Colloidal Silica Transport through Liquefiable Porous Media

Mitigation of liquefaction potential in loose granular soil can theoretically be achieved through permeation and subsequent gelation of dilute colloidal silica stabilizer. However, practical application of this technique requires efficient and adequate delivery of the stabilizer to the liquefiable soil prior to gelation. The purpose of this research was to evaluate colloidal silica transport mechanisms and to determine if an adequate concentration can be delivered to a soil column prior to gelation. The laboratory work consisted of grouting 15 short (0.9 m) columns tests packed with Nevada No. 120, Ottawa 20/30, or graded silty sand to identify the variables that influence stabilizer transport through porous media. It was found that colloidal silica can be successfully delivered through 0.9-m columns packed with loose sand efficiently and in an adequate concentration to mitigate the liquefaction potential. Transport occurs primarily by advection with limited hydrodynamic dispersion, so Darcy’s law can be used to predict flow. The Kozeny-Carmen equation can be used to include the effect of increasing viscosity on transport by incorporating the power law mixing rule of Todd. The primary variables influencing stabilizer transport were found to be the viscosity of the colloidal silica stabilizer, the hydraulic gradient, and the hydraulic conductivity of the liquefiable soil.     

Experimental Investigations of Colloidal Silica Grouting in Porous Media

This paper presents the results of an experimental investigation performed to understand the processes influencing the injection of colloidal silica grout into porous media. Based on the combined analysis of grout injection pressures and the visually observed grout distribution patterns, three major processes, gelation, shear, and viscous fingering, have been identified to occur during grout injection. The results demonstrate the dynamic interplay between grout viscosity variations and the resulting flow instabilities.     

Full-Scale Field Testing of Colloidal Silica Grouting for Mitigation of Liquefaction Risk

This paper reports results of a full-scale field test to assess the performance of dilute colloidal silica stabilizer in reducing the settlement of liquefiable soil. Slow injection methods were used to treat a 2-m-thick layer of liquefiable sand. Eight injection wells were installed around the perimeter of the 9-m-diameter test area and 8% by weight colloidal silica grout was slowly injected into the upper 2?m of a 10-m-thick layer of liquefiable sand. A central extraction well was used during grout injection to direct the flow of the colloidal silica towards the center of the test area. Details of the field injection are described. Subsequently, the injection wells were used to install explosive charges and liquefaction was induced by blasting. After blasting, approximately 0.3?m of settlement occurred versus 0.5?m of settlement in a nearby untreated area. The mechanism of improvement is thought to be bonding between the colloidal silica and the individual sand particles; the colloidal silica gel encapsulates the soil structure and maintains it during dynamic loading.     

Experimental Study of Horizontal Barrier Formation by Colloidal Silica

Migration of non-aqueous-phase liquids (NAPLs) such as trichloroethylene or gasoline can be controlled by barrier systems. The research presented in this paper aims to form a horizontal layer by injecting gelling liquids and to test the ability of horizontal barriers to isolate the downward migration of NAPLs in subsurface environments. We developed a methodology in the laboratory to form a contiguous horizontal barrier by injecting gelling liquids through horizontal and vertical wells. A series of batch, column, and 2D sandbox experiments were conducted to investigate the gel development and horizontal barrier formation. Prior to 2D barrier formation experiments, two different methods were employed to measure pre- and postinjection hydraulic conductivity in 1D columns to quantify hydraulic conductivity reductions. After an impervious grout formed, the durability of the grouted porous media in the presence of two NAPL contaminants was investigated. The hydraulic conductivity of filter sand treated with colloidal silica was reduced by 100% in 1D column experiments. In 2D experiments, a contiguous horizontal layer was formed by horizontal or vertical injection of the gelling liquid. The grouted material in 1D columns worked well in controlling the downward migration of contaminants. Although some penetration of the gelled layer by the contaminant was observed, the integrity of the horizontal layer was preserved. Finally, based on scaled capillary pressure versus saturation relationships, it was determined that capillary pressures can reduce as much as 50% with gelling of the colloidal silica solutions.     

