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硫酸铬钾结晶水合物用作气相色谱固定相的特性进行了研究 ,结果表明 ,其色谱性能良好 ,可作固定相使用。 相似文献
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《国际聚合物材料杂志》2012,61(2):129-140
Abstract Three types of polyethylene glycols of different molecular weights namely, 600, 4000 and 20000, were evaluated as liquid stationary phases in gas liquid chromatography. Thus, the retention mechanism for the studied polymer stationary phases, 15% by weight on chromosorb PAW and their thermodynamic parameters have been investigated via inverse gas chromatography. The effect of polymer molecular weight on their efficiency as liquid stationary phases for the gas chromatographic separation of different types of hydrocarbons is also studied. The dielectric constant of dilute solutions for the studied polymers as dissolved in solvent chloroform was studied corresponding to their polarities. Two different modes of clusters were determined due to the solute-solute and solute-solvent interaction through hydrogen bonds. All studied polymers have higher performance for separation of cyclic and aromatic compounds. Good chromatographic separation of n-alcohols is obtained toward polyethylene glycol (PEG20000) of relatively higher molecular weight. The saturated hydrocarbons can be separated very efficiently using low molecular weight polyethylene glycol (PEG600). 相似文献
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固相萃取-气相色谱法测定水中硝基苯类化合物的含量 总被引:1,自引:0,他引:1
建立了固相萃取-气相色谱法测定水中硝基苯类含量的方法。水样经固相萃取柱富集后,进入配有DB-5(30m×320μm×0.25μm)毛细管色谱柱的带ECD检测器的气相色谱中进行测定。测定的方法检出限分别为硝基苯:0.29μg/L,间-硝基氯苯:0.05μg/L,对-硝基氯苯:0.02μg/L,邻~硝基氯苯:0.01恤晷/L,对-二硝基苯:0.03μg/L,间-二硝基苯:0.08μg/L,邻-二硝基苯:O.01μg/L,2,4~二硝基甲苯:0.021μg/L,2,4-二硝基氯苯:0.021μg/L,2,4,6-三硝基甲苯:O.02μg/L,加标回收率在83.O%~118.6%之间,相对标准偏差为2.2%~9.7%。 相似文献
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在酒后驾车引发的交通肇事案中,对驾驶员进行酒精的定性和定量检验对事故责任的定性有至关重要的作用。对气相色谱法测定酒后人体汗液中乙醇含量的方法进行了研究与探讨。通过对酒后人体分泌的汗液进行实验.利用乙醇易挥发的性质,用火焰离子(FID)检测器,采用顶空-气相色谱法进行分析测定,以峰面积定量,利用两点法测定汗液中的乙醇含量。此方法具有操作简便,快速,测定结果准确等特点。 相似文献
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用商品十八烷基聚氧乙烯醚经电渗析制备了气相色谱固定液,用该固定液对环戊酮及环戊醇混合物进行了定性、定量分析,该固定液使用寿命可达12个月以上。 相似文献
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M. Hamdi Karagöz Özlem Selçuk Zorer Zülfiye İlter 《Polymer-Plastics Technology and Engineering》2013,52(7):785-789
In this study, physical and thermodynamic properties of poly(2-phenyl-1,3-dioxolane-4-yl-methyl-methacrylate-co-styrene) (PDMMA-ST) were investigated by using inverse gas chromatography. Two groups of solvents with different chemical natures and polarities were used to obtain information about PDMMA-ST-solvent interactions: alcohols and alkanes. The specific retention volume (Vg 0), the sorption enthalpy (ΔH1 S), sorption free energy (ΔG1 S), sorption entropy (ΔS1 S), the weight fraction activity coefficients of solute probes at infinite dilution (Ω 1 ∞), and Flory-Huggins interaction parameters (χ 12 ∞) between polymer and solvents were determined for the interactions of PDMMA-ST with alcohols and alkanes by inverse gas chromatography in the temperature range of 333–473 K. Also, the solubility parameters of PDMMA-ST at infinite dilution were found by plotting the graph of [(δ 1 2/RT) - χ 12 ∞/V1] versus solubility parameters, δ 1, of probes. 相似文献
