共查询到20条相似文献,搜索用时 15 毫秒
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FENG Tao CHEN Liangshi KE Wei Corrosion Science Laboratory Institute of Corrosion Protection of Metals Academia Sinica Shenyang China 《金属学报(英文版)》1991,4(9):168-173
The environment-sensitive fracture behaviour of 0Cr18Ni9Ti austenitic stainless steel inboiling 42% MgCl_2 under the specific load of low frequency and high mean stress was inves-tigated from the relations and differences of crack growth rates and fractographs betweenstress corrosion fatigue and stress corrosion cracking.The interaction between stress corro-sion cracking and corrosion fatigue was also studied from fracture characteristics with empha-sis on the effects of applied potential on the interaction. 相似文献
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本文作者研究了不同冶炼条件和不同奥氏体化温度热处理的40CrNiMoA钢试样在蒸馏水中的应力腐蚀和腐蚀疲劳行为,测定了试样的原始奥氏体晶粒度,对晶界杂质偏聚情况进行了Auger电子能谱分析,对应力腐蚀和腐蚀疲劳断裂的初始阶段进行了扫描电镜断口观察。根据实验结果,作者认为高强度钢40CrNiMoA在蒸馏水中的应力腐蚀和腐蚀疲劳行为主要与原始奥氏体晶粒度有关。晶粒大小与裂纹前端塑性区尺寸两者的相对比较决定了断裂方式,从而决定了材料的应力腐蚀和腐蚀疲劳萌生和扩展的难易程度。 相似文献
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郑文龙 《中国腐蚀与防护学报》1987,7(1):41-49
本文从两个实际人造水晶釜开裂形态观察及产物分析入手,研究丁CrNiMo低合金高强度钢在NaOH,水溶液中SCC及CF行为,提出人造水晶釜开裂的类型、机理及提高抗断裂能力的途径。试验结果还表明对CrNiMo低合金钢-NaOH水溶液体系,CF过程中的SCC行为可以降低CF裂纹扩展速率。 相似文献
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应变速率对管线钢近中性pH值环境敏感开裂的影响 总被引:5,自引:0,他引:5
以X-70管线钢近中性pH值溶液(NS4和实际土壤溶液)为研究对象,研究了恒载荷、慢应变速率拉伸(SSRT) 和循环蓑荷等不同条件下的环境开裂行为.结果表明,在该体系中局部应变速率是联系各种不同断裂过程的纽带,决定着断裂的模式.当该局部应变速率低于发生应力腐蚀开裂(SCC)敏感局部应变速率的上限(即5×10-5 s-1)时, SCC才能够发生;在循环载荷作用下,当该局部应变速率高于此上限时,将发生力学因素起主导作用的腐蚀疲劳(CF)开裂;该局部应变速率继续升高时,将发生机械断裂.对X-70管线钢在近中性pH值的环境开裂,不论开裂过程是溶解或(和)氨的作用占主导,均受局部应变速率控制.在通常遇到的现场服役条件下, X-70管线钢在近中性pH值溶液中的开裂模式是SCC,不是CF,应称之为“近中性pH值应变促进腐蚀开裂”,实质上这是一种由局部应变速率决定的环境开裂行为. 相似文献
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LU Minxu LIU Xiaokun WANG Jianjun FU Xiangjiong ZHENG Xiulin Northwestern Polytechnical University Xi''''an China Lecturer Department No..Northwestern Polytechnical University Xi''''an China 《金属学报(英文版)》1992,5(9):183-189
Comparative investigations were carried out of the effect of heat treatment regimes Jor steelGC-4(40CrMnSiMoVA)on its crack propagating rates,from corrosion fatigue,(da/dN)_(CF),or stress corrosion cracking,(da/dt)_(SCC),in media with various constituentsand pH values.Both(da/dN)_(CF) and(da/dt)_(SCC) accelerate with the increase of yield stressof the steel,yet the former is far less than the later.In comparison with media,the(da/dt)_(SCC) in distilled water is slightly greater than that in 3.5% NaCl solution,and the(da/dN)_(CF) in distilled water is far less than that in 3.5% NaCl solution.With the pH valueincreasing in 3.5% NaCl solution,the(da/dN)_(CF) lowers down and the(da/dt)_(SCC) speedsup.An explanation was also proposed with concept of the cyclic hardening and softening atcrack tip,as well as the crack closure and occluded cell effect. 相似文献
