on the nanoparticle size. Transmission electron microscopy (TEM) shows crystalline nanoparticles with relatively low dispersion. Optical absorption spectroscopy was mainly used to measure the band gap and size of the nanoparticles. Increasing the illumination time or illumination intensity increases the nanoparticle size, while higher capping agent concentration leads to smaller nanoparticle size. A band gap range of 2.75-3.4?eV was possible with our experimental conditions, corresponding to a 3.2-6.0?nm size range. 相似文献
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采用多元醇法在150~190℃合成了CoNi合金纳米粒子,利用SEM-EDX,XRD和VSM对所制备的CoNi纳米粒子形貌、成分、结构以及磁性能进行了研究,并进一步探讨了形核剂K2PtCl4对CoNi纳米粒子形貌及磁性能的影响。结果表明,在180℃用多元醇法制备的Co40Ni60(inat%)纳米粒子为FCC结构,Co2+要易于Ni2+被还原,导致最初10min内合成的CoNi纳米粒子中含有约78%(原子分数)Co,表现为高饱和磁化强度和高矫顽力,随着反应时间的延长,CoNi纳米粒子的Co含量、饱和磁化强度及矫顽力逐步下降。在150~190℃范围内,随着反应温度的提高,Ni2+的被还原能力增强,高温下合成的CoNi纳米粒子具有较低的饱和磁化强度和较小的矫顽力。形核剂K2PtCl4的加入,并不影响CoNi合金纳米粒子的成分和晶体结构。但是,随着形核剂浓度的增加,CoNi纳米粒子平均直径明显减小,其矫顽力有所增大。通过设计形核剂的浓度,CoNi纳米粒子的直径可以在96~580nm范围内任意控制。 相似文献
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YAN DONG YANJIAO CHANG QIAN WANG JIN TONG JIANG ZHOU 《Bulletin of Materials Science》2016,39(1):35-39
The present work investigated the influence of surfactants on size and structure of amylose nanoparticles (ANPs) prepared through precipitation. ANPs were fabricated using absolute ethanol containing surfactants (Tween80, Span80 and mixtures of Tween80 and Span80 with ratios of 25/75, 50/50 and 75/25, respectively) as non-solvents. The obtained ANPs were characterized using dynamic light scattering (DLS), scanning electron microscopy and X-ray diffraction. The results showed that surfactant type, concentration and hydrophilic–lipophilic balance (HLB) value had great impact on size of precipitated ANPs. The smallest ANPs with mean size of 155 nm determined by DLS were obtained by using 0.5% (in proportion of the amylose solution volume) of Tween80/Span80 mixture (HLB = 12.33). The precipitated ANPs possessed the V-type crystalline structure no matter whether using the surfactants or not. 相似文献
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当前金属纳米粒子主要采用物理和化学方法合成,但微生物也能合成金属纳米粒子,与常规方法相比,微生物合成金属纳米粒子不仅可大量减少还原剂的用量和降低能源成本,而且不污染环境。综述了国内外使用微生物合成金属纳米粒子的研究进展。 相似文献
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C. Venkataraju G. Satishkumar K. Sivakumar 《Journal of Materials Science: Materials in Electronics》2012,23(6):1163-1168
Nanoparticles of MnBixFe2−xO4(x = 0.0, 0.02, 0.04, 0.06) have been synthesized by a chemical co-precipitation method. X-ray diffraction analysis (XRD)
reveals that bismuth exits in its Bi3+ and Bi5+ state. It was also observed that bismuth substitution enhances the grain growth and density. The dielectric constant (ε′)
and the loss tangent (tan δ) increases with increase in bismuth content. Resistivity (ρ) and maximum magnetization (M) was
found to decrease with increasing bismuth content. 相似文献
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《Materials Letters》2007,61(19-20):4094-4096
ZnO nanoparticles have been synthesized by a low-temperature colloidal chemistry method using ethylene glycol as the reaction medium. Crystalline ZnO nanoparticles were formed at a temperature as low as 150 °C. The crystallite size of the ZnO nanoparticles ranged from 8 to 20 nm. The synthesized ZnO nanoparticles exhibited size-dependent photoluminescence. Photoluminescence of the ZnO nanoparticles depended largely on the post-annealing temperature. Both DL and UV emissions were suppressed at a lower post-annealing temperature of 300 °C; however they were recovered at a higher annealing temperature of 900 °C. 相似文献
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本文论述了在常温常压、无任何催化剂的条件下,通过电子束辐照制备纳米钴。利用X射线衍射仪(XRD)、透射电子显微镜(TEM)和差热分析仪(DSC)分别分析了纳米钴的结构、行貌、大小和熔点。利用激光散射粒度分布仪(LSPSDA)观察了纳米钴的粒度分布,并用样品振荡磁力计(VSM)分析了纳米钴的磁性。结果表明实验所制得的纳米钴粒子平均粒径32nm,粒度分布窄,熔点显著降低。最后,探讨了纳米钴的形成机理。 相似文献
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Fauziatul Fajaroh Heru Setyawan Adrian Nur I. Wuled Lenggoro 《Advanced Powder Technology》2013,24(2):507-511
Magnetite nanoparticles have been prepared by electrooxidation of iron in water. Surface modifications have been conducted by coating the nanoparticles with silica by a one-step synthesis in dilute sodium silicate solution. The mean size of particles was approximately 10–30 nm for the uncoated particles and 9–12 nm for the coated particles. The results obtained from thermal gravimetric/differential thermal analysis (TG/DTA) revealed that the silica layer formed by the electrochemical method was stable and could serve as a protective layer. Annealing the nanoparticles at 550 °C for 30 min converts magnetite into maghemite for the silica-coated particles, and it further converts the uncoated particles into hematite. The conversions cause the saturation magnetization to decrease for all samples. 相似文献