Study of an aqueous lithium chloride desiccant system: air dehumidification and desiccant regeneration

Desiccant systems have been proposed as energy saving alternatives to vapor compression air conditioning for handling the latent load. Use of liquid desiccants offers several design and performance advantages over solid desiccants, especially when solar energy is used for regeneration. For liquid–gas contact, packed towers with low pressure drop provide good heat and mass transfer characteristics for compact designs. This paper presents the results from a study of the performance of a packed tower absorber and regenerator for an aqueous lithium chloride desiccant dehumidification system. The rates of dehumidification and regeneration, as well as the effectiveness of the dehumidification and regeneration processes were assessed under the effects of variables such as air and desiccant flow rates, air temperature and humidity, and desiccant temperature and concentration. A variation of the Öberg and Goswami mathematical model was used to predict the experimental findings giving satisfactory results.     

太阳能液体除湿空调系统再生和蓄能特性的研究

太阳能液体除湿空调系统中,能量在液体除湿剂中以化学能的形式存在,蓄能潜力大,再生温度低,可以利用太阳能或其它低位余热和废热。着重分析了液体除湿空调系统中溶液的再生原理和再生过程的传热传质特性,对再生过程进行了实验研究,获得了再生过程对流传质和对流换热的实验准则方程,讨论了各主要因素对再生量的影响。对再生器的蓄能特性进行了分析,讨论了太阳能液体除湿空调系统蓄能工况的运行方式。     

Control performance of a dedicated outdoor air system adopting liquid desiccant dehumidification

Liquid desiccant is energy efficient for dehumidification in air-conditioning systems. In this study, a novel dedicated outdoor air system (DOAS) adopting lithium chloride solution as liquid desiccant is proposed to process supply air. The DOAS mainly consists of a membrane-based total heat exchanger, a liquid dehumidifier, a regenerator and a dry cooling coil. It can realize independent temperature and humidity controls for supply air. Control strategies for the supply air dehumidification and cooling process as well as the desiccant solution regeneration process in the DOAS are developed and verified. The control performances of the proposed dedicated outdoor air system are investigated at different operation conditions by simulation tests. The results show that the DOAS is more suitable for hot and humid climates. The effects of the total heat exchanger on the performance of the DOAS are also evaluated. It can improve the system energy performance by 19.9–34.8%.     

Experimental study of regenerative desiccant integrated solar dryer with and without reflective mirror

An indirect forced convection with desiccant integrated solar dryer has been built and tested. The main parts are: a flat plate solar air collector, a drying chamber, desiccant bed and a centrifugal blower. The system is operated in two modes, sunshine hours and off sunshine hours. During sun shine hours the hot air from the flat plate collector is forced to the drying chamber for drying the product and simultaneously the desiccant bed receives solar radiation directly and through the reflected mirror. In the off sunshine hours, the dryer is operated by circulating the air inside the drying chamber through the desiccant bed by a reversible fan. The dryer is used to dry 20 kg of green peas and pineapple slices. Drying experiments were conducted with and without the integration of desiccant unit. The effect of reflective mirror on the drying potential of desiccant unit was also investigated. With the inclusion of reflective mirror, the drying potential of the desiccant material is increased by 20% and the drying time is reduced. The drying efficiency of the system varies between 43% and 55% and the pick-up efficiency varies between 20% and 60%, respectively. Approximately in all the drying experiments 60% of moisture is removed by air heated using solar energy and the remainder by the desiccant. The inclusion of reflective mirror on the desiccant bed makes faster regeneration of the desiccant material.     

Effect of regeneration mode on the performance of liquid desiccant packed bed regenerator

The regenerator is one of the key components in liquid desiccant air-conditioning systems, in which desiccant is concentrated and can be reused in the system. The regeneration heat is supplied into the regenerator by either hot air or hot desiccant. The heat and mass transfer performances of these two regeneration modes are analyzed and compared in detail. In the hot air driven regenerator, the parallel-flow regenerator has the best mass transfer performance and the counter-flow performs poorest under the same conditions, because the heat transfer process is the governing process and the mass transfer performance depends on the promotion of the heat transfer to the mass transfer process. In the hot desiccant driven regenerator, counter-flow configuration has the best mass transfer performance and parallel-flow is the poorest at the same conditions, since mass transfer is the governing process. Regeneration heat should be chosen to heat the desiccant instead of the air in the packed bed regenerator, since the hot desiccant driven regenerator has apparent better mass transfer performance. The proposed regeneration mode and flow pattern will be helpful in the design and optimization of the regenerators.     

