"胶乳法"氯化天然橡胶薄层干燥影响因素的研究

采用二次回归正交设计方法,对“胶乳法“氯化天然橡胶(CNR)进行薄层干燥试验.分析了热风温度、风速和物料的粒径等因素对干燥速率、干燥后物料性能的影响规律,确定了影响物料薄层干燥速率各因素的主次,提出了较佳的干燥工艺和合理的性能参数.     

干燥工艺参数对颗粒状氯化天然橡胶干燥过程的影响

通过氯化天然橡胶的穿透干燥试验,探讨风温、风速以及粒径对CNR干燥速率的影响规律,通过对数据正交分析,寻找最佳干燥工况及参数,揭示影响干燥速率的规律。     

胶乳法氯化天然橡胶干燥历程中脱氯化氢反应动力学

新型工艺胶乳法氯化天然橡胶(CNR)产品在干燥过程中会有HCl脱出,其脱出量对CNR的制备、性能等有一定的影响。采用电导法可连续测定CNR在干燥历程中脱HCl量及速率,这是研究CNR在低温下热降解行为的有效方法。用改进工艺的"胶乳法"制备出湿的CNR,并在一定温度下通入氮气进行干燥,在此历程中会发生脱氯化氢反应,其反应过程可分为诱导期、恒速期和低速期。文中使用Friedman法分析该过程在恒速期、低速期的反应动力学参数,其脱氯化氢反应分别为0级反应、1级反应,活化能分别为26.65,36.79 kJ/mol。在80℃以下对产品进行加热(或干燥),虽有少量HCl脱出,但并不会对产品质量造成影响。所以干燥温度应以低于80℃为宜。     

纳米氧化锌对天然胶乳膜干燥及硫化性能影响研究

采用失重法和溶胀法研究了普通氧化锌和纳米氧化锌活化的天然胶乳膜的干燥动力学,以及干燥过程中胶乳膜交联密度变化.结果表明:天然胶乳厚胶膜在成膜后仍含有大量水分并且去除困难.纳米氧化锌活化胶膜的干燥速率明显高于普通氧化锌胶膜.干燥温度对干燥过程影响显著,干燥时间随干燥温度升高明显降低.随着干燥的进行,2种氧化锌活化的胶乳膜的交联密度均迅速上升,在相同条件下,纳米氧化锌活化胶乳膜交联密度均比普通氧化锌的大.纳米氧化锌对天然胶乳膜的干燥及硫化过程均有促进作用.     

酸、碱及盐对胶乳法氯化天然橡胶热稳定性的影响

采用热老化实验结合紫外光谱分析和热分析，分析了酸、碱及盐对胶乳法氯化天然橡胶(CNR)热稳定性的影响，并讨论了酸、碱及盐对CNR热降解的影响机理。研究结果表明：胶乳法CNR产品中含有酸、碱、盐时，对CNR的结构有不利的影响，其影响随含量增高而增大，其中又以碱对结构的不利影响最大。因此，在胶乳法生产CNR的生产工艺中，最后的酸碱中和、洗涤2道工序必须严格控制工艺条件，保证半成品的pH值和含盐量达到标准。     

胶乳法氯化天然橡胶溶胶和凝胶的分析

采用化学分析方法、高分辨裂解气相色谱－质谱、傅立叶红外光谱结合热分析技术对胶乳法氯化天然橡胶（CNR）中所含的溶胶和凝胶成分进行了分析。结果表明：胶乳法CNR中所含的凝胶成分主要为CNR分子的分子间交联物，具有与溶胶成分相似的氯化结构，氯含量较同等氯化程度的线性CNR稍低；胶乳法CNR中的凝胶成分的热稳定性及热氧稳定性较溶胶成分差，对胶乳法CNR的热稳定性及热氧稳定性会产生不利的影响。     

