Fate of fertiliser N applied to winter wheat growing on a Vertisol in a Mediterranean environment

A field study using 15N was conducted on a Vertisol in semi-arid Morocco to assess the fate and efficiency of fertiliser N split applied to winter wheat (Triticum aestivum L.). Splitting of fertiliser N is highly crucial in semi-arid regions, considering the increased moisture stress towards the end of the growing season. A N fertilisation rate of 100 kg N ha-1 was split according to two schemes: i) 25% at planting, 50% at tillering and 25% at stem elongation; or ii) 50% at tillering and 50% at stem elongation. The application of 100 kg N ha-1increased the vegetative dry matter production with more than 2000 kg dry matter ha-1 in comparison with the control treatment. Nitrogen fertilisation had no significant effect on the grain yield production. Moreover, the 1000 grain weight decreased from 32 to 26 g due to N fertilisation. Total N uptake was about 50 kg N ha-1 higher for the fertilised plants in comparison with the unfertilised plants, but it was not affected by the splitting pattern of the fertiliser N. Recoveries of 15N-labelled fertiliser by the plant (above-ground plant parts plus roots from the upper 20 cm layer) were low (31% and 24% for the 3-split and 2-split application, respectively). More N in the plant was derived from fertiliser when applied early in the growing season than when applied late in the season. About 13% of the N in the plants was derived from the 50 kg N ha-1 at tillering, while only 5% was derived from the N application (50 kg N ha-1) at stem elongation. At harvest, a high residual of fertiliser-derived N was found in the 0–90 cm profile (62% and 72%, for the 3-split and 2-split application, respectively). Less than 10% of the applied N could not be accounted for, the amount being highest for the application at tillering. This N not accounted for was mainly ascribed to denitrification after an important rainfall event. The application of fertiliser N led to an increase of about 20 kg N ha-1 in soil N uptake by the crop (positive ANI). The results suggested a dominant influence of moisture availability on the fertiliser N uptake by wheat.     

Yield response of lentil to directly applied and residual phosphorus in a Mediterranean environment

The response of lentil grown under rainfed conditions to directly applied and residual phosphorus (P) was described by a modified Mitscherlich equation, accounting for the effects of rainfall on (1) potential yield, and (2) the availability of soil-P to the crop. The response of lentil yield to directly applied and residual P was studied in two-course cereal–lentil rotational trials under rainfed conditions in a Mediterranean-type environment. Cereal crops were grown at different P application rates during 4 growing seasons at 3 sites, representing different rainfall zones in northwest Syria. Lentil (Lens culinaris Med.) was grown during 4 seasons at the same sites, each lentil crop following a cereal crop. In 3 out of 4 lentil-growing seasons, additional P was applied to lentil in subplots to compare the residual and direct effects of P application. The initial contents of extractable soil-P (P-Olsen) were low at all sites, in the range of 2–5 ppm P. Under the conditions of the experiments, lentil appeared to benefit slightly more from P applied to the preceding wheat crop (residual P) than from directly applied P. It is shown that the modified Mitscherlich equation could be used as a basis for P fertilizer recommendations for rainfed farming. As for lentil, it was concluded that a single application of P to the wheat crop in a wheat/lentil rotation could reduce the cost of lentil production, without reducing lentil yield.     

Nitrogen losses and fertilizer N use efficiency in irrigated porous soils

Porous soils are characterized by high infiltration, low moisture retention and poor fertility due to limitation of organic matter and nitrogen (N). However, wherever irrigated and properly managed, these are among the most productive soils in the world. For sustained productivity and prevention of N related pollution problems, fertilizer N management in porous soils needs to be improved by reducing losses of N via different mechanisms. Losses of N through ammonia volatilization are not favoured in porous soils provided fertilizer N is applied before an irrigation or rainfall event. Ammonium N transported to depth along with percolating water cannot move back to soil surface where it is prone to be lost as NH₃. Under upland conditions nitrification proceeds rapidly in porous soils. Due to high water percolation rates in porous soils, continuous flooding for rice production usually cannot be maintained and alternate flood and drained conditions are created. Nitrification proceeds rapidly during drained conditions and nitrates thus produced are subsequently reduced to N₂ and N₂O through denitrification upon reflooding. Indirect N-budget estimates show that up to 50% of the applied N may be lost via nitrification-denitrification in irrigated porous soils under wetland rice.High soil nitrate N levels and sufficient downward movement of rain water to move nitrate N below the rooting depth are often encountered in soils of humid and subhumid zones, to a lesser extent in soils of semiarid zone and quite infrequently, if at all in arid zone soils. The few investigations carried out with irrigated porous soils do not show substantial leaching losses of N beyond potential rooting zone even under wetland rice. However, inefficient management of irrigation water and fertilizer N particularly with shallow rooted crops may lead to pollution of groundwater due to nitrate leaching. At a number of locations, groundwater beneath irrigated porous soils is showing increased nitrate N concentrations. Efficient management of N for any cropping system in irrigated porous soils can be achieved by plugging losses of N via different mechanisms leading to both high crop production and minimal pollution of the environment.     