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本工作研究了应力比和载荷频率对高强度低碳硅锰钢在蒸馏水及3.5%NaCl溶液中腐蚀疲劳断口形貌的影响。试验结果表明,在介质影响疲劳裂纹扩展行为的范围内的断口上,随着应力比的增加或者载荷频率的减小,应力腐蚀开裂的断口形貌所占比例逐渐增加。根据多视域的观测结果,建立起了腐蚀疲劳断裂机制示意图。 相似文献
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H. Yanliang 《工业材料与腐蚀》2004,55(2):124-127
The corrosion failure behavior of marine steel is affected by stress, which exists in offshore structures at sea‐mud region. The sulfate reducing bacteria (SRB) in the sea‐mud made the steel more sensitive to stress corrosion cracking (SCC) and weaken the corrosion fatigue endurance. In this paper, a kind of natural sea‐mud containing SRB was collected. Both SCC tests by slow strain rate technique and corrosion fatigue tests were performed on a kind of selected steel in sea‐mud with and without SRB at corrosion and cathodic potentials. After this, the electrochemical response of static and cyclic stress of the specimen with and without cracks in sea‐mud was analyzed in order to explain the failure mechanism. Hydrogen permeation tests were also performed in the sea‐mud at corrosion and cathodic potentials. It is concluded that the effect of SRB on environment sensitive fracture maybe explained as the consequences of the acceleration of SRB on corrosion rate and hydrogen entry into the metal. 相似文献
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利用慢应变速率拉伸试验,研究2219铝合金母材及搅拌摩擦焊接头在不同腐蚀介质环境中的应力腐蚀行为.运用性能损失率指标和应力腐蚀指数评价材料的应力腐蚀敏感性.结果表明,应变速率为10-6 s-1时,2219铝合金母材和FSW接头在3.5%Na Cl介质环境中SCC敏感性小,断口由韧窝塑性区和腐蚀区组成;在剥蚀介质环境中,母材和FSW接头SCC敏感性大,断口呈冰糖状,有较深的腐蚀坑和二次裂纹,为沿晶脆性断裂.FSW接头SCC敏感性较母材大. 相似文献
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40CrNi2Si2MoVA钢的大气应力腐蚀行为 总被引:2,自引:0,他引:2
用单轴拉伸试样和预制裂纹试样研究40CrNi2Si2MoVA高强度钢在典型大气环境下的抗应力腐蚀性能.施加应力后的试样分别暴露于北京、青岛、万宁3个不同的大气试验站.研究表明:40CrNi2Si2MoVA钢的抗应力腐蚀性能取决于环境,在海洋性环境下应力腐蚀性较高.扫描电子显微镜微观分析表明裂纹起始于表面的腐蚀点,并向试样内部扩展,为沿晶开裂,有二次裂纹存在.随着应力水平的增大,二次裂纹明显增加. 相似文献
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采用慢应变速率试验(SSRT)、扫描电镜(SEM)观察研究了国产X80管线钢焊接接头在0.5mol/LNa2CO3 1mol/LNaHCO3溶液中的应力腐蚀开裂(SCC)敏感性。结果表明,拉伸试样全部断裂在焊缝或热影响区。在所研究的电位区间,拉伸试样随着外加电位正向增加,断面收缩率、断裂时间和断后伸长率增加,而断口部位的裂纹平均扩展速率减小,SCC敏感性降低。试样断口形貌在阴极电位条件下呈准解理断裂,在自腐蚀电位和阳极电位条件下,焊缝试样断口主要是韧性断裂。应力腐蚀机理可以用阳极溶解理论和氢致破裂来解释。 相似文献
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采用慢应变速率试验(SSRT)、扫描电镜(SEM)观察研究了国产X80管线钢焊接接头在 0.5 mol/L Na2CO3 1 mol/L NaHCO3 溶液中的应力腐蚀开裂(SCC)敏感性.结果表明,拉伸试样全部断裂在焊缝或热影响区.在所研究的电位区间,拉伸试样随着外加电位正向增加,断面收缩率、断裂时间和断后伸长率增加,而断口部位的裂纹平均扩展速率减小,SCC敏感性降低.试样断口形貌在阴极电位条件下呈准解理断裂,在自腐蚀电位和阳极电位条件下,焊缝试样断口主要是韧性断裂.应力腐蚀机理可以用阳极溶解理论和氢致破裂来解释. 相似文献
