环境气体对激光烧蚀制备纳米Si晶粒平均尺寸的影响

采用脉冲激光烧蚀装置,在不同环境气体下,沉积制备了含有纳米Si晶粒的薄膜.利用扫描电子显微镜(SEM)观察样品的表面形貌,并对晶粒尺寸进行统计分析,发现不同环境气体下,纳米Si晶粒平均尺寸均随衬底与靶的距离增加有着先增大后减小的规律;通过分析比较,同等条件下Ne气环境下制备的纳米Si晶粒平均尺寸最小.     

沉积位置对脉冲激光沉积纳米Si晶薄膜微观结构的影响

在4.0×10-4Pa的真空条件下,采用脉冲激光烧蚀技术在单晶Si衬底和石英衬底上制备了非晶纳米Si薄膜.在N2气氛下,经过900℃热退火得到纳米Si晶薄膜.采用表面台阶测试仪、扫描电子显微镜、拉曼光谱仪等检测手段对样品不同位置的微观结构进行了表征.测量结果表明制备的纳米Si晶薄膜厚度及其晶粒尺寸分布不均匀,随着测量点与样品沉积中心距离的增加,薄膜的厚度逐渐减小,纳米Si晶粒的尺寸逐渐增大.从脉冲激光烧蚀动力学的角度对实验结果进行了定性的分析.     

脉冲激光参数在烧蚀固体材料过程中的影响

介绍长脉冲激光和短脉冲激光与固体材料相互作用时的物理模型。介绍激光作用过程中,脉宽、波长等激光参数对材料烧蚀阈值以及加工质量的影响。     

超短脉冲激光烧蚀熔融硅的理论模型

在Fokker_P1anck方程的基础上,对超短脉冲激光烧蚀熔融硅的机理进行分析研究,建立了雪崩电离、多光子吸收电离导致的熔融硅烧蚀机理的数学模型.其计算得出的激光能量密度和临界烧蚀阀值与实验结果很好的吻合,定量解释了超短脉冲激光对熔融硅烧蚀损伤微观过程的影响.     

脉冲激光液相烧蚀贵金属Au/Ag产物的表征及反应机理研究

采用多波长(1064nm、532nm、248nm)脉冲激光在去离子水中对责金属Au、Ag片表面进行激光烧蚀(PLA).利用TEM、AFM、SEM对烧蚀金属片表层及产物(微/纳米尺度的金属颗粒)进行观察分析,认为在液相水环境中,整个烧蚀过程主要可分为激光诱导相沸腾爆炸和等离子体羽辉混合体膨胀2个过程.在这2个过程中分别产生得到具有微米尺度的球状金属颗粒和纳米尺度的金属颗粒.同时,具有纳米尺度金属Au/Ag颗粒经过强激光光子"二次"修饰改性过程,形成具有形状统一、分散性和稳定性较好的金属纳米胶体体系,这些胶体中金属纳米颗粒作为探针,在表面增强拉曼散射(SERS)光谱学方面有很好的应用价值.     

纳米颗粒的短脉冲激光烧蚀制备及其非线性光学应用

本文主要介绍了纳米颗粒的短脉冲激光制备及其在非线性光学领域的应用。短脉冲激光制备纳米颗粒具有纯度高、操作简单和适用性广等优点,所制备的非线性纳米颗粒尺寸分布均匀,粒度小且可调控,在非线性光学材料中有着独特的地位。为了更深入地对此进行研究,本文介绍了纳米颗粒的光学非线性和激光的特点和原理。在此基础上,通过阐述短脉冲激光与物质相互作用的机理,说明了激光制备纳米颗粒所具有的优点,详细分析了制备条件对合成纳米颗粒的影响,并结合激光制备不同的纳米颗粒,介绍当前激光制备各类纳米颗粒的研究现状。激光制备纳米颗粒是一种操作简便、适用性广,且对环境友好的方法。

     