Comparative response of bread and durum wheat cultivars to nitrogen fertilizer in a rainfed Mediterranean environment: soil nitrate and N uptake and efficiency

A 3-year multi-site study was carried out on rainfed Vertisols under Mediterranean conditions in southern Europe to determine the influence of the N fertilizer rate on soil nitrates, N uptake and N use efficiency in bread wheat (Triticum aestivum L.) and durum wheat (Triticum turgidum L. var. Durum Desf.) in rotation with sunflower (Heliathus annuus L.). Nitrogen fertilizer rates were 0, 100, 150 and 200 kg N ha⁻¹ applied in equal proportions at sowing, tillering and stem elongation. The experiment was designed as a randomized complete block with a split plot arrangement and four replications. Nitrogen harvest index (NHI), N uptake/grain yield (NUp/GY), N use efficiency (NUE), N utilization efficiency (NUtE), N uptake efficiency (NUpE) and N apparent recovery fraction (NRF) were calculated. Differences were observed in N use efficiency between the two modern bread wheat and durum wheat cultivars studied. In comparison to durum, bread wheat displayed greater N accumulation capacity and a more efficient use of N for grain production. While under N-limiting conditions, the behavior was similar for both wheat types. No difference was noted between wheat types with regard to changes in soil residual levels over the study period at the various sites. The 100-kg ha⁻¹ N fertilizer rate kept soil nitrates stable at a moderate level in plots where both wheat types were sown.     

一种氮缓释复混肥料的制备及其氮素缓释性评价

用化学方法制备了氮素不同程度缓释的复混肥(氮缓释肥),在实验室条件下肥料的淋洗实验表明,相比对照复混肥,这种复混肥的氮素具有一定程度的缓释性,且随着复混肥制备过程中所加入的缓释剂甲醛的增加,氮素的缓释性得到增强。用双曲线方程Xt=b-a/t对氮缓释肥的氮素累计溶出率进行拟合,采用拟合方程中b值和a值计算得到的缓释指数SRI来定性和定量评价氮缓释肥的氮缓释特性。结果表明:氮缓释肥的氮素缓释指数SRI与制肥中加入的缓释剂相对含量X具有较好的正相关,其直线相关系数达0.9905(P<0.01)。这种对相关养分淋洗数据用双曲线按淋洗时间段分段拟合,并引入缓释指数SRI评价缓释肥料缓释特性的方法,为缓释肥料缓释特性的快速定性和定量评价提供了依据。     

Yield,nitrogen recovery efficiency and quality of vegetables grown with organic waste-derived fertilisers

More sustainable production of high-quality, nutritious food is of worldwide interest. Increasing nutrient recycling into food systems is a step in this direction. The objective of the present study was to determine nitrogen (N) fertiliser effects of four waste-derived and organic materials in a cropping sequence of broccoli, potato and lettuce grown at two latitudes (58° and 67°N) in Norway during 3 years. Effects of anaerobically digested food waste (AD), shrimp shell (SS), algae meal (AM) and sheep manure (SM) at different N application rates (80 and 170 kg N ha^?1 for broccoli, and 80 and 60 kg N ha^?1 for potato and lettuce, respectively) and residual effects were tested on crop yield, N uptake, N recovery efficiency (NRE), N balance, N content in produce, mineral N in soil, product quality parameters and content of nitrate in lettuce. Mineral fertiliser (MF) served as control. Effects on yield, N uptake, NRE, N balance and product quality parameters could to a great extent be explained by estimated potentially plant-available N, which ranked in the order of AD > SS > SM > AM. Results for crops fertilised with AD and SS were not significantly different from MF at the same N application rate, while AM, in agreement with its negative effect on N mineralisation, gave negative or near-neutral effects compared to the control. No residual effect was detected after the year of application. The results showed that knowledge about N dynamics of relevant organic waste-derived fertilisers is necessary to decide on the timing and rate of application.     