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Prestressing steels occasionally fail by a process named “stress corrosion cracking”. This process has not been fully elucidated and several theories exists in order to explain the cases in which real structures have collapsed. This paper briefly mentions the different theories and identifies the progress in understanding whether it is necessary to use a testing method, which is able to separate the different steps and mechanisms contributing to the failures.This paper presents the methodology used for inducing controlled localized attack to study the susceptibility of the high strength steels resistance to stress corrosion cracking (SCC). The method is designed to study the growth of cracks initiated from a mechanical notch; the crack is not produced by fatigue.It consists of several stages: coating of the bar with epoxy resin, generation of a small notch, constant load and controlled potential test in the media, mechanical test in air and fractographic study. It allows us to calculate the crack propagation rate and the fracture toughness in the same test.Finally, it has been possible to apply the surface mobility mechanism (SMM) in order to identify the SCC mechanism that operates. 相似文献
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目的 对比研究原始、固溶和敏化态的304和321奥氏体不锈钢在模拟加氢催化氯化铵环境中的应力腐蚀(SCC)行为及机理。方法 将304和321奥氏体不锈钢经过热处理制备成固溶和敏化态试样,采用U形弯试样在模拟加氢催化氯化铵环境中浸泡的应力腐蚀试验方法对其进行研究,通过观察U形弯弧顶的腐蚀形貌和开裂时间,并结合腐蚀及裂纹的SEM照片和电化学测试结果进行分析。结果 原始和固溶状态304不锈钢U形弯试样在氯化铵溶液环境中开裂时间为25 d左右,断口形貌分别为穿晶断口和沿晶断口;敏化态试样18 d后发生开裂,断口形貌为穿晶和沿晶的混合断口。原始和固溶态321不锈钢U形弯试样在该环境中经过39 d均无应力腐蚀裂纹;敏化试样经30 d后产生宏观开裂。电化学测试结果显示,不同热处理态的304不锈钢在氯化铵溶液中均具有明显的点蚀敏感性,321不锈钢在该环境中耐点蚀和应力腐蚀的能力优于304不锈钢。结论 不同状态的304不锈钢在高温氯化铵环境中具有较强的应力腐蚀倾向,特别是敏化态试样;321不锈钢在该环境中的应力腐蚀敏感性相对较小,但敏化处理显著增加了其沿晶应力腐蚀倾向,而固溶态试样具有明显的沿晶腐蚀特征。 相似文献
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7050铝合金晶界偏析与应力腐蚀,腐蚀疲劳行为的研究 总被引:18,自引:0,他引:18
研究了不同时效状态的7050铝合金晶界偏析与应力腐蚀开裂及湿空气环境下疲劳裂纹扩展的关系,并采用修正的化学方法计算了晶界偏析对断裂应力的影响。结果表明:随着时效程度的增加,晶界上Mg偏析浓度减小,捕获H的能力减弱,晶界断裂应力的百分数随之下降,因而合金的抗应力腐蚀和腐蚀疲劳性能提高。 相似文献
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INTERPHASESTRESSCORROSIONCRACKINGOFALLOYTi-24Al-11NbINMETHANOLSOLUTION¥ZHANGYue;CHUWuyang;XIAOJimei(DepartmentofMaterialsPhys... 相似文献
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微弧氧化处理对AA7075铝合金在3.5%NaCl溶液中局部腐蚀行为的影响(英文) 总被引:2,自引:0,他引:2
A.VENUGOPAL Rajiv PANDA Sushant MANWATKAR K.SREEKUMAR L.RAMA KRISHNA G.SUNDARARAJAN 《中国有色金属学会会刊》2012,22(3):700-710
采用微弧氧化法在AA7075铝合金上生成氧化铝膜层,并对氧化铝膜层在3.5%NaCl溶液中的腐蚀和应力腐蚀开裂行为进行测试。采用电化学阻抗谱来研究膜层随浸泡时间的变化,构建合适的等效电路图。对常载荷应力腐蚀开裂测试后的试样进行金相观察。结果表明,微弧氧化膜可以有效避免富Cu、Fe金属间化合物相引发的严重局部腐蚀而导致的合金过早失效。 相似文献
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Stress corrosion cracking (SCC) of α-brass in ammonia solution was studied under mode III loading. The results showed that SCC occurred on the principal stress planes where shear stresses are zero. No SCC occurred on the maximum shear stress plane. Ammonia concentration affected fracture behaviour. When the concentration was low, many cracks with spacing of 10–150 μm were found on 45 ° planes, i.e., the principal stress planes. When the concentration was high, the cracks on 45 ° planes were not clearly visible because of serious general corrosion. 相似文献