Leakage currents over the Surface of CdHgTe-based photodiodes

The leakage current I _p over the surface of Cd_xHg_1−x Te-based photodiodes that have a cutoff wavelength of the photosensitivity spectrum of λ=9.8–11.6 μm and are fabricated by implanting Zn⁺⁺ ions into the p-type solid solution is investigated. The surface character of the I _p current is indicated by a coordinate shift of the peak in the sensitivity profile of n ⁺-p junctions, which is measured in a scanning mode by the beam of a CO₂ laser with a wavelength of 10.6 μm, with an increase in voltage U across the photodiode and the shift of spectral characteristics to shorter wavelengths with increasing U. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 38, No. 7, 2004, pp. 890–895. Original Russian Text Copyright ? 2004 by Biryulin, Turinov, Yakimov.     

Gain and internal losses in InGaAsSb/InAsSbP double-heterostructure lasers

We report on a study characterizing internal losses and the gain in InGaAsSb/InAsSbP diode-heterostructure lasers emitting in the mid-infrared (3–4 μm). Numerical simulations of the current dependence of the intensity of spontaneous emission above the laser threshold and of the differential quantum efficiency allowed us to determine the intraband absorption k ₀ ≈5.6×10⁻¹⁶ cm². The cavity-length dependence of the threshold current is used to estimate the internal losses at zero injection current α ₀≈5 cm⁻¹. Calculations of the internal losses at laser threshold showed that they increase more than fourfold when the cavity length is decreased from 500 μm to 100 μm. The temperature dependence of the differential quantum efficiency is explained on the assumption that intraband absorption with hole transitions into a split-off band occurs. It is shown that the maximum operating temperature of “short-cavity” lasers is determined by the intraband absorption rather than by Auger recombination. The internal losses are shown to have a linear current dependence. The separation of the quasi-Fermi levels as a function of current demonstrates an absence of voltage saturation of the p-n junction above threshold. Fiz. Tekh. Poluprovodn. 33, 759–763 (June 1999)     

Luminescence and electrical properties of InGaN/AlGaN/GaN light emitting diodes with multiple quantum wells

Luminescence spectra of light-emitting diodes based on InGaN/AlGaN/GaN heterostructures with multiple quantum wells are studied for currents in the range J=0.15 μA-150 mA. The comparatively high quantum efficiency for low J(J _max=0.5–1 mA) is a consequence of a low probability for the nonradiative tunnel current. The current-voltage characteristics J(V) are studied for J=10⁻¹²–10⁻¹ A; they are approximated by the function V=ϕk+mkT· [1n(J/J ₀)+(J/J ₁)^0.5] + J · R _s. The portion of V∞(J/J ₁)^0.5 and measurements of the dynamic capacitance indicate that i-layers adjacent to the active layer play an important role. The spectra are described by a model with a two-dimensional density of states with exponential tails in multiple quantum wells. The rise in T with increasing J is determined from the short-wavelength decay of the spectrum of the blue diodes: T=360–370 K for J=80–100 mA. An emission band is observed at 2.7–2.8 eV from green diodes at high J; this band may be explained by phase separation with different amounts of In in the InGaN. Fiz. Tekh. Poluprovodn. 33, 445–450 (April 1999)     

Manifestation of percolation conductivity of short-channel field-effect transistors in the spectrum of shallow interface states

The effective density of shallow interface states N _ss is investigated in the temperature range T=77–300 K using the field-effect method in short-channel (0.5–5 μm) Si-MNOS and GaAs-based FET’s with high (greater than 10¹² cm⁻²) concentrations of built-in charge in the subgate insulator. A peculiarity of the density of electronic states N _ss was found having the form of a peak, which manifests itself more distinctly at lower temperatures, higher concentrations of built-in charge, and shorter gates. The peak was observed at the same values of the channel conductance G∼q ²/h, regardless of variations in the above-enumerated parameters, the thickness of the sub-gate insulator, and the channel-length-to-width ratio. This means that the energy depth of the peak (∼40–120 meV) varies in proportion to T, which contradicts the current understanding of the interface states caused by both the fluctuation potential (FP) and surface defects or traps. The results are interpreted within the framework of percolation theory applied to the conductivity of strongly disordered systems. The N _ss peculiarity is associated with a transition from the conductivity of a two-dimensional effective solid, which occurs when the fluctuation potential is strongly screened by surface electrons, to conductivity via a quasi-one-dimensional potential trough organized by local regions with reduced surface potential under conditions of a strong fluctuation potential. Fiz. Tekh. Poluprovodn. 31, 1460–1467 (December 1997)     