天然胶乳厚胶膜热风干燥与红外干燥对比研究

采用失重法研究了天然胶乳厚胶膜在热风与红外线两种干燥方式下的干燥过程。研究结果表明,在相同条件下,红外干燥的干燥速率常数远大于热风干燥,采用红外干燥可大大缩短干燥时间,干燥温度和厚度均显著影响干燥过程,红外干燥对温度更敏感。通过动力学拟合结果,得到了干燥动力学方程,可以预测干燥时间。     

明胶热风干燥特性的实验研究

采用静态法研究了明胶的平衡含湿质量分数,得到了20℃下吸湿和解吸等温线,结果表明,当空气相对湿度在16%—39%,存在吸湿滞后现象。在对流干燥实验台上进行了明胶干燥特性的实验,以不同厚度的明胶块为实验对象研究了热风温度、风速、湿度对干燥过程的影响。实验结果表明:明胶的干燥过程只有降速阶段,提高热风温度、加大风速均可以在前期提高干燥速率,但在干燥后期干燥速率反而降低;明胶块中心温度受胶块厚度、热风温度影响较大,而在实验范围内空气相对湿度的变化对明胶中心温度影响甚微;明胶的相对含湿质量分数随时间呈指数规律下降,提高风温、加大风速后明胶含湿质量分数在开始阶段下降较快,但最终含湿质量分数反而偏高。     

新型“胶乳法”氯化天然橡胶的研制

采用新型的"胶乳法"工艺制备氯化天然橡胶(CNR),不仅相对于传统的"溶液法"具有污染少、工艺简单、投资小、成本低等突出优点,而且解决了原"胶乳法"氯化过程橡胶分子交联严重的问题,是CNR的发展方向。介绍了该方法的反应机理、工艺流程、反应历程以及影响氯化反应的因素。研究结果表明:对现行工艺下低浓度胶乳法的氯化反应,可采用经验式预测不同相对反应时间的含氯量。根据氯含量随相对时间的变化规律,可以把反应过程分为2个阶段:高速期和低速期。在CNR氯化反应的第2阶段,反应温度的升高有利于氯含量提高,但温度过高,能量耗费过大,加上要考虑到反应的宏观动力学等因素,CNR氯化的第2阶段反应温度以343.15~353.15 K为宜。第2阶段表面活性剂平平加O的质量分数大于3%,天然胶乳的质量分数小于1%时,引发剂质量分数以0.5%~1%为宜。     

颗粒状氯化天然橡胶穿透式干燥动力学模型

本试验通过氯化天然橡胶的薄层干燥试验,探讨风温、风速以及粒径对CNR含水量的影响规律,建立薄层干燥方程。试验结果表明,预测值与实测值一致性较好,所建数学模型可用于描述氯化天然橡胶的薄层干燥。     

生物质型煤热风干燥特性及模型研究

为降低生物质型煤干燥成本,提高干燥效率,研究热风干燥风速和温度对热风干燥特性的影响,拟合了生物质型煤在不同热风干燥条件下水分随时间变化的模拟曲线。结果表明:生物质型煤与多数多孔介质类似,干燥过程可分为加速干燥、恒速干燥、降速干燥3个阶段,其中恒速干燥阶段的干燥时间约25 min;热风温度越高,风速越大,生物质型煤的干燥速率越大,干燥时间越短,干燥时的裂纹率也越高。当干燥温度180℃,风速1.2 m/s时,生物质型煤热风干燥效果较好,干燥热效率最高为48.34%。通过对不同温度、风速条件下的生物质型煤干燥试验数据与常用干燥模型进行拟合分析,发现Sabbet干燥模型拟合度最好,当干燥温度180℃,风速1.2 m/s时相关性系数为0.997,二者相关性显著,因此Sabbet干燥模型可较好地反映生物质型煤在不同温度、风速下的干燥特性。     

