Analysis and forecast of the Tianjin industrial carbon dioxide emissions resulted from energy consumption

This paper analyses the carbon dioxide emissions caused by industrial energy consumption of Tianjin from 2005 to 2012. The carbon emissions decomposition illustrated that the scale of production factor played a major role in the growth of Tianjin industrial carbon emissions and the average contribution of carbon emissions is up to 220.8975% in the statistical period; the intensity of energy factor played an important role in slowing down the growth of industrial carbon dioxide emissions. The average contribution of carbon emissions was ?136.1994% in the statistical period. The prediction model based on carbon emissions data from industrial energy consumption from 2003 to 2012 reached a high accuracy, with an average error of 1.78% for stochastic impacts by regression on population, affluence, and technology (STIRPAT) model, 2.41% for the Logistic regression model and an average error of 1.54% for the grey model. This research can contribute to predict the carbon emission and through it some suggestions can be made.     

Reimagining future energy systems: Overview of the US program to maximize energy utilization via integrated nuclear-renewable energy systems

A sustainable, balanced energy portfolio is necessary for a country's continued economic growth. This portfolio must collectively be able to provide reliable, resilient electricity at stable, affordable prices. Nuclear energy is an important contributor to global clean energy supply, both as a primary source and by complementing and enabling other clean energy sources. As we look to the design and operation of future energy systems, we see an increasing need to think differently about how we utilize our energy resources to meet all of our energy needs—not just electricity but also industrial and transportation demands. Resource utilization in light of a broader desire to reduce environmental impacts leads us to consider transforming how we use nuclear energy, which currently provides more than half of the nonemitting electricity generated in the United States. A paradigm shift is required to develop optimal energy generation and use configurations that embrace novel approaches to system integration and process design. The US Department of Energy (DOE) Office of Nuclear Energy (NE) program on Integrated Energy Systems (IES)—formerly the Nuclear-Renewable Hybrid Energy Systems (N-R HES) program—was established to evaluate potential options for the coordinated use of nuclear and renewable energy generators to meet energy demands across the electricity, industrial, and transportation sectors. These formerly independent sectors are becoming increasingly linked through technology advances in data acquisition, communications, demand response approaches, and control technologies. Advanced modeling and simulation tools can be employed to design systems that better coordinate across these sectors. Implementation of integrated multi-input, multi-output energy systems will allow for expanded use of nuclear energy beyond the grid in a manner that complements the increased build-out of variable renewable energy generation. These integrated systems would provide enhanced flexibility while also providing energy services and supporting the production of additional, nonelectric commodities (eg, potable water, hydrogen, and liquid fuels) via excess thermal and electrical energy from the nuclear system. Increased flexibility of traditionally baseload nuclear systems will support energy security, grid reliability, and grid resilience while maximizing the use of clean energy technologies. This paper provides an overview of current efforts in the United States that assess the potential to increase utilization of nuclear energy systems, in concert with renewable energy generation, via the IES program. Analysis tools and approaches and preliminary analysis results are summarized, and planned experimental activities to demonstrate integrated system performance are introduced.     

Hydrogen production from solar energy powered supercritical cycle using carbon dioxide

A hydrogen production method is proposed, which utilizes solar energy powered thermodynamic cycle using supercritical carbon dioxide (CO₂) as working fluid for the combined production of hydrogen and thermal energy. The proposed system consists of evacuated solar collectors, power generating turbine, water electrolysis, heat recovery system, and feed pump. In the present study, an experimental prototype has been designed and constructed. The performance of the cycle is tested experimentally under different weather conditions. CO₂ is efficiently converted into supercritical state in the collector, the CO₂ temperature reaches about 190 °C in summer days, and even in winter days it can reach about 80 °C. Such a high-temperature realizes the combined production of electricity and thermal energy. Different from the electrochemical hydrogen production via solar battery-based water splitting on hand, which requires the use of solar batteries with high energy requirements, the generated electricity in the supercritical cycle can be directly used to produce hydrogen gas from water. The amount of hydrogen gas produced by using the electricity generated in the supercritical cycle is about 1035 g per day using an evacuated solar collector of 100.0 m² for per family house in summer conditions, and it is about 568.0 g even in winter days. Additionally, the estimated heat recovery efficiency is about 0.62. Such a high efficiency is sufficient to illustrate the cycle performance.     

