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甲基丙烯酸镁增强EVM硫化胶的结构与性能 总被引:1,自引:0,他引:1
将甲基丙烯酸镁(MDMA)直接与乙烯-乙酸乙烯共聚物(EVM)共混,并用过氧化物硫化,研究了过氧化二异丙苯(DCP)和MDMA用量对EVM硫化胶物理机械性能和交联结构的影响。结果表明,DCP用量为4.0份时硫化胶的性能较好;MDMA能明显地提高硫化胶的邵尔A型硬度和拉伸强度,同时保持较高的扯断伸长率,以MDMA用量为30-50份最佳。交联结构分析结果表明,硫化胶中离子键随着DCP和MDMA用量的增加而提高。动态力学分析结果表明,在硫化过程中MDMA发生反应使玻璃化转变温度移向低温区。傅里叶变换红外光谱分析表明,在硫化过程中,MDMA与EVM发生了接枝反应,形成了离子交联键。 相似文献
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原位生成甲基丙烯酸钠增强EVM硫化胶的性能 总被引:6,自引:0,他引:6
通过氢氧化钠(NaOH)和甲基丙烯酸(MAA)的中和反应,在乙烯-乙酸乙烯酯橡胶(EVM)中原位生成甲基丙烯酸钠(NaMAA),研究了NaMAA原位增强EVM的流变特性,应力软化和应力松弛以及老化前后的力学性能,并与炭黑(N330)增强的硫化胶进行对比,结果表明:NaMAA的引入对EVM混炼胶的门尼粘度几乎没有影响,但在硫化过程中提高了混炼胶的硫化速度,缩短了焦烧时间,与HAF相比,NaMAA对EVM硫化胶具有更好的增强效果,较好的耐老化性能,NaMAA增强的EVM硫化胶具有更明显的应力软化效应,应力松弛程度更大。 相似文献
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使用密炼机,采用动态硫化工艺制备了乙烯-乙酸乙烯酯共聚物/三元共聚尼龙热塑性硫化胶(EVM/tPA TPV)和乙烯-乙酸乙烯酯-甲基丙烯酸缩水甘油酯共聚物/三元共聚尼龙热塑性硫化胶(EVM-GMA/tPA TPV),研究了转子转速对两种热塑性弹性体体力学性能和耐热油等性能的影响。结果表明,在一定范围内提高转子转速,热塑性弹性体的力学性能呈上升趋势,当转子转速为80 r/min时,两种热塑性弹性体的综合力学性能最佳;当转子转速达到60 r/min以上时,两种热塑性弹性体的耐热油性能良好;随着转子转速的增加,两种热塑性弹性体的弹性得到改善;在相同转子转速条件下,EVM-GMA/tPA TPV比EVM/tPA TPV具有更好的力学性能、弹性和耐热油性能。 相似文献
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研究了甲基丙烯酸钠(NaMAA)和高耐磨炭黑(HAF)增强乙烯一乙酸乙烯酯橡胶(EVM)的断裂行为,采用Griffith能量平衡理论计算了引发硫化胶破坏的裂纹尺寸,并与扫描电子显微镜测得的裂纹尺寸进行了比较。结果表明,NaMAA和HAF填充EVM硫化胶的理论裂纹尺寸均明显小于纯EVM硫化胶;实际测得的裂纹尺寸小于理论裂纹尺寸;NaMAA增强EVM硫化胶的撕裂断面呈现黏滑式撕裂,而HAF增强EVM硫化胶的撕裂断面较平整,存在直的撕裂线。 相似文献
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将炭黑(CB)、氢氧化单甲基丙烯酸锌(HZMMA)和碳纳米管(CNTs)进行复配,以改性氢化丁腈橡胶(HNBR)/氟橡胶(FKM)共混胶,制备了HNBR/FKM复合材料,研究了复合型增强剂对HNBR/FKM共混胶硫化特性、硫化胶的物理机械性能、动态力学性能和耐热氧老化性能的影响。结果表明,当加入HZMMA和CNTs后,HNBR/FKM复合材料的硫化速率加快且交联程度提高;在HZMMA和CNTs的协同作用下,HNBR/FKM复合材料的物理机械性能明显提高;与纯CB增强的相比,加入3份(质量)CNTs的HZMMA增强的HNBR/FKM复合材料热氧老化后扯断伸长率的保持率最高,与此同时硬度变化率最低;随着CNTs添加量的增加,HNBR/FKM复合材料的玻璃化转变温度向低温方向移动,同时损耗因子呈逐渐下降的趋势。 相似文献
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丁腈橡胶的伏安特性与功率特性的研究 总被引:1,自引:0,他引:1
本文对乙炔碳黑填充丁腈橡胶(NBR)的伏安特性及其功率特性进行了研究,分析了丁腈橡胶在交、直流电场下的导电机理,并对环境温度变化时的丁腈橡胶的功率及功率与电压的变化规律提出了相应的关系式,同时对导电丁腈橡胶的物理机械性能进行了研究与测定。 相似文献
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E. S. Zainudin S. M. Sapuan K. Abdan M. T. M. Mohamad 《Polymer-Plastics Technology and Engineering》2013,52(1):97-101
Mechanical strengths of a banana pseudo-stem (BPS) fiber and unplasticized polyvinyl chloride (UPVC) composite were evaluated to assess the possibility of using it as a new material in engineering applications. Samples were fabricated by the compression molding process with reference to the effect of filler loading. The samples were submitted to mechanical tests to measure tensile, flexural, and impact properties of the composites. The nature of adhesion between the matrix and the reinforcement and information relating the structure of mechanical properties can be obtained by scanning electron microscopy (SEM) assessment of the composite fracture surface. The mechanical properties show that the composites did not have good adhesion between filler and matrix; on the other hand, the filler insertion improved the flexural modulus and the material rigidity. 相似文献
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王丽 《合成材料老化与应用》2014,(4):15-17
分别以聚四氢呋喃醚二醇(PTMEG)、聚氧化丙烯二醇(PPG-1000)为软段,以二苯基甲烷二异氰酸酯(MDI-50、MDI-100LL),以及扩链剂1,4-丁二醇(BDO)、三羟甲基丙烷(TMP)为硬段,采用预聚体法制备了聚氨酯弹性体。并系统研究了聚氨酯体系中各组分的种类对材料机械性能和阻尼性能的影响。 相似文献
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核壳纳米粒子作为复合纳米粒子一个重要的分支,由于其光、磁和催化等方面的优异性能,近年来引起了人们广泛的关注.本文主要介绍了核壳纳米粒子的制备方法及诸多性能,并对核壳纳米粒子的发展进行了展望. 相似文献
