太阳能超临界有机朗肯循环的工质选择和性能分析

选取R123、R134a、R152a、R22和R245fa 5种有机工质作为候选工质进行太阳能超临界有机朗肯循环的计算和分析。结果表明:当膨胀机出口工质过热度一定时,太阳能超临界有机朗肯循环的热效率高于亚临界工况,且R123在系统热效率方面表现出比其他工质更加明显的优势,是一种较理想的有机工质。以R123为例,蒸发器出口温度一定时,随着蒸发压力的升高,有机朗肯循环的工质流量不断增大。蒸发压力一定时,随着蒸发器出口温度的升高,工质流量不断减小,循环热效率先增后减,存在一个最佳的蒸发器出口温度,此时循环热效率最大。     

低温太阳能热力发电有机朗肯循环工质的选择

为了筛选出适宜于低温太阳能热力发电有机朗肯循环的工质,根据 PR 状态方程计算和分析了采用 11 种低沸点有机流体工质的低温太阳能发电朗肯循环的热力性能.结果表明:随着工质临界温度的升高,有机透平进口处的最大蒸发压力基本呈下降趋势;在凝结温度与有机透平进口温度一定的情况下,临界温度越高的流体,其循环热效率越高;使用正已烷和正戊烷能获得较高的循环热效率,凝汽器中的凝结压力比较适中,是比较适合用作低温太阳能热力发电有机朗肯循环的工质.     

有机朗肯循环在低温余热利用领域的应用分析

本文计算比较了 R134a,R245fa,R141b三种典型有机工质在特定传热条件下的朗肯循环热效率情况,最后选择R134a作为系统循环工质.以某化工厂温度为105℃的排空蒸汽余热为案例,提出了有机工质朗肯循环的简化模型,并且在理论上对其进行了热效率和火用效率的分析.依据条件通过计算选择了压比为4的螺杆膨胀机代替了传统...     

中低温热水发电系统循环参数和工质的选择

针对热源为80～150℃热水的有机朗肯循环（ORC）发电系统,以发电功率和效率为评价指标,分别分析了以R134a、R123和R245fa三种工质为循环介质时的系统,确定了最佳循环参数和工质。一般来说,最佳蒸发温度对应着最大的输出电功,且随着热流体温度的升高而升高;当热源温度大于120℃时,R134a的系统不存在最佳蒸发温度,此时输出电功随着蒸发温度的升高而增大。对于80～135℃的热水,工质R245fa的发电功率最大;当热水温度超过135℃时,工质R134a的发电功率最大。工质R245fa的发电效率始终是最大的。     

低温地热有机朗肯循环(ORC)工质选择

对低温(60～150℃)地热有机朗肯循环(ORC)系统,以净输出电功和系统能量损失作为评价指标,分析不同地热流体温度下有机工质R290,R134a,R600a,R600,R601a的做功能力,确定最佳循环工质.分析结果表明:对于湿流体工质,由于临界温度较低,当地热流体温度高于其临界温度20℃时,不存在最佳蒸发温度:对于60～80℃的地热流体,工质R601a的最大净输出电功最大;对于90～120℃的地热流体,工质R134a的最大净输出电功最大;对于125～150℃的地热流体,工质R290的净输出电功最大.这些结果为中低温地热利用提供设计依据.     

非共沸混合工质用于C-ORC系统的热力学分析

以低温烟气为热源,以R245fa、R152a及不同比例R245fa/R152a混合物为工质,提出新型的再热-抽汽-内回热联合有机朗肯循环(C-ORC)系统,基于美国NIST提供的制冷剂物性参数查询软件(REFPROP)及数学处理软件(MATLAB)混合编程,以净输出功和热效率为主要目标参数,分析系统性能随抽汽回热器出口温度、再热温度、不同比例混合工质的变化关系。结果表明,相同蒸发温度下纯工质R245fa的热力性能优于R152a,其最佳的抽汽回热器出口温度分别为70和55℃,抽汽回热器出口温度对系统的影响要大于再热温度的影响;混合工质分析中,在70℃抽汽回热器出口温度、105℃再热温度下,存在R245fa/R152a最佳质量分数比0.85/0.15,对应的净输出功为37.18 k W、热效率为18.52%、火用损为30.08 k W,其中蒸发器、冷凝器所占的火用损最大。     