Study of solar energy powered transcritical cycle using supercritical carbon dioxide

In this paper, the performance of solar energy powered transcritical cycle using supercritical carbon dioxide for a combined electricity and heat generation, is studied experimentally. The experimental set‐up consists of evacuated solar collectors, pressure relief valve, heat exchangers and CO₂ feed pump. The pressure relief valve is used to simulate operation of a turbine and to complete the thermodynamic cycle. A complete effort was carried out to investigate the cycle performances not only in summer, but also in winter conditions. The results show that a reasonable thermodynamic efficiency can be obtained and COP for the overall outputs from the cycle is measured at 0.548 and 0.406, respectively, on a typical summer and winter day. The study shows the potential of the application of the solar energy powered cycle as a green power/heat generation system. Copyright © 2006 John Wiley & Sons, Ltd.     

Analysis of energy and carbon dioxide emission caused by power consumption

The main objective of this on‐site study is to use a full‐scale Heating, Ventilating, and Air‐Conditioning (HVAC) system installed in an office building in Taiwan for comparing the power consumption, energy‐saving, and carbon dioxide (CO₂) reduction of two different strategies for controlling the HVAC. These strategies are the Constant Volume (CV) system [Constant Air Volume+Constant‐flow], and the Variable Volume (VV) system [Variable Air Volume +Variable‐flow]. The on‐site experimental results indicate that average power consumptions are 164 kW for the CV system, and 88 kW for the VV system; the average electric current drops from 469 A for the CV system to 258 A for the VV system. Approximately 46% of the average energy‐saving can be achieved if the HVAC system is operated as a VV system. Additionally, the reduced quantity of accumulated CO₂ emission varies from 67 to 3687 kg with 0.637 kg CO₂ kwh^?1 emission factor during the office hours of 08:30 (a.m.)–17:00 (p.m.). The results demonstrate that switching the operation of an office building HVAC system from CV to VV will significantly enhance energy‐savings and CO₂ reduction. This studywill offer useful information for evaluating an indoor environmental policy with respect to energy‐savings and CO₂ emission reduction for office HVACs used in subtropical regions. Copyright © 2010 John Wiley & Sons, Ltd.     

Investigation of convection‐based energy systems using supercritical carbon dioxide as a working fluid

Carbon dioxide is the best retrofit to meet the future demand on long‐term environmental friendly working fluids. The volumetric efficiency of supercritical carbon dioxide is very high, which makes it a promising working fluid in convection‐based energy systems with high efficiency and small volume. Here, the natural convection of supercritical carbon dioxide driven only by temperature difference is studied in circulation loops. The Reynolds number of the flow is about 10⁴ when the temperature difference is only 20 K, about two orders of magnitude greater than that of water. Furthermore, the heat transfer rate is about 3 times as great as that of water. These results demonstrate the potential of carbon dioxide as a working fluid in solar thermal conversion, nuclear power and waste heat utilization, etc. The influence of the tube diameter on the flow and heat transfer characteristics is discussed. Both the velocity and the Nusselt number are greater in the loop with a larger tube diameter where flow reversal occurs periodically. It is found that flow reversal degrades the system efficiency of the natural circulation loop. Therefore, the optimization about the geometric configuration of convection‐based energy systems using carbon dioxide as a working fluid does exist and is very important for their safe and effective operation. Copyright © 2010 John Wiley & Sons, Ltd.     

Gibbs free energy minimization as a way to optimize the combined steam and carbon dioxide reforming of methane

Gibbs free energy minimization was applied to study thermodynamic equilibrium of the combined steam and carbon dioxide reforming of methane. Coke deposition, the content of methane and carbon dioxide in syn-gas as well as H₂/CO ratio were investigated as a function of CO₂/CH₄ and H₂O/CH₄ mole ratios at different temperatures and pressures. The ranges of the molar ratios CH₄/CO₂/H₂O in the feed with H₂/CO = 2.1-2.2 were identified at which reforming of methane is not complicated by coke deposition. For each range optimized CH₄/CO₂/H₂O molar ratios characterized by the lowest content of methane and carbon dioxide in syn-gas were found.     

