应用电化学方法原位研究薄液膜下青铜的大气腐蚀行为(英文)

采用阴极极化曲线、开路电位和电化学阻抗谱,监测青铜在不同薄液膜厚度下的大气腐蚀行为。阴极极化曲线结果表明,阴极极限电流密度随着液膜的减薄而增大。电化学阻抗谱结果表明,在腐蚀初期,腐蚀速率随着液膜的减薄而增加,这主要是由于腐蚀速率是由阴极过程控制的;随着时间的延长,腐蚀程度随着液膜厚度的变化从强到弱的趋势为:150μm,310μm,100μm,本体溶液,57μm。开路电位和电化学阻抗谱实验较好地再现了原位电化学腐蚀信息,且电化学结果与物理表征具有良好的一致性。     

Corrosion protection of AA 2024-T3 by bis-[3-(triethoxysilyl)propyl]tetrasulfide in sodium chloride solution.: Part 2: mechanism for corrosion protection

The corrosion protection of AA 2024-T3 by films of bis-[3-(triethoxysilyl)propyl]tetrasulfide (bis-sulfur silane) was studied in a neutral 0.6 M NaCl solution using potential transient, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results showed that a highly crosslinked or dense interfacial layer that developed between the silane film and the aluminum oxide is the major contribution to the corrosion protection of AA 2024-T3. The formation of this interfacial layer heavily restricts pit growth underneath via retarding the transport of corrosion products, as well as effectively blocks a number of cathodic sites available for cathodic reactions.     

Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy

The 1,2,4-triazole, 3-amino-1,2,4-triazole, benzotriazole and 2-mercaptobenzothiazole were evaluated in the present work as corrosion inhibitors for protection of the 2024 aluminium alloy in neutral chloride solutions. The corrosion protection performance was investigated by means of DC polarization and electrochemical impedance spectroscopy (EIS). Scanning Kelvin probe force microscopy (SKPFM) and atomic force microscopy (AFM) were used to study the evolution of the Volta potential distribution and the surface topography during corrosion tests.The results show that all inhibitors under study confer corrosion protection to the AA2024 alloy forming a thin organic layer on the substrate surface. Benzotriazole and 2-mercaptobenzothiazole offer better corrosion protection in comparison with the other two. The inhibitors studied act decreasing the rate of both the anodic and cathodic processes. In the latter case the dealloying of the copper-reach particles is hindered, slowing down the oxygen reduction.     

The effects of Cl ion concentration and relative humidity on atmospheric corrosion behaviour of PCB-Cu under adsorbed thin electrolyte layer

The effects of Cl⁻ ion concentration and relative humidity on atmospheric corrosion behaviour of PCB-Cu under adsorbed thin electrolyte layer were investigated by cathodic polarization curves and electrochemical impedance spectroscopy. Results indicated that the cathodic process of PCB-Cu corrosion was dominated by the reduction of oxygen and corrosion products. The cathodic current density increased with increasing relative humidity and Cl⁻ ion concentration. The corrosion rate was initially dominated by oxygen reduction, but at the later stage of corrosion, the anodic process began to affect the corrosion rate due to the accumulation of corrosion products.     

己二酸铵对7075-T6铝合金硫酸阳极氧化的影响

研究硫酸电解液中添加己二酸铵对7075-T6铝合金阳极氧化的影响,采用场发射扫描电子显微镜(FE-SEM)对7075-T6铝合金在不添加和添加己二酸铵的硫酸电解液中制备的阳极氧化膜表面的微观形貌进行分析,采用线性阳极极化研究7075-T6铝合金在两种电解液中的极化行为。利用动电位极化技术和电化学阻抗谱(EIS)研究两种电解液中制备的阳极氧化膜的耐腐蚀性能。结果表明:硫酸电解液中添加己二酸铵可以通过降低电流密度来改善氧化膜的结构,减少氧化膜缺陷,降低微孔孔径,提高阻挡层厚度,从而降低氧化膜的自腐蚀电流密度,提高氧化膜耐腐蚀性能。     

电化学方法研究纯镁在薄液膜下的腐蚀行为 Ⅰ-O2对纯镁在薄液膜下腐蚀行为的影响

用电化学法研究了纯镁在未除氧和除氧的下不同厚度薄液膜下的腐蚀行为.结果表明:薄液膜下纯镁腐蚀的阴极过程受氢还原控制;液膜厚度的减小使其阴极过程和阳极过程都受到抑制,对阳极过程影响很大.氧气的存在对阳极过程的影响很大,并使得纯镁表面易于生成表面膜,表面膜更加连续和致密.     