不同工质对太阳能有机朗肯循环系统性能的影响

循环工质的特性是影响有机朗肯循环系统性能的重要因素之一,在不同的蒸发温度条件下,选取R600、R600a、R245fa、R236fa、R236ea、R601、R601a、RC318及R227ea共9种有机工质,基于热力学第一定律和第二定律对其热力循环特性进行了计算分析,并对各有机工质的蒸发压力、热效率、功比和不可逆损失等进行了比较.结果表明：R245fa作为太阳能低温热发电朗肯循环系统的循环工质具有较高的热效率和效率,并且产生的系统总不可逆损失较小,是一种较理想的有机工质;其次,R236fa和R236ea作为系统循环工质也具有较为良好的性能.     

耦合跨临界有机朗肯循环和蒸气压缩制冷循环系统经济性分析

提出了一种由烟气余热驱动的耦合跨临界有机朗肯循环(TORC)和蒸气压缩制冷循环(VCR)的冷电联产复合系统(PRCS),并以年净利润为评价指标、分别以R22、R134a和R290为循环工质对该复合系统进行了经济性分析。结果表明:在一定热源条件下,随着膨胀机进口压力的提高,年净利润先增大、后减小。当烟气温度较低、冷量需求不大时,采用R134a工质的系统年净利润最大;当烟气温度较高、冷量需求较大时,则R22更具优势。提高烟气进口温度和冷媒水出口温度、降低工质冷凝温度都可以有效提高系统经济性。     

有机朗肯循环与再热式循环低温热源发电系统热力性能研究

针对120℃以下的低温余热热源,探讨了基本有机郎肯循环发电系统和再热式有机朗肯循环发电系统模型的基本原理.从热力学第一定律角度出发,研究了纯工质R245fa和非共沸混合工质R21/R245fa在基本有机郎肯循环系统中,以及纯工质R245fa在再热式有机郎肯循环系统中,三种形式的有机郎肯循环系统热力性能随蒸发温度的变化情况.与纯工质基本有机郎肯循环系统相比,再热式有机郎肯循环最大可提高系统净输出功7.08％,而混合工质对提高整个系统热力性能具有较大的优势,净输出功和热效率最大可提高4.67％和2.91％.     

中温地热能驱动的跨临界有机朗肯-蒸气压缩制冷系统的性能分析

跨临界有机朗肯?蒸气压缩制冷系统可以使工质与地热流体更好地匹配,减小系统的不可逆性。本文建立该系统的热力学模型,利用EES软件编程,分别对以R143a、R218及R125为工质的系统进行性能分析。计算结果表明,相比R218及R125,以R143a为工质的系统的性能是最佳的。为了避免膨胀机内产生湿蒸气,对于一定的膨胀机进口温度,膨胀机入口存在一个极限压力,并且存在一个最优压力使得系统的性能最佳。地热流体温度的升高可以提高系统的制冷能力,但系统的性能系数则随之先增大后减小;随着地热流体干度的增加,地热流体释放的潜热会大大增加系统的制冷量,而系统的性能系数保持不变。冷凝温度及蒸发温度对系统性能有着重要影响,其中冷凝温度的影响更为明显。以R143a为工质的跨临界有机朗肯?蒸气压缩制冷系统的最佳性能优于以R245fa为工质的亚临界有机朗肯-蒸气压缩制冷系统的最佳性能。     

