共查询到20条相似文献,搜索用时 93 毫秒
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硫化镉纳米粒子的合成与应用 总被引:3,自引:0,他引:3
研究了用硫脲分子进行表面化学修饰的CdS纳米粒子的合成方法,并引入了一些表面活性剂作为平衡反离子,进一步对CdS表面作了修饰,增加了CdS纳米离子在有机溶剂中的稳定性和可分散性,我们还探讨了温度,浓度,pH等因素对合成的影响,并通过紫外一可见吸收光谱等手段进行了表征,所得微粒呈球形,硫脲分子与CdS纳米粒子富Cd^2 表面通过形成Cd-S配位键而修饰在粒子表面,这种表面修饰的CdS纳米材料在非线性光学及自组装方面具有优异的性能,还研究了含纳米硫化镉的有机/无机杂化非线性光学薄膜材料的制备。 相似文献
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接种疫苗是预防传染病的有效方法。疫苗可增强免疫力,并使个体对病原体感染具有抵抗力。蛋白亚单位疫苗虽具有良好的安全性,但其免疫原性较弱,需要佐剂辅助增强其免疫反应。佐剂作为增加疫苗免疫应答的关键部分,其设计理念和构建原理对开发有效的疫苗十分重要。表面修饰可赋予纳米材料预设的免疫调节功能,以优化疫苗诱导的免疫反应。本文对纳米粒子表面修饰在疫苗佐剂中的应用作一综述。 相似文献
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本文综述了近年来无机纳米粒子表面修饰的研究进展情况,着重介绍了其在制备聚合物/无机纳米复合材料中的应用。并对表征改性效果的方法进行了描述。 相似文献
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以具有不饱和双键的油酸为表面活性剂,对水溶胶中的CeO2纳米粒子进行表面修饰.TEM分析表明,经表面修饰的CeO2纳米粒子基本呈球形,粒径约为3 nm,分布均匀,并且表面包覆油酸的CeO2纳米粒子易溶于弱极性溶剂,不易溶于极性溶剂. 相似文献
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以3CdSO<,4>·8H<,2>O、Na<,2>S·9H<,2>O和EDTA为主要原料,在室温下,利用液相沉淀法制备CdS纳米晶.利用X射线粉末衍射(XRD)技术对产物进行表征,并用电化学分析仪测试产物对硫化物电解质溶液的催化性能.对产物的形成机理进行了初步分析.结果表明,产物纳米CdS为立方晶相,纯度较高.产物对1... 相似文献
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二氧化钛纳米粒子的表面修饰及表征 总被引:1,自引:0,他引:1
本文利用溶胶-凝胶法制备了6-氨基己酸修饰的TiO2纳米粒子,并对所得产物进行FT-IR、UVVis、XRD和TEM表征,结果证明所得产物表面包覆有有机层,产物的粒径范围为50~60nm,颗粒形状为球形,品型主要为锐钛矿型。在醇溶胶中,产物对紫外光的吸收性能大大提高。 相似文献
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Cadmium Sulfide Aggregates through Reverse Micelles 总被引:1,自引:0,他引:1
CdS aggregates, composed of primary nanocrystalline particles, were synthesized in cyclohexane-sorbitan monooleate (Span 80) reverse micelles at 80°± 1°C under mechanical agitation and sonication with varying Cd2+ concentrations in the solutions. The critical micelle concentration (CMC) of the surfactant Span 80 in cyclohexane was determined from discernible breaks in the surface tension and optical (ultraviolet) absorbance versus surfactant concentration curves. The synthesized aggregates were characterized using transmission electron microscopy, X-ray diffractometry, particle-size analysis, Fourier-transform infrared spectroscopy, and thermal analyses. The generated aggregates exhibited the characteristic green emission at 520 nm. A minor decrease in emission intensity with increased aggregate size at the same wavelength was observed. 相似文献
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Bonamali Pal Tsukasa Torimoto Shigeru Ikeda Tamaki Shibayama Kenji Sugawara Heishichiro Takahashi Bunsho Ohtani 《Topics in Catalysis》2005,35(3-4):321-325
Gold (Au) nanoparticles were deposited inside silica: (SiO2) shells containing cadmium sulfide (CdS) nanoparticles through photocatalytic reduction of potassium dicyanogold(I) by CdS.
Photocatalytic Au deposition occurred only when core-shell nanoparticles having a void space between the core and shell, i.e.,
a jingle-bell-shaped structure, were used. These core-shell nanoparticles were prepared by size-selective photoetching of
SiO2 -covered CdS nanoparticles. The size of Au nanoparticles could be controlled by adjustment of the void space in SiO2-covered CdS. Dissolution of CdS by acid treatment from the Au-deposited jingle-bell nanoparticles did not have any effect
on the surface-plasmon absorption by Au. These facts indicate that Au nanoparticles of adjustable size can be prepared in
an SiO2 shell that prevents mutual coalescence of Au nanoparticles but allows permeation of molecules and ions. 相似文献
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Dr. Yuki Honda Yuka Shinohara Prof. Dr. Motonori Watanabe Prof. Dr. Tatsumi Ishihara Prof. Dr. Hiroshi Fujii 《Chembiochem : a European journal of chemical biology》2020,21(23):3389-3397
An inorganic-biological hybrid system that integrates features of both stable and efficient semiconductors and selective and efficient enzymes is attractive for facilitating the conversion of solar energy to hydrogen. In this study, we aimed to develop a new photocatalytic hydrogen-production system based on Escherichia coli whole-cell genetically engineered as a biocatalysis for highly active hydrogen formation. The photocatalysis part was obtained by bacterial precipitation of cadmium sulfide (CdS), which is a visible-light-responsive semiconductor. The recombinant E. coli cells were sequentially subjected to CdS precipitation and heterologous [FeFe]-hydrogenase synthesis to yield a CdS@E. coli hybrid capable of light energy conversion and hydrogen formation in a single cell. The CdS@E. coli hybrid achieved photocatalytic hydrogen production with a sacrificial electron donor, thus demonstrating the feasibility of our system and expanding the current knowledge of photosensitization using a whole-cell biocatalyst with a bacterially precipitated semiconductor. 相似文献
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In this article, we report the synthesis of branched single crystal CdS nanowires. This branched CdS nanostructure is prepared
by a simple surfactant-directing method, which is of particular interest as it uses readily available reagents and provides
a convenient route to high-yield single crystal nanowires but with branched shape. These branched nanowires have an average
diameter of about 40 nm and length up to several micrometers. A possible mechanism has been proposed and the addition of surfactant
dodecylthiol into the two mixed-solvents would play an importance effect on the structure of the product. Based on the mechanism,
by controlling the synthesis conditions, such as the ratios between the surfactant, inorganic solvent, and organic solvent,
other kinds of nanostructures based on CdS nanowires were also prepared. Photoluminescence (PL) measurement reveals that the
branched CdS nanowires have a strong emission at about 700 nm which might be due to its special structure. 相似文献
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Polycrystalline n -CdS/ p -CdTe solar cells with a commerical carbon paint on the p -CdTe layer and an In-Ag paint on the n -CdS layer were fabricated by a coating and sintering method. Electrical properties of the conducting paints and solar cell parameters of the heterojunction solar cells were investigated as a function of electrode annealing conditions. The sintered CdS/CdTe solar cells whose electrode contacts were annealed at 350°C for 10 min in nitrogen showed maximum values of short-circuit current density, fill factor, and solar efficiency. Commercial carbon and silver paints can be used as electrodes to fabricate sintered CdS/CdTe solar cells with efficiency over 10%. 相似文献