Natural versus wastewater derived dissolved organic carbon: implications for the environmental fate of organic micropollutants

The interaction of organic micropollutants with dissolved organic carbon (DOC) can influence their transport, degradation and bioavailability. While this has been well established for natural organic carbon, very little is known regarding the influence of DOC on the fate of micropollutants during wastewater treatment and water recycling. Dissolved organic carbon-water partition coefficients (K_DOC) for wastewater derived and reference DOC were measured for a range of micropollutants using a depletion method with polydimethylsiloxane disks. For micropollutants with an octanol-water partition coefficient (log K_OW) greater than 4 there was a significant difference in K_DOC between reference and wastewater derived DOC, with partitioning to wastewater derived DOC over 1000 times lower for the most hydrophobic micropollutants. The interaction of nonylphenol with wastewater derived DOC from different stages of a wastewater and advanced water treatment train was studied, but little difference in K_DOC was observed. Organic carbon characterisation revealed that reference and wastewater derived DOC had very different properties due to their different origins. Consequently, the reduced sorption capacity of wastewater derived DOC may be related to their microbial origin which led to reduced aromaticity and lower molecular weight. This study suggests that for hydrophobic micropollutants (log K_OW > 4) a higher concentration of freely dissolved and thus bioavailable micropollutants is expected in the presence of wastewater derived DOC than predicted using K_DOC values quantified using reference DOC. The implication is that naturally derived DOC may not be an appropriate surrogate for wastewater derived DOC as a matrix for assessing the fate of micropollutants in engineered systems.     

Assessing the aggregation behaviour of iron oxide nanoparticles under relevant environmental conditions using a multi-method approach

Iron nanoparticles are becoming increasingly popular for the treatment of contaminated soil and groundwater; however, their mobility and reactivity in subsurface environments are significantly affected by their tendency to aggregate. Assessing their stability under environmental conditions is crucial for determining their environmental fate. A multi-method approach (including different size-measurement techniques and the DLVO theory) was used to thoroughly characterise the behaviour of iron oxide nanoparticles (Fe₂O₃NPs) under environmentally relevant conditions. Although recent studies have demonstrated the importance of using a multi-method approach when characterising nanoparticles, the majority of current studies continue to use a single-method approach.Under some soil conditions (i.e. pH 7, 10 mM NaCl and 2 mM CaCl₂) and increasing particle concentration, Fe₂O₃NPs underwent extensive aggregation to form large aggregates (>1 μm). Coating the nanoparticles with dissolved organic matter (DOM) was investigated as an alternative “green” solution to overcoming the aggregation issue instead of using the more commonly proposed polyelectrolytes. At high concentrations, DOM effectively covered the surface of the Fe₂O₃NPs, thereby conferring negative surface charge on the particles across a wide range of pH values. This provided electrostatic stabilisation and considerably reduced the particle aggregation effect. DOM-coated Fe₂O₃NPs also proved to be more stable under high ionic strength conditions. The presence of CaCl₂, however, even at low concentrations, induced the aggregation of DOM-coated Fe₂O₃NPs, mainly via charge neutralisation and bridging. This has significant implications in regards to the reactivity and fate of these materials in the environment.     

Interactions of diuron with dissolved organic matter from organic amendments

Diuron is frequently detected in some drinking water reservoirs under the Burgundy vineyards, where organic amendments are applied. The environmental effect of these amendments on pesticide transport is ambiguous: on the one hand it could enhance their retention by increasing soil organic carbon content; on the other hand, dissolved organic matter (DOM) could facilitate their transport. Elutions were performed using columns packed with glass beads in order to investigate DOM-diuron interactions, and the possible co-transport of diuron and DOM. Four organic amendments (A, B, C and D) were tested; C and D were sampled at fresh (F) and mature (M) stages. An increase in diuron leaching was observed only for A and D_F amendments (up to 16% compared to the DOM-free blank samples), suggesting a DOM effect on diuron transport. These results could be explained by the higher DOM leaching for A and D_F compared to B, C_F, C_M and D_M increasing diuron-DOM interactions. These interactions seem to be related to the aromatic and aliphatic content of the DOM, determining formation of hydrogen and non-covalent bonds. The degree of organic matter maturity does not seem to have any effect with amendment C, while a reduction in diuron leaching is observed between D_F and D_M. After equilibrium dialysis measurement of diuron-DOM complexes, it appeared that less than 3% of the diuron applied corresponded to complexes with a molecular weight > 1000 Da. Complexes < 1000 Da could also take part in this facilitated transport.     

