A Solution‐Processable,Omnidirectionally Stretchable,and High‐Pressure‐Sensitive Piezoresistive Device

The development of omnidirectionally stretchable pressure sensors with high performance without stretching‐induced interference has been hampered by many challenges. Herein, an omnidirectionally stretchable piezoresistive pressure‐sensing device is demonstrated by combining an omniaxially stretchable substrate with a 3D micropattern array and solution‐printing of electrode and piezoresistive materials. A unique substrate structural design and materials mean that devices that are highly sensitive are rendered, with a stable out‐of‐plane pressure response to both static (sensitivity of 0.5 kPa^?1 and limit of detection of 28 Pa) and dynamic pressures and the minimized in‐plane stretching responsiveness (a small strain gauge factor of 0.17), achieved through efficient strain absorption of the electrode and sensing materials. The device can detect human‐body tremors, as well as measure the relative elastic properties of human skin. The omnidirectionally stretchable pressure sensor with a high pressure sensitivity and minimal stretch‐responsiveness yields great potential to skin‐attachable wearable electronics, human–machine interfaces, and soft robotics applications.     

A generalized micromechanics model with shear-coupling

Summary A unified mathematical framework for a higher-order transverse shear-normal stress coupled micromechanical model is presented. The model is developed based on the analysis of a repeating unit cell in a doubly periodic array of fibers. The behavior in subregions within the unit cell is modeled using an expansion for the displacement field. The order and form of the displacement expansions in the subregions are arbitrary. The higher-order terms in the displacement expansion result in coupling between the transverse shearing and the normal deformation responses (shear coupling). The formulation is sufficiently general to allow generic elastic, plastic, viscoelastic, viscoplastic, or damage constitutive models (within the context of infinitesimal strain theory) for history-dependent behavior to be incorporated into the micromechanical framework. The proposed approach is analytical and provides closed-form expressions for the effective macroscopic behavior of a continuous fiber composite.The model is validated by comparison with existing micromechanics models. The agreement between the predicted effective moduli obtained from the current model and other existing models indicates that the current formulation accurately predicts the effective elastic behavior of a composite. Furthermore, comparison with existing data for the local elastic stress distributions around the inclusion indicates that the current model correctly captures the trends and magnitudes in these distributions. The predictions obtained from the current theory are shown to be more accurate than the corresponding MOC predictions. The ability to more accurately capture the spatial stress distributions can be directly attributed to the incorporation of the shear-coupling phenomena.Finally, the influence of the presence of shear coupling on the local field distributions is considered for the simple macroscopic loading cases of transverse tension and transverse shearing. It is shown that signficant coupling between the local transverse shearing and normal deformation responses exists even when the composite is subjected to a macroscopically simple loading field. The existence of this coupling has potentially significant implications in the implementation of history-dependent constitutive models.     

The effect of different forms of strain energy functions in hyperelasticity‐based crystal plasticity models on texture evolution and mechanical response of face‐centered cubic crystals

Micro‐mechanical and macro‐mechanical behavior of face‐centered cubic (FCC) crystals is investigated by using different forms of strain energy functions in hyperelastic material models in crystal plasticity finite element framework. A quadratic strain energy function with anisotropic elastic constants, a polyconvex strain energy function with invariants associated with the cubic symmetry, and a strain energy function from an inter‐atomic potential are considered in hyperelastic material models to describe the elastic deformation of FCC crystals. In our numerical experiments, the trajectories of {111} poles in the pole figure and the accumulated plastic slips of FCC coppers under uniaxial tension and simple shear depend on the choice of strain energy functions when the slip resistance of the slip systems is high. The ability of strain energy functions in this study to represent elastic lattice distortions in crystals varies with the amount of elastic deformation and the shape of deformed lattice. However, numerical results show that the change of macroscopic mechanical behavior of FCC coppers is not significant for the choice of strain energy functions, compared with the change of crystallographic texture evolution. Copyright © 2014 John Wiley & Sons, Ltd.     