Preparation and electrochemical characterization of amoxicillin-doped cellulose acetate films for AA2024-T3 aluminum alloy coatings

Cellulose acetate films doped with amoxicillin were deposited onto AA2024-T3 aluminum alloy and the corrosion protection in 0.05 M NaCl was evaluated by Electrochemical Impedance Spectroscopy (EIS) and the Scanning Vibrating Electrode Technique (SVET). The doping of the cellulose acetate film with amoxicillin resulted in a significant increase in the high frequency resistance and a decrease in the capacitance of the material. The protective effect could be observed under anodic polarization by way of a marked decrease in the anodic current. These results show the promising potential for the deposition of cellulose acetate films doped with amoxicillin onto AA2024-T3.     

电解液对 2A12 铝合金硬质阳极氧化膜层性能的影响

目的对硫酸、混合酸电解液体系中制备的2A12铝合金硬质阳极氧化膜层性能进行研究,找出混合酸电解液体系对2A12铝合金硬质阳极氧化过程的影响机理,为改善膜层的耐蚀性能提供一种思路。方法通过对膜层厚度、显微硬度、微观形貌、极化曲线、交流阻抗试验结果进行分析,研究不同电解液对2A12硬质阳极氧化膜层性能的影响。结果在有机酸的活性吸附作用下,混和酸电解液解决了硫酸电解液制备2A12铝合金硬质阳极氧化膜存在的厚度、硬度不均匀及烧蚀现象,制备的膜层厚度范围为35~38μm,硬度范围为386~407HV0.05,具有厚度和硬度分布均匀、离散性小的特点。极化曲线及电化学交流阻抗分析表明,混合酸电解液体系中制备的2A12铝合金硬质阳极氧化膜层未进行封孔处理时,膜层的自腐蚀电位为-619.93 m V,阻挡层电阻为1.4×105Ω·cm2;封孔处理后,膜层的自腐蚀电位为-74.69m V,阻挡层电阻为2.376×106Ω·cm2。这说明封孔处理能够改善阻挡层的质量,显著提高膜层的耐腐蚀性能。结论采用混合酸电解液体系能够稳定制备出2A12铝合金硬质阳极氧化膜层,制备的膜层应进行封孔处理。     

Corrosion behaviour of copper under chloride-containing thin electrolyte layer

The corrosion behaviour of copper under chloride-containing thin electrolyte layers (TEL) was investigated using electrochemical impedance spectroscopy (EIS), cathodic polarization, linear polarization, SEM/EDS and XRD. The results indicate that the copper corrosion rate increases as TEL thickness decreases during the initial stages. After 192 h of immersion, the corrosion rate of copper under TEL in this order: 300 > 402 > 199 > bulk solution > 101 μm. The corrosion behaviour is uniform under TEL, and pitting is the primary corrosion type in the bulk solution. A corrosion model of the behaviour of copper under chloride-containing TEL is proposed.     

使用Kelvin探头参比电极技术研究液层厚度对氧还原速度的影响

使用Ｋｅｌｖｉｎ探头参比电极技术研究了薄液上氧还原过程的特征。实验中发现随着液层的蒸发减薄，氧还原反应速度先逐渐增加，而后又逐渐降低，呈出了速度极大值现象。尽管溶液中氧的盐效应对氧还原速度可能有一定的影响，实验结果表明，它并不是造成氧还原速度降低的主要原因。     

Corrosion protection of AA 2024-T3 by bis-[3-(triethoxysilyl)propyl]tetrasulfide in neutral sodium chloride solution. Part 1: corrosion of AA 2024-T3

This study consists of two parts. In the first part, the corrosion of 2024-T3 aluminum alloy (AA 2024-T3) was studied using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The results showed that the anodic S phase (Al₂CuMg) particles dealloyed Al and Mg during the 3.5 h of immersion in a neutral 0.6 M sodium chloride (NaCl) solution; with the dealloying of Mg being the most severe. Simultaneously, a heavy dissolution was also observed for the surrounding Al matrix of the S phase particles. This Al dissolution is likely to be caused by a local alkalization resulting from the coupled cathodic reaction (water and/or oxygen reduction). Such corrosion in AA 2024-T3, however, can be inhibited efficiently after the treatment of bis-[3-(triethoxysilyl)propyl]tetrasulfide (bis-sulfur silane). The associated studies on bis-sulfur silane treated AA 2024-T3 will be presented in the second part.     