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《Ceramics International》2020,46(9):13695-13703
Manganese–copper ferrite (MCFO) and dysprosium (Dy)-doped manganese–copper ferrite nanocomposites (Mn0.5Cu0.5DyxFe2−xO4) (x = 0, 0.05, 0.10, and 0.15) were synthesized by sonochemical method. Crystal structure and the structural parameters of the MCFO were analyzed based on the doping concentration of Dy ion. It was observed that the average crystalline size of the synthesized nanocomposite decreases when the concentration of Dy increases. The existing spherical surface morphology of the MCFO and Dy-doped MCFO nanocomposites were obtained through scanning electron microscopy. In the UV spectrum, the pristine MCFO sample showed an absorbance peak at 743 nm whereas the absorbance values of Dy-doped ferrite nanocomposite considerably shifted (blue) toward a lower wavelength (231–222 nm). The dielectric parameters of all ferrite nanocomposites were studied in the frequency range of 100 Hz to 5 MHz. The dielectric spectrum revealed that dielectric constant and loss tangent decreased with increased doping concentration of Dy ion. The saturation magnetization also changed with Dy doping in MCFO. The impact of Dy on manganese–copper ferrite changed the optical, dielectric and magnetic properties of the prepared binary ferrite nanocomposite, which can be used for microwave-absorbing material applications. 相似文献
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Effects of support and additive on oxidation state and activity of Pt catalyst in propane combustion 总被引:1,自引:0,他引:1
The effects of support and additive on the oxidation state and catalytic activity of Pt catalyst in the low temperature propane combustion were systematically investigated on Pt/MgO, Pt/Al2O3 and Pt/SiO2–Al2O3. The catalytic activity varied much with both support materials and additives. The catalyst on the more acidic support showed higher activity, and the catalytic activity on every support materials increased as the electronegativity of additives increased, while some additives decreased the activity. The oxidation state of platinum, estimated by white line intensity of Pt LIII-edge XANES spectrum, also varied with the support and additives, and additives with higher electronegativity greatly prevented the platinum from its oxidation under oxidising atmosphere. Among almost all the catalysts with various supports and various additives, a clear relationship was observed between the oxidation state of platinum and the catalytic activity; the more metallic platinum showed higher activity. Thus, it was concluded that the total electrophilic/electrophobic property derived from those of the support and additive controls the oxidation state of platinum, which intensively affects the catalytic activity; i.e. higher electrophilic property provides less oxidised platinum, resulting in high catalytic activity. The mechanism of this effect was also discussed on the basis of thermochemical data, and it was proposed that the electrophobic materials promote the noble metal oxidation since the noble metal oxo-anion such as PtOδ− is more stabilised with electrophobic cation. 相似文献
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对苯二甲酸乙二酯/聚乙二醇共聚醚酯的热性能研究 总被引:2,自引:2,他引:0
将含有磺酸盐基团化合物及不同添加量的聚乙二醇(PEG)与对苯二甲酸乙二酯共聚合成共聚醚酯(COPEET),利用差示扫描量热分析法(DSC)研究了一系列COPEET的玻璃化转变温度、结晶温度以及熔融温度等的变化规律。结果表明:随PEG添加量的增加,COPEET的玻璃化转变温度有规律地下降;PEG质量分数小于30%时,有利于冷结晶、结晶度下降;继续增加PEG则COPEET变得难于结晶;PEG质量分数小于40%时,热结晶容易,但结晶度下降;PEG添加量更高时,熔融结晶变得困难了;添加PEG会降低COPEET的熔点。 相似文献