Zn含量对铸态Mg-2Er合金的微观结构及力学性能影响

采用XRD和SEM等微观表征技术研究不同Zn添加量对Mg-2Er合金微观组织和力学性能的影响。结果表明：当Zn添加量为1%和2%时,合金主要相组成为W相和α-Mg;当Zn添加量为4%-10%时,合金中则有I相析出,合金相成分变为W相、I相和α-Mg;当Zn添加量增加至12%时,W相消失,合金中主要第二相则为I相和Mg4Zn7相。当Zn添加量为6%时,合金具有较好的拉伸力学性能,其抗拉强度、屈服强度和伸长率分别为224 MPa、134 MPa和10.4%。     

Y/Zn摩尔比对Mg-Zn-Zr-Y合金相组成的影响(英文)

采用XRD和SEM/EDS等分析方法研究铸态和退火态富镁Mg-Zn-Zr-Y合金中相组成随着Y/Zn摩尔比的变化而演变的规律,并从相图计算的角度解释这种演变规律。结果表明:Mg-Zn-Zr-Y合金中第二相的形成严格依赖于Y/Zn摩尔比,X相(Mg12YZn)、W相(Mg3Y2Zn3)和I相(Mg3YZn6)随着Y/Zn摩尔比的降低依次析出。与相组成对应的摩尔比或摩尔比范围定量描述如下:当Y/Zn摩尔比约为0.164时,相组成为α-Mg+I;当Y/Zn摩尔比为0.164~0.33时,相组成为α-Mg+I+W;当Y/Zn摩尔比约为0.33时,相组成为α-Mg+W;当Y/Zn摩尔比为0.33~1.32时,相组成为α-Mg+W+X;当Y/Zn摩尔比约为1.32时,相组成为α-Mg+X。该研究为Mg-Zn-Zr-Y合金设计和合金选用提供了指导。     

Effects of Y on mechanical properties and damping capacity of ZK60 magnesium alloys

The microstructure,mechanical properties and damping capacity of ZK60-xY(x=0,1.5%,2.5%,4.0%,mass fraction) magnesium alloys were investigated by using the optical microscope(OM),X-ray diffractometer(XRD),universal tensile testing machine and dynamic mechanical analyzer(DMA).The mechanisms for damping capacity of referred alloys were discussed by Granato-Lücke theory.The results show that Y additions remarkably reduce grain size(the average grain size is 21.6,13.0,8.6 and 4.0μm,respectively),and the tensile properties are enhanced with grain refining(the yield tensile strength increases to 292 MPa from 210 MPa and ultimate tensile strength increases to 330 MPa from 315 MPa).For the ZK60-xY(x=0,1.5%,4.0%)alloys,the damping capacity decreases with the increase of Y content.However,for the ZK60-xY(x=2.5%)alloy,the damping capacity improves abnormally,which is possibly related to the formation of Mg3Y2Zn3(W)FCC phase in this alloy.     

Microstructures and properties of rapidly solidified Mg-Zn-Ca alloys

Ternary alloys based on the Mg-Zn-Ca system were produced by twin-roll rapid solidification.The alloys were characterized by OM,SEM,HRTEM,XRD,EDS and Micro-hardness.The results show that the rapidly solidified flakes are of fine dendritic cell structures with the cell size ranging from 1 to 5μm.The Mg-6Zn-5Ca alloy in RS and annealing(200℃for 1 h) states are mainly composed ofα-Mg,Mg_2Ca,Ca_2Mg_6Zn_3 and a small quantity of Mg_(51)Zn_(20),MgZn_2 and Mg_2Zn_3.Micro-hardness increases with the increment of...     