Energy spectrum of acceptors in the semimagnetic semiconductors p-Hg1−x MnxTe in the spin-glass region

The far-IR transmission and photoconductivity in the semimagnetic alloys p-Hg_1−x Mn_xTe (x=0.20–0.22) at temperatures 2–7 K were investigated at fixed frequencies of optically pumped molecular lasers in the region 49–311 μm. We report the observation of photoexcitation of acceptors from the ground into excited states under conditions when the direct interaction of the magnetic moments of the manganese ions becomes substantial and results in the formation of a spin-glass phase. It was found that the internal field produced by the spontaneous and external polarizations of the magnetic moments of the Mn²⁺ ions in the spin-glass temperature range influences the energy spectrum of acceptors in a magnetic field. Fiz. Tekh. Poluprovodn. 32, 450–452 (April 1998)     

Transformation of luminescence centers in CVD ZnS films subjected to a high hydrostatic pressure

The cathodoluminescence and optical-transmission spectra of ZnS were analyzed to study the effect of a high hydrostatic gas pressure (1500 atm at 1000°C) on the equilibrium between intrinsic point defects in zinc sulfide grown by chemical vapor deposition (CVD) with an excess of zinc. The cathodoluminescence spectra were measured at 80–300 K and excitation levels of 10²² and 10²⁶ cm⁻³ s⁻¹; the optical-transmission spectra were measured at 300 K in the wavelength range 4–12 μm. It is found that exposure to a high hydrostatic gas pressure transforms the self-activated emission in the cathodoluminescence spectrum: (i) a new short-wave-length band appears at 415 nm with its intensity increasing by one to three orders of magnitude; and (ii) the long-wavelength band that peaks at 445 nm and is observed in as-grown crystals becomes quenched. Simultaneously, the cathodoluminescence band peaked at 850 nm and related to vacancies V _S is no longer observed after high-pressure treatment. These effects are attributed to a partial escape of excess zinc (Zn_i) from crystals and additional incorporation of oxygen into lattice sites (O_S). A doublet band I ₁, which peaked at ∼331–332 nm at 80 K and at ∼342–343 nm at 300 K and is related to excitons bound to acceptor levels of oxygen centers, was observed. This band is found to be dominant in the cathodoluminescence spectrum at an excitation level of 10²⁶ cm⁻³ s⁻¹. Traces of the ZnO phase are apparent after the high-pressure treatment in both the cathodolumi-nescence spectra (the bands at 730 and 370 nm) and the transmission spectra (narrow bands in the region of 6–7 μm). __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 38, No. 1, 2004, pp. 39–43. Original Russian Text Copyright ? 2004 by Morozova, Karetnikov, Plotnichenko, Gavrishchuk, Yashina, Ikonnikov.     

Silicon carbide detectors of high-energy particles

The results of studying 4H-SiC p ⁺-n junctions ion-implanted with aluminum as detectors of high-energy particles are reported. The junctions were formed in SiC epitaxial films grown by chemical vapor deposition. The concentration of uncompensated donors was (3–5)×10¹⁵ cm⁻³, and the charge-carrier diffusion length was L _p=2.5 μm. The detectors were irradiated with 4.8–5.5-MeV alpha particles at 20°C. The efficiency of collection of the induced charge was as high as 0.35. The possibilities of operating SiC detectors at elevated temperatures (∼500°C) are analyzed. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 36, No. 6, 2002, pp. 750–753. Original Russian Text Copyright ? 2002 by Violina, Kalinina, Kholujanov, Kossov, Yafaev, Hallén, Konstantinov.     

Detection of paramagnetic recombination centers in proton-irradiated silicon

The method of spin-dependent recombination was used to record electron spin resonance (ESR) spectra of recombination centers in a thin (∼1 μm) surface layer of p-type silicon grown by the Czochralski method and irradiated by protons with energies of ∼100 keV. Spectra of excited triplet states of the oxygen + vacancy complex (A-centers) were observed along with complexes consisting of two carbon atoms and an interstitial silicon atom (C_S-Si_I-C_S complexes). The intensity of the ESR spectra of these radiation-induced defects was found to be largest at irradiation doses of ∼10¹³ cm⁻², and decreased with increasing dose, which is probably attributable to passivation of the radiation-induced defects by hydrogen. Fiz. Tekh. Poluprovodn. 33, 1164–1167 (October 1999)     

Recombination mechanisms in doped n-type Hg1−x CdxTe crystals and properties of diffusion p +-n junctions based on them