Ash-forming elements in four Scandinavian wood species. Part 1: Summer harvest

Woody biomass in Finland and Sweden comprises mainly four wood species: spruce, pine, birch and aspen. To study the ash, which may cause problems for the combustion device, one tree of each species were cut down and prepared for comparisons with fuel samples. Well-defined samples of wood, bark and foliage were analyzed on 11 ash-forming elements: Si, Al, Fe, Ca, Mg, Mn, Na, K, P, S and Cl. The ash content in the wood tissues (0.2–0.7%) was low compared to the ash content in the bark tissues (1.9–6.4%) and the foliage (2.4–7.7%). The woods’ content of ash-forming elements was consequently low; the highest contents were of Ca (410–1340 ppm) and K (200–1310), followed by Mg (70–290), Mn (15–240) and P (0–350). Present in the wood was also Si (50–190), S (50–200) and Cl (30–110). The bark tissues showed much higher element contents; Ca (4800–19,100 ppm) and K (1600–6400) were the dominating elements, followed by Mg (210–2400), P (210–1200), Mn (110–1100) and S (310–750), but the Cl contents (40–330) were only moderately higher in the bark than in the wood. The young foliage (shoots and deciduous leaves) had the highest K (7100–25,000 ppm), P (1600–5300) and S (1100–2600) contents of all tissues, while the shoots of spruce had the highest Cl contents (820–1360) and its needles the highest Si content (5000–11,300). This paper presented a new approach in fuel characterization: the method excludes the presence of impurities, and focus on different categories of plant tissues. This made it possible to discuss the contents of ash element in a wide spectrum of fuel-types, which are of large importance for the energy production in Finland and Sweden.     

NEXT GENERATION ENGINEERED MATERIALS FOR ULTRA SUPERCRITICAL STEAM TURBINES

正1 ABSTRACT To reduce the effect of global warming on our climate,the levels of CO2emissions should be reduced.One way to do this is to increase the efficiency of electricity production from fossil fuels.This will in turn reduce the amount of CO2emissions for a given power output.Using US practice for efficiency calculations,then a move from a typical US plant running at 37%efficiency to a 760℃/38.5 MPa(1 400/5 580 psi)plant running at 48%efficiency would reduce CO2emissions by 170kg/MW.hr or 25%.     

Contents in Volume 23,2014

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Aerodynamic performance effects of leading-edge geometry in gas-turbine blades

The purpose of this paper is to illustrate the advantages of the direct surface-curvature distribution blade-design method, originally proposed by Korakianitis, for the leading-edge design of turbine blades, and by extension for other types of airfoil shapes. The leading edge shape is critical in the blade design process, and it is quite difficult to completely control with inverse, semi-inverse or other direct-design methods. The blade-design method is briefly reviewed, and then the effort is concentrated on smoothly blending the leading edge shape (circle or ellipse, etc.) with the main part of the blade surface, in a manner that avoids leading-edge flow-disturbance and flow-separation regions. Specifically in the leading edge region we return to the second-order (parabolic) construction line coupled with a revised smoothing equation between the leading-edge shape and the main part of the blade. The Hodson–Dominy blade has been used as an example to show the ability of this blade-design method to remove leading-edge separation bubbles in gas turbine blades and other airfoil shapes that have very sharp changes in curvature near the leading edge. An additional gas turbine blade example has been used to illustrate the ability of this method to design leading edge shapes that avoid leading-edge separation bubbles at off-design conditions. This gas turbine blade example has inlet flow angle 0°, outlet flow angle −64.3°, and tangential lift coefficient 1.045, in a region of parameters where the leading edge shape is critical for the overall blade performance. Computed results at incidences of −10°,   −5°,   +5°,   +10° are used to illustrate the complete removal of leading edge flow-disturbance regions, thus minimizing the possibility of leading-edge separation bubbles, while concurrently minimizing the stagnation pressure drop from inlet to outlet. These results using two difficult example cases of leading edge geometries illustrate the superiority and utility of this blade-design method when compared with other direct or inverse blade-design methods.     

Hydrogen production by steam-gasification of carbonaceous materials using concentrated solar energy – V. Reactor modeling,optimization, and scale-up

A chemical reactor for the steam-gasification of carbonaceous particles (e.g. coal, coke) is considered for using concentrated solar radiation as the energy source of high-temperature process heat. A two-phase reactor model that couples radiative, convective, and conductive heat transfer to the chemical kinetics is applied to optimize the reactor geometrical configuration and operational parameters (feedstock's initial particle size, feeding rates, and solar power input) for maximum reaction extent and solar-to-chemical energy conversion efficiency of a 5 kW prototype reactor and its scale-up to 300 kW. For the 300 kW reactor, complete reaction extent is predicted for an initial feedstock particle size up to 35 μm at residence times of less than 10 s and peak temperatures of 1818 K, yielding high-quality syngas with a calorific content that has been solar-upgraded by 19% over that of the petcoke gasified.     