Comparison of several nitrogen fertilisers applied in surface irrigation systems. II. Nitrogen transformations

The movement and transformations in the mineral N pool below the hill and furrow were studied when different N fertilisers were applied in the irrigation water on three occasions during the growth of two maize crops. They included anhydrous ammonia, ammonium sulphate, potassium nitrate and urea. These were compared with anhydrous ammonia injected below the hill before the crop was sown. The ammonium-forming fertilisers increased the mineral-N in the surface of the furrow in both seasons. However no differential adsorption of NH₄ near the surface of the furrow was observed. We have postulated that NH₄ showed preferential movement through the voids in these cracking soils and was not adsorbed at the surface as occurs on soils with discontinuous voids. The proportion of NO₃ in the profile was higher after urea application than with NH₄ sources and was consistent with urea moving further into the peds than NH₄. Nitrification of the anhydrous ammonia band below the hill was rapid in these soils. The proportion of NO₃-N in the mineral N pool below both the hill and furrow declined with time in those locations where the air-filled porosity was generally below 10%. The implications of applying various N sources in the irrigation water on the potential loss processes taking place in the soil are discussed.     

Comparison of several nitrogen fertilisers applied in surface irrigation systems. I. Crop response

The effect of several N carriers applied in the surface irrigation water on the growth, yield and N status of maize was studied in 2 seasons. The carriers applied in the water included anhydrous ammonia, ammonium sulphate, ammonium nitrate, potassium nitrate and urea and they were compared with a preplant band application of anhydrous ammonia and a control treatment. All N treatments received 100 kg N ha^–1. The site used in the second experiment was less responsive to N fertiliser than the first site and the crop growth in the second season was affected by an attack of charcoal rot (Macrophomina phaseolina).Urea, as a N source for fertigation, was superior to the ammonium forms, while the nitrate carriers were the least efficient. Water-run urea increased the maize yield by 27% when compared with the band application in the first season but was 6% lower in the second season. Fertigation allowed N to be applied during the grand period of growth when N stress was most likely to occur. This technique for applying N fertiliser to surface irrigated crops has been adopted by commercial growers.     

Fate and efficiency of sulfur fertilizer applied to food crops in West Africa

Increased food production in West Africa must be linked to increased fertilizer use. However, the increased use of the high analysis sulfur-free materials currently available in the region will lead to increased incidence of sulfur (S) deficiency. In order to determine the S fertilizer requirements of major cereal crops, and compare the fate and efficiency of alternative S sources, experiments were conducted at six sites in semiarid and subhumid West Africa from 1985–1988. Sulfur fertilizers increased grain yields from 10% to 65% (200 to 2000 kg/ha) in 14 out of 20 site-years (at 5 out of 6 sites). Maximum response was generally obtained with only 5–10 kg S/ha. Both powdered (–60 mesh S⁰) and granular (S⁰-fortified TSP) elemental S sources were usually as effective as sulfate sources (gypsum or SSP). The residual effectiveness of S⁰, however, was superior to that of sulfate at most sites. Sulfur-35 balances demonstrated substantial leaching and low crop recovery (5%–10% of S applied) of fertilizer S. Up to 50% of the applied S was lost from sulfate sources, whereas <20% was lost from S⁰ sources. Although S⁰ sources were at least as effective as sulfate sources, the low S rates required suggest that S deficiencies in the region can be corrected at relatively low cost with sulfate-containing fertilizers, provided they can be supplied at more appropriate nutrient ratios.     

Agronomic and economic evaluation of site-specific nutrient management for irrigated wheat in northwest India

Similar to other regions of Asia, irrigated wheat (Triticum aestivum L.) yield increases in Punjab, India, have slowed in recent years. Future yield increases may occur in smaller increments through fine-tuning of crop management mainly by accounting for the large spatial and temporal variation in soil characteristics. On-farm experiments were conducted from 2002–03 to 2004–05 on 56 irrigated wheat farms (hereafter referred to as ‘sites’) in six key irrigated rice (Oryza sativa L.)-wheat regions of Punjab to evaluate an approach for site-specific nutrient management (SSNM). Site-specific N–P–K applications were calculated by accounting for the indigenous nutrient supply, yield targets, and nutrient demand as a function of the interactions between N, P, and K. The performance of SSNM was tested for two wheat crops. Compared with the current farmers’ fertilizer practice (FFP), average grain yield increased from 4.2 to 4.8 Mg ha⁻¹, while plant N, P, and K accumulations increased by 12–20% with SSNM. The gross return above fertilizer cost (GRF) was about 13% greater with SSNM than with FFP. Improved timing and/or splitting of fertilizer N increased N recovery efficiency from 0.17 kg kg⁻¹ in FFP plots to 0.27 kg kg⁻¹ in SSNM plots. The agronomic N use efficiency was 63% greater with SSNM than with FFP. As defined in our study, SSNM has potential for improving yields and nutrient use efficiency in irrigated wheat. Future research must build on the present approach to develop a more practical way for achieving similar benefits across large areas without site-specific modeling and with minimum crop monitoring.     