Effect of Dilution and Contaminants on Sand Grouted with Colloidal Silica

Colloidal silica is a low-viscosity chemical grout. Samples of grouted sand were made by pouring sand into liquid grout in molds, with the grout diluted to concentrations ranging from 5 to 27% silica by weight. The unconfined compressive strength of the grouted sand, measured after 7 days, was proportional to the silica concentration, up to a maximum of 400 kPa. The hydraulic conductivity of the grouted sand decreased with increasing silica concentration in a nearly log-linear manner down to a minimum of 2 × 10?9 cm∕s, and was below 1 × 10?7cm∕s for grouts with 7.4% silica or more. Inclusion of 5% volumetric saturation of organics (tetrachloroethene, CCl4, or aniline) in the samples had little effect on the strength or hydraulic conductivity. Samples were immersed in test liquids (organics, HCl diluted to pH 3, distilled water saturated with organics, and distilled water control) for up to 1 year. All samples increased in strength except for those immersed in aniline; samples immersed in water saturated with aniline were also weaker than control samples.     

溶胶-凝胶法制备95多品氧化铝纤维

以结晶氯化铝、铝粉和硅溶胶为主要原料,用溶胶-凝胶法制备95多晶氧化铝纤维.研究了PEG的加入量和胶体黏度对纤维平均直径和单丝拉伸强度的影响,并对不同温度烧成的纤维单丝拉伸强度和比表面积进行了对比.结果表明:当PEG加入质量分数为4%、胶体黏度为30 Pa·s时,纤维平均直径为3.7 μm,且拥有较好的强度;纤维的比表...     

Some properties of purified skeletal muscle alpha-actinin

Highly purified alpha-actinin can be made by using the low ionic strength extraction procedure previously described (Arakawa N., Robson, R. M., and Goll, D. E. (1970) Biochim. Biophys. Acta 200, 284-295) and then subjecting the crude alpha-actinin fraction obtained with this extraction procedure to successive chromatography on DEAE-cellulose and hydroxyapatite. Hydrozyapatite chromatography specifically removes a protein having a subunit molecular weight of 42,000 on sodium dodecyl sulfate (SDS)-polyacrylamide gel electrophoresis. Hydroxyapatite-purified alpha-actinin sediments entirely as a 6.21 S boundary in the analytical ultracentrifuge with no trace of the small 9 to 10 S boundary seen in earlier alpha-actinin preparations purified by DEAE-cellulose chromatography. In 100 mM KCl, 20 mM Tris-acetate, pH 7.5, hydroxyapatite-purified alpha-actinin has a diffusion coefficient (D020,w) of 2.71 X 10(-7) cm2-s-1, an intrinsic viscosity of 20.6 ml-g-1, a molecular weight of 201,000 +/- 4,300 (plus or minus least squares standard error) as determined by sedimentation equilibrium, and a molecular weight of 210,000 as determined by sedimentation diffusion. In 6 M guanidine HCl, hydroxyapatite-purified alpha-actinin has a molecular weight of 106,000 +/- 6,300 as determined by sedimentation equilibrium and a molecular weight of 100,000 as determined by a calibrated 4% agarose gel permeation column. SDS-polyacrylamide gel electrophoresis gives a molecular weight of 96,000 to 100,000 for hydroxyapatite-purified alpha-actinin. Rod-shaped particles 44 X 390 to 400 A are seen in electron micrographs of negatively stained alpha-actinin. By assuming 45% hydration and a molecular weight of 206,000, dimensions of approximately 40 X 500 A can be calculated for the alpha-actinin molecule by using either s 020, w, D 020, w, intrinsic viscosity, or a calibrated 6% agarose gel permeation column. Hydroxyapatite-purified alpha-actinin has an alpha-helical content of 74% as measured by circular dichroism at 208 nm.     

