Application of Light Hydrocarbon (C7 ) and Biomarker Analyses in Characterizing Oil from Wells in the North and North Central Sinai, Egypt

Seven representative oil show samples from wells in the north and north central Sinai have been characterized by means of a variety of organic geochemical techniques (C₇ hydrocarbon and biomarker analyses), to illustrate origin, differences, and similarity among oils. These oils were obtained from Cretaceous and Jurassic reservoirs. The C₇ oil correlation star diagram (OCSD) suggests closely related oils, derived mainly from similar source rocks, while the C₇ oil transformation star diagram (OTSD) and C₇ light hydrocarbon analyses indicate a minor degree of transformation of some oils, as Misri-1, Halal-1, and Nakhl-1 oils were subjected to evaporative fractionation. Moreover, the studied oils show no sign of water washing and biodegradation. Molecular characteristics suggest pre-Tertiary shales and carbonate source rocks, deposited under a saline oxic environment, rich in terrigeneous organic sources with significant bacterial and algal input. Since the studied oils are of mixed marine and terrestrial origin, C₇ signature of these oils is not representative of their origin and should be supported by other geochemical evidence (e.g., biomarkers) to predict their origin.     

Study of pertrographical and electrical properties of some Jurassic carbonate rocks,north Sinai,Egypt

The Jurassic sedimentary section in north Sinai is of a special interest in particular for its economic potentiality. The understanding of petrographical and electrical properties of these rocks is essential for investigating minerals and oil and water exploration. This paper presents a study of the petrographical and A. C. electrical properties of Jurassic carbonates. Electrical measurements have been conducted for twenty-nine (18) carbonate samples. The slight changes between samples in electrical properties were attributed to the changes in mineral composition, texture pore spaces and pore throat distribution of the samples. Electrical properties generally change with many factors (grain size, mineral composition, grain shape and facies). The dielectric constant decreases with frequency and increases with the presence of conductive solids (silt and clay) and its composition. The conductivity increases with the increase of conductor paths between electrodes. The main goal of this paper is to shed more light on interrelations between electrical properties (conductivity, dielectric constant and impedance as a function of frequency), petrography and mineral composition (carbonates that contain clays and quartz grains).     

Application of Light Hydrocarbon (C7+) and Biomarker Analyses in Characterizing Oil from Wells in the North and North Central Sinai,Egypt

Abstract

Seven representative oil show samples from wells in the north and north central Sinai have been characterized by means of a variety of organic geochemical techniques (C₇ hydrocarbon and biomarker analyses), to illustrate origin, differences, and similarity among oils. These oils were obtained from Cretaceous and Jurassic reservoirs. The C₇ oil correlation star diagram (OCSD) suggests closely related oils, derived mainly from similar source rocks, while the C₇ oil transformation star diagram (OTSD) and C₇ light hydrocarbon analyses indicate a minor degree of transformation of some oils, as Misri-1, Halal-1, and Nakhl-1 oils were subjected to evaporative fractionation. Moreover, the studied oils show no sign of water washing and biodegradation. Molecular characteristics suggest pre-Tertiary shales and carbonate source rocks, deposited under a saline oxic environment, rich in terrigeneous organic sources with significant bacterial and algal input. Since the studied oils are of mixed marine and terrestrial origin, C₇ signature of these oils is not representative of their origin and should be supported by other geochemical evidence (e.g., biomarkers) to predict their origin.     

论煤矿采煤技术的发展与采煤自动化技术

当下互联网技术的发展使得各行各业在工作的过程中进行了生产方式、工作状态的调整,而在煤炭生产行业中自动化技术的积极应用也成为了目前发展的主要的工作的趋势,为了使得煤矿企业的整体生产效益不断提升,就需要从自动化控制的质量、高效生产的质量方面进行相应的控制工作,从而获得更好的发展。在煤矿的挖掘、运输、洗煤等过程中各个环节都需要进行自动化设备的控制工作,尤其是在自动化控制方面可以使得生产能力和控制的精准化程度大大提升。     

基于光学显微观测的煤层裂隙发育特征、成因及其意义——以沁水盆地南部3~#煤层为例

基于光学显微观测,分析了沁水盆地南部3#煤层煤岩显微组分与内生裂隙的关系,并对外生裂隙的继承改造进行分类研究。结果表明:内生裂隙成因主要体现在显微组分的力学强度和煤化作用过程中的内张力,均质镜质体由于结构和成分均一,微孔隙发育,显微脆度高,内生裂隙最为发育;根据继承改造的方向差异,将外生裂隙继承改造类型划分为延伸型、剪切型和拓张型,外生裂隙中,张裂隙和剪裂隙发育规模大,裂隙网络发育,对储层渗透率贡献大。裂隙发育特征、类型及其成因研究,有助于认识煤储层裂隙在煤层气富集成藏和勘探开发中的作用。     

