Sustainable rural bioenergy production for developing countries

Bioenergy is a renewable energy source made from biomass, which are organic materials such as plants and animals. Until enough biomass resources to ensure energy demand in the world is available, the bioenergy obtained from biomass, there may be used for heat, electrical and transport. Main biomass thermo-chemical conversion technologies are pyrolysis, gasification, and liquefaction. Biomass can be burned to produce heat and electricity, changed to gas-like fuels such as methane, hydrogen, and carbon monoxide, or changed to a liquid fuel. Modern biomass can be used for the generation of electricity and heat using modern conversion technologies. Technological advances have made modern biomass cogeneration plants cleaner, more efficient, and, under certain conditions, cost-effective as compared to public utility grids and fossil-fuel boilers or generators. Biomass can be converted to liquid biofuels: bioethanol and biodiesel. Two biofuels are becoming more and more attractive and competitive as complementary to or substitutions for petroleum basic products, due to their economic and environmental benefits.     

Biogas (a promising bioenergy source): A critical review on the potential of biogas as a sustainable energy source for gaseous fuelled spark ignition engines

Increasing demand for energy accompanied by environmental concerns has raised the requirement for limiting the use of fossil fuels in energy generation and transportation applications. Among the green and renewable energy-based solutions, biogas is quite promising since it could be implemented for power generation applications (engines driving generators and pump sets) in rural areas, at domestic and industrial scales with lower capital investment and production cost by using the agricultural crop residues and other domestic biomass sources as raw materials. However, the composition of biogas varies depending on the raw materials, and higher concentration of carbon dioxide in biogas results in combustion variations affecting engine durability. This review focuses on the role of biogas in achieving sustainable development goals with an emphasis on its utilization in gaseous fuelled spark-ignited engines. Recent progress in biogas production and upgradation techniques are also detailed. Challenges related to the stability and characteristics of biogas fuelled spark-ignited engines could be addressed by either modifying the physical parameters of the engine or by enhancing the fuel quality (upgradation to biomethane or blending with hydrogen). A comprehensive review on the effects of these approaches on the performance, combustion, and emission characteristics of biogas-fuelled engines is discussed in detail with a note on engine operating parameters.     

Biomass combustion in IEA countries

Bioenergy use and potential, biofuels and bioenergy systems including combustion equipment and technology development are reviewed in the IEA member countries participating in the combustion activity. Focus has been put on pollutant emissions, emission measurement and reduction techniques, energy and emissions from contaminated wood combustion and fuel reactivity and modelling of pyrolysis and combustion. The paper describes the status on these topics within the IEA cooperation agreements.     

Biofuels from microalgae—A review of technologies for production,processing, and extractions of biofuels and co-products

Sustainability is a key principle in natural resource management, and it involves operational efficiency, minimisation of environmental impact and socio-economic considerations; all of which are interdependent. It has become increasingly obvious that continued reliance on fossil fuel energy resources is unsustainable, owing to both depleting world reserves and the green house gas emissions associated with their use. Therefore, there are vigorous research initiatives aimed at developing alternative renewable and potentially carbon neutral solid, liquid and gaseous biofuels as alternative energy resources. However, alternate energy resources akin to first generation biofuels derived from terrestrial crops such as sugarcane, sugar beet, maize and rapeseed place an enormous strain on world food markets, contribute to water shortages and precipitate the destruction of the world's forests. Second generation biofuels derived from lignocellulosic agriculture and forest residues and from non-food crop feedstocks address some of the above problems; however there is concern over competing land use or required land use changes. Therefore, based on current knowledge and technology projections, third generation biofuels specifically derived from microalgae are considered to be a technically viable alternative energy resource that is devoid of the major drawbacks associated with first and second generation biofuels. Microalgae are photosynthetic microorganisms with simple growing requirements (light, sugars, CO₂, N, P, and K) that can produce lipids, proteins and carbohydrates in large amounts over short periods of time. These products can be processed into both biofuels and valuable co-products.This study reviewed the technologies underpinning microalgae-to-biofuels systems, focusing on the biomass production, harvesting, conversion technologies, and the extraction of useful co-products. It also reviewed the synergistic coupling of microalgae propagation with carbon sequestration and wastewater treatment potential for mitigation of environmental impacts associated with energy conversion and utilisation. It was found that, whereas there are outstanding issues related to photosynthetic efficiencies and biomass output, microalgae-derived biofuels could progressively substitute a significant proportion of the fossil fuels required to meet the growing energy demand.     