Freeze-off limits in transient liquid-phase infiltration

Transient liquid-phase infiltration (TLI) involves a powder-metal skeleton and an infiltrant with similar composition containing a melting-point depressant (MPD). Upon infiltration, the MPD diffuses into the skeleton, causing isothermal solidification and allowing a homogeneous final-part composition. Diffusional solidification of the infiltrant can restrict liquid flow and result in premature freeze-off if the liquid solidifies before filling the entire part. A capillary-driven fluid-flow model was developed to predict the infiltration rate and freeze-off limit using a variable skeleton permeability. Diffusional solidification was measured via quenching experiments, compared to theory, and used to define the change in permeability of the skeleton. The infiltration rate was measured via mass increase and compared to the flow model for various skeletons with powder sizes ranging from 60 to 300 μm. The predicted horizontal infiltration freeze-off limits were proportional to the square root of d ³ γ/μDβ ², where d is the average powder diameter, γ and μ are the infiltrant surface tension and viscosity, respectively, D is the solid diffusivity, and β is a function of the solidus and liquidus concentrations. These relations can be used for selection of processing parameters and for evaluation of new material systems.     

Modeling of Corroded FRP-Wrapped Reinforced Concrete Columns in Axial Compression

This paper discusses the mechanical behavior of reinforced concrete columns wrapped with fiber-reinforced polymer (FRP) sheets. A numerical routine was developed to predict the behavior of the columns using a step-by-step technique. The routine is based on an existing model and was modified to account for confinement provided by the traditional steel as well as the external FRP wraps. Several empirical equations for the confined concrete were calibrated with results from experimental tests from different published papers. The most accurate equation was incorporated into the routine to predict the stress-strain relation of the column up to failure. A different confinement to the outer concrete cover and the inner core was used to account for the FRP wraps and the transverse steel. The model was calibrated with experimental results from different experiments on FRP-wrapped reinforced concrete columns.The model was taken one step further by using it to predict the behavior of reinforced concrete columns, with a combination of steel corrosion and CFRP wraps. The columns modeled were subjected to harsh corrosive environment over 44 months. The model successfully predicted the load deformation in both axial and circumferential directions in corroded and intact columns, both wrapped and unwrapped, with good accuracy. The analysis forms a solid foundation for accurate evaluation of the effect of corrosion and wrapping on reinforced concrete columns.     

Experimental Validation and Applications of a Fluid Infiltration Model

Horizontal infiltration experiments were performed to validate a plug flow model that minimizes the number of parameters that must be measured. Water and silicone oil at three different viscosities were infiltrated into glass beads, desert alluvium, and silica powder. Experiments were also performed with negative inlet heads on air-dried silica powder, and with water and oil infiltrating into initially water moist silica powder. Comparisons between the data and model were favorable in most cases, with predictions usually within 40% of the measured data. The model is extended to a line source and small areal source at the ground surface to analytically predict the shape of two-dimensional wetting fronts. Furthermore, a plug flow model for constant flux infiltration agrees well with field data and suggests that the proposed model for a constant-head boundary condition can be effectively used to predict wetting front movement at heterogeneous field sites if averaged parameter values are used.     

Determination of sterigmatocystin in corn and oats by gel permeation and high-pressure liquid chromatography

Corn and oats samples are extracted with acetonitrile-water, followed by partition of the extract against hexane, transfer to chloroform, and elution from a silica gel column. The extract is purified by gel permeation chromatography on an automatic instrument. Reverse phase high-pressure liquid chromatography, using a 254 nm ultraviolet detector and 0.1 M KH2PO4-acetonitrile (7+5) as the mobile phase, is used for quantitation. The average recovery from 6 samples of corn to which 0, 25, 50, and 100 mug sterigmatocystin/kg had been added was 59%, with a coefficient of variation of 8.4%. The average recovery from oats fortified at the same levels was 74%, with a coefficient of variation of 12%. A confirmation procedure based on hemiacetal derivative formation on a thin layer chromatographic plate is also described.     