Performance investigation of a new renewable energy-based carbon dioxide capturing system with aqueous ammonia

In this study, a novel wind energy-based carbon dioxide (CO₂) capturing system is developed and investigated for practical applications to reduce environmental emissions. The aqueous ammonia-based capturing technology is utilized. Wind turbines are used to operate the onsite ammonia synthesis as well as hydrogen production. The proton exchange membrane electrolysis system is considered for hydrogen production and the Haber-Bosch ammonia synthesis technique is utilized. The developed system is modeled in Aspen Plus software. The system performance for CO₂ capture is studied through economic, energy, and exergy perspectives. The CO₂ capture cost is evaluated to be between 0.1 and 0.23 $/kg CO₂. Furthermore, the system CO₂ capture rate is determined to be 3.5 kg/s. Moreover, for a unit mass of CO₂ captured, the energy consumption is found to be 640.1 kg CO₂/MWh. Several parametric studies are also conducted to analyze the effects of varying operating conditions on the system performance.     

Integrated design and evaluation of biomass energy system taking into consideration demand side characteristics

In this paper, a linear programming model has been developed for the design and evaluation of biomass energy system, while taking into consideration demand side characteristics. The objective function to be minimized is the total annual cost of the energy system for a given customer equipped with a biomass combined cooling, heating and power (CCHP) plant, as well as a backup boiler fueled by city gas. The results obtained from the implementation of the model demonstrate the optimal system capacities that customers could employ given their electrical and thermal demands. As an illustrative example, an investigation addresses the optimal biomass CCHP system for a residential area located in Kitakyushu Science and Research Park, Japan. In addition, sensitivity analyses have been elaborated in order to show how the optimal solutions would vary due to changes of some key parameters including electricity and city gas tariffs, biogas price, electricity buy-back price, as well as carbon tax rate.     

Analysis of advanced energy chain typologies

A method for estimating the effectiveness and CO₂ emissions of advanced energy conversion systems from primary to final energy is presented. A traditional condensing power plant for electricity production and a fuel boiler for heat production based on natural gas were used as the reference system. Several potentially better energy chains were analysed including CHP, tri‐generation, heat pumps and efficiency improvements in final energy use. All above solutions could provide clear reductions in primary energy use and emissions, in most cases tens of per cents, but the results are sensitive to operational conditions. In a heat pump system, the primary energy savings are considerable but emission reductions may turn out to be marginal or even negative whereas in co‐generation the emission reductions are higher than energy savings. Striving for high conversion efficiencies would ensure sustained benefits from the advanced energy chain typologies over the reference system even in the less favourable cases. Copyright © 2007 John Wiley & Sons, Ltd.     

Photocatalytic reduction of carbon dioxide over ferrocyanide-coated titanium dioxide powder

Photocatalytic reduction of carbon dioxide in aqueous media has been carried out over potassium-ferrocyanide-coated titanium dioxide powder. Formic acid and formaldehyde were identified as photoproducts, and were measured spectrophotometrically using Nash reagent. The effect of the variation of different parameters such as potassium ferrocyanide concentration, amount of photocatalyst (potassium-ferrocyanide-coated titanium dioxide powder), light intensity and particle size on the yield of photoproducts was also investigated. A tentative mechanism for this reduction has been proposed. © 1997 John Wiley & Sons, Ltd.     

Co-production of synthetic fuels and district heat from biomass residues,carbon dioxide and electricity: Performance and cost analysis

Large-scale systems suitable for the production of synthetic natural gas (SNG), methanol or gasoline (MTG) are examined using a self-consistent design, simulation and cost analysis framework. Three basic production routes are considered: (1) production from biomass via gasification; (2) from carbon dioxide and electricity via water electrolysis; (3) from biomass and electricity via hybrid process combining elements from routes (1) and (2). Process designs are developed based on technologies that are either commercially available or successfully demonstrated at precommercial scale. The prospective economics of future facilities coproducing fuels and district heat are evaluated from the perspective of a synthetic fuel producer. The levelised production costs range from 18–37 €/GJ for natural gas, 21–40 €/GJ for methanol and 23–48 €/GJ for gasoline, depending on the production route. For a given end-product, the lowest costs are associated with thermochemical plant configurations, followed by hybrid and electrochemical plants.     

A multivariate causality test of carbon dioxide emissions,energy consumption and economic growth in China

This paper uses multivariate co-integration Granger causality tests to investigate the correlations between carbon dioxide emissions, energy consumption and economic growth in China. Some researchers have argued that the adoption of a reduction in carbon dioxide emissions and energy consumption as a long term policy goal will result in a closed-form relationship, to the detriment of the economy. Therefore, a perspective that can make allowances for the fact that the exclusive pursuit of economic growth will increase energy consumption and CO₂ emissions is required; to the extent that such growth will have adverse effects with regard to global climate change.     

