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液化天然气储罐用超低温9Ni钢的研究与应用 总被引:1,自引:0,他引:1
杨秀利刘东风侯利锋崔天燮胡玉亭卫英慧 《钢铁研究学报》2009,21(9):1-1
9Ni钢是我国目前为缓解能源压力,建设液化天然气储罐所必须国产化的重要基础原材料。在本文中,作者较为详细地论述了9Ni钢的成分、组织结构与性能之间的关系,深入分析了该钢低温韧化机制,认为除了回转奥氏体之外可能还有其他重要的控制因素,诸如奥氏体∕铁素体界面结构﹑杂质元素含量等。提出应通过细化晶粒、提高钢的纯净度、添加合金元素等手段来改善9Ni钢的低温韧度,提高屈服强度,实现节约成本的目的。 相似文献
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ZHAO Xi qing PAN Tao WANG Qing feng SU Hang YANG Cai fu YANG Qing xiang 《钢铁研究学报(英文版)》2011,18(5):47-51
Mechanical properties of quenching, intercritical quenching and tempering (QLT) treated steel containing Ni of 9% were evaluated from specimens subject to various tempering temperatures. The detailed microstructures of steel containing Ni of 9% at different tempering temperatures were observed by optical microscope (OM) and transmission electron microscope (TEM). The volume fraction of austenite was estimated by XRD. The results show that high strength and cryogenic toughness of steel containing Ni of 9% are obtained when the tempering temperature are between 540 and 580 ℃. The microstructure keeps the dual phase lamellar structure after the intercritical quenching and there is cementite created in the Ni rich constituents when tempering temperature is 540 ℃. When tempering temperatures are between 560 and 580 ℃, the reversed austenites (γ′) grow up and the dual phase lamellar structure is not clear. The γ′ becomes instable at 600 ℃. When tempered at temperature ranging from 500 to 520 ℃, the increase of dislocation density in the lamellar matrix makes both tensile strength and yield strength decrease. When tempered at 540 ℃ and higher temperature, the yield strength decreases continuously because the C and alloying elements in the matrix are absorbed by the cementite and the γ′, so the yield ratio is decreased by the γ′. There are two toughness mechanisms at different tempering temperatures. One is that the precipitation of cementite absorbs the carbon in the steel which plays a major role in improving cryogenic toughness at lower temperature. Another is that the γ′ and the purified matrix become major role at higher tempering temperature. When the tempering temperature is 600 ℃, the stability of γ′ is decreased quickly, even the transformation takes place at room temperature, which results in a sharp decrease of Charpy V impact energy at 77 K. The tempering temperature range is enlarged by the special distribution of cementite and the lamellar structure. 相似文献
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随着液化天然气(LNG)储罐朝着大型化发展,在不增加容器壁厚的情况下,必须提高钢板强度。在传统9Ni钢中添加Cu,通过析出强化,使其强度水平得到显著提高。提出一种新型含1.25%Cu(质量分数)9Ni钢。试验钢经过控轧直接淬火(DQ);研究了DO材料分别经过1)QLT(奥氏体(γ)单相区淬火(Q)+两相区(α+γ)淬火... 相似文献
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The effect of carbide morphology and matrix structure on abrasion resistance of cast alloyed steel with 2.57% C, 16.2% Cr and 0.78% Mo was studied in the as‐cast and heat treated conditions. Samples were austenitized at three different temperatures of 980, 1050 and 1250 °C for 15 minutes and followed by tempering at 540 °C for 3 hours. The austenitizing temperature of 980 °C revealed fully martensitic structure with little amount of retained austenite, while at 1050 °C the matrix was austenitic with massive amount of coarse secondary carbides. The austenitic matrix with very fine secondary carbides was developed at 1250 °C. The maximum abrasion resistance was obtained at 1050 °C due to the highest structure hardness and existence of both eutectic and secondary carbides in larger size than the formed groove by the abrasive particles during the wear test. On the other hand, the as‐cast pearlitic structure showed high wear rate by an applied load of up to 0.2 bar, followed by very rapid increase in wear rate with higher applied loads. It could be considered that the austenitizing temperature of 1050 °C showed better combination of abrasion resistance and toughness in comparison with other heat treatment cycles. 相似文献
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《钢铁研究学报(英文版)》2011,(Z1):637-640
High strength abrasion resistant steel plates are widely used in mining,construction and agricultural machineries.The plates are,however,usually poor in impact toughness.An attempt is made to improve the impact toughness of HB400 grade abrasion resistant steel by controlling quenching and tempering of the plates.Optimized combination of the strength and the toughness has been achieved by choosing best fit set of quenching and tempering condition.Mechanism underlying the achievement has been investigated in terms of the microstructure consisting of tempered lath martensite,retained austenite and precipitated carbides. 相似文献
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一种高强双相不锈钢活塞杆在加工完成后的存放过程中开裂。实验通过金相显微镜、扫描电子显微镜(SEM)、拉伸试验机、冲击试验机、硬度仪等手段,对其开裂原因进行了分析。结果表明:活塞杆横向和纵向强度均较高,纵向抗拉强度最高达1 145 MPa;布氏硬度为HBW347,高于设计要求(HBW241-285)上限21.8%;但横向韧性较低,断后伸长率最低2.0%,仅为标准要求下限值14%的14.3%,平均冲击吸收能量只有5.8 J,仅为标准规范下限值60 J的10.5%。活塞杆材料合金元素符合标准要求,活塞杆组织为回火马氏体+细条带状铁素体,但氢含量达5.4×10-6(质量分数),高的氢含量导致在内部形成氢致延迟微裂纹是其纵向开裂的主要原因,条带状铁素体恶化了活塞杆的横向力学性能,对开裂起一定的促进作用。建议优化冶炼和热加工工艺,与此同时在活塞杆加工之前增加去氢退火,降低原材料中氢含量,以最大程度降低氢致延迟开裂倾向。 相似文献
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研制9%Ni钢焊条的难点在于满足熔敷金属强度和塑性指标的前提下提高其低温韧性。本文在9%Ni钢焊条熔敷金属力学性能分析的基础上,采用彩色金相分析、扫描电镜分析、X射线衍射分析技术研究了Nb对9%Ni钢焊条熔敷金属组织和性能的影响。试验结果表明,熔敷金属中Nb的加入,形成了共格有序的金属间化合物γ'相(Ni3Nb)作为强化相,使熔敷金属得到有效的强化,但当Nb含量过高时,会形成是脆性的金属间化合物Laves相,导致熔敷金属低温韧性下降。Nb含量较低时,随着Nb含量的增加,熔敷金属强度和塑性显著提高,同时低温韧性下降很少。当Nb含量达到3.5(wt%)时,熔敷金属的强度和塑性继续提高,但低温韧性指标明显下降。 相似文献