汽轮机数字电液调节系统挂闸异常的技术完善

分析了200MW汽轮机数字电液调节系统在运行中存在的挂闸异常问题,采取了相应的技术处理措施,且运行实践效果良好。     

新型高压共轨ECU升压模块的数字化开发与优化

为了提高喷油器电磁阀的响应速率,提出了一种基于CPLD(复杂可编程逻辑器件)应用于高压共轨ECU的数字升压模块。鉴于该升压电路结构参数多,其升压电压的恢复响应要求高等特征,基于Pspice建立了升压电路的仿真模型,研究了不同电路参数下升压模块的输出特性,全面优化了该升压模块的性能。结果显示,该升压模块的最大转换效率可以达90%以上。在柴油发动机上对ECU的试验表明,升压电压最大波动不超过10%,其恢复时间仅为1.3ms,功率管最大温升仅为41℃,满足整机运行范围内ECU的需求。     

Trace metal chemistry and silicification of microorganisms in geothermal sinter, Taupo Volcanic Zone, New Zealand

As part of a pilot study investigating the role of microorganisms in the immobilisation of As, Sb, B, Tl and Hg, the inorganic geochemistry of seven different active sinter deposits and their contact fluids were characterised. A comprehensive series of sequential extractions for a suite of trace elements was carried out on siliceous sinter and a mixed silica-carbonate sinter. The extractions showed whether metals were loosely exchangeable or bound to carbonate, oxide, organic or crystalline fractions. Hyperthermophilic microbial communities associated with sinters deposited from high temperature (92–94°C) fluids at a variety of geothermal sources were investigated using SEM. The rapidity and style of silicification of the hyperthermophiles can be correlated with the dissolved silica content of the fluid. Although high concentrations of Hg and Tl were found associated with the organic fraction of the sinters, there was no evidence to suggest that any of the heavy metals were associated preferentially with the hyperthermophiles at the high temperature (92–94°C) ends of the terrestrial thermal spring ecosystems studied.     

Assessment methods of material ageing using Sdobyrev''s creep rupture model

The physical aspects of the activation energy, in higher and high temperatures, of the metal creep process were examined. The research results of creep-rupture in a uniaxial stress state and the criterion of creep-rupture in biaxial stress states, at two temperatures, are then presented. For these studies creep-rupture, taking case iron as an example the energy and pseudoenergy activation was determined. For complex stress states the criterion of creep-rupture was taken to be Sdobyrev's, i.e. σ_red = σ₁ β + (1 − β)σ_i, where: σ₁-maximal principal stress, σ_i-stress intensity, β-material constant (at variable temperature β = β(T)). The methods of assessment of the material ageing grade are given in percentages of ageing of new material in the following mechanical properties: 1) creep strength in uniaxial stress state, 2) activation energy in uniaxial stress state, 3) criterion creep strength in complex stress states, 4) activation pseudoenergy in complex stress states. The methods 1) and 3) are the relatively simplest because they result from experimental investigations only at nominal temperature of the structure work, however, for methods 2) and 4) it is necessary to perform the experimental investigations at least at two temperatures.     

Production of hydrogen from sewage biosolids in a continuously fed bioreactor: Effect of hydraulic retention time and sparging

Hydrogen was produced from primary sewage biosolids via mesophilic anaerobic fermentation in a continuously fed bioreactor. Prior to fermentation the sewage biosolids were heated to 70 °C for 1 h to inactivate methanogens and during fermentation a cellulose degrading enzyme was added to improve substrate availability. Hydraulic retention times (HRT) of 18, 24, 36 and 48 h were evaluated for the duration of hydrogen production. Without sparging a hydraulic retention time of 24 h resulted in the longest period of hydrogen production (3 days), during which a hydrogen yield of 21.9 L H₂ kg⁻¹ VS added to the bioreactor was achieved. Methods of preventing the decline of hydrogen production during continuous fermentation were evaluated. Of the techniques evaluated using nitrogen gas to sparge the bioreactor contents proved to be more effective than flushing just the headspace of the bioreactor. Sparging at 0.06 L L min⁻¹ successfully prevented a decline in hydrogen production and resulted in a yield of 27.0  L H₂ kg⁻¹ VS added, over a period of greater than 12 days or 12 HRT. The use of sparging also delayed the build up of acetic acid in the bioreactor, suggesting that it serves to inhibit homoacetogenesis and thus maintain hydrogen production.