量子阱太阳能电池的外量子效率

通过实验比较了砷化镓量子阱太阳能电池与不含量子阱结构的普通砷化镓太阳能电池的外量子效率.结果表明,量子阱太阳能电池吸收光子的波长从870nm扩展到了1000nm.当波长小于680nm时,量子阱太阳能电池的外量子效率低于普通太阳能电池;而当波长大于于680nm时,量子阱太阳能电池的外量子效率高于普通太阳能电池.对这个现象给出了解释,并对用量子阱太阳能电池代替三结电池的中间子电池的可能性进行了讨论.     

量子阱太阳能电池的外量子效率

通过实验比较了砷化镓量子阱太阳能电池与不含量子阱结构的普通砷化镓太阳能电池的外量子效率. 结果表明,量子阱太阳能电池吸收光子的波长从870nm 扩展到了1000nm. 当波长小于680nm时,量子阱太阳能电池的外量子效率低于普通太阳能电池;而当波长大于于680nm时,量子阱太阳能电池的外量子效率高于普通太阳能电池. 对这个现象给出了解释,并对用量子阱太阳能电池代替三结电池的中间子电池的可能性进行了讨论.     

利用PtOEP掺杂改善Spiro发光器件的发光效率

为了利用有机三线态发光提高有机发光器件的发光效率,用磷光材料掺杂到聚合物主体中作为发光层,制备有机电致发光器件.在测量器件的电流-电压特性、发光亮度-电压特性和电致发光谱的基础上,计算了器件的外量子效率,研究了磷光材料的掺杂浓度对器件发光效率的影响.结果表明,对特定的材料体系,适当控制掺杂浓度,可以同时观察到荧光和磷光光谱,使掺杂器件的外量子效率在纯聚合物发光器件的基础上得到明显提高.     

利用PtOEP掺杂改善Spiro发光器件的发光效率

为了利用有机三线态发光提高有机发光器件的发光效率,用磷光材料掺杂到聚合物主体中作为发光层,制备有机电致发光器件.在测量器件的电流-电压特性、发光亮度-电压特性和电致发光谱的基础上,计算了器件的外量子效率,研究了磷光材料的掺杂浓度对器件发光效率的影响.结果表明,对特定的材料体系,适当控制掺杂浓度,可以同时观察到荧光和磷光光谱,使掺杂器件的外量子效率在纯聚合物发光器件的基础上得到明显提高.     

GaAs量子阱太阳能电池转换效率的计算

采用细致平衡模型计算了GaAs量子阱太阳能电池的转换效率,同时对量子阱结构带来的几种效应,如准费米能级分离、热载流子效应等进行了分析,并将碰撞离化效应引入此细致平衡模型中,通过计算研究了其对量子阱太阳能电池转换效率的影响.结果表明碰撞离化效应可以提高电池的转换效率,但提高幅度有限.     

GaAs量子阱太阳能电池转换效率的计算

采用细致平衡模型计算了GaAs量子阱太阳能电池的转换效率,同时对量子阱结构带来的几种效应,如准费米能级分离、热载流子效应等进行了分析,并将碰撞离化效应引入此细致平衡模型中,通过计算研究了其对量子阱太阳能电池转换效率的影响.结果表明碰撞离化效应可以提高电池的转换效率,但提高幅度有限.     

微光光照强度下太阳电池应用研究

在太阳电池标准测试条件之外,定义了太阳电池室内测试条件,研究了该条件下的微光光照强度对几种常见太阳电池效率的影响和它们的光谱响应。结合各种太阳电池自身的价格因素和器件性质,得出了一些可供室内光伏产品设计人员参考的结论。     

基于MoO/Au/ZnO中间层的有机叠层太阳能电池

采用宽带隙有机材料PTB7‑Th： PCBM作为前电池,窄带隙有机材料PTB7‑Th： IEICO‑4F作为后电池,MoO/Au/ZnO薄膜作为中间连接层制备叠层电池。在本研究中,利用真空热蒸发和磁控溅射镀膜的方法制备了MoO/Au/ZnO薄膜,不仅具有高透光率,而且有很好的抗溶剂侵蚀性能。此外,为了进一步降低在旋涂后电池活性层时溶液对前电池的侵蚀,采用低沸点的氯仿作为后电池活性层材料的溶剂,并利用动态旋涂成膜的方法,减少溶剂挥发时间。最后获得了效率为9.35%的有机叠层太阳能电池,与单结有机太阳能电池相比,拥有更高的效率,开路电压高达1.4 V。研究表明：MoO/Au/ZnO薄膜在制备叠层太阳能电池中具有很大的优势。     

碲镉汞红外探测器量子效率计算研究

首先分析了量子效率计算的相关方法,然后分析红外碲镉汞探测器测试过程。对器件进行电学性能测试及光谱响应测试基础上,利用测试方法和测试数据计算出探测器产生的电子数。再将实际电子数与理论分析的光子数相比,计算出探测器对不同红外波段量子效率,最高可达66%,达到了国外同类型器件响应的量子效率指标。本文的研究为评价碲镉汞探测器的光电转换性能提供了一种有效的方法。     

Implications of low breakdown voltage of component subcells on external quantum efficiency measurements of multijunction solar cells