飞秒激光烧蚀材料表面产生纳米波纹结构的实验

利用飞秒脉冲激光烧蚀可以获得远小于激光中心波长（775nm）量级的周期条纹．通过多脉冲飞秒激光烧蚀Ni、Al、Cu、Ti和Si等材料表面的实验,得到材料表面产生光栅的周期均小于飞秒激光中心波长;采用对比实验,改变入射光的偏振特性,发现波纹周期方向随入射光偏振方向的改变而改变;不改变激光偏振态、脉冲能量为4．2J／cm^2时,沿波纹周期走向,发现平台移动速度为0．1mm／s时,可获得清晰的551nm的金属周期结构;最后应用上述实验结果,在铜片表面制备了长为几十微米、周期为551nm的微纳光栅结构。     

近断层脉冲型地震动下位移谱阻尼修正系数

现行规范采用阻尼修正系数（DMF）调整阻尼比不同于5%时的弹性位移反应谱,然而未考虑到近断层脉冲型地震动的影响。本文选取了代表性前方向性脉冲记录,研究了矩震级、场地类别和距离对脉冲周期的影响,同时指出脉冲周期与相应伪速度谱峰值周期之间具有较好的线性相关性,然后以周期与脉冲周期比和阻尼比为双变量,采用Levenberg–Marquardt算法进行非线性回归分析,提出了能够较为准确反映数据点分布规律的DMF模型。结果表明,随着脉冲周期的减小,DMF峰值对应的周期越小,而在中长周期范围DMF越趋近于1.0;与现行规范相比,模型MDF强烈依赖于脉冲周期、结构振动周期和阻尼比,且当三者位于不同取值范围时,规范DMF过低或过高     

飞秒激光烧蚀Ag膜的研究

研究飞秒激光烧蚀Ag膜表面,采用扫描电镜(SEM)观测其表面烧蚀形貌,发现烧蚀点大致分为3个区域,烧蚀面积随着脉冲能量的增大而增大,脉冲数的增加而增大,但当脉冲数达到一定值后烧蚀面积变化不大.改变脉冲数在烧蚀点得到了周期为650和150nm的长短周期条纹结构.根据烧蚀区域面积与脉冲能量的关系算出单脉冲与多脉冲的烧蚀阈值...     

飞秒激光烧蚀制备纳米结构IT0薄膜

利用飞秒激光烧蚀ITO与ZnO双层薄膜的方法,制备具有大面积表面纳米结构的ITO薄膜.在激光频率lkHz、脉冲宽度130fs、波长775nm、能量20μJ时,在ITO薄膜表面,获得了大面积的周期为176nm左右的周期性平行条纹结构.通过改变激光能量,研究了大面积纳米结构与激光能量之间的关系,发现这种大面积纳米结构是在激...     

Luminescence hydrogenated nanoamorphous Si films fabricated by reactive pulsed laser ablation

Hydrogenated nanoamorphous Si (na-Si:H) films have been fabricated by reactive pulsed laser ablation technique with hydrogen as reactive gas. It is found that the hydrogen pressure has a great effect on both the structure and photoluminescence (PL) properties of the films. Increasing the hydrogen pressure leads to a structural transition of the films from amphorous Si to na-Si:H, and the PL center wavelength of the na-Si:H films is varied with the hydrogen pressure. The PL decay times of the na-Si:H films are in the nanosecond scale and are shorter on the high energy side of their PL spectrum. The results demonstrate that the na-Si:H films are promising candidates for visible, tunable and high-performance light-emitting devices.     

A linear differential equation with a time-periodic damping coefficient: stability diagram and an application

In this paper the second-order differential equation with time-dependent damping coefficientx + cos (2t) x + x = 0,will be studied. In particular the coexistence of periodic solutions corresponding with the vanishing of domains of instability is investigated. The coexistence of -periodic solutions occurs for 4n ² where n is integer. This implies that the instability area which is emanating from =4n ² in the – stability diagram disappears. In applications, this equation can be considered as a model equation for the study of rain-wind-induced vibrations of a special oscillator.on leave as a PhD reseacher at Delft University of Technology, The Netherlands     

铸造镁硅合金组织和阻尼性能研究

利用动态机械热分析仪研究了四种镁硅合金的阻尼性能.研究表明:铸造镁硅合金具有良好的阻尼性能.并且体现出有别于纯镁的新阻尼特征,铸造镁硅合金具有较纯镁在更大应变振幅范围内的弛豫型内耗.由于Mg2 Si对晶界的钉扎作用,界面阻尼峰出现在较纯镁更高的温度.少量钙的添加改善了Mg2 Si析出的形态,但对阻尼性能的影响似乎不明显.     