Hydrogen production from biomass coupled with carbon dioxide capture: The implications of thermodynamic equilibrium

In this work we report on the consequences of thermodynamic equilibrium for hydrogen (_H2)$({\mathrm{H}}_2)$ generation via steam gasification of biomass, coupled with in situ carbon dioxide (_CO2)$({\mathrm{CO}}_2)$ capture. Calcium oxide (CaO) is identified as a suitable sorbent for CO₂ capture, capable of absorbing CO₂ to very low concentrations, at temperatures and pressures conducive to the gasification of biomass. The proposed process exploits the reversible nature of the CO₂ capture reaction and leads to the production of a concentrated stream of CO₂, upon regeneration of the sorbent. We develop a thermodynamic equilibrium model to investigate fundamental reaction parameters influencing the output of H₂-rich gas. These are: (i) reaction temperature, (ii) reaction pressure, (iii) steam-to-biomass ratio, and (iv) sorbent-to-biomass ratio. Based on the model, we predict a maximum H₂ concentration of 83%-mol, with a steam-to-biomass ratio of 1.5 and a Ca-to-C ratio of 0.9. Contrary to previous experimental studies, this maximum H₂ output is reported at atmospheric pressure. Model predictions are compared with an experimental investigation of the pyrolysis of pure cellulose and the reactivity of CaO through multiple CO₂ capture and release cycles using a thermogravimetric analyser, coupled with a mass spectrometer (TGA–MS). On this basis, we demonstrate the applicability of thermodynamic equilibrium theory for the identification of optimal operating conditions for maximising H₂ output and CO₂ capture.     

Importance of biomass energy as alternative to other sources in Turkey

Energy plays a vital role in socio–economic development and raising standards of human beings. Turkey is a rapidly growing country; both its population and economy are expanding each year so its energy demand increases correspondingly and this increasing demand has to be met for keeping sustainable development in the economy and raising living conditions of mankind. Although Turkey has many energy sources, it is a big energy importer. Turkey has a lot of potential to supply its own energy, which could be put to use in order to avoid this energy dependence. Additionally, Turkey is a country that has an abundance of renewable energy sources and can essentially provide all energy requirements from indigenous energy sources. Biomass is one of the most promising energy sources considered to be alternative to conventional ones.     

Algal capture of carbon dioxide; biomass generation as a tool for greenhouse gas mitigation with reference to New Zealand energy strategy and policy

The use of algae to capture carbon dioxide as a method for greenhouse gas mitigation is discussed. A small fraction of the sunlight energy that bathes Earth is captured by photosynthesis and drives most living systems. Life on Earth is carbon-based and the energy is used to fix atmospheric carbon dioxide into biological material (biomass), indeed fossil fuels that we consume today are a legacy of mostly algal photosynthesis. Algae can be thought of as marine and freshwater plants that have higher photosynthetic efficiencies than terrestrial plants and are more efficient capturing carbon (Box 1). They have other favourable characteristics for this purpose. In the context of New Zealand energy strategy and policy I discuss progress in growing algae and seaweeds with emphasis on their application for exhaust flue carbon recycling for possible generation of useful biomass. I also introduce schemes utilising wild oceanic algae for carbon dioxide sequestration and the merits and possible adverse effects of using this approach. This paper is designed as an approachable review of the science and technology for policy makers and a summary of the New Zealand policy environment for those wishing to deploy biological carbon sequestration.     