The electrical and optical coupling between subcells in a multijunction solar cell affects its external quantum efficiency (EQE) measurement. In this study, we show how a low breakdown voltage of a component subcell impacts the EQE determination of a multijunction solar cell and demands the use of a finely adjusted external voltage bias. The optimum voltage bias for the EQE measurement of a Ge subcell in two different GaInP/GaInAs/Ge triple‐junction solar cells is determined both by sweeping the external voltage bias and by tracing the I–V curve under the same light bias conditions applied during the EQE measurement. It is shown that the I–V curve gives rapid and valuable information about the adequate light and voltage bias needed, and also helps to detect problems associated with non‐ideal I–V curves that might affect the EQE measurement. The results also show that, if a non‐optimum voltage bias is applied, a measurement artifact can result. Only when the problems associated with a non‐ideal I–V curve and/or a low breakdown voltage have been discarded, the measurement artifacts, if any, can be attributed to other effects such as luminescent coupling between subcells. Copyright © 2015 John Wiley & Sons, Ltd.     

宽带和窄带有机光电倍增探测器研究进展

有机光电倍增探测器因具有可大面积加工、柔性、光谱响应范围可调、低成本和轻质等优点而备受关注,在智能监测、通信、生物医疗、图像传感器和荧光显微镜等领域具有潜在的应用价值。根据光谱响应范围,有机光电倍增探测器可分为宽带和窄带有机光电探测器。文章首先详细介绍了有机光电倍增探测器的结构、工作原理及关键性能参数,其次阐述了宽带和窄带有机光电倍增探测器的研究进展,最后对宽带和窄带有机光电倍增探测器未来的发展前景进行了展望。     

高方块电阻发射区单晶硅太阳电池的性能优化

通过提高发射区的方块电阻和优化发射区的磷杂质浓度纵向分布,制备了性能优良的单晶硅太阳电池。I-V测量分析表明:高表面活性磷杂质浓度浅结发射区太阳电池短路电流密度、开路电压和填充因子分别提高了0.32mA/cm2,1.19mV和0.22%,因此转换效率提高了0.22%。内量子效率分析表明:高表面活性磷杂质浓度浅结发射区太阳电池短路电流密度的提高是由于短波光谱响应增强了。SEM分析表明:高表面活性磷杂质浓度浅结发射区太阳电池在发射区硅表面沉积的Ag晶粒分布数量更多、一致性更好,从而更容易收集光生电流传输到Ag栅线,改善了太阳电池的性能。     

The effect of bias light on the spectral responsivity of organic solar cells

The spectral responsivity, S, and the related spectrally resolved photon-to-electron external quantum efficiency, EQE, are standard device characteristics of organic solar cells and can be used to determine the short-circuit current density and power conversion efficiency under standardized test conditions by integrating over the spectral irradiance of the solar emission. However, in organic solar cells S and EQE can change profoundly with light intensity as a result of processes that vary non-linearly with light intensity such as bimolecular recombination of electrons and holes or space charge effects. To determine the S under representative solar light conditions, it is common to use modulated monochromatic light and lock-in detection in combination with simulated solar bias light to bring the cell close to 1 sun equivalent operating conditions. In this paper we demonstrate analytically and experimentally that the S obtained with this method is in fact the differential spectral responsivity, DS, and that the real S and the experimental DS can differ significantly when the solar cells exhibit loss processes that vary non-linearly with light intensity. In these cases the experimental DS will be less than the real S. We propose a new, simple, experimental method to more accurately determine S and EQE under bias illumination. With the new method it is possible to accurately estimate the power conversion efficiency of organic solar cells.     

Numerical simulation of the performance of the a-Si：H/a-SiGe：H/a-SiGe：H tandem solar cell

The computer program AMPS-1D（analysis of microelectronic and photonic structures） has been employed to simulate the performance of the a-Si：H/a-SiGe：H/a-SiGe：H triple-junction solar cell at the radiation of AM1.5G（100 mW/cm2/ and room temperature. Firstly, three sub-cells with band gaps of 1.8, 1.6 and 1.4 eV are simulated, respectively. The simulation results indicate that the density of defect states is an important factor, which affects the open circuit voltage and the filling factor of the solar cell. The two-step current matching method and the control variate method are employed in the simulation. The results show that the best solar cell performance would be achieved when the intrinsic layer thickness from top to bottom is set to be 70, 180 and 220 nm, respectively. We also optimize the tunnel-junction structure of the solar cell reasonably, the simulation results show that the open circuit voltage, filling factor and conversion efficiency are all improved and the S-shape current density–voltage curve disappears during optimizing the tunnel-junction structure. Besides, the diagram of the energy band and the carrier recombination rate are also analyzed. Finally, our simulation data are compared to the experimental data published in other literature. It is demonstrated that the numerical results agree with the experimental ones very well.     

太阳电池减反膜的设计

设计良好的减反膜系,提高太阳电池的光电转换效率是太阳电池研制中的一个重要问题.文章从减反膜理论出发,利用计算机软件模拟分析,获得了单层膜、双层膜系反射率百分比与波长的关系,并给出了具体入射波长(即632.8 nm、800 nm)条件下膜的最佳厚度.采用PC1D软件模拟了覆盖减反膜的单晶硅电池的I-V曲线,证实电池转换效率大大提高.研究结果可应用于太阳电池的设计中.