Optical bistability in BaTiO3

In this paper experimental results concerning the optical bistability of a ferroelectric monocrystal of BaTiO₃ are presented. Two laser beams were used to interact with the monocrystal which resulted in the bistability of the intensity of the transmitted wave. This was achieved without the application of any optical resonator. The feedback was provided by the electronic system through a mechanism typical to all photorefractive materials.     

Optical bistability of surface plasmon polaritons in nonlinear Kretschmann configuration

Optical bistability based on surface plasmon polaritons in the Kretschmann configuration involving a Kerr nonlinear medium is described by analytical solutions. The conditions of forming the optical bistability with different parameters are explored. The resonant angle of surface plasmon polaritons varying with the incident light intensity also generates the phenomenon of bistability. The system could form optical bistability with the special thickness of the metal film and incident angle. This kind of system has potential application in all-optical networks.     

Surface plasmon-assisted optical bistability in the quantum dot-metal nanoparticle hybrid system

We theoretically investigated optical bistability (OB) of a coupled excition–plasmon hybrid system in a unidirectional ring cavity. It is found that the threshold and the region of OB can be tuned by adjusting the center–center distance between the quantum dot and metal nanoparticle (MNP), the Rabi frequency of the control field and the radius of the MNP. Due to the significantly enhanced optical nonlinearity by the surface plasmon effect, the threshold of OB can be decreased greatly when the probe field is parallel to the major axis of the hybrid system. The enhanced OB may have promising applications in optical switching and optical storage.     

Exchange constants in ferrimagnetic garnets

The exchange constants in the ferrimagnetic garnets R₃ Fe₅ O₁₂ (R=Y³⁺, Gd³⁺ and Dy³⁺) have been obtained from the experimental data on saturation magnetisation and inverse susceptibility. The sign and magnitude of the exchange constants in Y₃Fe₅O₁₂ have been explained on the basis of Anderson’s theory of superexchange. The low temperature magnetisation data in Dy₃Fe₅O₁₂ have been explained by assuming canting on thec sublattice.     

Optical bistability and multistability driven by external magnetic field in a dielectric slab doped with nanodiamond nitrogen vacancy centres

Abstract

The theoretical investigation of controlling the optical bistability (OB) and optical multistability (OM) in a dielectric medium doped with nanodiamond nitrogen vacancy centres under optical excitation are reported. The shape of the OB curve from dielectric slab can be tuned by changing the external magnetic field and polarization of the control beam. The effect of the intensity of the control laser field and the frequency detuning of probe laser field on the OB and OM behaviour are also discussed in this paper. The results obtained can be used for realizing an all-optical bistable switching or development of nanoelectronic devices.     

Time evolution of entanglement and bistability of two coupled quantum dots in a driven cavity

Abstract

The time evolution of entanglement between two quantum dots (QDs) trapped inside a cavity driven by a coherent quantized field is studied. In the presence of dissipation, entanglement shows many interesting features such as sudden death and revival, and finite steady state value after sudden death. We also investigate dependence of entanglement on dot variables and its relation to bistability. It is found that entanglement vanishes when the cavity field intensity approaches the upper branch of the bistability curve. When the cavity is driven by a modulated field in the presence of dissipation, it can periodically generate entanglement, which is much larger than the maximum value attained in the steady-state for this system but the dots are never fully entangled.     

Experimental observation of low threshold optical bistability in exfoliated graphene with low oxidation degree

We have experimentally investigated low threshold Optical Bistability (OB) and multi-stability in exfoliated graphene ink with low oxidation degree. Theoretical predictions of N-layer problem and the resonator feedback problem show good agreement with the experimental observation. In contrary to the other graphene oxide samples, we have indicated that the absorbance does not restrict OB process. We have concluded from the experimental results and Nonlinear Schrödinger Equation (NLSE) that the nonlinear dispersion – rather than absorption – is the main nonlinear mechanism of OB. In addition to the enhanced nonlinearity, exfoliated graphene with low oxidation degree possesses semiconductors group III–V equivalent band gap energy, high charge carrier mobility and thus, ultra-fast optical response which makes it a unique optical material for application in all optical switching, especially in THz frequency range.     