2024-T3铝合金在硫酸-硼酸-磷酸中的阳极氧化和腐蚀行为

在含有10%硫酸、5%硼酸和2%磷酸的混合电解液中,对2024-T3铝合金进行阳极氧化处理,以提高其耐腐蚀性能。使用电化学阻抗频谱分析研究阳极氧化处理后合金的腐蚀行为。利用塔菲尔图和盐水喷雾技术进行对比发现,与只用磷酸或硫酸和硼酸的电解液相比,使用含有10%硫酸、5%硼酸和2%磷酸的混合电解液阳极氧化处理后的2024-T3铝合金,具有更好的耐腐蚀性和持久性。该电解液可以替代普遍用于阳极氧化铝合金的铬酸盐浴。     

Corrosion Evolution of High-Strength Aluminum Alloys in the Simulated Service Environment of Amphibious Aircraft in the Presence of Chloride and Bisulfite

The corrosion evolution of 2024-T351 and 7075-T651 aluminum alloys in the thin electrolyte layer (TEL) and wet-dry alter-nating cycle (WDAC) environment is studied in this work.The results show that in the TEL environment,the competitive effect between H+ that accelerates corrosion reactions and deposition of aluminum sulfate that impedes corrosion attacks exists during the corrosion exposure.The difference is that with increasing HSO3-,subsurface intergranular corrosion on 2024-T351 is promoted to form exfoliation corrosion eventually and the degree of exfoliation corrosion begins to decrease because the blocking effect of aluminum sulfate exceeds the expediting effect of H+.For 7075-T651,the corrosion area and the corrosion diameter decrease gradually,which is attributed to the HSO3-enhanced deposition of corrosion products and their blocking effect.In the WDAC environment,the corrosion processes of 2024-T351 and 7075-T651 are the acidic dissolution of the matrix during the soaking phase.When the HSO3-concentration is high enough (0.1 M),the inhibiting effect of aluminum sulfate becomes the dominant factor.     

Electrochemical corrosion behavior of X-65 steel in the simulated oil sand slurry. I: Effects of hydrodynamic condition

Oil sand slurry hydrotransport pipelines are experiencing serious corrosion and erosion. In this work, rotating disk electrode technique was used to study the effects of fluid hydrodynamics on corrosion of X-65 steel in the simulated oil sand slurry by potentiodynamic polarization curve and electrochemical impedance spectroscopy measurements. In the absence of sands, the cathodic polarization current increases with the increasing electrode rotating speed due to the accelerated oxygen diffusion and reduction. However, the anodic polarization current decreases because of the improved oxidation of the steel. Although the oxygen diffusivity increases with temperature, the resultant oxidation of steel by oxygen is not sufficient to offset the enhanced reactivity of steel at an elevated temperature. The presence of oils is believed to form a layer of oily phase on the steel surface, facilitating the cathodic reduction of oxygen and inhibiting dissolution of the steel. With the increasing sand content and size in the solution, the corrosion of steel is enhanced.     

Mechanisms of corrosion inhibition of AA2024-T3 by vanadates

The mechanisms of corrosion inhibition of AA2024-T3 by vanadates were studied using chronoamperometry, polarization curves and adsorption isotherms. The electrochemical behaviour of clear solutions containing metavanadates and orange solutions containing decavanadates was clearly distinctive. Metavanadates reduced the kinetics of oxygen reduction to an extent similar to chromates. Corrosion inhibition of AA2024-T3 by metavanadates was very rapid and it might occur by the formation of an adsorbed layer. Reduction of clear metavanadate solution was very slow. Approximately 35 min were required to develop a monolayer of a reduced vanadate species. The adsorption of the inhibitor likely blocked reactive sites on intermetallic particles, discouraging the oxygen reduction reaction (ORR). Adsorption of the inhibitor on the Al matrix could also displace Cl⁻ ions, increasing the stability of the passive film and reducing the breakdown of S-phase particles. In contrast, decavanadates were shown to be poor inhibitors of the ORR. A sharp current spike was observed after injection of decavanadates for both Cu and AA2024-T3 at various applied cathodic potentials. Integration of the current peaks suggested the formation of several monolayers of a reduced vanadate species. The formation of several monolayers was in line with the poor performance of decavanadates as inhibitors of AA2024-T3 corrosion.     