微间距录井法在卡煤层取心及分层中的应用

针对上古生界山西组、太原组煤层较脆、钻时较快的特点，为保证现场煤层卡取心层位和准确划分煤层厚度，结合综合录井仪的钻时录井间距可以根据地质需要人为缩小的功能，使用“微间距录井法”对煤层进行精细卡层。结合现场实例对上述方法的特点及应用效果进行了介绍，以数据对比的方式阐述了该方法的优越性。该方法在现场使用取得了较好的效果，值得在现场推广应用。     

Oil Families and Their Potential Sources in the Southern Gulf of Suez,Egypt

Abstract

Four oil families are identified in the southern Gulf of Suez, through high-resolution geochemical studies including gas chromatography, gas chromatography–mass spectrometry, and carbon isotope analyses. Biological features characterize oils in family 1a, suggesting tertiary carbonate source rocks for these oils, rich in type II organic matter and deposited under anoxic depositional environment. Family 1b oil shows minor variations in the source of organic matter and the depositional environment, as it was derived from carbonate source rock with more algal and bacterial contribution and minor input of terrestrial organic sources, deposited under less saline condition compared to family 1a oil. Family 2 oil, although genetically related to family 1a oil, has some distinctive features, such as diasterane to sterane and pristane to phytane ratios, which suggest clay-rich source rocks and a more oxic depositional environment. Also, the lack of oleanane indicates pre-tertiary source rocks for this oil. In contrast, family 3 oil is of mixed sources (marine and non-marine), generated from low sulfur and clay-rich source rock of tertiary and/or younger age. Family 4 oil seems to be mixed from family 1b and family 3 oils, sourced mainly from carbonate source rocks rich in clay minerals with algal and bacterial contributions. Family 4 oil is highly mature, family 1b oil lies within equilibrium values (peak oil generation stage), while the other families are more or less near equilibrium.     

Evaluation of organic matters,hydrocarbon potential and thermal maturity of source rocks based on geochemical and statistical methods: Case study of source rocks in Ras Gharib oilfield,central Gulf of Suez,Egypt

In this study, we apply geochemical and statistical analyses for evaluating source rocks in Ras Gharib oilfield. The geochemical analysis includes pyrolysis data as total organic carbon (TOC%), generating source potential (S2), production index (PI), oxygen and hydrogen indices (OI, HI) and (Tmax). The results show that the Cretaceous source rocks are poor to good source rocks with kerogen of type III and have the capability of generating gas while, the Miocene source rocks are good to excellent source rocks with kerogen of type III–II and type II and have the capability of generating oil and gas. The analyzed data were treated statistically to find some factors, clusters, and relations concerning the evaluation of source rocks. These factors can be classified into organic richness and type of organic matter, hydrocarbon potentiality and thermal maturity. In addition, cluster analysis separated the source rocks in the study area into two major groups. (1) Source rocks characterized by HI >300 (mg/g), TOC from 0.76 to 11.63 wt%, S1 from 0.44 to 9.49 (mg/g) and S2 from 2.59 to 79.61 (mg/g) indicating good to excellent source rocks with kerogen of type III–II and type II and are capable of generating oil and gas. (2) Source rocks characterized by HI <300 (mg/g), TOC from 0.31 to 2.07 wt%, S1 from 0.17 to 1.29 (mg/g) and S2 from 0.31 to 3.34 (mg/g) indicating poor to good source rocks with kerogen of type III and are capable of generating gas. Moreover, Pearson’s correlation coefficient shows a strong positive correlation between TOC and S1, S2 and HI and no correlation between TOC and Tmax, highly negative correlation between TOC and OI and no correlation between Tmax and HI.     

Bulk Compositions,Genetic Origin,Classifications, and Maturation of Crude Oils in the Gulf of Suez,Egypt

Abstract

API gravity, sulfur content, gas chromatography, and gas chromatography-mass spectrometry analyses were carried out for eight oil samples collected from different wells in the Gulf of Suez. The results showed that two types of oils could be recognized: (a) heavy oils, which are oils from Zafarana, Rahmi, West Bakr, and Ras Gharib wells, are of low maturation and originated mainly from terrestrial organic sources; and (b) light oils, which are oils from Um El Yuser, Ras El Ush, Gemsa-SE, and Hurghada wells, have a high level of maturation and orginate mainly from marine organic sources.     

