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1.
The objective of this investigation was to assess the potential effects of coal preparation on SRC-II liquefaction yields. Liquefaction yields were estimated from coal properties at standard SRC-II conditions using mathematical models. For Powhatan and Ireland Mine coals, the yields were most sensitive to changes in the total sulphur level and were not significantly affected by the small changes in total reactive macerals, H/C ratio or volatile matter. The fractions from both coals were ranked in order of decreasing liquid yields (or increasing organic vacuum bottoms yields) on a dry, ash-free basis as follows: middling > cleaned > ROM (run-of-mine) > deep cleaned. On a dry basis, all the washed fractions from each coal were superior to the ROM coal, giving higher liquid yields. 相似文献
2.
The Mössbauer effect has been used to study the transformations of FeS2 in four different coals: IL No. 6, Ky , Blacksville No. 2, and Powhatan No. 5. The transformations of FeS2 in the coals were studied in an inert atmosphere. It was observed that the pyrrhotites formed from FeS2 have a considerable reduction in the isomer shift at 440 °C as compared to the values obtained in the absence of coal. This effect is associated with the interaction of the pyrrhotites with the coal constituents at high temperatures. There is also a significant line-broadening at 440 °C. This broadening is due either to vacancy motion in the iron sulphides and/or to motional broadening due to particle motion in the coal-derived liquids. The percentage conversion of pyrite to pyrrhotite depends markedly on time as well as type of coal. The weathering of the coal has a detrimental effect on the rate of conversion of pyrite to pyrrhotite. The ferrous sulphate layers covering the pyrite particles hinder the removal of sulphur from that surface. The major factor affecting the ratio is the total amount of sulphur available for H2S formation. Partial H2S pressure is the crucial quantity controlling the stoichiometry of the pyrrhotites. Hence, a high percentage of H2S in the reactor at high temperature will assure the formation of pyrrhotites with a high number of metal vacancies. 相似文献
3.
Kenneth W. Johnson John C. Crelling Abhijit Biswas Kenneth L. Telschow Tasdiq Ahmed James M. Myers 《Fuel》1985,64(10):1453-1459
Photoacoustic microscopy, in which laser-light energy absorbed by coal macerals is converted into thermal energy, has recently emerged as an in-situ technique for coal maceral characterization. By employing two possible detection modes, different thermal properties can be measured and correlated with the material properties of the coal macerals. For the piezoelectric detection method, the photoacoustic signal is proportional to , where a is the coefficient of thermal expansion, B is the bulk modulus, p is the mass density, and c is the specific heat capacity of the maceral. The second method employs a gas microphone where the photoacoustic signal is proportional to , where K is the thermal conductivity. Photoacoustic data gathered by both methods on vitrinite and pseudovitrinite macerals from Appalachian basin coals agree with values predicted from known values of a, B, p and c. Data indicate that the thermal-elastic and thermal-conductance properties vary in a systematic manner from low- to high-rank coals. Throughout the entire rank range up to 92% carbon, vitrinite exhibits a significantly different photoacoustic response than pseudovitrinite. The photoacoustic measurements reflect the chemical composition and molecular structure of the individual coal macerals. 相似文献
4.
Bituminous coals produced in the Ostrava-Karviná coal basin show considerable variation in their maceral composition, vitrinite reflectance and fluidity. There is a close association of the latter with the atomic ratio expressing the different chemico-structural properties of vitrinites of lower coalification. These properties of the coal mass all influence the coke mechanical properties; moreover the parameter is of principal importance to the course of the coking process. Laboratory, pilot-plant and full-scale experiments show that coals rich in inertinite may give cokes of suitable mechanical properties, providing the , ratio and the bulk density are high enough. It should be noted, however, that these coals contain finely dispersed inertinite in the vitrinite mass and this may have a positive effect on the coke mechanical properties. 相似文献
5.
