半固态ZL101合金重熔加热时初生相的组织演变

利用低过热度浇注技术制备了半固态ZL101铝合金坯料,研究了半固态温度区间重熔加热时半固态ZL101铝合金坯料的初生相形貌的转变过程。研究结果表明,在半固态两相区保温,半固态ZL101合金的初生相逐渐团球化,该过程随保温温度的升高而加快。半固态ZL101铝合金晶粒的圆度与保温温度和保温时间的关系不大,但晶粒的尺寸随着保温温度和保温时间的增加而增大。半固态ZL101合金试样重熔加热最佳工艺制度为583℃下保温30m in,其晶粒平均等积圆直径为80μm,晶粒平均圆度为0.83。     

用低过热度浇注技术制备半固态ZL101-Sc铝合金

利用低过热度浇注工艺制备了ZL101-Sc铝合金半固态浆料,研究了Sc对半固态合金初生α-Al形貌的影响.采用正交设计方法研究了半固态ZL101-Sc铝合金初生α-Al形貌的影响因素.结果表明,经Sc细化及低过热度浇注(620℃)获得的半固态ZL101初生球晶的最佳工艺条件为保温温度590℃,保温时间200 s,Sc加入量0.6%.此时其晶粒在铸态下的形状因子为0.95,等效圆直径为27.45 μm,其中保温温度是晶粒形貌和尺寸的最主要影响因素,可信度达95%;其次是Sc的加入量和保温时间.     

半固态模锻ZL101铝合金车轮的组织与力学性能

采用低过热度浇注法制备半固态ZL101铝合金圆棒坯料,在200 T立式油压机上模锻成形铝合金车轮,研究了铝合金车轮的组织与力学性能.结果表明:低过热度浇注法制备ZL101铝合金圆棒坯的合理浇注温度为635 ～655 ℃,棒坯组织为细小均匀的等轴和球形α-Al晶粒,棒坯合适的二次加热工艺为600 ℃等温加热60 ～80 min.半固态模锻ZL101铝合金车轮组织由球形α-Al晶粒和α+Si共晶组织组成,经T6热处理后,其屈服强度、抗拉强度和伸长率分别为211.9 MPa、318.1MPa和5.9％,表明半固态模锻铝合金车轮具有较高的综合力学性能.     

半固态ZL101合金初生相在固液区间等温保温时形貌演变

研究了半固态ZL101铝合金初生相在固液相区等温保温下初生相形貌的演变,探讨了工艺参数对ZL101铝合金初生相在固液相区等温保温的影响。结果表明,在不同的保温温度下,随着保温温度的降低,ZL101铝合金的初生相形貌逐渐变好,尺寸变小;在相同的保温温度和不同的保温时间下,随着保温时间的延长,其初生相形貌逐渐圆整,颗粒尺寸仍较细小;浇注温度对初生相形貌及等温时的转变影响较大。获得了低过热度浇注制备半固态ZL101铝合金浆料合适的工艺参数。     

ZL101铝合金机械振动制浆工艺参数的研究

利用自行研制的机械振动装置成功制备了ZL101铝合金半固态浆料。研究了保温温度、浇注温度这两个参数对浆料质量的影响。研究表明,保温温度越低,固相率越高;保温温度升高,半固态浆料的显微组织较为圆整,但是晶粒的平均直径有所增大。浇注温度较低,制备的ZL101半固态浆料中的初生α-Al晶粒较圆整,尺寸细小,最终固相率也相对较高。合适的保温温度为595～605℃左右,浇注温度为635～660℃左右。     

半固态ZL201A铝合金浆料的制备

利用低过热度浇注和弱电磁搅拌方法制备了半固态ZL201A铝合金浆料,浇注温度分别为678、663、648℃,利用光学显微镜观察了不同条件下的浆料组织。试验结果表明,随着浇注温度的降低,半固态ZL201A铝合金浆料内部组织中的初生α-Al由蔷薇状向球状转变,晶粒尺寸逐渐变小,分布更均匀。同时,浆料边缘和底部组织中的初生α-Al的形貌由粗大的枝晶向蔷薇状转变。对于半固态ZL201A铝合金浆料的制备,较佳的浇注温度为663℃。电磁搅拌均匀了ZL201A铝合金液的温度场,加大了同时凝固的区域,细化了初生α-Al晶粒;同时结晶潜热的集中释放有助于蔷薇状初生α-Al的根部熔断,加速了球状初生α-Al的形成。     