We made p ⁺-n-type photodiodes for the 3–5 and 8–12 μm wavelength regions by diffusing As into single-crystal n-Hg_1−x Cd_xTe substrates, and investigated their electrical and photoelectric properties. Analysis of the temperature dependences of the differential resistance and current-voltage characteristics led us to conclude that charge-carrier transport is predominately due to the generation-recombination mechanism at a temperature of 77 K. As the temperature increases, a contribution from the diffusion component also appears. We obtained values of the product R ₀ A≅0.3–1.0, 1–10, and (1–10)×10⁴ Ω · cm² for diodes with long-wavelength photosensitivity cutoffs λ_c≅11.5, 10.5, and 6.0 μm, respectively, indicating that they could operate in the regime where performance is limited by background radiation fluctuations. Fiz. Tekh. Poluprovodn. 31, 350–354 (March 1997)     

Influence of tellurium impurity on the Properties of Ga1?XInXAsYSb1?Y (X>0.22) solid solutions

The influence of tellurium impurity on the electrical properties of Ga_1−X In_XAs_YSb_1−Y (X=0.22 and X=0.24) solid solutions grown by liquid-phase epitaxy from lead-containing solution-melts was studied. Defect healing was shown to take place at low tellurium doping levels (X _Te ^L <2×10⁻⁵ at. %) in inhomogeneous highly compensated p-type solid solutions. Thus, it is possible to produce slightly compensated p-type materials with a low density of impurities and structural defects. High doping levels allow production of n-type materials with the electron density n=10¹⁷–10¹⁹ cm⁻³. Electroluminescence spectra of n-GaInAsSb/p-GaSb heterostructures are promising for the development of light-emitting diodes with a wavelength λ=2.0–2.5 μm. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 36, No. 8, 2002, pp. 917–924. Original Russian Text Copyright ? 2002 by Voronina, Lagunova, Kunitsyna, Parkhomenko, Sipovskaya, Yakovlev.     

Arrays of 128×128 photodetectors based on HgCdTe layers and multilayer heterostructures with GaAs/AlGaAs quantum wells

A technology has been elaborated and photodetector modules based on Hg_1−x Cd_xTe/GaAs heterostructures and GaAs/AlGaAs multiquantum-well structures grown by molecular-beam epitaxy were fabricated for the 3–5 and 8–12 μm spectral ranges. The photosensitive HgCdTe layers were grown on the GaAs substrates with the intermediate buffer layer of CdZnTe. To decrease the surface effect on the recombination processes, the graded-gap Hg_1−x Cd_xTe layers with x increasing towards the surface were grown. A silicon multiplexer was designed and fabricated by CMOS/CCD technology with a frame rate of 50 Hz. The hybrid microassembly of the photodetector array and the multiplexer was produced by group cold welding on indium columns while monitoring the connection process. The fabricated 128×128 modules based on HgCdTe layers with the cutoff wavelengths 6 and 8.7 μm had a temperature resolution of 0.02 K and 0.032 K, respectively, at a temperature of 78 K and a frame rate of 50 Hz. The photosensitive GaAs/AlGaAs multilayer quantum well structures were fabricated by MBE. It is shown that the technology developed allows 128×128 multielement photodetector arrays (λ_peak=8 μm) to be produced with a temperature resolution of 0.021 K and 0.06 K at operating temperatures of 54 K and 65 K, respectively. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 9, 2001, pp. 1159–1166. Original Russian Text Copyright ? 2001 by Ovsyuk, Sidorov, Vasil’ev, Shashkin.     

Optical properties of crystals of the solid solutions (InSb)1−x (CdTe)x

The reflection and absorption spectra of crystals of the solid solutions (InSb)_1−x (CdTe)_x in the wavelength interval 2.5–25 μm were measured within the limits of solubility of CdTe in InSb (x⩽0.05) at room temperature. Analysis of the experimental results confirmed the applicability of the Kane theory for all compositions investigated. The variation of the optical band gap ɛ _g ^opt and the effective mass m _c at the Fermi level as a function of composition was determined. It is shown that the minimum values m _c=0.8×10⁻² m ₀ and ɛ _g ^opt =0.07 eV are reached for x=0.02–0.03. Information about the predominant mechanism of scattering for each alloy is obtained from the absorption curves in the region of absorption by free charge carriers. X-Ray crystallographic investigations were performed and the change Δa(x) in the lattice constant of the solid solutions relative to pure InSb was determined. It is shown that the behavior of m _c(x) and ɛ _g ^opt is uniquely determined by Δa(x). In turn, Δa(x) is determined by the complicated character of the interaction of the dopants with one another and with the InSb lattice. Fiz. Tekh. Poluprovodn. 32, 303–306 (March 1998)     

