The Oxidation Behavior of Ni–15Cr–5Al–xSi (x = 0, 1, 3, 5 wt%) Alloys in Air at 1100 °C

Oxidation of Metals - In order to explore effect of silicon on the oxidation resistance of Ni-based superalloys, the cyclic oxidation behavior of Ni–15Cr–5Al–xSi...     

The Effect of Sulfur Segregation on the Adherence of the Thermally-Grown Oxide on NiAl—II: The Oxidation Behavior at 900°C of Standard,Desulfurized or Sulfur-Doped NiAl(001) Single-Crystals

In Part II of this study, the characterization by TGA, SEM and AFM of the oxidation behavior at 900°C of NiAl(001) samples with various sulfur concentrations is reported. The formation of interfacial cavities is observed for all samples. A constant ratio of the oxide thickness to cavity depth is found showing that the formation of cavities at the metal–oxide interface is not due to sulfur but only to vacancy injection during the cationic growth of transient -alumina. It is also observed that the presence of sulfur in the alloy decreases the oxidation rate of the nickel aluminide and, consequently, lowers the formation of interfacial cavities. This effect is interpreted as an indirect evidence of the control of the transient-alumina growth by the aluminium diffusion in the alloy, also advanced as an explanation for the interfacial nucleation of alpha alumina. These results are combined with those presented in Part I to propose a model that explains how sulfur, present in small quantities in the alloy, has a deleterious effect on the oxide adherence. The indirect role of the cavities formed during the growth of the transient alumina is to create transitory conditions for the rapid segregation of sulfur at the interface. The segregated sulfur remains as a vestige of the initial stages of growth after the transformation of the scale into mature alumina and weakens its adherence.     

Precipitation of the icosahedral phase in amorphous Zr65Cu17.5−xAl7.5Ni10Agx (x=0,2.5, 5, 7.5 and 10) alloys

An amorphous phase in Zr₆₅Al_7.5Cu_17.5Ni₁₀ crystallizes via co-precipitation of the I-phase and NiZr₂ phase in the first crystallization step, followed by decomposition of the I-phase into the CuZr₂ and NiZr₂ phases. The NiZr₂ phase transforms to a stable Zr₆NiAl₂ phase at a high temperature. The alloys containing Ag crystallize via a two-step process: firstly, the I-phase nucleates homogeneously and grows in an amorphous matrix; secondly, the quasicrystal and remaining amorphous phase transforms into the stable CuZr₂ and Zr₆NiAl₂ phases. With increasing Ag, the I-phase becomes more thermally stable and the grain size in the I-phase decreases due to increased frequency of homogeneous nucleation. The quasi-lattice constant of the I-phase decreases with increasing Ag content. This article is based on a presentation made in the “Symposium on Metastable Phases”, held at Korea Institute of Science and Technology, Seoul, Korea, November 10, 2000 sponsored by The Korean Institute of Metals and Materials.     

The Accumulation and Annealing of Radiation-Induced Defects and the Effect of Hydrogen on the Physicomechanical Properties of the V−4Ti−4Cr and V−10Ti−5Cr Vanadium-Based Alloys under Low-Temperature (at 77 K) Neutron Irradiation

The processes of the accumulation and annealing of radiation-induced defects that occur under low-temperature (at 77 K) irradiation (with an energy E > 0.1 MeV) of V?4Ti?4Cr and V?10Ti?5Cr bcc alloys both nonmodified and modified with hydrogen isotopes in a concentration of 200 ppm, as well as the effect of these processes on the physicomechanical properties of these alloys, have been studied. It has been found that the saturation of these alloys with hydrogen leads to slight changes in their strength and ductility characteristics. The irradiation of the alloys at the temperature of 77 K results in a substantial increase in their yield stress and ultimate strength, as well as a decrease in their ductility. In the course of the postradiation annealing of the alloys at a temperature of 130 K, the stage related to the migration of interstitial atoms is observed. At temperatures of 290–320 K, the recovery stage occurs due to the formation of vacancy clusters. The stage that occurs at a temperature of 470 K can be attributed to the formation of impurity-vacancy clusters. Possible mechanisms of the radiation-induced strengthening of the alloys during irradiation and subsequent annealing have been discussed.     

On calorimetric study of the fragility in bulk metallic glasses with low glass transition temperature: (Ce0.72Cu0.28)90−x Al10Fex (x = 0, 5 or 10) and Zn38Mg12Ca32Yb18

Compared with conventional bulk metallic glasses, Ce-based and Zn-based bulk metallic glasses have received considerable attention because of their possible application as structural and functional materials. Kinetic fragility parameter m in amorphous material presents degree of deviations from the Arrhenius law above the glass transition temperature (T_g) of the material. Kinetic fragility parameter (m) and Kauzmann temperature (T_K) in (Ce_0.72Cu_0.28)_90?x Al₁₀Fe_x (x = 0, 5 or 10) and Zn₃₈Mg₁₂Ca₃₂Yb₁₈ bulk metallic glasses have been determined by differential scanning calorimetry (DSC). Results show that Zn₃₈Mg₁₂Ca₃₂Yb₁₈ presents a higher m than (Ce_0.72Cu_0.28)_90?x Al₁₀Fe_x (x = 0, 5 or 10). The activation energies E_g for glass transition are 1.51 eV (x = 0), 1.59 eV (x = 5) and 1.83 eV (x = 10) in (Ce_0.72Cu_0.28)_90?x Al₁₀Fe_x (x = 0, 5 or 10), and 3.59 eV in Zn₃₈Mg₁₂Ca₃₂Yb₁₈, respectively. The values of E_g increase with increasing the Fe content in (Ce_0.72Cu_0.28)_90?x Al₁₀Fe_x (x = 0, 5 or 10) bulk metallic glasses. Kinetic fragility parameter m of bulk metallic glasses increases with the glass transition temperature T_g of bulk metallic glasses, in agreement with previous investigations.     

Effect of Si and Y<Subscript>2</Subscript>O<Subscript>3</Subscript> Additions on the Oxidation Behavior of Ni–<Emphasis Type="Italic">x</Emphasis>Al (<Emphasis Type="Italic">x</Emphasis> = 5 or 10 wt%) Alloys at 1150 °C

The effect of Si and Y₂O₃ additions on the oxidation behavior of Ni–xAl (x = 5 or 10 wt%) alloys at 1150 °C was studied. The addition of Y₂O₃ accelerates oxidation rate of alloys, especially growth rate of NiO, but improves adherence of the scale to the substrate. The addition of Si facilitates the selective oxidation of Al, suppresses the formation of NiO and therefore reduces the critical Al content to form continuous layer of alumina scale. Higher Al content decreases the oxidation rate of alloys in binary Ni–Al alloys and increases the oxidation rate of alloys in ternary Ni–Al–Si alloys. The effect of third-element Si is more significant and beneficial than that of Al content in ternary Ni–Al–Si alloys.