Response of three sorghum varieties to N supply and plant density in a tropical environment

Field trials were conducted at Samaru, Nigeria to investigate the growth, yield and grain quality response of three grain sorghum (Sorghum bicolor L. Moench) varieties (L. 187, SK 5912 and FFBL) to N fertilization under varying plant densities (33300, 50000 or 66600 plants ha^–1). Year × N interactions were significant for yield components and so were variety × N and variety × plant density interactions. Grain yield increased 41, 42, and 126% with application of 60 kg N ha^–1, the optimum N rate, a response which was associated with variations in grain weight per panicle, panicle weight and grain number. Varieties SK 5912 and FFBL produced more straw in response to added N than did var. L. 187 while yield components in var. SK 5912 and L.187 responded better than those in var. FFBL. Yield components declined in var. SK 5912 and L. 187 as plant density was increased to either 50000 or 66600 plants ha^–1. Grain crude protein (CP) content and protein yield were increased 8 and 52% respectively by 60 kg N ha^–1 but CP content declined as plant density was increased. Grain tannin content was virtually unaffected by increasing N supply. Optimum plant density for grain sorghum production in this environment is in the range of 50000 plants ha^–1.     

Hydrodynamic and mass transfer efficiency of ceramic foam packing applied to distillation

In addition to a high void volume and specific area, solid foams possess other properties (low density, good thermal, mechanical, electrical, and acoustical behaviour) that make them attractive for applications such as heat exchangers and reformers. Applications using foams as catalysts or structured catalyst supports have demonstrated higher performance than classical catalysts. Several studies have explored the hydrodynamic behaviour of foams in monophasic and countercurrent systems and have reported very low pressure drops. This paper describes the application of ceramic foam to distillation. The β-SiC foam contains 5 pores per inch (PPI) with a 91% void volume and a surface area of 640 m²/m³. Performance parameters including pressure drop for the dry and wet packing, flooding behaviour, and dynamic liquid hold-up were measured in a column of 150 mm internal diameter. The mass transfer efficiency in terms of the height equivalent to theoretical plate (HETP) was determined by total reflux experiments using a mixture of n-heptane and cyclohexane at atmospheric pressure. The experimental results were used to develop a set of correlations describing pressure drop and liquid hold-up in terms of a dimensionless number. The hydrodynamic performance and mass transfer efficiency were compared with classical packing materials used in distillation.     

新型普钙生产混合装置的应用及经济效益

新型普钙生产混合装置的优越性及使用它为增加产量,提高经济效益,创新了良好的条件。     

Nitrogen use efficiency of irrigated tropical rice established by broadcast wet-seeding and transplanting

Broadcast wet-seeding is gradually replacing transplanting in irrigated rice systems of Southeast Asia. Previous studies reported higher fertilizer-N use efficiency for broadcast-seeded than transplanted rice despite similar grain yields in treatments that received N fertilizer. To re-examine this issue, we compared crop performance and the recovery efficiency (_r, N uptake per unit N applied), agronomic efficiency (_a, grain yield per unit N applied), and partial factor productivity from applied N (PFP, grain yield per unit N applied) in broadcast-seeded and transplanted rice across a wide range of N fertilizer rates at research stations and in farmers' fields. Rice crop established by broadcasting had more rapid leaf area development, dry matter accumulation, and N uptake than transplanting during vegetative growth stages, but slower growth rates and N uptake after panicle initiation, particularly during the grain filling period. Without applied N, grain yield and N accumulation at maturity were significantly lower in broadcast-seeded than transplanted rice, whereas yields and N uptake were comparable for both planting methods with equivalent rates of applied N. Although both _r and _a were higher for broadcast-seeded than transplanted rice, this advantage was an artifact of lower yields and reduced N uptake by broadcasting without applied N rather than improved performance with applied N. In contrast, PFP values were similar for broadcast-seeded and transplanted rice at comparable fertilizer-N rates and in the absence of lodging. We conclude that the PFP from applied N provides a more relevant measure of N use efficiency of different crop establishment methods, and that the system-level N use efficiency of broadcast-seeded rice was not greater than that of transplanted rice.     