Prospects of biodiesel production from microalgae in India

Energy is essential and vital for development, and the global economy literally runs on energy. The use of fossil fuels as energy is now widely accepted as unsustainable due to depleting resources and also due to the accumulation of greenhouse gases in the environment. Renewable and carbon neutral biodiesel are necessary for environmental and economic sustainability. Biodiesel demand is constantly increasing as the reservoir of fossil fuel are depleting. Unfortunately biodiesel produced from oil crop, waste cooking oil and animal fats are not able to replace fossil fuel. The viability of the first generation biofuels production is however questionable because of the conflict with food supply. Production of biodiesel using microalgae biomass appears to be a viable alternative. The oil productivity of many microalgae exceeds the best producing oil crops. Microalgae are photosynthetic microorganisms which convert sunlight, water and CO₂ to sugars, from which macromolecules, such as lipids and triacylglycerols (TAGs) can be obtained. These TAGs are the promising and sustainable feedstock for biodiesel production. Microalgal biorefinery approach can be used to reduce the cost of making microalgal biodiesel. Microalgal-based carbon sequestration technologies cover the cost of carbon capture and sequestration. The present paper is an attempt to review the potential of microalgal biodiesel in comparison to the agricultural crops and its prospects in India.     

Are plants the new oil? Responsible innovation,biorefining and multipurpose agriculture

Bioenergy is seen as one of the options for industrialised countries to wean themselves off fossil fuels. However bioenergy, transport biofuels in particular, has faced considerable environmental and social controversies. Biorefining has been proposed in the UK and Denmark to address these concerns by using biomass efficiently for multiple purposes (food, feed, fuel, chemicals). Drawing from frameworks on responsible innovation, this paper opens up the implicit assumptions within the biorefinery concept about how biomass should be produced.Stakeholder interviews show that the biorefinery concept is framed within an industrial agricultural paradigm that aims to overcome controversies through large-scale production stimulated by biotechnology innovation. By contrast, an “alternative agriculture” paradigm envisions sustainable multipurpose biomass production in terms of on-farm nutrient and energy cycling and local, smaller scale production. However, there is a potential overlap through the concept of quality industrial biomass production. These three visions provide different perspectives on the bioeconomy in terms of the differences between biomass and fossil fuels; and where biomass should come from. Policy development for bioenergy must reckon with these different visions in innovation pathways for multipurpose biomass.     

The role of renewable and sustainable energy in the energy mix of Malaysia: a review

Energy consumption has risen in Malaysia because of developing strategies and increasing rate of population. Depletion of fossil fuel resources, fluctuation in the crude oil prices, and emersion of new environmental problems due to greenhouse gasses effects of fossil fuel combustion have convinced governments to invest in development of power generation based on renewable and sustainable energy (RSE) resources. Recently, power generation from RSE resources has been taken into account in the energy mix of every country to supply the annual electricity demand. In this paper, the scenario of the energy mix of Malaysia and the role of RSE resources in power generation are studied. Major RSE sources, namely biomass and biogas, hydro‐electricity, solar energy, and wind energy, are discussed, focusing more toward the electrical energy demand for electrification. It is found that power generation based on biomass and biogas utilization, solar power generation, and hydropower has enough spaces for more development in Malaysia. Moreover, minihydropower and wind power generation could be effective for rural regions of Malaysia. Copyright © 2014 John Wiley & Sons, Ltd.     