Alginate fibers as photocatalyst immobilizing agents applied in hybrid photocatalytic/ultrafiltration water treatment processes

Ca alginate polymer fibers were developed to effectively disperse and stabilize an efficient photocatalyst such as AEROXIDE^® TiO₂ P25 in their matrix. The biopolymer/TiO₂ fibers were prepared and tested either in the hydrogel non-porous form or in the highly porous aerogel form prepared by sc-CO₂ drying. Batch photocatalytic experiments showed that the porous, Ca alginate/TiO₂ fibers, exhibited high efficiency for the removal of methyl orange (MO) from polluted water. In addition, their high porosity and surface area led to high MO degradation rate which was faster than that observed not only for their non-porous analogs but also of the bulk P25 TiO₂ powder. Specifically, 90% removal for 20 μM MO was achieved within 220 min for the porous sc-CO₂ dried fibers while for their non-porous analogs at 325 min. The corresponding value (at 60 μM MO) for the porous sc-CO₂ dried fibers was 140 min over 240 min for the AEROXIDE^® TiO₂ P25 as documented in the literature. Furthermore the composite alginate/photocatalyst porous fibers were combined with TiO₂ membranes in a continuous flow, hybrid photocatalytic/ultrafiltration water treatment process that led to a three fold enhancement of the MO removal efficiency at 400 ml of 20 μM MO total treated volume and to dilution rather than condensation in the membrane retentate as commonly observed in filtration processes. Furthermore the permeability of the photocatalytic membrane was enhanced in the presence of the fibers by almost 20%. This performance is achieved with 26 cm² and 31 cm² of membrane and stabilized photocatalyst surfaces respectively and in this context there is plenty of room for the up-scaling of both membranes and fibers and the achievement of much higher water yields since the methods applied for the development of the involved materials (CVD and dry-wet phase inversion in a spinning set-up) are easily up-scalable and are not expected to add significant cost to the proposed water treatment process.     

Strategic planning practice of construction firms in Ghana

In Ghana, the operating environment for construction firms is constantly changing in the face of a volatile economic environment, shifting political climate and a highly competitive market. Confronted with such instability, companies need strategic planning to combat the threat to their survival. A survey was conducted to determine how widespread strategic planning is used as a management tool by contractors in Ghana. Construction firms with classification A₁B₁, A₂B₂, D₁ and D₂ were used in the survey. Only 8.5% of D₂ firms use strategic planning. The other firms have a combined average of 86.7%. Civil engineering contractors are far ahead of the building contractors in the practice of strategic planning. Strategic plans are drawn to cover an average of three years. There is an urgent need for contractors in the D₂ class to be encouraged to seek insight into strategic planning and employ the technique to enhance their chances of surviving risks in the business environment.     

Bewehren mit vorgespannten Betonstäben – Neue Chancen für ein vergessenes Bewehrungskonzept

Reinforcing with prestressed concrete bars. Nearly a half century ago, experiments with prestressed concrete lathes were abandoned because of the loss of their linearity as a consequence of even smallest excentricities of the prestressing force. Meanwhile, the prestress as well as the formwork technology made great progresses regarding their accuracy and make now reinforcing with prestressed concrete bars interesting again. Their advantages are based on their high tension stiffness, which surpass that of steel ten to thirty times (E_sb = 10…33 · E_s). That results in a spectacular bending stiffness which doesn't decrease by shrinkiage and creep (S'C). The consequence is a large pressure range in the cross‐section similar to a partially prestressed cross‐section. Fifteen years ago, the author favoured the application of prestressed bars in AAC [1], which would also make every protection against corrosion dispensable. Indeed, the statical advantages of cross‐sections reinforced with prestressed concrete bars are for the first time explained in the present article, which also develops the design fundamentals.     