Evolution of Quasicrystals and Long-Period Stacking Ordered Structures During Severe Plastic Deformation and Mixing of Dissimilar Mg Alloys Upon Friction Stir Welding

Microstructural evolution during severe plastic deformation and mixing of Mg_(95.8)Zn_(3.6)Gd_(0.6) and Mg_(97)Cu_1Y_2(at%) alloys upon friction stir welding was studied.A laminated onion-ring structure composed of alternative distribution of layers with significantly refined microstructures from diff erent alloys was formed in the stirred zone.Coarse quasicrystals were broken up and dispersed with most of them being transformed into cubic W-phase particles,and thick 18 R long-period stacking ordered plates were fractured and transformed into fine 14 H-LPSO lamellae in the stirred zone(SZ) experiencing complex material flow under high strain rate.Fine W-phase particles and 14 H-LPSO lamellae formed during dissimilar friction stir welding(FSW) usually have no specific orientation relationship with surrounding Mg matrix.Chemical measurements demonstrated occurrence of interdiff usion between dissimilar layers in the SZ.Phase transformation was observed for some particles of quasicrystals and long-period stacking ordered(LPSO) in regions slightly outside the SZ.An ultimate tensile strength of ～ 415 MPa and an elongation to failure of ～ 27.8%,both exceeding those of base materials,were obtained in the SZ,due to microstructural refinement and formation of a laminated structure.     

Microstructure,anticorrosion, biocompatibility and antibacterial activities of extruded Mg−Zn−Mn strengthened with Ca

To find suitable biodegradable materials for implant applications, Mg?6Zn?0.3Mn?xCa (x=0, 0.2 and 0.5, wt.%) alloys were prepared by semi-continuous casting followed by hot-extrusion technique. The microstructure and mechanical properties of Mg?6Zn?0.3Mn?xCa alloys were investigated using the optical microscope, scanning electron microscope and tensile testing. Results indicated that minor Ca addition can slightly refine grains of the extruded Mg?6Zn?0.3Mn alloy and improve its strength. When 0.2 wt.% and 0.5 wt.% Ca were added, the grain sizes of the as-extruded alloys were refined from 4.8 to 4.6 and 4.2 μm, respectively. Of the three alloys studied, the alloy with 0.5 wt.% Ca exhibits better combined mechanical properties with the ultimate tensile strength and elongation of 334 MPa and 20.3%. The corrosion behaviour, cell viability and antibacterial activities of alloys studied were also evaluated. Increasing Ca content deteriorates the corrosion resistance of alloys due to the increase of amount of effective cathodic sites caused by the formation of more Ca₂Mg₆Zn₃ phases. Cytotoxicity evaluation with L929 cells shows higher cell viability of the Mg?6Zn?0.3Mn?0.5Ca alloy compared to Mg?6Zn?0.3Mn and Mg?6Zn?0.3Mn? 0.2Ca alloys. The antibacterial activity against Staphylococcus aureus is enhanced with increasing the Ca content due to its physicochemical and biological performance in bone repairing process.     

Microstructure and mechanical properties of a compound reinforced Mg95Y2.5Zn2.5 alloy with long period stacking ordered phase and W phase

The microstructure evolution of Mg100-2xYxZnx(x=2, 2.5, 3, 3.5) alloys was investigated. Results show that the Mg100-2xYxZnx alloys are composed of α-Mg, long period stacking ordered(LPSO) phase and eutectic structure phase(W phase), and the Mg95Y2.5Zn2.5 alloy has the best comprehensive mechanical properties. Subsequently, the microstructure evolution of the optimized alloy Mg95Y2.5Zn2.5 during solidification and heat treatment processes was analyzed and discussed by means of OM, SEM, TEM, XRD and DTA. After heat treatment, the lamellar phase 14H-LPSO precipitated in α-Mg and W phase transforms into particle phase(MgYZn2). Due to the compound reinforcement effect of the particle phase and LPSO phase(18R+14H), the mechanical properties of the alloy are enhanced. The tensile strength and elongation of the Mg95Y2.5Zn2.5 alloy is improved by 9.1% and 31.3% to 215 MPa and 10.5%, respectively, after solid-solution treatment.     