Optimization study of soybean intermittent drying in fixed-bed drying technology

Intermittent drying of materials is an alternative operation that aims at reducing energy consumption, improve the preservation of dried products or decrease effective drying time. Intermittent drying supplies the system with time-varying input air properties that are opposite to traditional operations, where air properties are constant at the dryer inlet. The major objective of this study is to establish the most satisfactory patterns of air temperature and velocity modulation at the dryer entrance to reduce energy consumption. This optimization study was based on a heterogeneous model for the drying of grains in fixed bed validated with experimental data. Intermittent and conventional operation experiments were conducted using equal energy consumption, and the influence of air temperature and velocity modulation on the drying rates related to the percentage of evaporated water were assessed. Results indicated that higher drying rates can be achieved under intermittent operation, and the validated model based on these results could reasonably predict temperature and moisture content profiles. Simulations pointed out that the best modulation patterns of air properties is a function of a variety of system conditions such as initial temperature and moisture content of both soybean and drying air. However, a tendency to reduce energy consumption was observed when the system operation is initially at high temperature and constantly at low velocity.     

Drying Kinetics of Oil Palm Frond Particles in an Agitated Fluidized Bed Dryer

The drying kinetics of oil palm frond particles in a laboratory-scale agitated fluidized bed dryer were investigated under various operating conditions: inlet air temperature (50–80°C), superficial air velocity (0.6–1.0 m/s), bed load (200–300 g), and agitation speed (300–500 rpm). To study the effects of these variables on the drying time and drying rate, an experimental design using Taguchi orthogonal array was employed. Based on analysis of variance (ANOVA), the results indicated that inlet air temperature greatly affected the drying rate, followed by superficial air velocity and bed load. The effect of agitation speed on the drying rate was found to be small. The experimental drying kinetics data were compared with the values obtained from three different models, namely, the Page model, modified quasi-stationary method (MQSM), and a new composite model. It was found that the proposed new model could satisfactorily predict the complete drying rate curve for the drying of oil palm fronds.     

膏糊状物料气流对流干燥试验研究

以分子筛滤饼作被干燥物料,模拟带式干燥机进行了干燥试验研究。考察了气流速度、温度以及干燥时间对物料干燥效果的影响,并与烘箱干燥试验数据进行对比。结果表明:气流速度越高,干燥温度越高,干燥后物料的水分含量越低;带式气流干燥机干燥时间短,处理量大,可以连续操作,干燥效果明显优于箱式干燥器,可以作为膏糊状物料的干燥设备。     

精对苯二甲酸干燥动力学模型

分析了精对苯二甲酸(PTA)干燥过程中干燥温度,物料初始含湿量,空气流速对干燥速率的影响。结果表明:PTA干燥过程由预热阶段、恒速阶段和降速阶段组成,临界含湿量为5%。随着干燥温度或初始含湿量的升高,干燥速率升高,随着载气流量的升高,干燥速率变化不明显。干燥温度对干燥速率的影响最为显著。通过模型比较得出合适的PTA干燥模型为Page模型,模型计算值与实验值吻合较好。     

Measurement of constant drying rate of wet material placed in a fluidized bed of inert particles under reduced pressure

The objective of this study is to estimate the drying characteristics of a relatively large material immersed in a fluidized bed under reduced pressure by measuring the constant drying rate. The constant drying-rate period in a fluidized bed under reduced pressure is difficult to measure because it is extremely short. To maintain the constant drying-rate period, distilled water is directly supplied to the drying material. Through our experiment, the heat transfer coefficient of the material surface was also determined. The results were compared with data on hot air drying. The constant drying rate is higher for fluidized bed drying than for hot air drying. It suggests that the heat transfer coefficient on the surface of the drying material is much larger for fluidized bed drying than for hot air drying. For fluidized bed drying, the effect of pressure in the drying chamber on the heat transfer coefficient is slight at the same normalized mass velocity of dry air (G/G_mf). The temperature difference between the inside of the drying chamber and the drying material is much smaller for fluidized bed drying than for hot air drying. The constant drying rate increases as the pressure in the drying chamber decreases.