蛇形通道浇注法制备半固态ZL101铝合金浆料

采用蛇形通道浇注法制备半固态ZL101铝合金浆料,研究了浇注温度、弯道数量、冷却方式对半固态浆料组织的影响。结果表明,浇注温度在640~680℃范围时可获得理想的半固态ZL101铝合金浆料,其组织随浇注温度的降低,由蔷薇状向近球状或球状组织演变。在相同浇注温度下,弯道数量增加,可以改善初生α-Al晶粒的形貌,降低晶粒尺寸。弯道内的合金熔体具有"自搅拌"作用,使初生晶核演变为球状或近球状晶粒。     

近液相线半连续铸造A356铝合金显微组织

采用近液相线半连续铸造法制备铸造A356铝合金，获得金属半固态加工要求的细小，等轴的“非枝晶”组织，研究了铸造温度、保温时间及冷却速度对该组织的影响规律。结果表明，在液相线附近，降低铸造温度，有利于减小晶粒尺寸；晶粒平均等积圆直径最小可达42．6μm，初始固相体积分数最多可达98．4％，同一温度下，晶粒尺寸随保温时间的延长而粗化；冷却速度快，晶粒尺寸细小；同一铸锭，其中心部位的组织比边缘部位的组织粗大，且分布均匀、等轴特征明显。     

蛇形通道法制备ZL101铝合金半固态浆料（英文）

采用蛇形通道法制备ZL101铝合金半固态浆料,研究浇注温度、弯道数量、蛇形通道温度对ZL101铝合金半固态浆料显微组织的影响。结果表明:浇注温度在630~680°C范围时可获得满意的ZL101铝合金半固态浆料,随浇注温度的降低,初生α(Al)由蔷薇状向近球状或球状组织演变。在相同浇注温度下,弯道数量增加,可以改善初生α(Al)晶粒的形貌,降低晶粒尺寸。当蛇形通道温度提高时,通过降低浇注温度,同样可以获得合格的半固态浆料。弯道内的合金熔体具有"自搅拌"作用,使初生晶核演变为球状或近球状晶粒。     

液相线半连续铸造112Al合金的组织

液相线半连续铸造是 1种先进的半固态浆制备方法。考察了铸造温度、冷却强度及铸造速度对液相线半连续铸造法制备 112铝合金半固态浆料组织的影响。合金熔体在常规铸造温度 (690℃ )下浇注获得的锭坯边部是粗大的枝晶 ,中间部位组织极不均匀 ;在接近液相线温度以上 (60 5℃ )保温 2 0min后浇注的铸造组织较好 ,中心部位和边部组织的差异较小。在液相线温度 (5 88℃ )保温 2 0min后进行半连续铸造获得的锭坯中心和边部组织元均是均匀、细小的近球形组织。降低一次冷却强度、增大二次冷却强度和减小铸造速度均有利于均匀、细小、等轴的半固态组织的形成。结果表明 ,液相线半连续铸造能有效地制备 112Al合金的半固态浆料     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

Thermodynamics Study on the Decomposition of Chromite with KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

Influence of Heat Treatment on Damping Behaviour of the Magnesium Wrought Alloy AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Effect of Rare Earth Doping on Impedance,Modulus and Conductivity Properties of Multiferroic Composites:0.5(BiLa_xFe_(1-x)O_3)–0.5(PbTiO_3)

The Lanthanum-doped bismuth ferrite–lead titanate compositions of 0.5(Bi LaxFe1-xO3)–0.5(Pb Ti O3)(x = 0.05,0.10,0.15,0.20)(BLxF1-x-PT) were prepared by mixed oxide method.Structural characterization was performed by X-ray diffraction and shows a tetragonal structure at room temperature.The lattice parameter c/a ratio decreases with increasing of La(x = 0.05–0.20) concentration of the composites.The effect of charge carrier/ion hopping mechanism,conductivity,relaxation process and impedance parameters was studied using an impedance analyzer in a wide frequency range(102–106Hz) at different temperatures.The nature of Nyquist plot confirms the presence of bulk effects only,and non-Debye type of relaxation processes occurs in the composites.The electrical modulus exhibits an important role of the hopping mechanism in the electrical transport process of the materials.The ac conductivity and dc conductivity of the materials were studied,and the activation energy found to be 0.81,0.77,0.76 and 0.74 e V for all compositions of x = 0.05–0.20 at different temperatures(200–300 °C).     