The potential role of hydrogen as a sustainable transportation fuel to combat global warming

Hydrogen is recognized as a key source of the sustainable energy solutions. The transportation sector is known as one of the largest fuel consumers of the global energy market. Hydrogen can become a promising fuel for sustainable transportation by providing clean, reliable, safe, convenient, customer friendly, and affordable energy. In this study, the possibility of hydrogen as the major fuel for transportation systems is investigated comprehensively based on the recent data published in the literature. Due to its several characteristic advantages, such as energy density, abundance, ease of transportation, a wide variety of production methods from clean and renewable fuels with zero or minimal emissions; hydrogen appears to be a great chemical fuel which can potentially replace fossil fuel use in internal combustion engines. In order to take advantage of hydrogen as an internal combustion engine fuel, existing engines should be redesigned to avoid abnormal combustion. Hydrogen use in internal combustion engines could enhance system efficiencies, offer higher power outputs per vehicle, and emit lower amounts of greenhouse gases. Even though hydrogen-powered fuel cells have lower emissions than internal combustion engines, they require additional space and weight and they are generally more expensive. Therefore, the scope of this study is hydrogen-fueled internal combustion engines. It is also highlighted that in order to become a truly sustainable and clean fuel, hydrogen should be produced from renewable energy and material resources with zero or minimal emissions at high efficiencies. In addition, in this study, conventional, hybrid, electric, biofuel, fuel cell, and hydrogen fueled ICE vehicles are comparatively assessed based on their CO₂ and SO₂ emissions, social cost of carbon, energy and exergy efficiencies, fuel consumption, fuel price, and driving range. The results show that when all of these criteria are taken into account, fuel cell vehicles have the highest average performance ranking (4.97/10), followed by hydrogen fueled ICEs (4.81/10) and biofuel vehicles (4.71/10). On the other hand, conventional vehicles have the lowest average performance ranking (1.21/10), followed by electric vehicles (4.24/10) and hybrid vehicles (4.53/10).     

Co-firing—A strategy for bioenergy in Poland?

Biomass provides the largest reduction of carbon dioxide (CO₂) emission when it replaces coal, which is the dominating fuel in heat and electricity production in Poland. One means of replacing coal with biomass is to co-fire biofuels in an existing coal-fired boiler. This paper presents an analysis of the strengths and weaknesses of co-firing biofuels in Poland with respect to technical, environmental, economical and strategic considerations. This analysis shows that co-firing is technically and economically the most realistic option for using biofuels in the large pulverized fuel (PF) boilers in Poland. However, from an environmental perspective, co-firing of biofuels in large combined heat and power (CHP) plants and power plants provides only a small reduction in sulphur dioxide (SO₂) emission per unit biofuel, since these plants usually apply some form of desulphurization technology. In order to maximize the SO₂ emission reduction, biofuels should be used in district heating plants. However, co-fired combustion plants can handle disruptions in biofuel supply and are insensitive to moderate changes in fuel prices, which makes them suitable utilizers of biofuels from perennial energy crops. Co-firing could therefore play an important role in stimulating perennial crop production.     

A review of hydrogen utilization in power generation and transportation sectors: Achievements and future challenges

Decarbonizing the power generation and transportation sectors, responsible for ∼65% of Green House Gas (GHG) emissions globally, constitutes a crucial step to addressing climate change. Accordingly, the energy paradigm is shifting towards carbon-free and low-emission alternative fuels. Even though the current decarbonization using hydrogen is not large since 96% of global hydrogen production is relying on conventional fossil fuels that produce GHGs in the process, hydrogen fuel has been considered a promising fuel for fuel cell and combustion engines. Various renewable approaches utilizing biomass and water have been investigated to produce green hydrogen. With this, recent developments showed viability to achieve deep decarbonization in the power generation and transportation sectors. Hydrogen-powered vehicles are commercially available in many countries, and over 300,000 fuel cell appliances were sold to produce hot water and electricity. This review aims to provide an overview of the potential role of hydrogen in power generation and transportation systems, recent achievements in research development, and technical challenges to successfully applying hydrogen as a primary fuel. Especially this review will focus on the hydrogen application in power generation and transportation sectors using fuel cells, gas turbines, and internal combustion engines (ICEs).     

