凝胶固相反应合成法粉体制备技术研究

凝胶固相反应法是一种新型的多组元功能陶瓷粉体合成技术 ,本文对该工艺中凝胶过程的工艺参数、干燥和收缩过程进行了研究 ,并用该工艺合成了铁氧体吸收剂粉体 ,电磁参数测试表明 ,用该工艺制备的铁氧体吸收剂粉体具有良好的性能     

吸波材料电磁参数频率跟踪逼近优化方法

首先介绍了单层吸波材料的吸波机理，然后提出了一种电磁参数频率跟踪逼近优化方法，并用该方法设计了单层吸波材料，得到了电磁参数的最佳配合下的吸波材料的幅频特征。分析讨论了电磁参数的频散效应对吸波材料的吸波性能的影响，得到了同时考虑电磁参数与频率和吸收剂厚度组合匹配是解决吸波材料优化的根本途径的结论。     

多晶铁纤维吸收剂微波复磁导率和复介电常数的理论计算

由麦克斯韦方程出发,导出了多晶铁纤维吸收剂微波复磁导率和复介电常数的理论计算公式;通过对５ＧＨｚ频率点多晶铁纤维吸收剂的数值计算,分析了多晶铁纤维的直径、长径比及电导率等对其电磁参数的影响。     

铁氮化合物吸收剂的制备及其微波吸收特性的研究

采用固气反应法制备铁氮化合物吸收剂,研究了工艺参数对产物组成、微波电磁参数的影响,既而确定产物中形成较高比例Fe4N的条件.结果表明:在360℃,3h反应条件下,产物中Fe4N质量分数最高,为45%;反应时间不变,产物介电常数随反应温度升高而增加,磁导率则相反;反应温度不变,产物磁导率随反应时间的增加而降低;产物经分散处理后制得的吸波材料反射率优于处理前,在11.67GHz处,可达-11.18dB.     

工艺参数对Ni包WC爆炸喷涂涂层组织与耐磨性能的影响

采用不同的爆炸喷涂工艺参数制备了Ni包WC涂层，用扫描电镜观察了不同工艺参数下的涂层组织与磨损面形貌，分析了工艺参数对涂层组织形貌及耐磨性的影响，结果表明，当比值O2／C2H2=2时，可获得致密的涂层，涂层的耐磨性能较高，其它条件下的涂层由于组织较疏松，WC颗粒在滑动摩擦时容易脱落而造成较大的磨损量。     

核壳型铁钴复合材料的制备及其微波吸收性能的研究

采用多元醇还原工艺和自组装技术,通过在微米级Fe粉表面包覆纳米Co粒子,制备了一种具有核壳结构的复合磁性微球,表征了它们的相组成结构,测试了它们的微波电磁参数,研究了它们的微波吸收性能。结果表明：用该法制备的核壳型Fe／Co复合材料能够实现表面包覆致密,将其作为微波吸收剂,可以改善传统羰基铁粉吸收剂的频散特性,可使吸收量大于8dB的频带宽度达到7GHz。     

电刷镀电磁屏蔽涂层制备工艺与性能研究

采用电刷镀方法在环氧树脂表面制备镍铜层状电磁屏蔽复合镀层。分析了工作电压对复合镀层表面形貌、沉积速率、复合镀层与基体的结合力的影响,最后对不同工艺参数下层状复合电磁屏蔽镀层的电磁屏蔽效能进行了测试。结果表明,电刷镀铜的最佳刷镀电压是5V,电刷镀镍的最佳电压是4V,镀笔运动最佳速度为6m/min。在此工艺条件下制备的复合镀层与基体的结合力可达20.44N,电磁屏蔽效能达到74dB以上。     

石英砂物料气流冲击粉碎效果影响因素分析

通过对石英砂物料在不同实验条件下的粉碎结果分析，论述了流化床式超细气流粉碎机工艺参数对产品粒度的影响。     

吸收剂含量对电磁吸收喷墨油墨印刷适性的影响

目的制备性能优异的电磁吸收喷墨油墨,研究电磁吸收剂含量对油墨印刷适性的影响。方法测试吸收剂含量不同时的电磁吸收油墨的粒径、表面张力、粘度、光固化速度,研究电磁吸收剂含量的变化对电磁吸收喷墨油墨印刷适性的影响规律,获得最合适的电磁吸收剂用量。结果当吸收剂质量分数为0.025%,0.05%或0.1%时,油墨粒径在200~300 nm范围内呈现正态分布;当吸收剂质量分数为0.2%时,大部分油墨的粒径超过500 nm,分散性相对较差。随着电磁吸收剂质量分数的增加,油墨表面张力和粘度均呈下降趋势。当吸收剂质量分数为0.025%和0.05%时,油墨表面张力分别为25.76,25.94 m N/m,油墨粘度分别为0.1354,0.1083 Pa·s,均与喷墨3D打印机专用树脂表面张力和粘度接近。此外,该2种油墨光固化过程中的相对反应速率与3D打印机专用树脂也较接近。结论经综合考虑,当吸收剂质量分数为0.05%时的油墨印刷适性和固化速度最佳。     