Reducing Water Seepage with Anionic Polyacrylamide: Application Methods and Turbidity Effects

Researchers used column and flume experiments with uniform silica sand with and without suspended solids to examine the extent and longevity of hydraulic conductivity reduction (HCR) resulting from three anionic polyacrylamide (PAM) application methods, liquid injection, slurry surface, and granular surface application. Low turbidity (0.4 NTU) liquid injection column tests showed 20–65% HCR, likely caused by an extensional viscosity mechanism. HCR increased as turbidity increased, especially at low PAM concentrations. High turbidity (100 NTU) liquid injection column tests showed 66–77% HCR, likely through surficial PAM–clay aggregate filtration. Column and adsorption tests strongly suggest PAM–sand adsorption does not cause substantial HCR. In low turbidity flume tests, PAM slurry application to the sand surface produced up to 100% HCR, likely through a viscosity mechanism, and granular application to the media surface produced up to 100% HCR, likely through fixed surficial polymer gel formation. Hydraulic conductivity returned to control-adjusted pretreatment levels following PAM application in all tests except granular surface application at high mass loads or with high turbidity.     

ANSWAPPS: Model for the Analysis of Grass Swale-Perforated Pipe Systems

A computer model for the analysis and design of grass swale perforated pipe systems is presented. The model, which was calibrated and validated using experimental as well as field data, performs detailed computations for flow through the system on a lot by lot basis (i.e., from one catchbasin to another). Several parameters affecting the system performance are considered in the modeling approach. These especially included lot size and imperviousness, grass swale dimensions and its infiltration capacity, pipe length, number of orifices and their configuration, trench dimensions, and native soil infiltration capacity. The model was used to simulate the minimum trench depth required to capture runoff from a 25?mm storm for different native soils and different lot imperviousness ratios. Trench depths varied from 0.3 to 1.4?mm depending on native soil infiltration capacity and lot imperviousness.     

Feasibility of Using Coal Fly Ash for Mine Waste Containment

This study investigates the feasibility of using coal fly ash and fly ash-bentonite mixtures as a barrier material for mine waste. The hydraulic conductivity of the coal fly ash was measured to be in the order of 2×10?9?m/s when it was permeated with deionized water, and this value decreased significantly when the permeant was switched to acid mine drainage (AMD). The addition of bentonite to coal fly ash lowered the hydraulic conductivity during water permeation but no further significant change was observed upon switching the permeant to AMD. Chemical analyses on the effluent from the hydraulic conductivity tests indicated that heavy metals present in AMD were attenuated and were well below the leachate criteria set by the Ontario Government. X-ray diffraction and scanning electron microscopy analyses results of postpermeation samples showed significant structural differences and formation of secondary minerals after AMD permeation. The results of this study suggest that the addition of 10% bentonite to coal fly ash reduced the hydraulic conductivity of the coal fly ash to less than 1×10?9?m/s and improved the chemical compatibility for mine waste containment.     

Finite element modeling of distortion during liquid phase sintering

Liquid phase sintering (LPS) is a common technique to consolidate materials that are difficult to process by fusion techniques, such as tungsten heavy alloys. One of the major processing difficulties associated with liquid phase sintered alloys is component distortion and loss of component shape. In LPS, this distortion is the result of viscous flow driven by curvature effects and gravity. A finite element model is developed for viscous flow of the semisolid sintering structure using Stokes equations. This model considers solid volume fraction and effective viscosity of the solid-liquid mixture. The simulation predictions are compared to distortion results for microgravity and ground-based sintering experiments, and they show good agreement. The model results indicate that the effective semisolid viscosity is significantly greater than the liquid metal viscosity. Hence, future work needs to quantitatively examine the factors controlling viscosity and the benefits from such high viscosities in liquid phase sintered systems.     

Utility of Column Lysimeter for Design of Soil Aquifer Treatment System for Wastewater Renovation Using Artificial Neural Networks

An artificial neural network (ANN) model is developed to study the correlation of data with reference to various wastewater pollution parameters (biochemical oxygen demand, chemical oxygen demand, suspended solids, NH4, PO4) using two scales of experiments viz. column lysimeter and a pilot soil aquifer treatment (SAT) system for wastewater renovation in India. A unique feature of the study is that the primary treated wastewater was directly applied to SAT system for renovation in contrast to the secondary treated effluent used in most of the other studies that have been reported. The analysis of data using ANN as a tool indicates that the column lysimeter data are useful for design of SAT systems and it is possible to predict the effluent quality for SAT system based on the inputs from lysimeter experiments. The study highlights the utility of column lysimeter studies for evolving design parameters for a full-scale SAT system thereby obviating the need for pilot SAT studies which are site specific, time consuming, and expensive. Thus, the study suggests that the experimental data from lysimeter studies at a particular site can be used to predict performance of field-scale SAT systems without going in for actual experimentation. Further, the field data from one site could be utilized for design of SAT systems at other locations provided the climatic and hydrogeological conditions viz. soil matrix characteristics and wastewater characteristics, etc., are similar.     