提高隔膜电解电流效率增加经济效益

大连染料化工有限公司现有金属阳极电解槽96台,氢氧化钠生产能力2万t/a,氢氧化钾生产能力1.5万t/a,长期以来,一直延续着老的氯碱生产工艺,电解电流效率很低,2002-2005年平均电流效率为氢氧化钠85.7%,氢氧化钾仅82.3%,提高电流效率势在必行.……     

The influence of controlled release fertilisers and the form of applied fertiliser nitrogen on nitrous oxide emissions from an andosol

A laboratory experiment was conducted to determine whether applying controlled release nitrogen fertilisers could reduce nitrous oxide emissions from an andosol maintained at different water contents, compared with applying standard nitrogen fertiliser. The effect of the form of N applied (NH₄-N or NO₃-N) was also investigated. Soil was collected from an arable field and sub-samples were treated with controlled release or standard fertiliser, applied at a rate of 200 g N g^–1 dry soil either as NH₄ ⁺ or NO₃ ^–. The soils were maintained at 40%, 55%, 70% or 85% water filled pore space (WFPS) and incubated at 25 °C for 50 days. Gas samples were collected and analysed every 3–4 days and soil samples were analysed on five occasions during the incubation. Emissions of N₂O were much greater from ammonium sulphate than from calcium nitrate fertiliser, indicating that nitrification was the main source of the N₂O. Emissions at 85% WFPS were greater than at the lower water contents in all treatments. The use of controlled release NH₄-N fertilisers reduced and delayed the maximum peak of emissions, but at 55% and 70% WFPS this did not always result in lower total emissions. Emissions from the controlled release NO₃-N fertiliser were very low, but only significantly lower than from standard NO₃-N fertiliser at water contents below 85% WFPS. The results demonstrate that choosing the appropriate form of fertiliser in relation to expected soil moisture could significantly reduce N₂O emissions. Applying the fertiliser in a controlled-release form could further reduce emissions by reducing the length of time that fertiliser nitrogen is present in the soil and available for nitrification or denitrification.     

Plant response to the management of fluid and solid N fertilizers applied to furrow-irrigated corn

The use of fluid fertilizers has increased in recent years. Plant response to field management practices of fluid and solid N fertilizers in furrow-irrigated field studies has not been well-documented. This research studied the response of corn (Zea mays L.) to several field management practices of fluid and solid N fertilizers applied at several rates. Corn grown with sidedressed applications of the fluid fertilizers, urea ammonium nitrate (UAN) and 18-0-0+7Ca, generally had higher grain yields, higher yield efficiencies, higher ear populations, larger seed size, more kernels per ear, and a higher ear leaf N concentration than corn grown with preplant broadcast treatments of urea, ammonium nitrate (AN), and UAN. In 1988, corn grown with 280 kg N ha^–1 of AN applied preplant broadcast had a lower grain yield, yield efficiency, kernels per ear, and ear leaf N concentration, while ear population and kernel size were unchanged, in comparison to split applications of UAN at 224 kg N ha^–1. In 1989, corn grown with three split applications of UAN at 280 kg N ha^–1 had a higher grain yield and produced more kernels per ear without affecting yield efficiency, ear population, kernel size, or ear leaf N concentration compared with treatments at the 224 kg N ha^–1 rate. Use of split, side-dressed N management practices in furrow-irrigated corn should eliminate the need to use excessive N rates while maintaining grain yields and other plant responses, resulting in more efficient N use than traditionally achieved.     

Evaluation and model of temperature and rainfall effects on response to N sources applied to grassland in spring

Direct and residual effects of urea and calcium ammonium nitrate (CAN) on dry matter (DM) response were measured at a total of 12 application times in early spring over three years. The variation in the direct effect was described by models that included temperature and long-term rainfall for CAN and, additionally, short-term rainfall for urea. The operative temperature was the accumulated mean daily air temperature for combined intervals pre-application and postapplication of N. The effect of rainfall was apparent only when the data were adjusted for temperature.Simulation studies with the models indicated that, although the influence of temperature was dominant, rainfall modified it strongly in terms of the relative efficiencies of the two N sources and the magnitude of response. For instance, the temperature-induced increase in DM response to urea between cold and normal years was 402 kg ha^–1 for a specified period, whereas differences between dry and wet years were decreases of 166 and 259 kg ha^–1 in the case of urea and CAN, respectively. Short-term rainfall had a positive effect on response to urea.The experimental values varied widely both between and within years. The direct effect of the application of urea at 50 kg N ha^–1 varied from 0 to 750 kg DM ha^–1, and the residual effect varied from 0 to 1620 kg DM ha^–1. The corresponding values for apparent N recovery varied from 0.1 to 45% and from 7 to 68%, respectively. The efficiency of urea was comparable to, and in instances better than, CAN.