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The main goal of this review is to provide an overview of the trends in the technological development of complexation gas chromatography. This kind of chromatography, despite the passage of years, continues to offer new opportunities. The authors would like to show how complexation gas chromatography evolved over the years, due to the variety of stationary phases with complexation properties, their ability to separate, very specifically, the structures of the molecules and chemical compounds, improving the quality of the obtained results, and continuously lowering the detection limits of the analysed compounds in very complex matrices, including environmental and medical samples. The work is dedicated to the memory of Professor E. Gil-Av, whose scientific achievements were the inspiration for the improvement and widening of the research on the use of complexing metal ions and coordination metal compounds for selective separation in gas chromatography. 相似文献
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采用气相色谱法对二硫化碳中甲苯含量进行测试,找出影响测量不确定度的因素,通过建立数学模型对影响测量的各不确定度分量进行计算,求出合成不确定度和扩展不确定度,给出了气相色谱法测定二硫化碳中甲苯含量测量的相对扩展不确定度. 相似文献
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阐明了气相色谱在乙苯脱氢制备苯乙烯实验中的应用,叙述了气相色谱的工作原理、工作程序、数据处理、结果分析。 相似文献
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2.4-二硝基甲苯的气相色谱分析 总被引:2,自引:0,他引:2
建立了以丙酮溶解试样,经OV-225石英毛细管柱分离的2.4-二硝基甲苯气相色谱分析方法.平均回收率为98.92%~104.69%,标准偏差(δ)为0.0020~0.0097,相对标准偏差(RSD)为0.0098%~2.58%,为工业品2.4-二硝基甲苯的质量控制提供了一个简便、准确、快速的分析方法. 相似文献
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采用正辛烷做连续相,以Span80和Tween60为复合乳化剂,过硫酸铵-亚硫酸氢钠为氧化还原引发剂体系,通过反相微乳聚合制备丙烯酰胺-丙烯酸钠纳米粒子.研究了乳化剂、单体、引发剂配比及用量和温度等因素对聚合的影响.在反应温度为30 ℃,乳化剂浓度为油相质量的12 %~14 %,单体浓度为水相质量的35 %~40 %,引发剂浓度为单体质量的0.05 %~0.07 %时,得到稳定透明的微乳液.经扫描及透射电镜分析,所得共聚物的粒径为40~60 nm之间,粒子均匀分布的规则球形. 相似文献
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建立一种简单、灵敏的用于测定水果、蔬菜中氯丹残留量的气相色谱检测方法.样品用乙腈提取,经Florisil(弗罗里硅土)SPE小柱净化,由配有ECD检测器的气相色谱(GC-ECD)进行测定.该方法对水果、蔬菜中氯丹检出限为0.0002 mg/kg,工作曲线在0.001~0.08 μg/mL范围内呈良好的线性关系.在该线性范围内,苹果、柿子、西红柿和鲜笋中回收率为82.6% ~93.1%. 相似文献
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Ismet Kaya 《Polymer-Plastics Technology and Engineering》2013,52(2):385-396
In this study, the sorption enthalpy (δHS1), sorption free energy (δG1), sorption entropy (δS1), enthalpy, and free energy at infinite dilution (δH1 and δG1) values were calculated for selected probes such as alcohols, ketones, acetates, cyclic ethers, aromatics, and alkanes in the temperature range 403-433 K for poly(methyl methacrylate) (PMMA), poly(vinyl chloride) (PVC) homopolymers, and the PVC-PMMA blend system. The values of the Flory-Huggins interaction parameters χ1(23) have been calculated in this temperature range and show the importance of specific interactions between the polymers and the solvents. The values of the polymer-polymer interaction parameters χ23(for the temperature range 403–433 K) were found to change from +3.57 to +1.16 for alcohols, from +2.99 to +0.52 for ketones, from + 1.60 to ?0.48 for acetates, from +0.96 to ?1.46 for cyclic ethers, from +2.66 to +0.12 for aromatics, and from +8.73 to +1.06 for alkanes. 相似文献
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阐述了选择毛细管柱的四个因素:固定相、柱长、内径、膜厚。介绍了大口径毛细管柱的优点及其对填充柱的取代。提出了使用毛细管柱时应注意的事项。 相似文献