Land use changes, greenhouse gas emissions and fossil fuel substitution of biofuels compared to bioelectricity production for electric cars in Austria

Bioenergy is one way of achieving the indicative target of 10% renewable energy in the transportation sector outlined in the EU Directive 2009/28/EC. This article assesses the consequences of increasing the use of bioenergy for road transportation on land use, greenhouse gas (GHG) emissions, and fossil fuel substitution. Different technologies, including first and second generation fuels and electric cars fuelled by bioelectricity are assessed in relation to existing bioenergy uses for heat and power production. The article applies a spatially explicit energy system model that is coupled with a land use optimization model to allow assessing impacts of increased biomass utilization for energy production on land use in agriculture and forest wood harvests. Uncertainty is explicitly assessed with Monte-Carlo simulations of model parameters. Results indicate that electric mobility could save GHG emissions without causing a significant increase in domestic land use for energy crop production. Costs of electric cars are still prohibitive. Second generation biofuels are more effective in producing fuels than first generation ethanol. However, competition with power and heat production from ligno-cellulosic feedstock causes an increase in GHG emissions when introducing second generation fuels in comparison to a baseline scenario.     

Life cycle assessment of various cropping systems utilized for producing biofuels: Bioethanol and biodiesel

A life cycle assessment of different cropping systems emphasizing corn and soybean production was performed, assuming that biomass from the cropping systems is utilized for producing biofuels (i.e., ethanol and biodiesel). The functional unit is defined as 1 ha of arable land producing biomass for biofuels to compare the environmental performance of the different cropping systems. The external functions are allocated by introducing alternative product systems (the system expansion allocation approach). Nonrenewable energy consumption, global warming impact, acidification and eutrophication are considered as potential environmental impacts and estimated by characterization factors given by the United States Environmental Protection Agency (EPA-TRACI). The benefits of corn stover removal are (1) lower nitrogen related environmental burdens from the soil, (2) higher ethanol production rate per unit arable land, and (3) energy recovery from lignin-rich fermentation residues, while the disadvantages of corn stover removal are a lower accumulation rate of soil organic carbon and higher fuel consumption in harvesting corn stover. Planting winter cover crops can compensate for some disadvantages (i.e., soil organic carbon levels and soil erosion) of removing corn stover. Cover crops also permit more corn stover to be harvested. Thus, utilization of corn stover and winter cover crops can improve the eco-efficiency of the cropping systems. When biomass from the cropping systems is utilized for biofuel production, all the cropping systems studied here offer environmental benefits in terms of nonrenewable energy consumption and global warming impact. Therefore utilizing biomass for biofuels would save nonrenewable energy, and reduce greenhouse gases. However, unless additional measures such as planting cover crops were taken, utilization of biomass for biofuels would also tend to increase acidification and eutrophication, primarily because large nitrogen (and phosphorus)-related environmental burdens are released from the soil during cultivation.     

Energy and environmental balance of biogas for dual-fuel mobile applications

Considerable research is currently being devoted to seeking alternative fuels to comply with transportation needs while reducing the environmental impact of this sector. Within the transport activity sector, on road vehicles and agricultural machinery require around 2 Mtoe energy in France. The anaerobic digestion of farm waste could roughly cover these needs. This paper aims to study the environmental and energy interest of this short power supply path. An ideal biogas production system has been built up from the average characteristics of current rural biogas plants in France. Pollutant emissions, energy demands and production are assessed for various scenarios in order to produce methane for dual fuel engines. Life cycle assessment (LCA) is used to evaluate the environmental impact of dual fuel agricultural machines, compared to diesel engines. The energy balance is always in disfavour of biogas fuel, whereas LCA energy indicators indicate a benefit for biogas production. This gap is related to the way in which the input of biomass energy is handled: in conventional biofuel LCA, this energy is not taken into account. A carbon balance is then presented to discuss the impact of biogas on climate change. Dual fuel engines were found to be interesting for their small impact. We also show, however, how the biogenic carbon assumption and the choice of allocation for the avoided methane emissions of anaerobic digestion are crucial in quantifying CO₂ savings. Other environmental issues of biogas fuel were examined. Results indicate that are management and green electricity are the key points for a sustainable biogas fuel. It is concluded that biofuel environmental damage is reduced if energy needs during biofuel production are covered by the production process itself. As agricultural equipment is used during the biofuel production process, this implies that a high substitution rate should be used for this equipment.     