Corrosion behaviour of AM60 magnesium alloys containing Ce or La under thin electrolyte layers. Part 1: Microstructural characterization and electrochemical behaviour

The corrosion behaviour of AM60 containing Ce or La (AMRE1) under thin electrolyte layers (TEL) in 3.5 wt.% NaCl solution was investigated by cathodic polarization and EIS. The results indicated corrosion resistance was enhanced by TEL decrease until 100 μm. There were three kinetic regions in polarization curves of AMRE1, whereas the second region disappeared for AM60. Meanwhile, EIS results showed capacitive loop at LFs for AMRE1 appeared under 200-300 μm thickness. The presence of second regions in polarization curves and capacitive loops at LFs in EIS was attributed to performance of new phases (γ) as indicated in microstructural characterization.     

胞外聚合物对飞机油箱2024铝合金腐蚀行为影响

目的 探究飞机油箱内有积水存在的环境中硫酸盐还原菌分泌的胞外聚合物（EPS）对飞机油箱2024铝合金腐蚀行为的影响,为飞机油箱中微生物腐蚀与防护提供理论依据。方法 针对航煤中微生物滋生导致飞机油箱材料2024铝合金腐蚀失效的问题,通过傅里叶红外光谱（FT-IR）分析EPS的组成,并利用电感耦合等离子体发射光谱仪（ICP-MS）分析金属离子含量,采用表面分析法和电化学法研究了硫酸盐还原菌EPS在模拟飞机油箱积水环境中诱导飞机油箱2024铝合金的腐蚀行为。结果 与无EPS添加的介质条件相比,在相同的试验条件下,EPS导致航煤积水模拟溶液中的2024铝合金腐蚀电流密度减小,腐蚀产物膜呈疏松多孔的形貌,腐蚀形貌以点蚀为主。试验结束时,2024铝合金在EPS质量浓度为200 mg/L的模拟溶液中腐蚀速率大致为无EPS添加的模拟溶液中的1/10。当溶液中EPS质量浓度为100 mg/L和200 mg/L时,尽管EPS与Al3+络合产生的EPS-金属络合物会促进2024铝合金试样阳极溶解速度,但起主要影响的是抑制溶解氧扩散减缓阴极吸氧反应,抑制腐蚀的效果与EPS浓度仍成正比。结论 航煤积水模拟溶液中...     

利用Kelvin探针进行金属薄液层下电化学测量

利用线性回归法测Kelvin电位装置对铜,锌及碳钢进行了阴极极化曲线测试和腐蚀电位随相对湿度变化的监测结果表明阴极极限电流密度随液膜厚度的减小而增大金属腐蚀电位随相对湿度增加而下降.     

The corrosion of tin under thin electrolyte layers containing chloride

The corrosion of tin under thin electrolyte layers containing chloride was investigated by electrochemical measurements and surface characterization. The results show that the corrosion rate increases as the electrolyte layer thickness deceases in the initial stage. Moreover, the corrosion rate under the same electrolyte layer thickness increases firstly and then decreases with the exposure time. In the later stage, the anodic processes under thin electrolyte layers of 50 and 100 μm are inhibited due to the difficult diffusion of dissolved metal ions. The corrosion products formed on tin surface are composed of stannous and stannic oxides and hydroxides.     

Characterization of corrosion of X70 pipeline steel in thin electrolyte layer under disbonded coating by scanning Kelvin probe

Scanning Kelvin probe technique was used to characterize the electrochemical corrosion behavior of X70 steel in a thin layer of near-neutral pH and high pH solutions, respectively. Results demonstrate that passivity can be developed on steel in the near-neutral pH solution layer as thin as 60 μm, which is attributed to the fact that Fe²⁺ concentration in aqueous phase could reach saturation in the thin solution layer. The solubility of FeCO₃ is reached to drop out of solution as a precipitate. With the increase of solution layer thickness, it becomes more difficult for Fe²⁺ concentration to reach saturation. Consequently, the passivity cannot be maintained, and the steel shows an active dissolution state. Anodic dissolution rate of steel increases with the immersion time. The electrochemical polarization behavior of X70 steel in high pH solution is approximately independent of the solution layer thickness and immersion time. In thin solution layer, diffusion and reduction of oxygen dominate the cathodic process, as demonstrated by the presence of cathodic limiting diffusive current. In the bulk solution, the absence of limiting diffusive current density in cathodic polarization curve indicates that the main cathodic reaction is reduction of H₂CO₃ and , and the formed film is thus mainly FeCO₃.