Electrochemical degradation of chlortetracycline using N-doped Ti/TiO2 photoanode under sunlight irradiations

The appearance and the persistence of pharmaceutical products in the aquatic environment urgently call for the development of an innovative and practical water treatment technology. This study deals with the development of nanostructured nitrogen-doped TiO₂ photoanodes and their subsequent use for chlortetracycline (CTC) photoelectrocatalytic oxidation under visible light. The N-doped TiO₂ photoanodes with different nitrogen contents were prepared by means of a radiofrequency magnetron sputtering (RF-MS) process, with the objective to tune shift their optical absorption from the UV towards the visible. The N-doped TiO₂ consist of nanostructured anatase phase with average TiO₂ nanocrystallite size of 29 nm. The nitrogen doping is clearly shown to produce the desired red shift of the absorption onset of the TiO₂ coatings (from ∼380 nm to ∼550 nm). Likewise, the N-doped TiO₂ are found to be highly photo-electroactive not only under the UV light but most interestingly under the visible light as well. Using the optimal N-doped photoanodes, 99.6% of CTC (100 μg/L) was successfully degraded after 180 min of treatment time with a current intensity of 0.6 A. Under these conditions, a relatively high mineralization of CTC (92.5% ± 0.26% of TOC removal and 90.3% ± 1.1% of TN removal) was achieved.     

Preserving Shipboard AFFF Fire Protection System Performance While Preventing Hydrogen Sulfide Formation

There is a very serious problem aboard US Navy ships from generation of toxic hydrogen sulfide (H₂S) in Aqueous Film-Forming Foam (AFFF) solutions used for shipboard fire protection. This is the result of the action of sulfate reducing bacteria (SRB) in mixtures of seawater and AFFF, which remain stagnant for significant time periods in shipboard fire protection system piping. Similar to microbial generation of H₂S in sewage, over time microbes present in seawater consume organic materials in the AFFF mixture and can deplete the dissolved oxygen. If the reduction-oxidation potential falls low enough, anaerobic action of the SRB on the sulfate present in seawater can then result in H₂S generation, reaching dangerous levels. The recommended ceiling for exposure to H₂S is only 10 ppm. If the microbes causing oxygen depletion and/or the SRB can be eliminated (or sufficiently minimized), the dangerous generation of H₂S would not occur. The Navy Technology Center for Safety and Survivability is participating in a research project for the Naval Sea Systems Command (NAVSEA) to evaluate several treatment modalities for their ability to inhibit H₂S formation in AFFF/seawater mixtures and for possible deleterious effects on AFFF performance. Various approaches have been considered employing laboratory evaluations (dynamic surface tension and Ross-Miles foamability), and 28 ft² (2.6 m²) pool fire extinguishment and burnback protection field tests (Military Standard MIL-F-24385F). The protocol selected for NAVSEA shipboard H₂S generation mitigation testing is a combination of a commercial broad-spectrum biocide with a molybdenum compound which is a specific inhibitor of SRB.     

Real‐time transformation of outdoor aerosol components upon transport indoors measured with aerosol mass spectrometry

Outdoor aerosols are transported indoors, where their component concentrations depend on aerosol size, physiochemical properties, indoor sources and losses, and cross‐environment gradients of temperature and relative humidity. We explored these dependencies by measuring real‐time outdoor and indoor non‐refractory, submicron (PM₁) aerosol component mass concentrations in a mixed‐use laboratory space with an Aerodyne mini‐aerosol mass spectrometer (AMS) and black carbon (BC) with an aethalometer. The median indoor/outdoor (I/O) ratios were 0.60 for sulfate, 0.25 for nitrate, 0.52 for ammonium, 0.73 for organics, and 0.61 for BC. Positive matrix factorization (PMF) on organic aerosol data identified hydrocarbon‐like (HOA), cooking (COA), and oxygenated (OOA) factors. By assuming sulfate was nonvolatile, lost only by mechanical processes, and without indoor sources, the transformations of other components i due to partitioning changes or indoor sources were parameterized by normalizing their I/O ratios by sulfate's I/O ratio, that is, (I/O)_i/SO4. Component‐specific behavior was quantified by regressions of (I/O)_i/SO4 to outdoor‐to‐indoor temperature differences. Nitrate and HOA strongly and OOA weakly showed losses with increasing temperatures indoors vs. outdoors, and HOA likely had an indoor source. To our knowledge, this is the first reported deployment of an AMS to analyze real‐time indoor aerosol composition and outdoor‐to‐indoor transformation.     