CO sensing devices based on indium oxide nanoparticles prepared by laser ablation in water

A simple and effective solution route for synthesizing colloidal indium oxide (In₂O₃) nanocrystallites, i.e. laser ablation in liquid (LAL), is reported. The morphology and chemical structure of the as-prepared samples were analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectra (XPS). The results showed the formation of In₂O₃ nanoparticles with a bimodal distribution, consisting mainly of particles of small diameters (2-5 nm). Sensor devices prepared by spraying directly the LAL colloidal solutions on interdigitated alumina substrates exhibited good sensing properties for the detection of CO at very low concentrations.     

Structural, optical, and nonlinear optical absorption/refraction studies of the manganese nanoparticles prepared by laser ablation in ethanol

The structural, optical, and nonlinear optical properties of the manganese nanoparticles prepared by laser ablation in various liquids were investigated using the 532 and 1064 nm, 50 ps laser pulses. The TEM and spectral measurements showed temporal dynamics of size distribution of Mn nanoparticles in solutions. The nonlinear absorption (β = 2 × 10⁻¹⁰ and 4 × 10⁻¹¹ cm W⁻¹) and positive nonlinear refraction (γ = 8 × 10⁻¹⁵ and 2 × 10⁻¹⁴ cm² W⁻¹) of picosecond radiation were observed in the Mn colloidal suspensions using the 1064 and 532 nm radiation, respectively     

紫外激光烧蚀铜诱导电子辐射的研究

通过时间分辨技术对XeCl紫外激光烧蚀金属Cu过程中收集板上电荷的时间分辨测量,获取收集板电压信号的时间分辨,分析了激光烧蚀过程中电子与离子到达收集板的特征.结果表明,电子首先从靶面出射,离子紧随其后.收集板上的正、负电压信号分别由激光烧蚀金属Cu产生离子和电子发射而引起,高能电子对环境气体具有碰撞电离的作用.连续辐射的产生与持续时间和收集板上接收电子的负电压信号相对应.结合连续辐射强度的空间分布,对电子辐射的机理进行了探讨.认为电子辐射主要为韧致辐射,韧致辐射来源于近靶处高能电子与等离子体中的粒子相互作用,它是产生连续辐射的主要成因.     

Surface ablation of RbTiOPO4 by femtosecond laser

We report here the results obtained in surface ablation of RbTiOPO₄ single crystals by femtosecond laser. We fabricated and characterized one-dimensional (1D) diffraction gratings with different lattice spacings of 15 and 20 μm, and with a sub-modulation of the period introduced in the later. The optical and electronic microscopy characterization and filling factor analysis of these diffraction gratings are reported. We also show that the roughness generated on the grooves by the ablation process can be improved by chemical etching.     

Elucidation of the capillarity-promoted sintering of silver nanoparticles produced by a spark ablation vapor source

Through the spark ablation method, high purity, spherical silver nanoparticles (Ag NPs) with a size of 5 ± 3 nm are prepared. A solvent-assisted sintering method is developed to modulate the sintering structure and properties of the as-prepared Ag NPs. The effects of the solvents terpineol, polyethylene glycol-200, 1,2-propanediol, and ethylene glycol are explored. The results show that treatment with ethylene glycol causes the shear strength of the sintered Ag NPs at 180, 220, 260, and 300 °C to significantly improve from 0, 3.7, 22.1, and 64.6 MPa to 37.1, 56.1, 76.6, and 93.1 MPa respectively. Additionally, the size and number of voids in the sintered structure are significantly reduced. From the perspective of the capillary pressure induced by the solvent during sintering, a correlation between low solvent wettability and small agglomerate size of the Ag NPs is revealed, which reasonably explains the structure and properties of the sintered Ag NPs that were treated with different solvents. The spark ablation and solvent-assisted sintering methods provide a new approach for the fabrication and structure–property design of metal NPs for electronic applications.