The use of polycyclic aromatic in the assessment of marine life and the impact on petroleum pollution in the Suez Gulf,Egypt

This study represents the concentrations of 16 PAHs in a commercial aquatic species Sauridaund squamis; Euthynnus affinis; Rhabdosargus haffara; Argyrops Spinifer; Nemipterus Japonicus, Oreochromis Niloticus; Trachurus Indicus; Peneus Japonicas; Scomber Japonicus; and Pomadasys Stridens, which were collected from the coastal area of the Suez Gulf waters. The analyses of polycyclic aromatic hydrocarbons (PAHs) were determined using HPLC to identify the sources of PAHs. The results revealed that low molecular weight of PAHs were more than high molecular weight in aquatic species, Benzo (a)Anthracene/(Benzo (a) Anthracene?+?Chrysene) BaA/(BaA?+?Chr), Indeno (1,2,3-cd) pyrene/(Indeno (1,2,3-cd) pyrene?+?Benzo (ghi) perylene) IP/(IP?+?BP) and Fluoranthene/Pyrene (Fl/Pyr), they reflected that the PAHs sources in aquatic species are petrogenic as a main sources, pyrogenic sources. The study area was generally contaminated with hydrocarbons and continuous consumption of food from this area may pose public health hazards.     

Energy return on investment, energy payback time, and greenhouse gas emissions of coal seam gas (CSG) production in China: a case of the Fanzhuang CSG project

The studies and development of coal seam gas (CSG) have been conducted for more than 30 years in China, but few of China’s CSG projects have achieved large-scale commercial success; faced with the boom of shale gas, some investors are beginning to lose patience and confidence in CSG. China currently faces the following question: Should the government continue to vigorously support the development of the CSG industry? To provide a reference for policy makers and investors, this paper calculates the EROI_stnd [a standardized energy return on investment (EROI) method], EROI_ide (the maximum theoretical EROI), EROI_3,i (EROI considering the energy investment in transport), and EROI_3,1+e (EROI with environmental inputs) of a single vertical CSG well in the Fanzhuang CSG project in the Qinshui Basin. The energy payback time (EPT) and the greenhouse gas (GHG) emissions of the CSG systems are also calculated. The results show that over a 15-year lifetime, EROI_stnd, ERO_Iide, EROI_3,1, and EROI_3,1+e are expected to deliver EROIs of approximately 11:1, 20:1, 7:1, and 6:1, respectively. The EPT within different boundaries is no more than 2 years, and the life-cycle GHG emissions are approximately 18.8 million kg CO₂ equivalent. The relatively high EROI and short EPT indicate that the government should take more positive measures to promote the development of the CSG industry.     

Stratigraphic distribution of the palynomorphs and the particulate organic matter in subsurface Lower/Middle Cretaceous deposits,Western Desert of Egypt: Palynological and geochemical approach

The stratigraphic distribution of the palynomorphs and particulate organic matter was studied in the subsurface Lower/Middle Cretaceous sections in Ii-26-1 and Ig-30-1 wells, located in north Western Desert of Egypt. Some important palynofacies parameters were employed as indicators of proximal–distal trends. The spatial and stratigraphical variations of six palynofacies categories had been illustrated. Optically, the type and nature of the recovered particulate organic matter together with their quantity were combined to reveal the prevailing paleoenvironmental conditions during deposition of the concerning sections. Thirty-seven samples were selected from the two wells to carry the total organic carbon (TOC) and Rock–Eval Pyrolysis analyses in order to geochemically evaluate the source rock.TOC and Rock–Eval Pyrolysis analyses illustrate extremely low TOC and HI values, demonstrating that the Alam El Bueib, Alamein, Dahab, Kharita and Bahariya formations are comprised principally of type IV kerogen and a few type III kerogen components. Therefore, they are inert to slightly gas prone, signifying a strong deficiency of hydrogen-enriched organic matter. Palynofacies analysis implies that all the studied formations have highly oxidized terrestrial organic matter (brown phytoclasts and black woods).     