High‐Entropy Alloy (HEA)‐Coated Nanolattice Structures and Their Mechanical Properties

Nanolattice structure fabricated by two‐photon lithography (TPL) is a coupling of size‐dependent mechanical properties at micro/nano‐scale with structural geometry responses in wide applications of scalable micro/nano‐manufacturing. In this work, three‐dimensional (3D) polymeric nanolattices are initially fabricated using TPL, then conformably coated with an 80 nm thick high‐entropy alloy (HEA) thin film (CoCrFeNiAl_0.3) via physical vapor deposition (PVD). 3D atomic‐probe tomography (APT) reveals the homogeneous element distribution in the synthesized HEA film deposited on the substrate. Mechanical properties of the obtained composite architectures are investigated via in situ scanning electron microscope (SEM) compression test, as well as finite element method (FEM) at the relevant length scales. The presented HEA‐coated nanolattice encouragingly not only exhibits superior compressive specific strength of ≈0.032 MPa kg^?1 m³ with density well below 1000 kg m^?3, but also shows good compression ductility due to its composite nature. This concept of combining HEA with polymer lattice structures demonstrates the potential of fabricating novel architected metamaterials with tunable mechanical properties.

     

Microtopography‐Guided Conductive Patterns of Liquid‐Driven Graphene Nanoplatelet Networks for Stretchable and Skin‐Conformal Sensor Array

Flexible thin‐film sensors have been developed for practical uses in invasive or noninvasive cost‐effective healthcare devices, which requires high sensitivity, stretchability, biocompatibility, skin/organ‐conformity, and often transparency. Graphene nanoplatelets can be spontaneously assembled into transparent and conductive ultrathin coatings on micropatterned surfaces or planar substrates via a convective Marangoni force in a highly controlled manner. Based on this versatile graphene assembled film preparation, a thin, stretchable and skin‐conformal sensor array (144 pixels) is fabricated having microtopography‐guided, graphene‐based, conductive patterns embedded without any complicated processes. The electrically controlled sensor array for mapping spatial distributions (144 pixels) shows high sensitivity (maximum gauge factor ≈1697), skin‐like stretchability (<48%), high cyclic stability or durability (over 10⁵ cycles), and the signal amplification (≈5.25 times) via structure‐assisted intimate‐contacts between the device and rough skin. Furthermore, given the thin‐film programmable architecture and mechanical deformability of the sensor, a human skin‐conformal sensor is demonstrated with a wireless transmitter for expeditious diagnosis of cardiovascular and cardiac illnesses, which is capable of monitoring various amplified pulse‐waveforms and evolved into a mechanical/thermal‐sensitive electric rubber‐balloon and an electronic blood‐vessel. The microtopography‐guided and self‐assembled conductive patterns offer highly promising methodology and tool for next‐generation biomedical devices and various flexible/stretchable (wearable) devices.     

EGaIn‐Assisted Room‐Temperature Sintering of Silver Nanoparticles for Stretchable,Inkjet‐Printed,Thin‐Film Electronics

Coating inkjet‐printed traces of silver nanoparticle (AgNP) ink with a thin layer of eutectic gallium indium (EGaIn) increases the electrical conductivity by six‐orders of magnitude and significantly improves tolerance to tensile strain. This enhancement is achieved through a room‐temperature “sintering” process in which the liquid‐phase EGaIn alloy binds the AgNP particles (≈100 nm diameter) to form a continuous conductive trace. Ultrathin and hydrographically transferrable electronics are produced by printing traces with a composition of AgNP‐Ga‐In on a 5 µm‐thick temporary tattoo paper. The printed circuit is flexible enough to remain functional when deformed and can support strains above 80% with modest electromechanical coupling (gauge factor ≈1). These mechanically robust thin‐film circuits are well suited for transfer to highly curved and nondevelopable 3D surfaces as well as skin and other soft deformable substrates. In contrast to other stretchable tattoo‐like electronics, the low‐cost processing steps introduced here eliminate the need for cleanroom fabrication and instead requires only a commercial desktop printer. Most significantly, it enables functionalities like “electronic tattoos” and 3D hydrographic transfer that have not been previously reported with EGaIn or EGaIn‐based biphasic electronics.     

Defect‐Free,Highly Uniform Washable Transparent Electrodes Induced by Selective Light Irradiation

A simple route to fabricate defect‐free Ag‐nanoparticle–carbon‐nanotube composite‐based high‐resolution mesh flexible transparent conducting electrodes (FTCEs) is explored. In the selective photonic sintering‐based patterning process, a highly soft rubber or thin plastic substrate is utilized to achieve close and uniform contact between the composite layer and photomask, with which uniform light irradiation can be obtained with diminished light diffraction. This well‐controlled process results in developing a fine and uniform mesh pattern (≈12 μm). The mesh patternability is confirmed to be dependent on heat distribution in the selectively light‐irradiated film and the pattern design for FTCE could be adopted for more precise patterns with desired performance. Moreover, using a very thin substrate could allow the mesh to be positioned closer to the strain‐free neutral mechanical plane. Due to strong interfacial adhesion between the mesh pattern and substrate, the mesh FTCE could tolerate severe mechanical deformation without performance degradation. It is demonstrated that a transparent heater with fine mesh patterns on thin substrate can maintain stability after 100 repeated washing test cycles in which a variety of stress situations occurring in combination. The presented highly durable FTCE and simple fabrication processes may be widely adoptable for various flexible, large‐area, and wearable optoelectronic devices.     

