共查询到17条相似文献,搜索用时 109 毫秒
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一步共沉淀法合成钇铝石榴石纳米粉体 总被引:1,自引:0,他引:1
以Ai(NO3)y9H20和Y(NO3)3-6H20为原料,NH4HCO3为沉淀剂,十二烷基苯磺酸(C18H30SO3)为分散剂,采用一步共沉淀法合成钇铝石榴石(Y3A15O12,YAG)纳米粉体。利用X射线衍射仪、Fourier红外光谱仪、同步热分析仪和场发射扫描电子显微镜对YAG前驱体及不同温度煅烧后的粉体进行表征。结果表明:YAG前驱体化学组成为10[Al(Oh)3]·3[Y2(CO3)3+3H2O],900℃煅烧2h后转变为纯YAG相,1000℃煅烧2h后得到的粉体晶型完整、分散性好、颗粒尺寸分布均匀,形状近似球形,平均粒径约为65nm。该方法较传统共沉淀法操作步骤简化、参量减少、可重复性提高,因此,更有利于实现工业化批量生产。 相似文献
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超细钛酸钡粉体湿化学合成技术 总被引:2,自引:0,他引:2
近十年来,钛酸钡粉体的合成技术发展十分迅速。其中,超细钛酸钡粉体的湿化学合成技术倍受关注,主要包括溶胶-凝胶、溶胶-沉淀、燃烧合成、化学共沉淀和水热合成等多种方法。简要综述了这5种主要的湿化学合成工艺,并重点分析了溶胶-凝胶法等制备钛酸钡粉体过程中各种因素对粉体的粒径和形态的影响。 相似文献
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Akira Kondo Takahiro Kozawa Toshihiro Ishikawa Makio Naito 《International Journal of Applied Ceramic Technology》2022,19(2):681-687
In this study, synthesis of yttrium aluminum garnet (YAG):Ce3+ phosphor powders for white light emitting diodes was investigated by mechanical method using the attrition-type mill with no external heating and no flux in dry phase. High mechanical energy input to the starting powder mixture of Y2O3, Al2O3 and CeO2 achieved the synthesis of YAG:Ce3+ without any flux materials. X-ray diffraction patterns of the processed powders after 5 min processing revealed the peaks of YAG were clearly identified. The maximum temperature of the mill chamber during the processing was 240℃. The YAG phosphor obtained by the mechanical method revealed the internal quantum yield of 65% in the case of the sample mechanically processed under a reducing atmosphere. The synthesized powder showed granule structure consisting of submicron size of YAG particles, which is better handling for the fabrication of light emitting diode devices. 相似文献
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Wenbin Liu Wenxin ZhangJiang Li Huamin KouDi Zhang Yubai Pan 《Journal of the European Ceramic Society》2011,31(4):653-657
Neodymium doped yttrium aluminum garnet (Nd:YAG) ultrafine powders were synthesized by co-precipitation method using MgO as dopant. The addition of small amount of MgO can reduce the agglomeration and particle size of the produced Nd:YAG powders. The results show that pure phase YAG powders can be achieved by calcining of the precursors at 1000 °C for 2 h. The MgO doped Nd:YAG powders show better dispersion compared with the undoped powders. When the MgO content is 0.01 wt.%, well-dispersed Nd:YAG powders with spherical particles of 100 nm diameter were obtained. The transmission of the corresponding Nd:YAG ceramics is 82.6% at the wavelength of 1064 nm, which is comparable to Nd:YAG single crystals. 相似文献
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Yttrium aluminum garnet (YAG) nano-sized powders were synthesized using the co-precipitation method with ammonium hydrogen carbonate as precipitant, nonionic, anionic and cationic surfactant as dispersant, respectively. The composition of YAG precursor, the phase formation process of YAG and the properties of the powders were investigated by means of IR, XRD and TEM. The results show that the anionic surfactant is beneficial for the dispersion of the resulting YAG powders. Highly crystalline, well-dispersed nano-sized YAG crystallites were obtained by calcining at 1000 °C for 2 h in the presence of the anionic surfactant. The average size of the particle is about 30 nm. Luminescence properties of the Nd-doped YAG powders prepared with surfactant and with no surfactant were also studied. 相似文献
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钇铝石榴石(YAG)激光透明陶瓷由于具有单晶、玻璃激光材料无可比拟的优势而成为研究热点,并得到迅速发展,高性能的稀土元素掺杂YAG透明激光陶瓷被相继报导.本文综述了近年来国内外关于YAG激光透明陶瓷的最新研究成果.主要包括YAG微细粉体合成、烧结添加刺及多晶YAG透明陶瓷的致密化烧结技术,并对比了YAG透明陶瓷相对于Y... 相似文献
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《Ceramics International》2017,43(14):10673-10682
The present work aims to establish a correlation between the characteristics of YAG and Er:YAG commercial powders produced by two different synthesis routes and sintered ceramic microstructures and their optical aspect by taking into account the influence of pressure applied during the Spark Plasma Sintering (SPS) process. Physical and chemical characteristics of the powders were compared using various techniques such as SEM, XRD, laser diffraction and chemical analyses. Their behaviours were evaluated through a rheological study, compressibility tests and dilatometry cycles using SPS. This paper pinpoints the most important powder features which influence the optical quality of YAG and Er:YAG ceramics. The optical quality is mainly affected by the porosity, related to powder characteristics that affect particle rearrangement, densification and grain growth. The applied pressure induces microstructural heterogeneities depending on the starting material used and resulting in core-shell aspects of sintered ceramics. 相似文献
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Mahsa Rahmani Omid Mirzaee Mohammad Tajally Mohammad Reza Loghman-Estarki 《Ceramics International》2018,44(9):10035-10046
Pure yttrium-aluminum-garnet (YAG) nano particles were synthesized via normal and reverse co-precipitation methods using nitrate starting solutions and ammonium hydrogen carbonate (AHC) as precipitator agent. The impact of titration method on the phase evolution, thermal behavior, precipitate's composition, morphology and chemical bonds of powders were studied by XRD, TG-DTA, FTIR, FESEM, TEM, EDS and BET analysis. The results revealed that in the normal method, the precipitates were composed of relatively dense particles compared with more homogenous fluffy precipitates with higher carbonate content obtained by the reverse method. The precursors achieved by the reverse method formed less agglomerated and smaller size YAG powders after calcination at 900?°C. Calcined nano powders were processed by spark plasma sintering (SPS) technique at 1350?°C for 10?min without any sintering aids or dispersive agents. The sintering of both powders led to a highly dense and fine submicron-structured YAG ceramic. However, the YAG ceramic produced by SPS of reverse co-precipitated nano powders showed higher transparency (43% at 680?nm and 58% in near-infrared range) and finer micro-structure (about 210?nm in grain size) as compared with normal co-precipitated nano particles. 相似文献
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YAG纳米粉体的制备技术研究进展 总被引:9,自引:0,他引:9
近年来YAG纳米粉体因其具有特殊的性能而备受人们的关注。以此为原料采用先进的陶瓷制备工艺可以得到透明的YAG固体激光工作介质 ,其物理化学及光学性能可与单晶相比拟。YAG粉体通过掺杂Ce3 ,Tb3 ,Eu3 等离子还可以作为超短余辉荧光粉 ,在发光材料领域有广泛的应用。本文着重介绍了目前应用较多的几种YAG纳米粉体的制备方法 ,并简要地比较了各种方法的优劣。 相似文献