添加Nd、Zn、Ti的Mg2Ni基合金微观组织及氢化动力学

为了提高Mg2Ni基合金的储氢动力学性能,通过熔炼方法分别添加金属元素Nd,Zn和Ti来防止镁的氧化和蒸发,将Mg2Ni基合金在有覆盖剂保护的电阻炉中进行熔炼。借助XRD 和 SEM/EDS研究了铸态合金的相组成和微观组织。采用定容法在Sievert’s型PCT测试仪上测试了合金的氢化动力学性能。Nd、Zn和Ti的添加导致了微量相Mg6Ni和Ni3Ti的生成。Nd和Zn溶解在Mg2Ni基合金的α-Mg、Mg2Ni和MgNi2相中。添加Nd元素后,合金的首次吸氢量高于Mg2Ni的,达到2.86%（质量分数）。Mg2Ni基合金的吸氢动力学性能和活化性能均有所提高。在前3次吸放氢循环过程中,添加Zn和Ti的合金吸氢量和吸氢动力学性能均得到提高。采用Hirooka动力学模型分析了合金的氢化动力学性能及反应机制。     

Zn、Y含量的变化对Mg-Zn-Y合金组织和性能的影响

以Mg6Zn2Y为基础研究了Zn、Y含量的变化对Mg-Zn-Y基合金组织和性能的影响.结果表明铸态下增加1%Zn的合金的组织变得粗大,抗拉强度降低约10%,伸长率降低25%;同时添加1%Zn和1%Y的合金组织明显细化,抗拉强度和伸长率分别提高11%和17%;挤压后由于Y的加入形成了高熔点的化合物相,合金受这些相抑制,没有发生动态再结晶,力学性能因挤压变形得到不同程度的提高,对比分析Mg7Zn3Y合金拥有抗拉强度355 MPa和伸长率4.5%较好的综合性能.     

Texture and stretch formability of rolled Mg-Zn-RE （Y, Ce, and Gd） alloys at room temperature

To develop a new magnesium alloy with excellent formability at room temperature, the effect of Y, Ce, and Gd addition on texture and stretch formability of Mg-1.5Zn alloys was carried out. The result shows that Y, Ce, and Gd addition in Mg-1.5Zn alloys can effectively weaken and modify the basal plane texture, characterized by TD-split texture in which the position of basal is titled from normal direction （ND） toward transverse direction （TD）. When Mg-1.5Zn alloy with Gd addition appears low texture intensity and TD-split texture, where the position of basal poles is tilted by about 4-35° from ND toward to TD, the largest Erichsen value of 7.0 and the elongation rate reaches 29.1% in TD direction. However, Y and Ce addition in Mg-1.5Zn alloys promote a large number of second phase particles, which cancel the contribution of the unique basal texture to stretch formability and ductility.     

高强Mg-Gd-Y-Zn-Zr合金的微观组织和力学性能

通过金属模铸、热挤压和时效处理(T5)工艺过程制备出高强Mg-7Gd-4Y-1.6Zn-0.5Zr合金,并利用光学显微镜、XRD、SEM及TEM分析研究Mg合金不同状态下的显微组织和力学性能。结果表明:Mg-7Gd-4Y-1.6Zn-0.5Zr合金的铸态组织主要由α-Mg基体和沿晶界分布的片层状第二相Mg12Zn(Gd,Y)组成,经过热挤压变形后,合金晶粒显著细化,时效处理过程中Mg12Zn(Gd,Y)相上析出少量细小的颗粒状Mg3Zn3(Gd,Y)2相。时效态合金的抗拉强度、屈服强度和伸长率分别达到446 MPa、399 MPa和6.1%,其强化方式主要为细晶强化和第二相强化。     

Effects of phase composition on the mechanical properties and damping capacities of as-extruded Mg-Zn-Y-Zr alloys