转轮复合式空调系统的数值计算及能耗分析

主要研究了以太阳能作为再生热源的转轮除湿和蒸气压缩制冷相结合及转轮除湿、蒸气压缩和蒸发冷却相结合的2种复合式空调系统,同时对电能作为再生热源的上述空调系统进行研究,建立了系统的物理模型,并对系统性能参数进行数学描述。通过与相同条件下常规蒸气压缩空调系统的比较分析,得出复合式空调系统制冷剂质量流量分别减少50.20％和66.67％；压缩系统性能系数COP分别提高了26.49％和32.16％；压缩机能耗分别节省了62.64％和76.92％。电能作为再生热源时,总负荷能耗分别节省了32.68％和42.00％；当采用太阳能作为再生热源时,总负荷能耗节省更多的能量,分别为61.86％和71.16％(认为1kW电能等价于3kW热能)。研究还发现,室内相对湿度相同,随室内设计温度的提高,复合式系统压缩机能耗明显减少,节能率呈上升趋势；相反总负荷能耗的节能率呈下降趋势。干热气候条件下,系统节能较为明显：71.75％和85.96％(电能再生)。热湿气候条件下,系统节能不明显,甚至消耗更多能量,而采用太阳能时,复合式系统均具有明显节能效果。     

Experimental investigation of a solar desiccant cooling installation

Desiccant cooling is a technique based on evaporative cooling and air dehumidification using desiccant regenerated by thermal energy. It is particularly interesting when it is driven by waste or solar heat making this technique environmentally friendly.In this paper, an experimental investigation is carried on a desiccant air handling unit powered by vacuum-tube solar collectors. First, the components are studied under various operating conditions. Then overall performance of the installation is evaluated over a day for a moderately humid climate with regeneration solely by solar energy. In these conditions the overall efficiency of the solar installation is 0.55 while the thermodynamic coefficient of performance is 0.45 and the performance indicator based on the electrical consumption is 4.5. Finally, the impact of outside and regeneration conditions on the performance indicators is studied.     

Experimental investigation of a liquid desiccant system for solar cooling and dehumidification

Growing demand for air conditioning in recent years has caused a significant increase in demand for primary energy resources. Solar-powered cooling is one of the environmentally-friendly techniques which may help alleviate the problem. A promising solar cooling method is through the use of a liquid desiccant system, where humidity is absorbed directly from the process air by direct contact with the desiccant. The desiccant is then regenerated, again in direct contact with an external air stream, by solar heat at relatively low temperatures. The liquid desiccant system has many potential advantages over other solar air conditioning systems and can provide a promising alternative to absorption or to solid desiccant systems.Earlier work by the authors included theoretical simulations and preliminary experiments on the key components of the liquid desiccant system. The objective of the present study has been to construct a prototype system based on the knowledge gained, to monitor its performance, identify problems and carry out preliminary design optimization. A 16 kWt system was installed at the Energy Engineering Center at the Technion, in the Mediterranean city of Haifa. The system comprises a dehumidifier and a regenerator with their associated components operating together to dehumidify the fresh (ambient) air supply to a group of offices on the top floor of the building. LiCl-water is employed as the working fluid. The system is coupled to a solar collector field and employs two methods of storage – hot water and desiccant solution in the regenerated state. The performance of the system was monitored for five summer months under varying operating conditions. The paper describes the operation of the experimental system and presents the measured data and the calculated performance parameters.     

Effectiveness of heat and mass transfer in packed beds of liquid desiccant system

A liquid desiccant system (using CaCl₂) is presented for air dehumidification using solar energy or any other low grade energy to power the system. The system utilizes two packed beds of counterflow between an air stream and a solution of liquid desiccant for the processes of air dehumidification and solution regeneration. To simplify the prediction of the performance of the system an effectiveness of heat transfer and an effectiveness of mass transfer in the packed beds are defined. A finite difference model is developed to model the heat and mass transfer in packed beds during the air dehumidification mode and the solution regeneration mode. This finite difference model is used to calculate the effectiveness of heat and mass transfer in the packed beds at various bed heights, various air and solution flow rates, various inlet temperatures of air and solution to the bed, and various concentrations of CaCl₂ solution at the bed entrance. Charts of the effectiveness of heat and mass transfer are presented in a convenient form. A designer of a liquid desiccant system may use the charts in predicting the performance of these systems without having to use the finite difference model for this purpose.     