埃及西沙漠盆地中生界烃源岩特征及剩余资源分布

西沙漠盆地是埃及三大主要含油气区之一,已发现大量的油气田,现处勘探发现中期,预探风险增大。为此,在详细评价盆地烃源岩地球化学特征基础上,运用盆地数值模拟技术定量分析剩余资源潜力。研究认为,中侏罗统Khatatba组Safa段和Zahra段煤系暗色泥页岩以及上白垩统Abu Roash组AR-F段暗色泥页岩是盆地的3套主力烃源岩,各凹陷烃源岩广泛分布,厚度变化较大。Khatatba组烃源岩TOC含量在0.5%~10%,裂解烃S₂含量高,为中等-很好烃源岩;Abu Roash组AR-F段烃源岩TOC主要在0.5%~3%,裂解烃S₂含量中-高,属中等-好烃源岩。这3套烃源岩有机质干酪根类型以混合Ⅱ型为主,其次是Ⅲ型,少量为Ⅰ型。指出Khatatba组2套烃源岩全盆处于热演化成熟大量生排烃阶段,凹陷中心达高熟生烃、局部过熟生气阶段,油气并生;Abu Roash组AR-F段烃源岩仅Abu Gharadig和Natrun凹陷进入成熟生烃阶段。提出盆地北部地区主要由侏罗系Khatatba组烃源岩供给油气,东南部地区则有侏罗系Khatatba组和白垩系AR-F段双源供烃。计算表明,盆地剩余可采资源量达6.51×10⁸ t,剩余资源潜力很好;其中,南部Abu Gharadig凹陷古生界、侏罗系和下白垩统AEB,北部Matruh凹陷古生界、Faghur凹陷上白垩统,油气探明程度低,剩余资源可观,为下步勘探的有利方向。     

Biomarker characteristics of crude oils from Ashrafi and GH oilfields in the Gulf of Suez,Egypt: An implication to source input and paleoenvironmental assessments

The present work aims to evaluate the organic geochemistry of the crude oils recovered from Ashrafi and GH oilfields within the Gulf of Suez to assess and investigate oil characterization, maturation, source depositional environments and oil families. The saturated hydrocarbons were determined by gas chromatography and gas chromatography/mass spectrometry. Pristane/phytane, isoprenoids/n-alkanes, CPI, homohopane, diasteranes, gammacerane index, C29 20S/20S+20R, C29/C30 hopane and Ts/Tm are determined. The results suggest that the studied crude oils belong to marine oil and are characterized by high level of maturation and sourced mainly from organic matters of marine origin with few terrestrial inputs.     

Effect provenance of organic matters in surface sediments from coastal stations in the Gulf of Suez Gulf,Egypt: An implication from occurrence of triterpanes and steranes fragmentgrams

Effect of provenance of organic matter evaluated through the distribution of occurrence of triterpanes and steranes in surface sediments from coastal stations located in the Gulf of Suez Gulf. The samples have been studied in four coastal stations located in the Gulf of Suez namely: Al–Nasr Oil Company (NPC), West outlet of SOPC, Inlete of SOPC, and El-Sukhna of Loloha Beach. Saturated hydrocarbons were analyzed by gas chromatography–mass spectrometry, to assessing of organic content and maturity level of the sediments. The results showed that the hydrocarbons are originated mainly from predominance of petrogenic and biogenic hydrocarbons with high maturity level.     

API gravities,vanadium, nickel,sulfur, and their relation to gross composition: Implications for the origin and maturation of crude oils in Western Desert,Egypt

In the present study, the geochemical analyses of API gravities, vanadium, nickel, sulfur, and bulk composition were performed on eight samples from productive wells in Gindi, South Deep Abu-gharadig, Abu-gharadig, Dahab-Merier, and Faghure basins locates in the North Western Desert. The results were used to describe the source organic matter input, depositional environment, assess the degree of thermal maturity, and to correlate between crude oils to determine the genetic relationship between hydrocarbon generation and their source rock for the studied oil samples. The results showed that a wide range of crude oil parameters exists in this data, indicating that a variety of oil types is represented. Crude oils range from unaltered to altered by vanadium, nickel, and sulfur concentrations, V/Ni and saturate fraction were used to classify the oils. Oils are classified into two groups. Group I contains oil samples from Gindi, South deep Abu-gharadig and Abu-gharadig, and Dahab-Merier that are generated from organic matter input deposited in marine environment under anoxic to suboxic conditions. Group II from Faghur basin possess high Pr/Ph ratios suggesting high contribution of terreginous organic matter deposited under relatively oxic conditions.     