Nanomechanical characterization of thermally evaporated Cr thin films — FE analysis of the substrate effect

We study the substrate effect on the deformation and hardness behaviour of chromium thin films using nanoindentation technique. Two different substrates namely Si (100) and AISI-304 SS are used in order to obtain a soft film on a hard substrate and a hard film on a soft substrate combination. Typical hardness variations for the two combinations are obtained. It is also observed that Cr thin films deposited on two different substrates deform distinctly. Radial cracks are found to develop in the case of Cr film on Si whereas circumferential cracks are produced in the case of Cr film on SS substrate. Using 2-D finite element analysis, it is found that the substrate not only affects the development of plastic zone but also the stress distribution in the films which results in observed distinct hardness and deformation behaviour.     

Lattice and internal relaxation of ZnO thin film under in-plane strain

Detailed ab initio density-functional calculations were carried out on the effect of lattice and internal relaxation of ZnO thin film under in-plane strain. It was found that the classical elastic deformation behaves under a restricted joint mechanism including lattice relaxation and internal relaxation. The internal relaxation works to enhance the effect of the in-plane strain on the perpendicular direction and, reduce the residual stress and the strain energy and, thus finally elevate the energetic stability of the resulting structure. By contrast, the free lattice and internal relaxation could consume part of the elastic strain energy to lead to a more stable structure with a degenerated space-group symmetry and no residual stress in any direction. In addition, the free relaxation brings about some different behaviors in many respects relative to the elastic deformation, such as the smaller Poisson ratio, the decreased piezoelectric effect, a “Λ” shaped variety in bandgap at the Γ point and the reduced shift in homogeneity of charge distribution between the two kinds of Zn-O bonds.     

On‐Skin Triboelectric Nanogenerator and Self‐Powered Sensor with Ultrathin Thickness and High Stretchability

Researchers have devoted a lot of efforts on pursuing light weight and high flexibility for the wearable electronics, which also requires the related energy harvesting devices to have ultrathin thickness and high stretchability. Hence, an elastic triboelectric nanogenerator (TENG) is proposed that can serve as the second skin on human body. The total thickness of this TENG is about 102 µm and the device can work durably under a strain of 100%. The carbon grease is painted on the surface of elastomer film to work as stretchable electrode and thus the fine geometry control of the electrode can be achieved. This elastic TENG can even work on the human fingers without disturbing body movement. The open‐circuit voltage and short‐circuit current from the device with a contact area of 9 cm² can reach 115 V and 3 µA, respectively. Two kinds of self‐powered sensor systems with optimized identification strategies are also designed to demonstrate the application possibility of this elastic TENG. The superior characteristics of ultrathin thickness, high stretchability, and fine geometry control of this TENG can promote many potential applications in the field of wearable self‐powered sensory system, electronics skin, artificial muscles, and soft robotics.     

Equivalent localization element for crack band approach to mesh‐sensitivity in microplane model

The paper presents in detail a novel method for finite element analysis of materials undergoing strain‐softening damage based on the crack band concept. The method allows applying complex material models, such as the microplane model for concrete or rock, in finite element calculations with variable finite element sizes not smaller than the localized crack band width (corresponding to the material characteristic length). The method uses special localization elements in which a zone of characteristic size, undergoing strain softening, is coupled with layers (called ‘springs’) which undergo elastic unloading and are normal to the principal stress directions. Because of the coupling of strain‐softening zone with elastic layers, the computations of the microplane model need to be iterated in each finite element in each load step, which increases the computer time. Insensitivity of the proposed method to mesh size is demonstrated by numerical examples. Simulation of various experimental results is shown to give good agreement. Copyright © 2004 John Wiley & Sons, Ltd.     