The effect of Wyodak coal properties on liquefaction reactivity as measured by distillate yield and cyclohexane conversion has been investigated. Spot samples of four Wyodak subbituminous coals from the Anderson and Canyon coal seams in the Powder River Basin of NE Wyoming were liquefied in microautoclave and batch reactor experiments. Runs were made using two different Wyodak coal-derived solvents. Emphasis in this work was directed toward correlation of C4-700 K distillate yield and cyclohexane conversion as functions of measurable physical, chemical and petrographic properties of the feed coal. Reactivity rankings were found to be the same using either measure of coal reactivity. However, the data indicated that distillate yields were a function of both solvent quality and feed coal properties. For each solvent studied, selected coal properties, including carbon content, total and organic sulphur content, vitrinite content and total reactive maceral (vitrinite plus exinite) content, were found to give statistically significant correlations with distillate production and cyclohexane conversion. Pyritic and sulphate sulphur contents did not appear to enhance liquefaction yield or conversion at the reaction conditions studied. However, any catalytic effects due to pyrite or sulphate sulphur may have been masked by the use of two high quality liquefaction solvents. 相似文献
6.
Low-ash vitrinite concentrates of representative South African coals have been prepared and analysed. Various properties when plotted against carbon content show inflections at to 2% lower carbon content than normal British coals. These differences are ascribed to the heating effects of dolerite intrusions. 相似文献
7.
Jeffrey C. Evans Christopher C. Rowlands Geoffrey Barker-Read Robert M. Cross Neal Rigby 《Fuel》1985,64(8):1172-1174
Nine South Wales coals of different rank and composition and seven structurally disturbed outburst prone coal samples were studied using electron paramagnetic resonance. An increase in baseline spin concentration with fixed carbon content was observed across the South Wales coalfield. Enhanced spin concentrations were observed for the structurally disturbed outburst prone coal samples. The value remained more or less constant with varying structural condition, fixed carbon, and volatile matter content of the coal. 相似文献
8.
The removal of sulphur and ash from coal treated with aqueous hydrogen peroxide/sulphuric acid solutions has been studied at ambient temperature, under a variety of experimental conditions. Almost complete elimination of the sulphate and the pyritic sulphur was observed in most cases, as well as substantial reduction in the ash content. The other components of the organic coal matrix were not affected to a significant extent, indicating high selectivity of the system towards sulphur oxidation. An optimal H2SO4 concentration was established, above which the acid was found to have an adverse effect on the oxidation of pyrite by hydrogen peroxide. 相似文献
9.
In connection with studies of the dependence of liquefaction behaviour on coal characteristics, parameters were needed that might effectively characterize the organic chemical structures. Accordingly, the phenolic hydroxyl contents of 37 coals from three geological provinces of the USA have been determined, by acetylation with 14C-labelled acetic anhydride. The results, when expressed as fractions of the total organic matter in the coals, showed a good inverse correlation with the carbon contents (dmmf). However, application of a stepwise multiple regression analysis to the data developed a linear equation relating hydroxyl content to the vitrinite reflectance, calorific value and vitrinite content, the fraction of variance explained being 92%. When the hydroxyl contents were expressed in the alternative manner, as fractions of the total oxygen content, no correlation could be seen with carbon content. However, in the wide scatter of points on the graph, the data are seen to fall into three reasonably distinct populations such that at the same level of rank, hydroxyl contents typically decrease for coals from the three provinces in the order Interior > Eastern > Rocky Mountain, implying that coals from these areas differ in structure as a result of differing antecedents. Statistical analyses showed that has some significance in determining liquefaction behaviour, but it is not among the coal properties found most significant. 相似文献
10.
Three Western Canadian coals were gasified with air and steam in a fluidized bed of 0.73 mm sand and coal, at atmospheric pressure and temperatures of 1023–1175K to produce a low-calorific-value gas. One non-caking and two caking coals were tested. The effects of temperature, coal feed rate, ratio, ratio, coal quality, coal particle size and bed depth on gas composition, gas calorific value and operating stability of the gasifier were established. Results are compared with those previously obtained for the same three coals when gasified in essentially the same equipment, but operated as a spouted bed. 相似文献
11.
This paper summarizes the experimental work performed on a bench-scale pre-pilot unit for investigating hydrogen mass transfer and mixing energy effects in SRC-II coal liquefaction reactors. Experiments were carried out with an Ireland Mine coal where the effects of mixing energy level (150–1000 rpm), method of hydrogen introduction (preheater flow and direct reactor sparging) and hydrogen treat rate (4 to 6 g of hydrogen/100 g of feed slurry) were investigated. Several runs using Powhatan No. 6 coal were also carried out where the effect of mixing energy level (200–1000 rpm) was investigated. Other run conditions were fixed to correspond to those likely to be used in commercial operation. The experimental results clearly indicated that below a mixing energy level corresponding to 400 rpm a significant cement-like solid deposition within the reactor (hydrogen mass transfer limitation) occurred. Below this mixing energy level the C5+ liquid yield decreases, and the selectivity of the reaction changes, resulting in an increase in the C1C4 yield. This critical mechanical mixing level corresponds to a mixing energy per unit of reactor volume of ≈3500 ergs/cm3 s (350 watts m?3). For the run conditions employed, increasing the preheater hydrogen flow from 4 to 6 g of of slurry prevented the formation of solid deposits at a mechanical mixing energy level as low as that corresponding to 200 rpm. Furthermore, the highest C5+ yield in the entire data set occurred when the preheater hydrogen flow was at the higher level. 相似文献
12.