吸收剂形状对雷达吸波材料性能的影响研究

以片状铁、针状多晶铁纤维、球形羰基铁粉吸收剂为原材料分析探讨了磁性吸收剂形状对其微波电磁参数的影响。结果表明，2GHz时磁导率实部最大的为片状，其次是针状，最小的为球形吸收剂，片状铁吸收剂磁导率实部在2GHz时可达4．65，磁导率虚部2～18GHz均高于多晶铁纤维和羰基铁粉。模拟其吸波性能发现片状铁吸收剂吸波性能在2～9．6GHz优于多晶铁纤维和羰基铁粉，可用于提高吸波材料的低频吸波性能。     

Confining Tiny MoO2 Clusters into Reduced Graphene Oxide for Highly Efficient Low Frequency Microwave Absorption

Herein, a supermolecular‐scale cage‐confinement pyrolysis strategy is proposed to build two dielectric electromagnetic wave absorbents, in which MoO₂ nanoparticles are sandwiched uniformly between porous carbon shells and reduced graphene oxide (RGO). Both sandwich structures are derived from hybrid hydrogels doped by two different crosslinkers (with/without oxygen bridge), which can precisely confine Mo source (e.g., PMo₁₂). Without adding magnetic components, both absorbents exhibit excellent low frequency absorption performance in combination with electrically tunable ability and enhanced reflection loss value, which is superior over other relative 2D dielectric absorbers and satisfies the requirements of portable electronics. Notably, introducing oxygen bridges in the crosslinker generates a more stable confining configuration, which in turn renders its corresponding derivative exhibiting an extra multifrequency electromagnetic wave absorption trait. The intrinsic electromagnetic wave adjustment mechanism of the ternary hybrid absorbent is also explored. The result reveals that the elevated electromagnetic wave absorbing property is attributed to moderate attenuation constant and glorious impendence matching. The cage‐confinement pyrolysis route to fabricate 2D MoO₂‐based dielectric electromagnetic wave absorbents opens a new path for the design of electromagnetic wave absorbents used in multi/low frequency.     

Ni_(1-x)Co_xFe_2O_4铁氧体纳米粉末的磁性能和微波吸收特性

利用柠檬酸溶胶-凝胶自蔓延燃烧法合成了Ni1-xCoxFe2O4(x=0,0.1,0.3,0.5)铁氧体纳米粉末。利用XRD、VSM和矢量网络分析仪测定了粉末样品的晶体结构、磁性能和电磁参数。定性分析了样品的饱和磁化强度、矫顽力、复磁导率和复介电常数随频率和Co含量的变化关系。结果表明,自蔓延的所有粉末样品经过600℃,2h高温退火后均为尖晶石相纳米晶颗粒。随着Co替代量x的增加,样品的自然共振频率先增大后减小,并对微波吸收特性有一定的改善。     

Improving Impact Strength in FSW of Polymeric Nanocomposites Using Stepwise Tool Design

In recent years, many studies have been conducted on process parameters of polymers friction stir welding, while material parameters are still facing serious problems especially in polymeric nanocomposites. In the present study, the impact behavior of friction stir–welded polycarbonate (PC) nanocomposites under different material and process conditions has been investigated using Taguchi approach. A stepwise tool design procedure has been carried out to enhance the welding process. The samples containing various weight percentages of alumina nanoparticles have been welded under different welding process parameters. The analysis of variance results illustrated that nanoalumina content is the most effective parameter on impact strength followed by rotational and transverse speeds. Impact strength of welded samples was conspicuously improved up to 15% by adding 2?wt% of nanoalumina compared with pure PC samples. Also increasing rotational speed and decreasing transverse speed leads to increase of impact strength. In order to optimize the process, signal-to-noise ratio analysis was performed. The results indicated that the optimum levels of input parameters that give the maximum impact strength are as following: 2?wt% of nanoalumina, 2500?rpm of rotational speed, and 8?mm/min of transverse speed which causes 26.14% improvement in impact strength of samples.     