InAsSb/InAsSbP double-heterostructure lasers emitting in the 3–4 µm spectral range

Our earlier reports concerning the fabrication by liquid-phase epitaxy and investigation of InAsSbP/InAsSb/InAsSbP double heterostructure lasers emitting at 3–4 μm are reviewed. The dependences of spectral characteristics and the spatial distribution of the laser emission on temperature and current are discussed. Lasing modes are shifted by 0.5–1.0 cm⁻¹ to longer wavelengths with increasing temperature. The tuning of the lasing modes by means of current is very fast (10⁻⁸–10⁻¹² s). With increasing current, the modes are shifted to shorter wavelengths by 50–60 ? at 77 K. The maximum mode shift of 104 ? (10 cm⁻¹) is observed at 62 K. The spectral line width of the laser is as narrow as 10 MHz. Abnormally narrow directional patterns in the p-n junction plane are observed in some cases in the spatial distribution of laser emission. The current tuning of lasers, due to nonlinear optical effects, has been modeled mathematically in good agreement with the experiment. Transmittance spectra of OCS, NH₃, H₂O, CH₃Cl, and N₂O gases were recorded using current-tuned lasers. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 12, 2001, pp. 1466–1480. Original Russian Text Copyright ? 2001 by Danilova, Imenkov, Kolchanova, Yakovlev. See [1].     

Emission-line broadening of current tunable InAsSbP/InAsSb/InAsSbP heterostructure lasers

The dependence of emission-line broadening on the drive current was studied at 50–80 K for tunable InAsSbP/InAsSb/InAsSbP double heterostructure lasers operating in the 3.3–3.4 μm spectral region. For a small increase of the injection current I over the threshold current I _th, the line width depends on the I-I _th difference hyperbolically, in accordance with the Schawlow-Townes and Henry theories that assume a homogeneous distribution of the nonequilibrium carrier concentration across the resonator width. With the current raised to (3–4)I _th, line narrowing ceases and the line starts to broaden with increasing current. The observed line broadening is explained by the effect of the nonequilibrium carrier concentration gradient between the middle of the resonator and its edges. In tunable lasers, this gradient increases with current, the lasing wavelength simultaneously decreasing. The minimal width of the lasing line is 10–20 MHz. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 34, No. 12, 2000, pp. 1468–1471. Original Russian Text Copyright ? 2000 by Imenkov, Kolchanova, Kubat, Civish, Yakovlev.     

Cathodoluminescence of p-n-p microstructures in CuInSe2 crystals

Microstructures in p-CuInSe₂ single crystals tailored by the strong electric field have been studied using the method of local (d⩽1 μm) cathodoluminescence (CL). The shortest-wavelength radiation (ℏω=1.023 eV) has been observed from the n-type layer and longer-wavelength radiation (ℏω=1.006 eV)—from the p-type regions. An analysis of the cathodoluminescence spectra has allowed us to attribute the experimental features to optical transitions associated with donor and acceptor levels of V _Cu, V _Se, and Cu_i point defects in the crystal. Test measurements of EBIC, the C–V characteristics, and the DLT spectra confirm the cathodoluminescence data and reveal additional features of the p-n-p microstructures. Fiz. Tekh. Poluprovodn. 31, 114–119 (January 1997)     

A pulsed synthesis of β-FeSi2 layers on silicon implanted with Fe+ ions

Continuous layers and fine-grained films of β-FeSi₂ were synthesized using the implantation of Fe⁺ ions into Si(100) with subsequent pulsed nanosecond ion-beam treatment of the implanted layers. The X-ray diffraction studies showed that the pulsed ion-beam treatment brings about the formation of a mixture of two phases: FeSi and β-FeSi₂ with strained crystal lattices. Subsequent rapid thermal annealing led to the complete transformation of the FeSi phase into the β-FeSi₂ phase with the formation of a textured layer. The data obtained using Raman spectroscopy corroborate the formation of the β-FeSi₂ phase with a high degree of silicon crystallinity. The results of measuring the optical absorption point to the formation of β-FeSi₂ layers and precipitates with a direct-gap structure, an optical gap of E _g≈0.83 eV, and an Urbach tail extent of E ₀≈220 meV. The photoluminescence band peaked at λ≈1.56 μm and caused by direct band-to-band transitions in β-FeSi₂ was observed at temperatures lower than 210 K. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 11, 2001, pp. 1320–1325. Original Russian Text Copyright ? 2001 by Batalov, Bayazitov, Terukov, Kudoyarova, Weiser, Kuehne.     