Imaging of engineered nanoparticles and their aggregates under fully liquid conditions in environmental matrices

The increasing industrial production of engineered nanoparticles (ENPs) raises concern over their safety to humans and the environment. There is a lack of knowledge regarding the environmental fate and impact of ENPs and in situ methods are needed to investigate e.g. nanoparticle aggregation and adsorption in the media of concern such as water, sediment and soil. In this study, the application of wet scanning electron microscopy (WetSEM™) technology in combination with energy dispersive x-ray spectroscopy (EDS) to visualise and elementally identify metal and metal oxide nanoparticles (Au, TiO₂, ZnO and Fe₂O₃) under fully liquid conditions in distilled and lake water as well as in a soil suspension has been investigated. WetSEM™ capsules comprise an electron transparent membrane enabling the imaging and EDS analysis of liquid samples. Results are compared with conventional SEM images and show that WetSEM™/EDS is a promising complementary tool for the in situ investigation of ENPs and their aggregates in natural matrices. In combination with other analytical tools (e.g. HDC- or FFF-ICP-MS, DLS), WetSEM™ could help to provide a better understanding of the fate and behaviour of ENPs in the environment.     

Hydraulic anisotropy of homogeneous soils and rocks: influence of the densification process

Many values of the ratio k_max/k_min are available for clays and rocks which can be cut for tests in different directions. In comparison, few reliable results are available for non-cohesive materials. The hydraulic anisotropy ratios of homogeneous clays, rocks and granular soils appear to be very similar. In particular, k_max/k_min seems to be lower than 4, which confirms that this ratio has an upper limit related to the shape of particles, their arrangement, or the directional tortuosity within the pore space. In the bedding plane of sedimentary rocks, the ratio k_b.max/k_b.min is usually lower than 1.5, thus these rocks are nearly isotropic in their bedding plane. In granular soils, the k_h/k_v, contrary to common opinion, is not always higher than 1. Experimental values for sands and gravels are in the 0.75 to 4.1 range. The influence of densification on hydraulic anisotropy is found to be similar for a sand and a clay, and probably for any soil having settled in still water and influenced subsequently only by gravity. The hydraulic anisotropy of sandstone is found to be in continuity with that of sand, and it increases with densification.     

Reconsideration of the settlement behavior of peat from view point of hydraulic conductivity

This paper deals with the settlement of peat from the view point of hydraulic conductivity (k). The validity of using the oedometer tests, including the calculation method, for measuring k is carefully examined by numerical analysis as well as a test combined with an oedometer and a hydraulic conductivity test. It is found from these studies that the conventional oedometer test (JIS A 1217, 2009) can be evaluated to measure k for peat with the same accuracy as that for usual clays, provided that the incremental load ratio is unity. The significant difference in the characteristics of k for peat and usual clayey soils is their relation between the compression index (C_c) and the hydraulic conductivity change index (C_k). As a result, rather than remaining constant during consolidation, the coefficient of consolidation (c_v) of peat decreases considerably with increasing consolidation pressure (p), while the c_v coefficient for usual clayey soil is almost constant at the normally consolidated stage. The influence of c_v dependent on p is studied by a numerical analysis for the one dimensional consolidation problem as well as for the ground improved by vertical drain. It is found that if the incremental consolidation pressure (Δp/p) is large, careful judgment is required when adopting conventional consolidation analyses, especially in case of the vertical drain.     

Innovation perspectives in construction

ABSTRACT

This study conducted a comparison between biocide treatments based on nanoparticles of silver, copper, ZnO, TiO₂ and silver/ TiO₂ nanocomposites to analyse their capability to inhibit microalgal fouling on stone buildings. Biofouling is one of the main alterations on stone façades, causes degradation of their constituent materials and interferes with their aesthetic values. The proposed treatments were tested on a limestone from the historic quarry of Estepa (Spain), widely used as construction material in the South of Spain. The applicability of the treatments was evaluated by colorimetry. The biocidal effectiveness of the nanoparticles was studied on stone surfaces by multispectral imaging, digital image analysis and optical coherence tomography. This is a low-cost and efficient protocol to validate biocidal treatments for limestone monuments, and our results demonstrate the potential of silver and ZnO nanoparticles as a protective treatment for stone façades. The results have implications for practitioners working on historic buildings.     

Modeling residential indoor concentrations of PM2.5, NO2, NOx,and secondhand smoke in the Subpopulations and Intermediate Outcome Measures in COPD (SPIROMICS) Air study