转轮式固体干燥剂制冷空调系统的数值计算与分析

阐述了一种新型制冷空调机－转轮式固体干燥剂制冷空调系统的组成及其原理，并建立了物理模型和数学模型。在此基础上用编制的ＤＡＣＳ程序，对一种通风式系统的性能进行了计算。     

Novel, low cost CaCl2 based desiccants for solar crop drying applications

Drying with solar-heated air is satisfactory so long as the sun is shining. To continue this process through the night-time and periods of cloud cover, it is necessary to either store some of this energy in a thermal mass or incorporate desiccants within the drying system. This paper reports the results from studies undertaken to develop three low cost, solar regenerative clay–CaCl₂ based solid desiccant materials; establish their moisture sorption and regeneration characteristics; assess their performance when compared with commercial desiccants; and integrate these within a low cost solar drying system for small-scale village-based crop drying. The moisture sorption and desorption performance of the desiccants were characterised in a Fison Environmental Cabinet at conditions of 85% (RH) and 25°C for 120 h for moisture sorption and 50°C and 20% (RH) for 8 h for regeneration. These conditions were representative of the environmental conditions monitored in the solar drying system. The bentonite–CaCl₂ (type 1) desiccant gave a maximum moisture sorption of 45% dry weight basis (dwb) while bentonite–CaCl₂ (type 2) and kaolinite–CaCl₂ (type 3) solid desiccants each gave moisture sorption values of 30% (dwb). It was concluded from the moisture sorption and regeneration characteristics that their application in solar crop drying and air dehumidification is highly useful due to their low regeneration temperatures, sub 100°C.     

Evaporation rate of a novel tilted solar liquid desiccant regeneration system

The regeneration system represents a vital part of any desiccant air conditioning system. The need of a solar assisted desiccant regeneration system is more important today. In this paper, an experimental study of a novel regeneration system modified from solar tilted still is carried out. A corrugated blackened surface is used to heat the desiccant and an air flow is used to regenerate calcium chloride solution. The effect of the liquid to air flow rate ratio; the desiccant temperature; the desiccant concentration and the inlet air humidity ratio on the evaporation rate has been studied experimentally. A wide range of liquid to air flow rate ratios are employed. The optimum value of the liquid to air flow rate ratio for higher evaporation rate is reported.     

Improvement of Dehumidification Performance of Desiccant Rotors Regenerated at a Low Temperature

This paper presents a highly effective desiccant rotor that can be regenerated at a temperature between 20 and 30°C, corresponding to return air exhausted from conditioned spaces. The desiccant rotor consists of a honeycomb structure, which is coated with organic polymer desiccant materials. For a specific operating condition, the desiccant rotor functions as a rotary total heat exchanger. Desiccant rotors with thickness of 0.2 m and more lead to both higher dehumidification and temperature efficiencies compared to conventional total rotary heat exchangers in different states of the inlet process and regeneration airflows. Both the dehumidification and temperature efficiencies achieve 100% at a thickness of 0.4 m, and at rotational speeds between 100 and 300 rph. Dehumidification, together with cooling, is very effective. For the desiccant rotor with a thickness of 0.4 m, the humidity change of the process air corresponds closely to isothermal dehumidification. In terms of the dehumidification and cooling functions, the performance of the desiccant rotor with thickness of 0.2 m and more is very advantageous compared to conventional desiccant rotors and rotary total heat exchangers.     

溴化锂溶液除湿系统再生过程实验研究

溶液除湿技术是解决空调热湿解耦控制以及将废热与太阳能引入空调的有效途径.溶液再生则是溶液除湿的一个关键过程.设计了一套溴化锂溶液再生实验装置,对溶液流量、进口溶液温度、空气流量、进口空气温度、进口空气相对湿度对系统的再生性能进行了实验研究.结果表明:对于一定结构参数和进出口溶液、空气参数的再生装置,溶液流量存在一个最佳...     

Using power ultrasound for the regeneration of dehumidizers in desiccant air-conditioning systems: A review of prospective studies and unexplored issues

Regeneration of dehumidizers is the most important stage in the working cycle of desiccant system. The lower regeneration temperature will be favorable for the energy efficiency of the whole system. Ultrasonic technology may be a promising method of dehydration applied to the regeneration of desiccant. As a non-heating method, the power ultrasonic may help lower the regeneration temperature and bring about energy savings. In the present paper, the mechanism of ultrasonic regeneration is set forth based on the ultrasonic theory as well as the mass transfer model in solid–gas and liquid–gas system. The recent studies related to ultrasonic dehydration are extensively reviewed, which is of significant reference to the study of desiccant regeneration assisted by power ultrasound. In addition, this work gives the basic ideas of ultrasonic dehydrator for solid/liquid-desiccant regeneration, which will promote the development of relevant equipments. Finally, some unexplored issues on this topic are addressed, including insight into the effects of ultrasonic on the regeneration, drying kinetics model for ultrasonic regeneration and the challenges possibly faced for the ultrasonic transducer development.     