Magnetic shaping of columns of liquid sodium

The meniscus of a cylindrical column of liquid sodium in mineral oil was shaped under an electromagnetic field. The electromagnetic field was generated by an alternating current flowing through a coil surrounding the liquid metal column. The equilibrium shape of the meniscus, under the influence of electromagnetic field, was experimentally measured and compared with the predicted results from the mathematical model. The experimental technique used to measure the meniscus shape of the liquid metal column and the development of the mathematical model are presented. The validity of the mathematical model to predict the meniscus shapes is also discussed.     

Criteria for the Formation of Sediment Plugs in Alluvial Rivers

A sediment plug is defined as aggradation in a river that completely blocks the main channel. Information from documented cases of sediment plug development in alluvial rivers was used to develop criteria for plug formation and to identify the setup conditions for sites that are prone to plug formation. Site characteristics, processes, and associated parameters were evaluated based on a comprehensive literature review and evaluation of data. A plug formation theory was developed and tested using a unique sediment transport/movable bed numerical model that simulates the key processes considered to affect plug formation. The theory and model were calibrated and validated against field data, and then used to develop simplified criteria that can be used to predict plug formation. Findings from this study can be used to identify sites that may be prone to plug formation, and the criteria can be used to evaluate the potential for plug formation based upon field site conditions when data are not available to complete a more detailed study.     

Analytical Model for Fracture Grouting in Sand

A conceptual, analytical model has been developed to describe the fracture grouting process in sand. The objective of the model is to improve understanding about this process in sand and to model propagation of the fractures. The results can be used to assess the parameters that control the fracture process. It is assumed that the complicated shape of a fracture in sand can be simplified to a geometrical shape (such as a tube or a plane) as a first approximation. Filtration of the grout appears to have a significant influence on the fracture shape when grout is injected into permeable subsoil such as sand. By assuming a pressure at which a fracture starts and a minimum pressure for propagation, it appeared possible to calculate the width-to-length ratio of the fracture independent of other soil properties. Quantification of the flow inside a fracture and the filtration processes resulted in a model that has been used to study differences in fracturing behavior in model tests and field tests on fracture grouting in sand. It was concluded that the width-to-length ratio of the fractures in a permeable soil decreases if the injection pressure of the grout or the permeability of the grout cake is decreased.     

Fiber Reinforced Polymer Composite–Wood Pile Interface Characterization by Push-Out Tests

Structural restoration of spliced or damaged wood piles with fiber reinforced polymer (FRP) composite shells requires that shear forces be transferred between the wood core and the encasing composite shells. When a repaired wood pile is loaded, shear stresses develop between the wood pile and the FRP composite shell through the grouting material. Alternatively, shear force transfer can be developed through mechanical connectors. The objective of this study was to characterize the interfaces in wood piles repaired with FRP composite shells and grout materials. Two interfaces were studied: wood pile/grout material and a grout material/innermost FRP composite shell. A set of design parameters that control the response of both interfaces was identified: (1) extent of reduction of cross section of wood pile due to deterioration (necking); (2) type of grout material (cement-based or polyurethane); (3) use of mechanical connectors; and (4) addition of frictional coating on the innermost shell. Push-out tests by compression loading were performed to characterize the interfaces and discriminate the effect of the design parameters. The outcome of the push-out tests was evaluation of the shear stress and force versus slip response and characterization of the failure mechanism. A set of repair systems that represent different combinations of the design parameters was fabricated and the interfaces evaluated. It was found that the combination of cement-based grout and polymer concrete overlay on the innermost shell provided the most efficient shear force-slip response. A simplified piecewise linear model of shear stress versus slip at the wood/grout and grout/FRP composite interfaces with and without mechanical connectors is proposed to synthesize the experimental response.