Increased outdoor concentrations of fine particulate matter (PM_2.5) and oxides of nitrogen (NO₂, NO_x) are associated with respiratory and cardiovascular morbidity in adults and children. However, people spend most of their time indoors and this is particularly true for individuals with chronic obstructive pulmonary disease (COPD). Both outdoor and indoor air pollution may accelerate lung function loss in individuals with COPD, but it is not feasible to measure indoor pollutant concentrations in all participants in large cohort studies. We aimed to understand indoor exposures in a cohort of adults (SPIROMICS Air, the SubPopulations and Intermediate Outcome Measures in COPD Study of Air pollution). We developed models for the entire cohort based on monitoring in a subset of homes, to predict mean 2-week–measured concentrations of PM_2.5, NO₂, NO_x, and nicotine, using home and behavioral questionnaire responses available in the full cohort. Models incorporating socioeconomic, meteorological, behavioral, and residential information together explained about 60% of the variation in indoor concentration of each pollutant. Cross-validated R² for best indoor prediction models ranged from 0.43 (NO_x) to 0.51 (NO₂). Models based on questionnaire responses and estimated outdoor concentrations successfully explained most variation in indoor PM_2.5, NO₂, NO_x, and nicotine concentrations.     

Hydraulische Modellierung und die Ermittlung des repräsentativen Elementarvolumens (REV) im Kluftgestein

The objective of the following study is the development of a method for the evaluation of the hydraulic conductivity and the representative elementary volume (REV) in fractured rock aquifers, which can be used for the hydraulic modelling of large-scale fractured systems. Two-dimensional stochastic discrete fracture networks were simulated for the evaluation of hydraulic conductivity. Due to the strongly variable fracture density in the considered area, a sensitivity study was performed which examined three various fracture densities according to their hydraulic properties. The flow behaviour in the discrete fracture networks is described with the cubic law. The hydraulic modelling in the fractured rock showed that an REV could not be determined for all discrete fracture networks. With one exception, an REV with a size of 10 m × 10 m could be determined for discrete fracture networks with a medium (P₂₁ = 13.1 m^–1) and high fracture density (P₂₁ = 16.9 m^–1). In contrast, no REV could be found for discrete fracture networks with a low fracture density (P₂₁ = 5.1 m^–1).     

Maximum and Minimum Void Ratio Characteristics of Sands

Characteristics of the maximum and minimum void ratios of sands and their possible use for material characterization have been investigated in this study. Data of over 300 natural sandy soils including clean sands, sands with fines and sands containing small amount of clay-size particles have been used to examine the influence of fines, grain-size composition and particle shape on e_max, e_min and void ratio range (e_max - e_min). A set of empirical correlations are presented which clearly demonstrate the link between these void ratios and material properties of sands. The key advantage of (e_max - e_min) over-conventional material parameters such as Fc and D₅0 is that (e_max - e_min) is indicative of the overall grain-size composition and particle characteristics of a given sand and that it shows off the combined influence of relevant material factors. The void ratio range provides a general basis for comparative evaluation of material properties over the entire range of cohesionless soils.Important issues related to the laboratory procedures used for determination of e_max and e_min as well as their applicability to fines-containing sands are also addressed. Three distinct linear correlations were found to exist between e_max and e_min for clean sands, sands with 5-15% fines and sands with 15-30% fines respectively, thus illustrating that the standard JGS procedures for minimum and maximum densities of sands can provide reasonably consistent e_max and e_min values for sands with fines content of up to 30%. The importance of the grain-size distribution and presence of gaps in the grading of composite soils or mixtures of sands with fines produced in the laboratory is also discussed.     

Exceptional arsenic (III,V) removal performance of highly porous,nanostructured ZrO2 spheres for fixed bed reactors and the full-scale system modeling

Highly porous, nanostructured zirconium oxide spheres were fabricated from ZrO₂ nanoparticles with the assistance of agar powder to form spheres with size at millimeter level followed with a heat treatment at 450 °C to remove agar network, which provided a simple, low-cost, and safe process for the synthesis of ZrO₂ spheres. These ZrO₂ spheres had a dual-pore structure, in which interconnected macropores were beneficial for liquid transport and the mesopores could largely increase their surface area (about 98 m²/g) for effective contact with arsenic species in water. These ZrO₂ spheres demonstrated an even better arsenic removal performance on both As(III) and As(V) than ZrO₂ nanoparticles, and could be readily applied to commonly used fixed-bed adsorption reactors in the industry. A short bed adsorbent test was conducted to validate the calculated external mass transport coefficient and the pore diffusion coefficient. The performance of full-scale fixed bed systems with these ZrO₂ spheres as the adsorber was estimated by the validated pore surface diffusion modeling. With the empty bed contact time (EBCT) at 10 min and the initial arsenic concentration at 30 ppb, the number of bed volumes that could be treated by these dry ZrO₂ spheres reached ∼255,000 BVs and ∼271,000 BVs for As(III) and As(V), respectively, until the maximum contaminant level of 10 ppb was reached. These ZrO₂ spheres are non-toxic, highly stable, and resistant to acid and alkali, have a high arsenic adsorption capacity, and could be easily adapted for various arsenic removal apparatus. Thus, these ZrO₂ spheres may have a promising potential for their application in water treatment practice.     