An experimental study of a solar-regenerated liquid desiccant ventilation pre-conditioning system

A solar-regenerated liquid desiccant ventilation pre-conditioning system has been installed and experiments were carried out for a period of nine months covering rainy, cold, and hot seasons in a hot and humid climate (Thailand). A heat exchanger was used to cool the dehumidified air instead of typical evaporative cooling to maintain the dryness of the air. The use of solar energy at the regeneration process and cooling water from a cooling tower makes the system more passive. The evaporation rate at the regeneration process was always greater than the moisture removal rate at the dehumidification process indicating that the concentration of the desiccant in the system would not decrease and so the performance would not drop during continuous operation. The system could reduce the temperature of the delivered air by about 1.2 °C while the humidity ratio was reduced by 0.0042 kg_w/kg_da equivalent to 11.1% relative humidity reduction. The experimental results were also compared with models in literature.     

Analysis and Modeling of a Novel Hybrid Solid–Liquid Dehumidifier System

A novel waste-heat-driven hybrid solid–liquid dehumidifier (HSLD) system is proposed and its performance modeling is carried out. This new type of dehumidification system can be efficiently driven by low-temperature heat sources such as solar energy, while achieving high dehumidification performance due to its unique serial dehumidification and regeneration processes. The process airflow is first dehumidified by a liquid dehumidifier and then by a solid one; at the same time, the regeneration air first regenerates the solid dehumidifier and then the liquid one. The reason is because the liquid dehumidifier is more efficient to dehumidify humid air with low-temperature regeneration heat, while the solid dehumidifier can effectively dehumidify drier air with higher temperature regeneration heat. Theoretical analysis and performance analysis of the HSLD system are carried out under varied process air conditions and regeneration temperatures. The results show that this new HSLD system is promising for dehumidification performance improvement with low-temperature regeneration heat. It can be efficiently driven by waste heat as low as 60～70°C with a satisfactory dehumidification performance. For the HSLD system, the dehumidification ratio between the liquid and the solid dehumidifiers varies according to the regeneration temperature and process air inlet conditions.     

Experiments in a solar simulator on solid desiccant regeneration and air dehumidification for air conditioning in a tropical humid climate

This paper presents an indoor and analytical study to evaluate the performance of a desiccant cooling system that uses silica gel as desiccant, electric light bulbs to simulate solar radiation, and forced flow of air through an IDC (integrated Desiccant/Collector). In the regeneration process, the rate at which water is removed from the desiccant increases with irradiation and decreases with air flowrate. In the air dehumidification process, the adsorption rate decreases with irradiation and increases slightly with flowrate. Comparisons between analytical calculations and experimental data show good agreement, and the calculations show that it should be possible to operate this system in tropical humid climates using the regeneration process in the day and the air dehumidification in the night time.     

Experimental and theoretical analysis of heat and mass transfer in a packed column dehumidifier/regenerator with liquid desiccant

This paper presents the experimental tests and the theoretical analysis on the chemical dehumidification of air by a liquid desiccant and desiccant regeneration in an absorption/desorption column with random packing.The experimental set-up is fully described together with measurements, procedures, data reduction and accuracy. The experimental tests include dehumidification and desiccant regeneration runs carried out with the traditional hygroscopic salt solutions H₂O/LiCl and H₂O/LiBr and the new salt solution H₂O/KCOOH in the typical operative ranges of air conditioning applications.A theoretical model of the packed column and the relative simulation computer code was developed to predict the performance of the system and to analyse the system sensitivity to the main operating parameters. A fair agreement was found between the experimental tests and the simulation computer code.The experimental tests and the theoretical analysis show that the chemical dehumidification of air by hygroscopic salt solutions ensures consistent reduction in humidity ratio, which is suitable for applications to air conditioning or drying processes. Moreover, desiccant regeneration requires a temperature level around 40–50 °C which can be easily obtained by using solar energy or heat recovered from an industrial process or from a thermal engine.     

Measurements of effectiveness in a silica gel rotary exchanger

Desiccant air conditioning systems that incorporate rotary heat and mass exchangers are getting a closer look in view of the pressure on the industry to decrease the use of chlorofluorocarbons and for fuel economies. Heat and mass exchangers that utilize LiCl, silica gel and other desiccants have been considered as possibilities. The performance features of a silica gel rotary mass exchanger wheel, which is the primary component in a desiccant system, has been measured. The process air flow velocities and temperatures ranged from 0.5 to 2.5 m/s, and 20 to 30°C with 30 to 100% relative humidities. Similar velocity and relative humidity conditions were used for regeneration air. The desiccant data are compared to two different theories from the literature; the method of characteristics and a numerical approach. The method of characteristics appears to be good for only a small range of conditions, generally for low values of specific capacities. The numerical approach appears to predict the trends well, though sometimes with large errors.