Biomass carbon & its prospects in electrochemical energy systems

Activated carbon has now become a vital active material in multifarious applications such as catalytic supports, removal of pollutants, battery electrodes, capacitors, gas storage etc., and these applications require carbon powders with desirable functionalities like surface area, chemical constituents and pore structure. Hence the production of activated carbon materials, especially from cheap and natural bio-precursors (biomass) is a highly attractive research theme in today's science of advanced materials. Though abundant and detailed reports on activated carbons for these applications are available in the literature, creating a consolidated account on the biomass derived activated carbon would serve as a database for the researchers and thus appears justified. Hence an overview on activated carbons (preparation, physical and electrochemical properties) derived especially from biomass for the specific application as electrodes in electrochemical energy devices has been presented to stress the importance of biomass, bioenergy and conversion of wastes into energy concept further. It is certain from the survey of around 100 recent published articles that the biomass carbons have outstanding capability of being applied as electrodes in the energy devices. Particularly, carbon (unactivated) derived from pyrolized peanut shells exhibited a maximum specific capacity of 4765 mAhg⁻¹ in the case of lithium-ion batteries and coconut shell derived carbon in KOH electrolyte gave capacitance of 368 Fg⁻¹ and ZnCl₂ activated carbon from waste coffee grounds exhibited 368 Fg⁻¹ in H₂SO₄. Undoubtedly the study indicates that the biomass derived carbons have economic and commercial promise in the near future.     

Urban energy use and carbon emissions from cities in China and policy implications

Urban areas contain 40% of the population and contribute 75% of the Chinese national economy. Thus, a better understanding of urban energy uses is necessary for Chinese decision-makers at various levels to address energy security, climate change mitigation, and local pollution abatement. Therefore, this paper addresses three key questions: What is the urban contribution to China's energy usage and CO₂ emissions? What is the contribution of large cities, and what alternate energy–economy pathways are they following? How have energy uses and CO₂ emissions transformed in the last two decades in key Chinese cities? This three-tier analysis illustrates the changes in urban energy uses and CO₂ emissions in China. The results show that the urban contributions make up 84% of China's commercial energy usage. The 35 largest cities in China, which contain 18% of the population, contribute 40% of China's energy uses and CO₂ emissions. In four provincial cities, the per capita energy usage and CO₂ emissions have increased several-fold. Rapid progress was made in reducing the carbon intensity of economic activities in cities throughout the 1990s, but alarmingly, such progress has either slowed down or been reversed in the last few years. These results have important policy implications.     

Thermodynamic analysis of a novel compressed carbon dioxide energy storage system with low-temperature thermal storage

Research projects on new electrical energy storage (EES) systems are underway because of the role of EES in balancing the electric grid and smoothing out the instability of renewable energy. In this paper, a novel compressed carbon dioxide energy storage with low-temperature thermal storage was proposed. Liquid CO₂ storage was employed to increase the storage density of the system and avoid its dependence on geological formations. Low-temperature thermal energy storage technology was utilized to recycle the heat of compression and reduce the challenges to system components. The system configuration was introduced in detail. Four evaluation criteria, the round trip efficiency (RTE), exergy efficiency (η_Ex), thermal efficiency (η_TE), and energy density (ρ_E) were defined to show the system performance. Parametric analysis was carried out to examine the effects of some key parameters on system performance and the genetic algorithm was adopted for system optimization. The calculated results show that, for the novel EES under the basic working condition, its RTE is 41.4%, η_TE is 59.7%, η_Ex is 45.4%, and ρ_E is 15 kWh m⁻³. The value of ρ_E increases with the increasing pump outlet pressure for a fixed value of pressure ratio, and the changes of RTE, η_TE, and the total exergy destruction of the system (E_D,total) with pump outlet pressure are complicated for different values of pressure ratio. When both pressure ratio and pump outlet pressure are high, the values of RTE and ρ_E can be maximized whereas the value of E_D,total can be minimized. Besides, no matter how pump outlet pressure and pressure ratio change, the exergy destruction of the system mainly come from compressors and regenerators, which accounts for about 50% of the total exergy destruction.     

Energy consumption-economic growth relationship and carbon dioxide emissions in China

This paper applies the panel unit root, heterogeneous panel cointegration and panel-based dynamic OLS to re-investigate the co-movement and relationship between energy consumption and economic growth for 30 provinces in mainland China from 1985 to 2007. The empirical results show that there is a positive long-run cointegrated relationship between real GDP per capita and energy consumption variables. Furthermore, we investigate two cross-regional groups, namely the east China and west China groups, and get more important results and implications. In the long-term, a 1% increase in real GDP per capita increases the consumption of energy by approximately 0.48–0.50% and accordingly increases the carbon dioxide emissions by about 0.41–0.43% in China. The economic growth in east China is energy-dependent to a great extent, and the income elasticity of energy consumption in east China is over 2 times that of the west China. At present, China is subject to tremendous pressures for mitigating climate change issues. It is possible that the GDP per capita elasticity of carbon dioxide emissions would be controlled in a range from 0.2 to 0.3 by the great effort.