Wedge indentation of a thin film on a substrate based on micromorphic plasticity

In this article, we use the small strain micromorphic plasticity (MP) to study the wedge indentation of a thin film on a substrate and find qualitative agreement with experiments. A two-dimensional plane strain finite element formulation of the entire MP theory framework is outlined. The generalization of the radial return method for modeling the elasto-plastic deformation is presented. The numerical results show that the MP theory is capable of describing the initial fall in hardness at small depth of indentation and then the rise at larger depth for a soft film on a hard substrate. The indentation force and hardness increase with decreasing film thickness for a given depth. It is also shown that the hardness falls monotonically as the indentation depth increases and never approaches a constant for a hard film on a soft substrate. Contrary to the soft film/hard substrate system, the force and hardness diminish with decreasing film thickness for a given depth. Besides, the influences of internal length scale and hardening modulus of the film on hardness predictions are investigated.     

Misfit dislocations and stress in In<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Ga<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>As/GaAs heterostructures

We have estimated the elastic properties of In_{1 − x} Ga _x As/GaAs heterostructures and the characteristics of misfit dislocations in such heterostructures: misfit dislocation spacing, Burgers vector length in various interfaces, surface density of dangling bonds, film/substrate interface energy, critical film thickness below which pseudomorphic growth is possible without misfit dislocations, elastic strain energy of the film-substrate system, average elastic strain of a thin-film island as a function of its radius, thermal stresses induced by the thermal-expansion and lattice mismatches between the layers in contact, and crack length in the film.     

Generalized finite element approaches for analysis of localized thermo‐structural effects

This work addresses computational modeling challenges associated with structures subjected to sharp, local heating, where complex temperature gradients in the materials cause three‐dimensional, localized, intense stress and strain variation. Because of the nature of the applied loadings, multiphysics analysis is necessary to accurately predict thermal and mechanical responses. Moreover, bridging spatial scales between localized heating and global responses of the structure is nontrivial. A large global structural model may be necessary to represent detailed geometry alone, and to capture local effects, the traditional approach of pre‐designing a mesh requires careful manual effort. These issues often lead to cumbersome and expensive global models for this class of problems. To address them, the authors introduce a generalized FEM (GFEM) approach for analyzing three‐dimensional solid, coupled physics problems exhibiting localized heating and corresponding thermomechanical effects. The capabilities of traditional hp‐adaptive FEM or GFEM as well as the GFEM with global–local enrichment functions are extended to one‐way coupled thermo‐structural problems, providing meshing flexibility at local and global scales while remaining competitive with traditional approaches. The methods are demonstrated on several example problems with localized thermal and mechanical solution features, and accuracy and (parallel) computational efficiency relative to traditional direct modeling approaches are discussed. Copyright © 2015 John Wiley & Sons, Ltd.     

Synergistic Gating of Electro‐Iono‐Photoactive 2D Chalcogenide Neuristors: Coexistence of Hebbian and Homeostatic Synaptic Metaplasticity

Emulation of brain‐like signal processing with thin‐film devices can lay the foundation for building artificially intelligent learning circuitry in future. Encompassing higher functionalities into single artificial neural elements will allow the development of robust neuromorphic circuitry emulating biological adaptation mechanisms with drastically lesser neural elements, mitigating strict process challenges and high circuit density requirements necessary to match the computational complexity of the human brain. Here, 2D transition metal di‐chalcogenide (MoS₂) neuristors are designed to mimic intracellular ion endocytosis–exocytosis dynamics/neurotransmitter‐release in chemical synapses using three approaches: (i) electronic‐mode: a defect modulation approach where the traps at the semiconductor–dielectric interface are perturbed; (ii) ionotronic‐mode: where electronic responses are modulated via ionic gating; and (iii) photoactive‐mode: harnessing persistent photoconductivity or trap‐assisted slow recombination mechanisms. Exploiting a novel multigated architecture incorporating electrical and optical biases, this incarnation not only addresses different charge‐trapping probabilities to finely modulate the synaptic weights, but also amalgamates neuromodulation schemes to achieve “plasticity of plasticity–metaplasticity” via dynamic control of Hebbian spike‐time dependent plasticity and homeostatic regulation. Coexistence of such multiple forms of synaptic plasticity increases the efficacy of memory storage and processing capacity of artificial neuristors, enabling design of highly efficient novel neural architectures.     