Quantitative Analysis of the Crystallographic Orientation Relationship Between the Martensite and Austenite in Quenching–Partitioning–Tempering Steels

The orientation relationships(ORs)between the martensite and the retained austenite in low-and medium-carbon steels after quenching–partitioning–tempering process were studied in this work.The ORs in the studied steels are identified by selected-area electron diffraction(SAED)as either K–S or N–W ORs.Meanwhile,the ORs were also studied based on numerical fitting of electron backscatter diffraction data method suggested by Miyamoto.The simulated K–S and N–W ORs in the low-index directions generally do not well coincide with the experimental pole figure,which may be attributed to both the orientation spread from the ideal variant orientations and high symmetry of the low-index directions.However,the simulated results coincide well with experimental pole figures in the high-index directions{123}_(bcc).A modified method with simplicity based on Miyamoto’s work was proposed.The results indicate that the ORs determined by modified method are similar to those determined by Miyamoto’method,that is,the OR is near K–S OR for the low-carbon Q–P–T steel,and with the increase of carbon content,the OR is closer to N–W OR in medium-carbon Q–P–T steel.     

Using Finite Element and Contour Method to Evaluate Residual Stress in Thick Ti-6Al-4V Alloy Welded by Electron Beam Welding

This work was to reveal the residual stress profile in electron beam welded Ti-6Al-4V alloy plates(50 mm thick) by using finite element and contour measurement methods.A three-dimensional finite element model of 50-mmthick titanium component was proposed,in which a column–cone combined heat source model was used to simulate the temperature field and a thermo-elastic–plastic model to analyze residual stress in a weld joint based on ABAQUS software.Considering the uncertainty of welding simulation,the computation was calibrated by experimental data of contour measurement method.Both test and simulated results show that residual stresses on the surface and inside the weld zone are significantly different and present a narrow and large gradient feature in the weld joint.The peak tensile stress exceeds the yield strength of base materials inside weld,which are distinctly different from residual stress of the thin Ti-6Al-4V alloy plates presented in references before.     

Microstructures and Tensile Properties of Ultrafine-Grained Ni–(1–3.5) wt% SiC_(NP) Composites Prepared by a Powder Metallurgy Route

Silicon carbide nanoparticle-reinforced nickel-based composites(Ni–Si CNP),with a Si CNPcontent ranged from1 to 3.5 wt%,were prepared using mechanical alloying and spark plasma sintering.In addition,unreinforced pure nickel samples were also prepared for comparative purposes.To characterize the microstructural properties of both the unreinforced pure nickel and the Ni–Si CNPcomposites transmission electron microscopy(TEM) was used,while their mechanical behavior was investigated using the Vickers pyramid method for hardness measurements and a universal tensile testing machine for tensile tests.TEM results showed an array of dislocation lines decorated in the sintered pure nickel sample,whereas,for the Ni–Si CNPcomposites,the presence of nano-dispersed Si CNPand twinning crystals was observed.These homogeneously distributed Si CNPwere found located either within the matrix,between twins or on grain boundaries.For the Ni–Si CNPcomposites,coerced coarsening of the Si CNPassembly occurred with increasing Si CNPcontent.Furthermore,the grain sizes of the Ni–Si CNPcomposites were much finer than that of the unreinforced pure nickel,which was considered to be due to the composite ball milling process.In all cases,the Ni–Si CNPcomposites showed higher strengths and hardness values than the unreinforced pure nickel,likely due to a combination of dispersion strengthening(Orowan effects) and particle strengthening(Hall–Petch effects).For the Ni–Si CNPcomposites,the strength increased initially and then decreased as a function of Si CNPcontent,whereas their elongation percentages decreased linearly.Compared to all materials tested,the Ni–Si CNPcomposite containing 1.5% Si C was found more superior considering both their strength and plastic properties.     

Directional Growth of Tin Crystals Controlled by Combined Solute Concentration Gradient Field and Static Magnetic Field

A new method was introduced to achieve directional growth of Sn crystals. Microstructures in liquid(Pb)/liquid(Sn) diffusion couples were investigated under various static magnetic fields. Results show that the β-Sn crystals mainly reveal an irregular dendritic morphology without or with a relatively low static magnetic field(B0.3 T). When the magnetic field is increased to 0.5 T, the β-Sn dendrites close to the final stage of growth begin to show some directional character. With a further increase in the magnetic field to a higher level(0.8–5 T), the β-Sn dendrites have an enhanced directional growth character, but the dendrites show a certain deflection. As the magnetic field is increased to 12 T, the directional growth of the β-Sn dendrites in the center of the couple is severely destroyed. The mechanism of the directional growth of the β-Sn crystals and the deflection of the β-Sn crystals with the application of static magnetic field was tentatively discussed.     

电化学噪声数据处理方法概述

综述了常见的电化学噪声数据处理方法,介绍了直流趋势剔除、统计分析、快速傅立叶变换(FFT)法计算功率谱密度(PSD)以及小波变换处理电化学噪声信号的基本过程,并阐释了各种数学处理及所得参数的物理意义。