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Yona Lee Seungpyeong Heo Sung‐Gon Kim 《Advanced Synthesis \u0026amp; Catalysis》2015,357(7):1545-1550
A synthetic method for the construction of fully substituted enantioenriched 1,4‐dihydroquinolines using an organocatalytic aza‐Michael/Michael cascade reaction has been developed. The asymmetric reaction of 2‐(tosylamino)phenyl α,β‐unsaturated ketones with alkynyl aldehydes, promoted by diphenylprolinol O‐TMS ether as an organocatalyst, generated chiral 1,4‐dihydroquinolines in good to high yields with excellent enantioselectivities (up to 97 % ee).
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Ryo Watari Yoshihito Kayaki Shin‐ichi Hirano Norio Matsumoto Takao Ikariya 《Advanced Synthesis \u0026amp; Catalysis》2015,357(7):1369-1373
Hydrogenation of carbon dioxide to formate was achieved using copper (Cu) catalysts in the presence of strong organic bases including amidines and guanidines. Specifically, 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) proved to be effective for the transformation of a 1:1 mixture of hydrogen and carbon dioxide into its formate salt under increased pressure in the presence of various Cu(I) and Cu(II) salts at 100 °C. A novel complex derived from copper iodide and DBU equally promoted the same reaction, indicating that DBU–Cu species are involved as real catalysts in this hydrogenation.
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Tong‐Hao Zhu Shun‐Yi Wang Tian‐Qi Wei Shun‐Jun Ji 《Advanced Synthesis \u0026amp; Catalysis》2015,357(4):823-828
A novel and efficient cobalt‐catalyzed oxidative isocyanide insertion with amines via two C N bond formation reactions under ultrasound irradiation conditions has been developed. This protocol provides a simple, clean and general way to synthesize guanidines or their corresponding hydrochlorides from simple starting materials under ultrasonic conditions. This chemistry could also be applied to an efficient synthesis of optically active guanidines without loss of enantioselectivity.
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A simple combination of dichloro(para‐cymene)ruthenium(II) dimer, a chiral amino alcohol and isopropyl alcohol allowed for in‐situ generation of the bifunctional catalyst responsible for the transfer hydrogenation reaction of trifluoromethyl ketimines in excellent yields with high enantioselectivities (up to 93% ee). Herein, we describe the optimization, scope, limitations, and applications of the method.
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Ek Raj Baral Yong Rok Lee Sung Hong Kim 《Advanced Synthesis \u0026amp; Catalysis》2015,357(13):2883-2892
The regioselective direct 3‐arylation of indoles with 1‐diazonaphthalen‐2‐(1H)‐ones was developed by means of a rhodium(II) pivalate‐catalyzed cross‐coupling reaction. This procedure provided a variety of novel 3‐naphthylindoles in high yield. The direct coupling of benzofuran, pyrrole or furan with 1‐diazonaphthalen‐2‐(1H)‐ones afforded 2‐ or 3‐naphthyl substituted heterocycles.
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This paper describes the aerobic oxidation of styrenes catalyzed by iron(III) chloride (FeCl3) to form β‐keto‐N‐alkoxyphthalimides in fair to good yields. This oxidative process employs mild conditions with green and atom efficient dioxygen (O2) as the oxidant.
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