Ralph J. Tyler 《Fuel》1980,59(4):218-226
The devolatilization behaviour of ten bituminous coals was investigated under rapid heating conditions using a small-scale fluidized-bed pyrolyser. The pyrolyser operated continuously, coal particles being injected at a rate of 1–3 g h?1 directly into a heated bed of sand fluidized by nitrogen. Yields of tar, C1–C3 hydrocarbon gases, and total volatile-matter and an agglomeration index are reported for all coals. Maximum tar yields were obtained at about 600 °C and were always substantially higher than those from the Gray-King assay. Total volatile-matter yields were also substantially higher than the proximate analysis values. The maximum tar yields appear to be directly proportional to the coal atomic ratio. The elemental analysis of the tar is strongly dependent on pyrolysis temperature. The tar atomic ratio is proportional to that of the parent coal. The effect on the devolatilization behaviour of two coals produced by changes in the pyrolyser atmosphere and the nature of the fluidized-bed material were also investigated. Substituting an atmosphere of hydrogen, helium, carbon dioxide or steam for nitrogen, has no effect on tar yield and, with one exception, little effect on the hydrocarbon gas yields. In the presence of hydrogen the yield of methane was increased at temperatures above 600 °C. Tar yields were significantly reduced on substituting petroleum coke for sand as the fluid-bed material. A fluidized bed of active char virtually eliminated the tar yield. 相似文献
13.
A suite of naturally oxidized coals from a single coal seam from southeastern British Columbia was examined by means of pyrolysis gas chromatography together with ultimate and petrographic analysis. With increasing degree of oxidation (FSI decreasing from 7.5 to 0) a consistent decrease in fixed carbon and hydrogen and an increase in oxygen and moisture were found. Comparing the mildly oxidized coal (FSI 7.5 to 3) with the unweathered coal, there is very little detectable change in pyrolysis gas composition or chemistry. At more advanced stages of oxidation (FSI 3 to 0) the pyrolysis gas is markedly depleted in CO, CH4, C2H4 and C2H6 and correspondingly enriched in CO2. The carbon and hydrogen contents decrease and the oxygen content increases significantly. In the mildly oxidized coal, oxidation rinds develop on vitrinite particles, whereas in the more oxidized coal, microfissures and a darkish cast are evident. 相似文献
14.
The paper presents the results of investigation of organic sulphur occurrence in the coal of Upper Silesian coal basin. Six hundred coal samples from 52 mines were tested. It has been found that the content of organic sulphur in the coal depends on the stratigraphic layer, coalification grade and geographic location in the Upper Silesia region. The highest mean content of organic sulphur has been found in the most recent (ca. 0.85%) and in the oldest (ca. 0.5%) strata. The lowest mean contents of organic sulphur have been found in the intermediate strata. In the case of the most recent coals, the content of organic sulphur decreases with increasing of coalification grade. When the carbon content (Cdaf) exceeds 82%, the increase of coalification grade causes no further decrease of the mean content of organic sulphur. The share of organic sulphur in the total sulphur is lower in the case of more recent (<50%) and higher in the case of older coals (>50%). 相似文献
15.
A study was carried out to ascertain the effects of coal preoxidation and carbonization conditions on the structure and relative gasification potential of a series of bituminous coal chars. Chars were prepared from two freshly mined bituminous coals and preoxidized samples derived from them. Carbonization conditions included a wide range of heating rate (0.2–10000K s?1), temperature (1073–1273 K) and time (0.25–3600 s). Char properties were characterized in terms of analysis of char morphology, surface area, elemental composition, and gasification reactivity in air. Over the range of conditions used, preoxidation substantially reduced coal fluid behaviour and influenced macroscopic char properties (char morphology). Following slow heating (0.2 K s?1), preoxidized coals yielded chars having higher total surface areas and higher reactivities toward gasification in air than did similar chars prepared from fresh coal. Following rapid heating (10000 K s?1) and short residence times (0.25 s), chars prepared from preoxidized and fresh coals exhibited similar microstructural and chemical properties (surface area, ratios, gasification rates). Carbonization time and temperature were found to be the critical parameters influencing char structure and gasification potential. 相似文献
16.