轴向运动导电薄板的磁弹性振动

针对磁场环境中轴向运动导电薄板的磁弹性振动问题进行研究。在给出薄板运动的动能、应变能以及电磁力虚功表达式的基础上,应用哈密顿变分原理,推得磁场中轴向运动矩形薄板的磁弹性振动方程。基于麦克斯威尔电磁场方程并考虑相应的电磁关系式,得到薄板所受电磁力的表达式。针对横向磁场中矩形板的自由振动问题,通过位移函数的设定并应用伽辽金积分法,得到三种边界约束条件下轴向运动薄板的磁弹性振动微分方程。通过数值算例,给出了不同边界条件下矩形板的磁弹性振动特性曲线图,分析了轴向运动速度和磁感应强度等参量对薄板固有振动频率的影响,讨论了临界速度的变化规律。     

Dynamics of solidification and development of morphology of Cu‐base alloys with a metastable miscibility gap in the range of the undercooled melt

The Cu‐Co system shows a metastable miscibility gap in the range of the undercooled melt. In this work the method of electromagnetic levitation (EML) and drop tube experiments have been used to examine the metastable state of Cu‐Co alloys. The experiments show that both methods allow deep undercooling of the melt into the range of the miscibility gap. Due to the deep undercooling the velocity of the solidification front is very high and the actual microstructure is frozen in. The process of demixing can be observed and the binodal has been determined with high precision. The microstructure of samples processed in the electromagnetic levitation shows an influence of the electromagnetic stirring due to the induction of electric currents into the melt. Drop tube experiments, which lead to a rapid solidification under reduced gravity conditions, in contrary result in a homogeneous distribution of spherical particles of the minority phase. For this reason space experiments under microgravity conditions in the TEMPUS facility are under consideration. In these experiments the stirring effect would be greatly reduced compared to the EML.     

硫酸亚铁掺杂聚苯胺的固相合成及其电磁性能研究

采用七水硫酸亚铁与本征态聚苯胺的固相掺杂反应，获得了同时具有导电性和导磁性能的新型结构复合材料。考察了不同的掺杂反应条件对固相合成产物导电率和磁化率的影响，获得了适宜的固相合成条件。通过红外光谱（FT—IR）、现场紫外光谱（in—situ UV—vis）、元素分析、扫描电子显微镜（SEM）等测试手段对合成产物进行了表征，测定了产物的室温电导率、质量磁化率及吸波电磁参数。实验结果表明，通过改变固相掺杂反应条件可以调控产物的电导率和磁化率，所得掺杂产物在2～18GHz微波范围内具有一定的介电损耗和磁损耗。     

Architecture Design and Interface Engineering of Self-assembly VS4/rGO Heterostructures for Ultrathin Absorbent

The employment of microwave absorbents is highly desirable to address the increasing threats of electromagnetic pollution.Importantly,devel-oping ultrathin abso...     

纳米相电磁波吸收剂的研究现状与趋势

讨论了纳米相电磁波吸收剂的结构特点及吸波机理，评述了纳米相电磁波吸收剂的研究及发展情况，并指出了纳米相电磁波吸收剂的发展趋势。     

基于电磁超声的塑性损伤铝材抗拉强度预测

针对电磁超声信号信噪比低这一问题,在利用相对非线性系数预测抗拉强度的同时引入应力三轴度来提升塑性损伤试件抗拉强度预测的准确性.建立了电磁超声非线性检测塑性损伤试件的有限元三维仿真模型,计算两个特征参量:应力三轴度和相对非线性系数,研究试件的内部应力状态特征和电磁超声检测信号的频谱特征.仿真分析结果表明这两个特征参量敏感...     

不同热处理状态铝合金在电磁成形条件下的成形性研究

目的 研究不同热处理状态下多种铝合金在准静态拉伸和电磁单向拉伸条件下的成形性能,并探究其中机理.方法 选择不同牌号(1060,3003,5052)和不同热处理状态(加工硬化态和完全退火态)的铝合金材料,获得材料在准静态和电磁成形条件下材料的成形性能,并通过扫描电镜(SEM)和透射电镜(TEM)对1060铝合金试样进行显微断口和微观组织分析.采用数值仿真方法,获取板料和线圈的最佳相对位置.结果 与退火态材料相比,在电磁成形条件下加工硬化态材料的成形性能提高得更多,特别是在1060铝合金中,退火态试样准静态拉伸的伸长率和动态拉伸的伸长率几乎一致,而H24态试样的动态拉伸伸长率(20.2％)为准静态拉伸(5.1％)的3.96倍.扫描断口发现电磁成形断裂面更窄,韧窝大小更均匀.1060-O试样电磁成形后,晶粒内部位错密度低,微观结构主要为亚晶.1060-H24试样电磁成形后的组织中位错密度较高,出现位错胞.结论 加工硬化态材料中存在的初始缺陷有利于电磁成形过程中位错的产生和交滑移的发生,从而提高合金成形性.