Cost-effective policy instruments for greenhouse gas emission reduction and fossil fuel substitution through bioenergy production in Austria

Climate change mitigation and security of energy supply are important targets of Austrian energy policy. Bioenergy production based on resources from agriculture and forestry is an important option for attaining these targets. To increase the share of bioenergy in the energy supply, supporting policy instruments are necessary. The cost-effectiveness of these instruments in attaining policy targets depends on the availability of bioenergy technologies. Advanced technologies such as second-generation biofuels, biomass gasification for power production, and bioenergy with carbon capture and storage (BECCS) will likely change the performance of policy instruments. This article assesses the cost-effectiveness of energy policy instruments, considering new bioenergy technologies for the year 2030, with respect to greenhouse gas emission (GHG) reduction and fossil fuel substitution. Instruments that directly subsidize bioenergy are compared with instruments that aim at reducing GHG emissions. A spatially explicit modeling approach is used to account for biomass supply and energy distribution costs in Austria. Results indicate that a carbon tax performs cost-effectively with respect to both policy targets if BECCS is not available. However, the availability of BECCS creates a trade-off between GHG emission reduction and fossil fuel substitution. Biofuel blending obligations are costly in terms of attaining the policy targets.     

Present and prospective role of bioenergy in regional energy system

Bioenergy is the energy released from the reaction of organic carbon material with oxygen. The organic material derived from plants and animals is also referred to as biomass. Biomass is a flexible feedstock capable of conversion into solid, liquid and gaseous fuels by chemical and biological processes. These intermediate biofuels (such as methane gas, ethanol, charcoal) can be substituted for fossil based fuels. Wood and charcoal are important as household fuels and for small scale industries such as brick making, cashew processing etc. The scarcity of biofuels has far reaching implications on the environment. Hence, expansion of bioenergy systems could be influential in bettering both the socio-economic condition and the environment of the region. This paper examines the present role of biomass in the region’s (Uttara Kannada District, Karnataka State, India) energy supply and calculates the potential for future biomass provision and scope for conversion to both modern and traditional fuels. Based on the detailed investigation of biomass resource availability and demand, we can categorise the Uttara Kannada District into two zones (a) Biomass surplus zone consisting of Taluks mainly from hilly area (b) Biomass deficit zone, consisting of thickly populated coastal Taluks such as Bhatkal, Kumta, Ankola, Honnavar and Karwar. Fuel wood is mainly used for cooking and horticulture residues from coconut, arecanut trees are used for water heating purposes. Most of the households in this region still use traditional stoves where efficiency is less than 10%. The present inefficient fuel consumption could be brought down by the usage of fuel efficient stoves (a saving of the order of 27%). Availability of animal residues for biogas generation in Sirsi, Siddapur, Yellapur Taluks gives a viable alternative for cooking, lighting fuel and a useful fertiliser. However to support the present livestock population, fodder from agricultural residues is insufficient in these Taluks. There is a need to supplement the fodder availability with fodder crops as successfully tried in Banavasi village by some progressive farmers.     

Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 2: Gasification systems

Gasification as a thermo-chemical process is defined and limited to combustion and pyrolysis. The gasification of biomass is a thermal treatment, which results in a high production of gaseous products and small quantities of char and ash. The solid phase usually presents a carbon content higher than 76%, which makes it possible to use it directly for industrial purposes. The gaseous products can be burned to generate heat or electricity, or they can potentially be used in the synthesis of liquid transportation fuels, H₂, or chemicals. On the other hand, the liquid phase can be used as fuel in boilers, gas turbines or diesel engines, both for heat or electric power generation. However, the main purpose of biomass gasification is the production of low- or medium heating value gas which can be used as fuel gas in an internal combustion engine for power production. In addition to limiting applications and often compounding environmental problems, these technologies are an inefficient source of usable energy.     

Biofuels and thermal barrier: A review on compression ignition engine performance,combustion and exhaust gas emission

The performance of an internal combustion engine is affected when renewable biofuels are used instead of fossil fuels in an unmodified engine. Various engine modifications were experimented by the researchers to optimise the biofuels operated engine performance. Thermal barrier coating is one of the techniques used to improve the biofuels operated engine performance and combustion characteristics by reducing the heat loss from the combustion chamber. In this study, engine tests results on performance, combustion and exhaust emission characteristics of the biofuels operated thermal barrier coated engines were collated and reviewed. The results found in the literature were reviewed in three scenarios: (i) uncoated versus coated engine for fossil diesel fuel application, (ii) uncoated versus coated engine for biofuels (and blends) application, and (iii) fossil diesel use on uncoated engine versus biofuel (and blends) use on coated engine. Effects of injection timing, injection pressure and fuel properties on thermal barrier coatings were also discussed. The material type, thickness and properties of the coating materials used by the research community were presented. The effectiveness and durability of the coating layer depends on two key properties: low thermal conductivity and high thermal expansion coefficient. The current study showed that thermal barrier coatings could potentially offset the performance drop due to use of biofuels in the compression ignition engines. Improvements of up to 4.6% in torque, 7.8% in power output, 13.4% in brake specific fuel consumption, 15.4% in brake specific energy consumption and 10.7% in brake thermal efficiency were reported when biofuels or biofuel blends were used in the thermal barrier coated engines as compared to the uncoated engines. In coated engines, peak cylinder pressure and exhaust gas temperature were increased by up to 16.3 bar and 14% respectively as compared to uncoated condition. However, changes in the heat release rates were reported to be between ?27% and +13.8% as compared to uncoated standard engine. Reductions of CO, CO₂, HC and smoke emissions were reported by up to 3.8%, 11.1%, 90.9% and 63% respectively as compared to uncoated engines. Significant decreases in the PM emissions were also reported due to use of thermal barrier coatings in the combustion chamber. In contrast, at high speed and at high load operation, increase in the CO and CO₂ emissions were also reported in coated engines. Coated engines gave higher NO_x emissions by about 4–62.9% as compared to uncoated engines. Combined effects of thermal barrier coatings and optimisation of fuel properties and injection parameters produced further performance and emissions advantages compared to only thermal barrier coated engines. Overall, current review study showed that application of thermal barrier coatings in compression ignition engines could be beneficial when biofuels or biofuel blends are used instead of standard fossil diesel. However, more research is needed combining coatings, types of biofuels and other engine modifications to establish a concrete conclusion on the effectiveness of the thermal barrier when biofuels are used in the compression ignition engine. Reduction of NO_x emissions is another important R & D area.     

Perspectives of Stirling engines use for distributed generation in Brazil

This work presents an evaluation of the development of Stirling engines and the advantages and the main obstacles against their widespread introduction in energy-generation practices. It also shows how the economic, technical and environmental characteristics presented by these engines support their insertion in the energy sector. An economic and environmental evaluation of this technology aiming at introducing it in the Brazilian energy scenario is also presented. Changes in legislation, financing and technology within the next few years must encourage the implementation of alternative generation technologies that present lower environmental impacts. Also, tendencies and economical studies are presented, trying to find the optimal condition for this technology to be feasible. The option regarding the trading of carbon credits when biomass is used as fuel is analyzed as well.     