Low temperature ash (LTA) samples prepared from nine US coals were characterized by X-ray diffraction. X-ray fluorescence, and surface area analyses. The results showed that illite, kaolinite, quartz and pyrite are major components in LTAs and that ratios of some LTAs decreased significantly after H2 treatment implying the occurrence of a partial reduction of pyrite during this treatment. Surface areas of LTAs increased drastically on H2 treatment but decreased after exposure to sulphur and nitrogen compounds in activity testing. Correlations for the surface areas of LTAs before and after H2 treatment were found in terms of clay content and element concentrations. 相似文献
17.
Coal combustion experiments were carried out over the temperature range 25–900 °C using air at atmospheric pressure in a derivative thermogravimetric analysis system. Sixty-six coals high in vitrinite (> 80% mineral-matter-free basis) and low in inorganics (all but 12 samples < 10%) were examined as part of a coal characterization programme. The coals varied in rank from lignites (69% carbon on a dry, mineral-matter-free basis) to low-volatile bituminous (91% carbon). Combustion rates increased progressively with increasing temperature, passed through maxima and then declined. The rate data were fitted to an Arrhenius equation and plots showed four distinct regions of combustion. Apparent activation energies were calculated for each region and varied from ≈4 kJ mol?1 in the high-temperature, diffusion-controlled region to 290 kJ mol?1 in the chemical-reaction controlled, low-temperature region. The temperatures at which 50% of the sample had burned away () were rectilinearly related to oxygen and carbon contents (correlation coefficient squared values of 0.88 and 0.86, respectively). 相似文献
18.
Eight coals were reduced by hexamethylphosphoramide (HMPA)-Na-t-BuOH at room temperature and atmospheric pressure. More than 70 wt % of the coal is soluble in pyridine after this reduction. Coals having ≈88 wt% of carbon content show a maximum solubility in pyridine after reduction. The pyridine-soluble material has a higher ratio after reduction. l.r. and n.m.r. spectra show that the reaction product is richer in aliphatic and olefinic structures and that the aromatic ring systems are extensively saturated. From g.p.c. separations and molecular weight measurements, it is found that the molecular weight distribution has a maximum at lower and higher molecular weight values. The average molecular weight of the reduced pyridine-soluble material decreases with increase in rank of the coal. Coking properties of these coals can be related to proportions of material in the two modes of distribution of molecular weight. 相似文献
19.
The influence of cations on the pyrolysis behaviour of brown coals under flash heating conditions was investigated by means of a small fluidized-bed pyrolyser. A stream of coal particles in nitrogen was injected at rates of 1–3 g coal/h directly into a heated bed of sand fluidized by nitrogen. Yields of tar, C1–C3 hydrocarbons and total volatile matter from four Gelliondale brown coals and a Montana lignite were determined as a function of pyrolysis temperature. With all coals the maximum tar yield was obtained at 600 °C. Removal of cations present in the coals markedly increased the yields of tar and total volatile matter, with little effect on the yields of hydrocarbon gases. The converse was also observed in that the addition of Ca2+ to a cation-free coal decreased the yields of tar and total volatile matter. The extent of the reduction in tar yield at 600 °C in the presence of cations was found to be similar for all coals. After acid washing, tar yields appear to correlate with the atomic ratios of the coals in a manner similar to that observed previously with bituminous coals. 相似文献
20.
The aromaticities of samples from nine Australian coal seams, including pairs of hand-picked vitrains and durains, have been determined by 13C cross-polarization n.m.r. spectroscopy with magic angle sample spinning. The results clearly show that the aromaticity (fa) of the coals increases with increase in vitrinite reflectance and carbon content and decrease in atomic H/C ratio. For a given coal seam, durain (inertinite-rich coal) has a higher fa value than vitrain (vitrinite-tich coal). The trends for carbon content and atomic H/C are in good agreement with results from North American coals, although the aromaticities of Australian coals obtained in this study appear to be slightly lower than some of those reported for North American coals of similar carbon content. 相似文献