Spectral line width of the current-tunable lasers on the base of InAsSb/InAsSbP at low temperature

Current-tunable diode lasers with a narrow emission line (7–10 MHz) were designed on the basis of a InAsSb/InAsSbP heterostructure for low-temperature (15–60 K) operation within the range of 3.2–3.4 μm. It is shown that the fast modulation of radiation frequency can be attained only if the current far exceeds the threshold value. This is due to the fact that a smooth optical waveguide can be formed only if the concentration of nonequilibrium charge carriers at the lateral edges of the cavity is in sufficient excess over the threshold. It is noted that the current-induced increase in the hole concentration near the p region due to a reduction in the effective lifetime of the carriers in the lasing mode additionally extends the frequency tuning range. The absorption spectrum of ammonia is presented within the range from 3232 to 3237 cm⁻¹ as measured with the use of the laser developed. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 36, No. 5, 2002, pp. 622–628. Original Russian Text Copyright ? 2002 by Imenkov, Kolchanova, Kubat, Tsivish, Yakovlev.     

Luminescence spectra and efficiency of GaN-based quantum-well heterostructure light emitting diodes: Current and voltage dependence

Luminescence spectra and quantum yield in light emitting diodes (LEDs) based on InGaN/AlGaN/GaN heterostructures with multiple quantum wells (MQWs) were studied in the range of currents J=10⁻⁶–10⁻¹ A. Minor spread in the quantum yield at operating currents (±15% at J≈10 mA) was observed in these LEDs, which were fabricated by Hewlett-Packard. The spread is due to differences in the current and voltage dependences of the diode emission intensity, caused by differences in the charged center distribution across the space-charge region (SCR) of the structures and in the role of the tunnel current component at low voltages. In the diodes with a thin (≲120 nm) SCR, a tunnel emission band was observed for J≲100 μA; the peak energy of this band ℏω_max=1.92–2.05 eV corresponds to the voltage applied. At low currents (J=0.05–0.5 mA), the spectral position of the main peak ℏω_max=2.35–2.36 eV is independent of the voltage and is determined by the radiative transitions between the localized states. At J>1 mA, this band shifts with the current (ℏω_max=2.36–2.52 eV). Its shape corresponds to the model for the occupation of states in the two-dimensional energy band tails, which are caused by the microscopic potential fluctuations. The four parameters in this model are related to the calculated energy band diagram of the MQW structure. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 7, 2001, pp. 861–868. Original Russian Text Copyright ? 2001 by Kudryashov, Mamakin, Turkin, Yunovich, Kovalev, Manyakhin. Part of this study was reported at the 3rd All-Russia Workshop on Structures and Devices Based on Gallium, Indium, and Aluminum Nitrides (Moscow State University, 1999); the 3rd International Conference on Nitride Semiconductors (Montpellier, 1999); and the 4th European Gallium Nitride Workshop (Nottingham, 2000).     

The effect of pulsed laser annealing on the parameters of CdxHg1−x Te photoresistors

The effect of nanosecond-pulse radiation of a Nd laser (pulse duration τ=10 ns, wavelength λ=1.06 μm) at 300 K on the parameters of Cd_0.19Hg_0.81Te photoresistors was studied. At the optimal energy density W=0.2–0.3 J/cm², the surface melts to yield a 0.04–0.52-μm-thick inversion layer with increasing sensitivity and detectivity of the photoresistors. At higher energy densities W, the parameters of the photoresistors deteriorate, and the dark resistance grows. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 4, 2001, pp. 464–466. Original Russian Text Copyright ? 2001 by Ryzhkov, Ibragimova, Baryshev.     

Electrical properties of hydrogenated amorphous Ge0.90Si0.1:Hx films

Amorphous 1-μm thick films of the Ge_0.90Si_0.1:H_x solid solution (x=1.3, 5.1, 8.7, 14.2, and 23.7 at. %) were grown in a hydrogen atmosphere under various partial hydrogen pressures. The method of plasmachemical deposition with a rate of 0.3–0.5 ?/s was employed. Electrical conductivity of the films was measured within a temperature range of 100–420 K. The dark conductivity of the films was measured. The activation energy of hopping at T=100 K, the hop range, the mobility of electrons at the levels ɛ_F and ɛ_C, and the activation energy of conductivity were calculated. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 34, No. 11, 2000, pp. 1383–1385. Original Russian Text Copyright ? 2000 by Nadzhafov.