The present work mainly investigated the microstructures, mechanical properties, and damping capacities of as-extruded Mg-Zn-Y-Zr alloys with varied phase composition. Alloys of MgZn₂, W-phases (Mg₃Y₂Zn₃), I-phases (Mg₃YZn₆), and X-phases (Mg₁₂YZn) were obtained by adjusting the Zn/Y ratio (in wt%). The crystallographic structure of the X-phase [long period stacking ordered (LPSO) phase] and the crystallographic relationship between the W-phase and the Mg matrix were determined. The strengthening effects of the phase composition on the alloys exhibited the following trend: W + LPSO > LPSO>W + I > MgZn₂. Variations in the phase composition resulted in almost consistent variations in the damping capacities of the alloys compared with their mechanical properties. The LPSO structural phase could enhance the mechanical properties and simultaneously maintain the good damping capacity of the alloys.     

Mg94TM(Zn,Cu,Ni)2Y4合金的铸态组织及摩擦磨损性能

利用普通铸造法制备了Mg94TM(Zn,Cu,Ni)2Y4三种合金,并研究其铸态组织特征、物相组成及耐磨性能.Mg94Zn2Y4和Mg94Cu2Y4合金组织呈现[明显的树枝晶结构,而Mg94Ni2Y4以等轴晶为主;Mg94Cu2Y4和Mg94Ni2Y4两种合金的金属间化合物组成要比Mg94Zn2Y4合金复杂.三种合金材料中,Mg94Zn2Y4合金的硬度最低,耐磨性最差,其磨损机制均主要表现为犁沟磨损、粘着磨损和氧化磨损.     

Effects of Sn and Ca additions on microstructure,mechanical properties,and corrosion resistance of the as‐cast Mg‐Zn‐Al‐based alloy

Effects of Sn and Ca additions on microstructure, mechanical properties, and corrosion resistance of the as‐cast Mg‐6Zn‐2Al‐based alloy were investigated by SEM, XRD, tensile tests, electrochemical measurements, etc. The higher the Sn content, the higher the yield strength of the Mg‐6Zn‐2Al‐based alloy. Trace Ca addition refined both grains and divorced eutectics in the Mg‐Zn‐Sn‐Al alloys, leading to the best combination of strength and plasticity. Moreover, its influence was more significant for the alloy with a higher Sn content. Furthermore, the combined addition had a beneficial effect on the corrosion resistance improvement of the Mg‐6Zn‐2Al alloy. The Mg‐6Zn‐2Al‐3Sn‐0.2Ca alloy was the most corrosion‐resistant alloy among the nine alloys studied, better than AZ91 and ZA85. It could be ascribed to the decrease and the refinement of divorced eutectics, the higher hydrogen overvoltage of Sn and the Ca grain refinement.     

挤压态和时效态Mg-Zn-Mn-Sn-Y合金的组织性能

利用光学显微镜、X射线衍射和扫描电镜等对挤压态和时效态Mg-6Zn-1Mn-4Sn和Mg-6Zn-1Mn-4Sn-0.5Y镁合金的微观组织和力学性能进行研究。结果表明：与ZMT614镁合金相比,添加Y元素后,ZMT614-0.5Y晶粒得到细化,综合力学性能得到提高。Mg-6Zn-1Mn-4Sn-0.5Y合金的相组成为α-Mg、Mg Zn2、Mn、Mg2Sn和MgS n Y相。经过T6热处理后,合金的抗拉强度和屈服强度明显得到提高,伸长率明显被降低。理论计算表明,在挤压态合金中,细晶强化和固溶强化产生重要的作用,而在T6热处理态合金中,析出强化产生决定作用。     

Effects of Y content on microstructures and mechanical properties of as-cast Mg-Zn-Nd alloys