Performance of biodiesel/higher alcohols blends in a diesel engine

Alcohols extensively used in internal combustion engines are important renewable and sustainable energy resources from environmental and economical perspectives. Besides, bio production of alcohols decreases consumption of fossil‐based fuels. Although there are many studies with regards to the use of lower alcohols such as methanol and ethanol in internal combustion engines, there are a limited number of investigations with higher alcohols. Higher alcohols such as propanol, n‐butanol, and 1‐pentanol are part of the next generation of biofuels, given they provide better fuel properties than lower alcohols. Biodiesel–higher alcohol blends can be used in diesel engines without any engine modification but need to be tested under various engine conditions with long periods in order to evaluate their impacts on engine performance and environmental pollutants. The objective of this study was to evaluate the effect of using propanol, n‐butanol, and 1‐pentanol in waste oil methyl ester (B100) on engine performance and exhaust emissions of a diesel engine running at different loads (0, 3, 6, and 9 kW) with a fixed engine speed (1800 rpm). Test fuel blends were prepared by adding propanol, n‐butanol, and 1‐pentanol (10 vol.%) into waste oil methyl ester to achieve blends of B90Pr10, B90nB10, and B90Pn10, respectively. According to engine performance and exhaust emissions results, the addition of propanol, n‐butanol, and 1‐pentanol to B100 had the effect of increasing brake specific fuel consumption and exhaust gas temperatures. The brake thermal efficiency (BTE) decreased for B90Pr10 and B90nB10, while B90Pn10 showed a slight increase in BTE as compared with B100. When compared with B100, B90Pr10, B90nB10, and B90Pn10 decreased carbon monoxide emissions at lower loads while it increased slightly at 9 kW load. The decrement in oxides of nitrogen emission was observed at whole loads for B90Pr10, B90nB10, and B90Pn10 compared with B100. When considering all loads, B90Pn10 presented the best mean hydrocarbon emission with a reduction of 45.41%. Copyright © 2016 John Wiley & Sons, Ltd.     

Spray combustion of fast pyrolysis bio-oils: Applications,challenges, and potential solutions

This article provides a comprehensive review of the spray combustion of fast pyrolysis bio-oil (FPBO, also called bio-oil, pyrolysis oil or pyrolysis liquid biofuel), which is widely regarded as one of the most economically feasible renewable resources to facilitate the replacement of fossil oils. The utilization of FPBO as a fuel is challenging due to its unique atomization and combustion characteristics but it is important given the need to develop a more sustainable energy infrastructure. Significant efforts have been made in utilizing FPBO as a practical alternative fuel and the first FPBO facilities for heat and/or power generation have been brought online in recent years. FPBO-fueled burners, boilers, and furnaces are ready from a technical perspective for large-scale industrial use, and even small-scale systems show excellent flame stability, low emissions, and minimal requirements for secondary fuel usage. FPBO applications in gas turbine and compression-ignition engines are technically more challenging, currently having had only limited successes in larger-scale units and for short time intervals in smaller ones. With recent research and technological advances, however, FPBO use in small-scale combustion engines appears to be technically feasible. In the literature, extensive research efforts have been dedicated to this topic either as a fuel itself or its utilization for practical applications. Nonetheless, inadequate considerations have been given to the critical role of FPBO atomization and its subsequent fuel/air mixing, which in turn controls the combustion efficiency and emission characteristics of a system. Understanding the spray combustion properties of FPBO is especially important because of the fuel's unfavorable properties compared to fossil oils including low energy density, high viscosity, high water content, containing suspended solid particulates and non-volatile residue, chemical instability, and an incompatibility with conventional fossil oils. The information presented herein, therefore, focuses on understanding the challenges and constraints that are unique to FPBO applications, along with proposing several strategies to properly atomize and combust this fuel in order to enhance combustion efficiency and reduce pollutant emissions in practical systems. Although substantial progress has been made in understanding the FPBO spray combustion as revealed by this review, better standardization of FPBO properties, more efficient techniques for optimizing atomization and combustion for different applications, and more studies to understand the long-term reliability of devices running on FPBO are needed.