Application potential of solar air-conditioning systems for displacement ventilation

Solar air-conditioning can have higher application potential for buildings through the strategy of high temperature cooling. In recent years, displacement ventilation (DV), which makes use of the indoor rising plumes from the internal heat gains, provides a more effective supply air option than the traditional mixing ventilation (MV) in terms of both thermal comfort and indoor air quality. As it is possible to raise the supply air temperature to 19 °C for DV, it would enhance the competitive edge of the solar air-conditioning against the conventional vapour compression refrigeration. Through dynamic simulation, a solar-desiccant-cooling displacement ventilation system (SDC_DV) was developed for full-fresh-air provision, while a solar-hybrid-desiccant-cooling displacement ventilation system (SHDC_DV) for return air arrangement. The latter was further hybridized with absorption chiller (AB) to become SHDC_AB_DV, or adsorption chiller (AD) to be SHDC_AD_DV, in order to be wholly energized by the solar thermal gain. Benchmarked with the conventional system using MV, the SDC_DV had 43.3% saving in year-round primary energy consumption for a typical office in the subtropical climate; the SHDC_AB_DV had 49.5% saving, and the SHDC_AD_DV had 18.3% saving. Compared with their MV counterparts, the SDC_DV, the SHDC_AB_DV and the SHDC_AD_DV could have 42.4%, 21.9% and 30.3% saving respectively.     

Volatile disinfection by-product analysis from chlorinated indoor swimming pools

Chlorination of indoor swimming pools is practiced for disinfection and oxidation of reduced compounds that are introduced to water by swimmers. However, there is growing concern associated with formation for chlorinated disinfection by-products (DBPs) in these settings. Volatile DBPs are of particular concern because they may promote respiratory ailments and other adverse health effects among swimmers and patrons of indoor pool facilities. To examine the scope of this issue, water samples were collected from 11 pools over a 6 month period and analyzed for free chlorine and their volatile DBP content. Eleven volatile DBPs were identified: monochloramine (NH₂Cl), dichloramine (NHCl₂), trichloramine (NCl₃), chloroform (CHCl₃), bromoform (CHBr₃), dichlorobromomethane (CHBrCl₂), dibromochloromethane (CHBr₂Cl), cyanogen chloride (CNCl), cyanogen bromide (CNBr), dichloroacetonitrile (CNCHCl₂), and dichloromethylamine (CH₃NCl₂). Of these 11 DBPs, 10 were identified as regularly occurring, with CHBrCl₂ only appearing sporadically. Pool water samples were analyzed for residual chlorine compounds using the DPD colorimetric method and by membrane introduction mass spectrometry (MIMS). These two methods were chosen as complementary measures of residual chlorine, and to allow for comparisons between the methods. The DPD method was demonstrated to consistently overestimate inorganic chloramine content in swimming pools. Pairwise correlations among the measured volatile DBPs allowed identification of dichloromethylamine and dichloroacetonitrile as potential swimming pool water quality indicator compounds.     

A three-compartment model for micropollutants sorption in sludge: Methodological approach and insights

In sludge resulting from wastewater treatment, organic micropollutants sorb to particles and to dissolved/colloidal matter (DCM). Both interactions may influence their physical and biological fate throughout the wastewater treatment processes. To our knowledge, sludge has never been considered as a three-compartment matrix, in which micropollutants coexist in three states: freely dissolved, sorbed-to-particles and sorbed-to-DCM. A methodology is proposed to concomitantly determine equilibrium constants of sorption to particles (K_part) and to DCM (K_DCM). Polycyclic Aromatic Hydrocarbons (PAHs) were chosen as model compounds for the experiments. The logarithm of estimated equilibrium constants ranged from 3.1 to 4.3 and their usual correlation to PAH hydrophobicity was verified. Moreover, PAH affinities for particles and for DCM could be compared. Affinity for particles was found to be stronger, probably due to their physical and chemical characteristics. This work provided a useful tool to assess the freely dissolved, sorbed-to-particles and sorbed-to-DCM concentrations of contaminants, which are necessary to accurately predict their fate. Besides, guidelines to investigate the link between sorption and the fundamental concept of bioavailability were proposed.