The effects of Y addition amount on the microstructures and mechanical properties of as-cast MgZn-Nd alloy have been investigated by using an optical microscope, a scanning electron microscope, backscattered electronic imaging technique, an X-ray diffractometer, a differential thermal analyzer and a universal testing machine. There are three kinds of ternary phases in the Mg-Zn-Y system alloys, such as I phase(Mg3Zn6Y), W phase(Mg3Zn3Y2) and Z or X phase(Mg12Zn Y). The experimental results in the present study indicate that the Mg-Zn-RE(RE includes Y and Nd) ternary phases change from the I + W phases in turn to unique W, W + Z and unique Z as the Y content increases from 0% to 3%. Simultaneously, their distribution gradually changes from small particle-like form to continuous network form. The grain size first decreases as the Y content increases from 0% to 1% Y, then increases when the Y content exceeds 1% and finally decreases again when the content exceeds 3% due to the variation of growth restriction factor caused by the increased Y element and the change of the ternary phases. The hardness continuously increases because of the increased ternary phase amount. The ultimate tensile strength and elongation first increase within the range of 0-1% Y, also due to the increased ternary phase amount and grain refinement, and then decreases because of the grain coarsening, porosity formation and continuous network distribution of the ternary phases. The grain bonding strength of the W phase-containing alloys is quite strong and the W phase is an ideal strengthening phase if a given amount of it distributes in discontinuous and small-sized form. The alloy with 1% Y only has one ternary phase of W, but has the best combination of mechanical properties. The fracture regimes of these alloys always present a transgranular mode.     

Effect of Ce addition on microstructure of Mg–9Li alloy

The as-cast and as-extruded Mg–9Li, Mg–9Li–0.3Ce alloys were respectively prepared through a simple alloying process and hot extrusion. The microstructures of these alloys were investigated by optical microscope (OM), scanning electron microscope (SEM), X-ray diffractometer (XRD) and energy dispersive spectrometer (EDS). The results indicate that Ce addition produces a strong grain refining effect in Mg–9Li alloy. The grain size of the as-extruded alloy reduces abruptly from 88.2 μm to 10.5 μm when the addition of Ce is 0.36%. Mg₁₂Ce is verified and exists inside the grains or at the grain boundaries, thus possibly pins up grain boundaries and restrains the grain growth.     

Effect of Gd content on microstructure and mechanical properties of Mg-Y-RE-Zr alloys

Four kinds of Mg-Y-RE-Zr alloys with different Gd contents were prepared,and the effect of Gd content on microstructure and mechanical properties of the alloys was researched.Based on the experimental investigation,the compounds at the grain boundaries are mainly Mg_(24)Y_5,Mg_(41)Nd_5,and Mg_5Gd phases.The average grain size of as-cast alloys is 50-60μm.After T4(535℃, 24 h)treatment,Mg_5Gd phases mostly decompose and dissolve into the matrix,and the disperse spotted phases are mainly Mg_(24)Y_5 and Mg_(...     

Morphological evolutions of cast and melt-spun Mg_(97)Zn_1Y_2 alloys during deformation and heat-treating

Mg_(97)Zn_1Y_2 alloy has been studied as an elevated temperature creep resistant Mg-based alloy for nearly ten years.While, the strength of the cast Mg_(97)Zn_1Y_2 alloy with long-period stacking(LPS) structure is lower than that of the commercial AZ91 alloy at room temperature.The microstructure evolutions in Mg_(97)Zn_1Y_2(molar fraction,%) alloys with LPS phase,processed by rolling and annealing the as-cast alloy and rapidly solidifying/melt-spinning and age treating at different temperatures respecti...     

复合添加Y和Nd对Mg-Li合金显微组织及室温压缩织构的影响

采用OM,SEM,XRD,EBSD及电子万能试验机,对比研究了Mg-5Li-3Al-2Zn和Mg-5Li-3Al-2Zn-1.2Y-0.8Nd铸态合金的显微组织、力学性能以及室温单向压缩后的织构演变.研究发现,复合添加Y和Nd 2种稀土元素后,合金中絮丝状AlLi相明显减少,晶粒得到显著细化,平均尺寸在30μm左右.2种合金的塑性表现良好,加入少量稀土的合金室温压缩的变形量可达到27%.复合添加的稀士元素大幅度降低了Mg品格的c/a值,显著弱化了合金的基面织构,激活了锥面滑移系的同时,也使得室温下少见的柱面滑移破激活.