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《国际聚合物材料杂志》2012,61(3-4):243-248
Abstract In this article emphasis will be placed on selectively from 45 papers presented at the spring meeting and 33 papers also presented at the fall meeting. 相似文献
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Ye Gao Jean’ne M. Shreeve 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(1):19-36
This article is one of a number of reviews in a special issue to honor Prof. Dr. Ian Manners of the University of Bristol,
UK, for his outstanding contributions in the field of organometallic polymers. The focus of this review is on the syntheses,
properties, and characterization of ferrocene-containing liquid crystalline polymers in which ferrocene moieties are in or
pendent to the backbone and also dendrimers and [60]fullerene-ferrocene liquid crystalline materials. 相似文献
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基于各种正式发表的文献 ,澄清了热致液晶聚合物发展过程中的一些问题 ,并对各种形式热致液晶聚合物的热增强属性作一系统阐述。 相似文献
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Imidization of the precursor of a liquid crystalline polyimide was investigated using modulated differential scanning calorimetry (MDSC), Fourier transform infrared (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), and thermogravimetric analyzer (TGA) coupled to FTIR (TG‐IR). The FTIR study revealed that the rate and degree of imidization are functions of curing temperature and time. Imidization proceeds in two stages under isothermal condition. The initial weight loss up to 250 °C as observed from TGA was due to thermal cyclization, i.e., imidization process. The XPS analysis shows that the poly(amic acid) has two nitrogen 1s species at 400.3 and 399.2 eV possibly due to the isomerism of the dianhydride carbonyl, while liquid crystalline polyimide shows only a single nitrogen 1s species at 400.8 eV due to imide species.
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一种新型液晶环氧树脂单体的合成与固化研究 总被引:2,自引:1,他引:1
合成了一种新型复合联苯和芳香酯型的液晶环氧单体(4,4'-双(4-羟基苯甲氧基)-3,3,5,5'-四甲基联苯二缩水甘油醚,DGE-BHBTMBP),并用FT-IR、1H-NIVlR和13C-NMR对产物进行结构表征.用4,4'-二氨基二苯基砜(DDS)和4,4'-双(氨基苯氧基)二苯砜(BAPS)两种芳香二胺固化剂在DSC中进行等温和非等温固化研究,从固化过程来看,BAPS比DDS更适合作为DGE-BHBTMBP的固化剂. 相似文献
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Shingo Tanaka Fusao Hojo Yoshitaka Takezawa Kiyoshi Kanie Atsushi Muramatsu 《Polymer-Plastics Technology and Engineering》2018,57(4):269-275
The liquid crystalline (LC) order was introduced on aluminum nitride particles by the surface effect to increase the thermal conductivities of aluminum nitride/LC epoxy composites. X-ray diffraction and grazing incidence small-angle X-ray scattering analyses revealed that the LC epoxy resin cured on the surface of an α-Al2O3 substrate formed homeotropically aligned smectic layers to increase the thermal conductivity. Therefore, thermally treated aluminum nitride particles, which formed α-Al2O3 layers on their surfaces, were applied to prepare the composites with high thermal conductivity. The thermal conductivities of the resulting composites were 11–36% higher than those with the composites prepared using untreated aluminum nitride particles. 相似文献
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J. G hde R. Mix R. -P. Krü ger H. Goering W. Funke U. Hermann 《The Journal of Adhesion》1996,58(3):243-251
Linear liquid crystalline polyurethane (LC-PU) were synthesized by the reaction of 2,4-toluene diisocyanate (TDI), 4,4'-bis-(6-hydroxyhexoxy)biphenyl (BHHBP), and poly(butylene adipate) (PBA). The BHHBP as mesogenic unit was incorporated into the hard segment formed by the reaction with the TDI. The hard segments are incompatible with the PBA soft segments. The mesomorphic behaviour is influenced by both the soft segment length and the hard segment concentration.
The adhesion of such polyurethanes used as primer in composites based on steel as substrate and alkyd melamine resin as coating is dependent on the polyurethane structure, the thickness of the polyurethane layer and its drying conditions. The highest wet adhesion stability is achieved by the hard-segment-type polyurethane composed of TDI and the mesogenic unity BHHBP. Partial substitution of BHHBP by 2,2-bis-(hydroxymethyl)propionic acid (BHMPA) in this LC polyurethane enhances the effectiveness of the primer. 相似文献
The adhesion of such polyurethanes used as primer in composites based on steel as substrate and alkyd melamine resin as coating is dependent on the polyurethane structure, the thickness of the polyurethane layer and its drying conditions. The highest wet adhesion stability is achieved by the hard-segment-type polyurethane composed of TDI and the mesogenic unity BHHBP. Partial substitution of BHHBP by 2,2-bis-(hydroxymethyl)propionic acid (BHMPA) in this LC polyurethane enhances the effectiveness of the primer. 相似文献
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These two papers form part of a research project investigating the effect of dye orientation in liquid crystalline media. The first paper describes briefly the principles underlying the development of present–day liquid crystal displays, and the second describes a method used for the quantitative investigation of the efficiency of such media in orienting dye molecules (order parameter) in relation to the chemical structure of the dye and the effects of solvent orientation and polarity on absorbance and colour. The data obtained should permit choices of dye to be made to improve visibility and contrast in current liquid crystal display systems. 相似文献
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