Tribological properties of Ta‐C‐N and Ta‐N thin films

The amorphous Ta‐C‐N and Ta‐N thin films were deposited using magnetron sputtering on silicon wafer under the similar condition. The as‐prepared thin films were characterized using scanning electron microscope (SEM), optical profiling system, nano‐indentation and friction test instruments. The results show that, compared with the Ta‐N thin film, the Ta‐C‐N thin film has higher nano‐hardness (9.45 GPa) and elastic modulus (225.71 GPa). Furthermore, the lower friction coefficient and wear rate of the Ta‐C‐N thin film are 0.238 and 5.94×10^–6 mm^–3· N^–1·m^–1, respectively. The wear surface of Ta‐C‐N thin film is smoother than that of the Ta‐N thin film. Therefore, it shows better anti‐wear properties.     

Modification of the quadratic 10‐node tetrahedron for thin structures and stiff materials under large‐strain hyperelastic deformation

The concept of energy‐sampling stabilization is used to develop a mean‐strain quadratic 10‐node tetrahedral element for the solution of geometrically nonlinear solid mechanics problems. The development parallels recent developments of a “composite” uniform‐strain 10‐node tetrahedron for applications to linear elasticity and nonlinear deformation. The technique relies on stabilization by energy sampling with a mean‐strain quadrature and proposes to choose the stabilization parameters as a quasi‐optimal solution to a set of linear elastic benchmark problems. The accuracy and convergence characteristics of the present formulation are tested on linear and nonlinear benchmarks and compare favorably with the capabilities of other mean‐strain and high‐performance tetrahedral and hexahedral elements for solids, thin‐walled structures (shells), and nearly incompressible structures.     

Delaminating buckling model based on nonlocal Timoshenko beam theory for microwedge indentation of a film/substrate system

A novel model built on the basis of nonlocal Timoshenko beam theory is presented for delaminating buckling in the microwedge indentation test of a thin film on an elastic substrate. Two size effects are accounted for in the proposed model. One is the delamination size effect, and the other is the film thickness effect. The influence of the elastic deformation in the substrate and the indentation-induced impression or notch on the buckling behaviors are taken into consideration by employing coupled line springs as the boundary conditions of the buckled film. The critical stress for buckling, the energy release rate and the phase angle of the interface delamination crack are calculated and compared with those by classical beam theories. Sensitivity of the two size effects is observed.     

Self‐Organization of Thin Polymer Films Guided by Electrostatic Charges on the Substrate

The self‐organization of thin polymer films into functional patterns is important both scientifically and technologically. Electric fields have been exploited as an efficient and powerful means to induce the destabilization and self‐organization of soft materials. Previous attention, however, has mainly focused on externally applied electric fields. It is shown herein that the internal electric field is strong enough to guide the self‐organization of thin polymer films as well. Patterns of electrostatic charges with micrometer resolution are first introduced on a dielectric substrate. A thin polymer film is then spin‐coated onto the topographically flat substrate. Upon thermal annealing, the thin polymer film destabilizes due to a lateral gradient of electrostatic stress and flows away from the electroneutral regime to the charged area, resembling the patterns of charges on the substrate. Theoretical and numerical modeling based on the electrohydrodynamic instability shows excellent agreement with experimental observations both qualitatively and quantitatively. It is also demonstrated that the interplay between charge‐driven instability with spinodal dewetting and Rayleigh instabilities can generate finer and hierarchical polymeric patterns that are completely different from the charge patterns preintroduced on the substrate. This study provides direct evidence that the internal electric field caused by charges on the substrate is strong enough to destabilize thin polymeric films and generate patterns. This study also demonstrates new strategies for bottom‐up fabrication of structured functional materials.     

Template Engineering of CuBi2O4 Single‐Crystal Thin Film Photocathodes

To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from copper‐based oxide photoelectrodes due to the occurrence of significant defects such as copper or oxygen vacancies and grains. Here, the CuBi₂O₄ (CBO) single‐crystal thin film photocathode is achieved using a NiO template layer grown on single‐crystal SrTiO₃ (STO) (001) substrate via pulsed laser deposition. The NiO template layer plays a role as a buffer layer of large lattice mismatch between CBO and STO (001) substrate through domain‐matching epitaxy, and forms a type‐II band alignment with CBO, which prohibits the transfer of photogenerated electrons toward bottom electrode. The photocurrent densities of the CBO single‐crystal thin film photocathode demonstrate ?0.4 and ?0.7 mA cm^?2 at even 0 V_RHE with no severe dark current under illumination in a 0.1 m potassium phosphate buffer solution without and with H₂O₂ as an electron scavenger, respectively. The successful synthesis of high‐quality CBO single‐crystal thin film would be a cornerstone for the in‐depth understanding of the fundamental properties of CBO toward efficient photo‐electrochemical water‐splitting.