Application of a genetic algorithm: near optimal estimation of the rate and equilibrium constants of complex reaction mechanisms

In iterative non-linear least-squares fitting, the reliable estimation of initial parameters that lead to convergence to the global optimum can be difficult. Irrespective of the algorithm used, poor parameter estimates can lead to abortive divergence if initial guesses are far from the true values or in rare cases convergence to a local optimum. For determination of the parameters of complex reaction mechanisms, where often little is known about what value these parameters should take, the task of determining good initial estimates can be time consuming and unreliable. In this contribution, the methodology of applying a genetic algorithm (GA) to the task of determining initial parameter estimates that lie near the global optimum is explained. A generalised genetic algorithm was implemented according to the methodology and the results of its application are also given. The parameter estimates obtained were then used as the starting parameters for a gradient search method, which quickly converged to the global optimum. The genetic algorithm was successfully applied to both simulated kinetic measurements where the reaction mechanism contained one equilibrium constant and two rate constants to be fitted, and to kinetic measurements of the complexation of Cu²⁺ by 1,4,8,11-tetraazacyclotetradecane where two equilibrium and two rate constants were fitted. The implementation of the algorithm is such that it can be generally applied to any reaction mechanism that can be expressed by standard chemistry notation. The control parameters of the algorithm can be varied through a simple user interface to account for parameter range and the number of parameters involved.     

溅射气压对TbFeCo磁光薄膜的光学常数的影响

利用直流磁控溅射制备了TbFeCo/Si薄膜，采用可变入射角全自动椭圆偏振光谱仪，测量了用磁控溅射法制备的TbFeCo/Si薄膜的光学常数，测量能量范围为1．5～4．5eV。分析了不同氩气压强对磁控溅射制备的TbFeCo/Si磁光薄膜的光学常数的影响。实验结果表明，在低能区域，样品的所有光学常数均随压强增加而增加，受制备工艺影响较大。但在高能区域，光学常数随压强的变化相对说来不再明显．     

Optical constants in the ultraviolet region of evaporated high index thin films

A suitable method to determine the optical constants of high index thin films is essential for developing high efficiency dielectric thin film devices in theuv region from 240 nm to 400 nm. A quick and accurate method is established to determine these constants. Using this method the optical losses, refractive index, absorption coefficient and extinction coefficient of ZrO₂ films prepared by the method of reactive evaporation were evaluated in theuv region.     

Higher order elastic constants of rare earth metals: gadolinium,dysprosium and erbium

The expressions for the second and third order elastic constants of the rare earth metals, gadolinium dysprosium and erbium have been worked out and their values have been determined. The present theoretical values are compared with the experimentally observed results. It is also suggested that the third order elastic constants of these metals may be measured using ultrasonic technique under high pressures.     

Investigation of loading assumptions on the effective electroelastic constants for PFRC materials

Single- and multiple-loading assumptions were previously used to derive the closed-form formulas for the effective constants of composite materials. This paper aims at investigating the effects of various loading assumptions, i.e., single- and multiple-loading assumptions, on the effective electroelastic constants for piezoelectric fibre reinforced composite materials. The required closed-form formulas under various loading assumptions are derived using the linear piezoelectric theory and iso-field assumptions. A numerical study reveals that the predicted electroelastic constants under various loading assumptions are generally bounded by those obtained under the single- and multiple-loading assumptions. The effective constants along the fibre direction obtained under the single-loading assumption are the same as those evaluated using the rule of mixtures, and those predicted under the multiple-loading assumption are close to the finite element analysis and testing results available in the literature.     

First-principles calculations of elastic constants for epsilon-carbide and the consequences

ABSTRACT

The elastic constants of ?-carbide at 0?K and zero pressure have been calculated using first-principle methods. The iron to carbon ratio for the carbide is not established and may, in fact, vary between 3 and 2. As a consequence, the calculations have been conducted as a function of the chemical composition using the special quasi-random structures method. In all cases, the elastic constants obtained are consistent with ?-carbide being mechanically stable. The analysis indicates that in comparison with cementite, ?-carbide should be more brittle; that when present as a precipitate in steel, it would be less effective in participating in the overall plastic deformation, and that its coherency strain field in the surrounding matrix should be less extensive than cementite.     