关于石油、天然气和煤炭的成因机理的探讨

提出了二氧化碳基源学说的成煤机理和过程,论证了这一机理的正确性,解释了传统成煤理论无法解释的一些现象,并且证明了天然气、石油、煤的同源性。得出了石油、天然气和煤炭是可再生资源,而且来源于二氧化碳的结论。     

Significance of GC/FT-IR and GC/MS in recognizing the sources of organic materials from sediments along the Suez Gulf Shoreline,Egypt

The present work aims to using the application of GC, GC/MS, UV, and FT/IR spectroscopy organic matters extracted from sedimentary hydrocarbons from six coastal stations located in the Gulf of Suez and proposed to evaluate hydrocarbons in the sediments. The results the origins of hydrocarbons are multiple sources from terrestrial inputs, biogenic, and pyrolytic. Abundance of vascular plant n C₂₃– n C₃₃ alkanes with a high odd-to-even predominance, pristane, and phytane beside nC₂₉/nC₁₇ ratios and the presence of biogenic hopanes indicate the predominance of biogenic in combination with petrogenic hydrocarbons. FT-IR spectroscopic analysis indicates high concentrations of aliphatic hydrocarbons as well as mono- and polynuclear aromatic hydrocarbons are useful tool in organic geochemistry studies. UV analysis for organic matters incorporated in sediments reveals that oil pollutants have considerable amounts of aromatic compounds.     

Burial and thermal history simulation of the subsurface Paleozoic source rocks in Faghur basin,north Western Desert,Egypt: Implication for hydrocarbon generation and expulsion history

Paleozoic Zeitoun, Desouqy and Dhiffah formations represent source rocks to hydrocarbon in Faghur basin, north Western Desert, Egypt. They are characterized by a sufficient amount of organic matter belonging to kerogen type III and mixed type II/III, which are in maturation stage. A 1D-basin modeling was performed by using geological and geochemical data of the Paleozoic source rocks from five wells in Faghur basin, north Western Desert, Egypt. These data used in 1D basin modeling for constructing and understanding of burial and thermal geo-histories of Faghur basin and for simulating and predicting the timing of petroleum and expulsion for the Paleozoic source rocks in the studied wells. Burial and thermal history models indicate that the Zeitoun Formation entered onset of oil generation in the studied wells during Late Cretaceous (100.10–91.65 my) with transformation ratio (TR) 10–25, peak oil during Late Cretaceous (91.65–79.30 my) with TR 25–50 and late oil stage at Late Cretaceous (79.30 my-0) to present day with TR 50–60.45. Desouqy Formation entered onset of oil generation also during Late Cretaceous (94.43–73.60 my) with TR 10–25 in the studied wells, peak oil during Late cretaceous (73.60–62.40 my) with TR 25–50 and Late oil stage during Late Cretaceous to present day (62.40 my-0) with TR 50–61.82. Dhiffah Formation entered onset of oil generation in the studied wells during Early to Late Cretaceous (102.11–92.27 my) with TR 10–25, peak oil during Late Cretaceous (92.27–86.40 my) with TR 25–50 and late oil stage at Late Cretaceous to present day (86.40 my-0) with TR 50–67.27. No cracking oil to gas in the studied Paleozoic source rocks in the studied wells. These basin modeling results also suggest that the Paleozoic source rocks act as an effective source rock where a significant amount of petroleum is expected to be generated and expelled to any nearby prospect reservoir rocks in the Faghur basin.     

鄂尔多斯盆地子洲及邻区山西组二段高分辨率层序地层和煤沉积模式

鄂尔多斯盆地山西组既有煤层又含天然气,是重要的能源勘探目标。山西组二段主要属于湖盆三角洲沉积体系,山₂³亚段的三角洲分流河道砂体是子洲气田的主力储层。子洲及邻区山西组划分为2个长期、4个中期和8个短期基准面旋回,现已识别出5种短期基准面旋回结构。中-短期基准面旋回的划分,不仅采用了识别地层中层序界面、湖泛面和沉积旋回的方法,而且详细考虑了三角洲体系中煤层在高分辨率层序中的位置。文中运用了滨线轨迹分析法,将其与煤沉积模式研究紧密结合,精确地再现了研究区山₂³亚段煤沉积环境的演变过程。山₂³亚段是以间断性湖进-湖退为特征的三角洲环境沉积产物。山₂³期发生了4次短期的湖进-湖退过程,在下三角洲平原沉积了4个煤层。其中,最后一次湖进-湖退的规模最大,下三角洲平原大面积沼泽泥炭化,形成了几乎覆盖全区的较厚的5^#煤层。