高度有序多孔阳极氧化铝薄膜光学常数的确定

采用二步阳极氧化法制备了多孔阳极氧化铝(PAA)薄膜,借助于扫描电子显微镜(SEM)分析了多孔阳极氧化铝薄膜的微观形貌,发现在其表面孔径为70～90 nm的六边形孔洞分布均匀,且垂直于表面平行生长.依据PAA反射光谱的实验数据,利用Kramers-Kronig关系计算出PAA薄膜的复折射率、复介电常数以及光学能隙等光学常数.通过分析吸收系数与入射光子能量之间的关系,表明PAA具有直接带隙(能隙约为3.4eV)半导体的光学性质.     

Third order elastic constants of hexagonal boron nitride

Third order elastic constants of hexagonal Boron Nitride have been evaluated using the Lannard-Jones potential. The results obtained are presented and compared with the only available measurement ofC ₃₃₃ for this material.     

Two opposite effects of sodium on elastic constants of silicate binary glasses

(1 - x)SiO₂-xNa₂O glasses have been studied by Brillouin scattering when sodium oxide molar concentration x, varies in the range 0.05 < x < 0.44. Non-linear dependence of elastic constants on sodium oxide concentration is shown unambiguously for the first time and the compressive elastic constant C₁₁ experienced a non-monotonic behaviour with a minimum value around x = 0.15. These results are compared with those obtained previously in the case of other alkali silicate glasses (Li, K). The variations of elastic constants of these glasses with the alkali metal nature and concentration are discussed on the basis of relations with the molar density of silicon atoms and the force constants between modifiers and non-bridging oxygens.     

Effects of disoriented grains on the elastic constants of directionally solidified superalloys

Two models, namely, coaxial and non-coaxial, are proposed to estimate the elastic constants of directionally solidified superalloys, which behave like transversely isotropic materials and require five independent elastic constants. Coaxial model considers each grain as an individual and obtains the averaged values. Because of the longitudinal grain structure, three independent constants are carried over from original cubic single crystal and the other two are obtainable through the averaging process. For each disoriented direction in the non-coaxial model, a lumped grain, which behaves like a transverse isotropy is proposed. By assuming the disoriented angle follows Weibull distribution, non-coaxial model obtains the expectations of compliances from probability consideration. Disoriented effect could be simulated through the parameters of Weibull distribution. Experimental off-axis Young's modulus data are compared with numerical predictions by both models. Excellent agreement is observed between coaxial model and 90° off-axis experimental data. However, the coaxial model over predicts the 45° off-axis Young's modulus, because anisotropic coupling effect is very strong in the real off-axis specimens. As non-coaxial model considers the disoriented effect, excellent agreement is observed between non-coaxial model and 45° off-axis experiment data. Disoriented grain consideration reduces the anisotropic coupling effect and predicts better to the real off-axis specimens.     

Extraction of optical constants of zinc oxide thin films by ellipsometry with various models

Spectroscopic ellipsometry was used to extract the optical constants of zinc oxide (ZnO) thin films deposited on (100) silicon substrate by filtered cathodic vacuum arc technique. Three dispersion models, namely, Sellmeier dispersion model, Cauchy model and Forouhi–Bloomer model, were evaluated for determining the optical constants of ZnO thin films below the energy band gap. The study shows that the Cauchy model provides the best spectral fittings among these three models. Above the energy band gap, two ellipsometric models, namely, two-phase model and three-phase point-by-point fit, were used. This study reveals that the initial values used in the point-by-point fitting play a critical role. It also shows that the refractive index and the extinction coefficient calculated with the two-phase model can be used as the initial values for the point-by-point fitting. The spectral dependence of the refractive index and extinction coefficient obtained in this work is comparable with the data reported in the literature. In sum, a reliable methodology for determining the optical constants of ZnO thin films in the ultraviolet-visible-near infrared range (2501100 nm) has been developed.     

Crystal structure and elastic constants of Dharwar cotton fibre using WAXS data

Wide-angle X-ray scattering (WAXS) recordings were carried out on raw Dharwar cotton fibres available in Karnataka. Using this data and employing linked atom least squares (LALS) method, we report here the molecular and crystal structure of these cotton fibres. Employing structural data, we have computed elastic moduli tensor components of these fibres. From these investigations, it turns out that the intrinsic strains present in the fibre arise due to hydrogen bonds and not covalent bonds, which is a significant result.