Life cycle assessment of hydrogen fuel cell and gasoline vehicles

A life cycle assessment of hydrogen and gasoline vehicles, including fuel production and utilization in vehicles powered by fuel cells and internal combustion engines, is conducted to evaluate and compare their efficiencies and environmental impacts. Fossil fuel and renewable technologies are investigated, and the assessment is divided into various stages.     

Optimization of hydrogen feeding procedure in PEM fuel cell systems for transportation

The hydrogen feeding sub-system is one of balance of plant (BOP) components necessary for the correct operation of a fuel cell system (FCS). In this paper the performance of a 6 kW PEM (Proton Exchange Membrane) FCS, able to work with two fuel feeding procedures (dead-end or flow-through), was experimentally evaluated with the aim to highlight the effect of the anode operation mode on stack efficiency and durability. The FCS operated at low reactant pressure (<50 kPa) and temperature (<330 K), without external humidification. The experiments were performed in both steady state and dynamic conditions. The performance of some cells in dead-end mode worsened during transient phases, while a more stable working was observed with fuel recirculation. This behavior evidenced the positive role of the flow-through procedure in controlling flooding phenomena, with the additional advantage to simplify the management issues related to hydrogen purge and air stoichiometric ratio. The flow-through modality resulted a useful way to optimize the stack efficiency and to reduce the risks of fast degradation due to reactant starvation during transient operative phases.     

Projecting full build-out environmental impacts and roll-out strategies associated with viable hydrogen fueling infrastructure strategies

A transition from gasoline internal combustion engine vehicles to hydrogen fuel cell electric vehicles (FCEVs) is likely to emerge as a major component of the strategy to meet future greenhouse gas reduction, air quality, fuel independence, and energy security goals. Advanced infrastructure planning can minimize the cost of hydrogen infrastructure while assuring that energy and environment benefits are achieved. This study presents a comprehensive advanced planning methodology for the deployment of hydrogen infrastructure, and applies the methodology to delineate fully built-out infrastructure strategies, assess the associated energy and environment impacts, facilitate the identification of an optimal infrastructure roll-out strategy, and identify the potential for renewable hydrogen feedstocks. The South Coast Air Basin of California, targeted by automobile manufacturers for the first regional commercial deployment of FCEVs, is the focus for the study. The following insights result from the application of the methodology:

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Compared to current gasoline stations, only 11%-14% of the number of hydrogen fueling stations can provide comparable accessibility to drivers in a targeted region.

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To meet reasonable capacity demand for hydrogen fueling, approximately 30% the number of hydrogen stations are required compared to current gasoline stations.

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Replacing gasoline vehicles with hydrogen FCEVs has the potential to (1) reduce the emission of greenhouse gases by more than 80%, reduce energy requirements by 42%, and virtually eliminate petroleum consumption from the passenger vehicle sector, and (2) significantly reduce urban concentrations of ozone and PM2.5.

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Existing sources of biomethane in the California South Coast Air Basin can provide up to 30% of the hydrogen fueling demand for a fully built-out hydrogen FCEV scenario.

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A step-wise transition of judiciously located existing gasoline stations to dispense and accommodate the increasing demand for hydrogen addresses proactively key infrastructure deployment challenges including a viable business model, zoning, permitting, and public acceptance.

     

Model-based development of low-level control strategies for transient operation of solid oxide fuel cell systems

The exploitation of an SOFC-system model to define and test control and energy management strategies is presented. Such a work is motivated by the increasing interest paid to SOFC technology by industries and governments due to its highly appealing potentialities in terms of energy savings, fuel flexibility, cogeneration, low-pollution and low-noise operation.The core part of the model is the SOFC stack, surrounded by a number of auxiliary devices, i.e. air compressor, regulating pressure valves, heat exchangers, pre-reformer and post-burner. Due to the slow thermal dynamics of SOFCs, a set of three lumped-capacity models describes the dynamic response of fuel cell and heat exchangers to any operation change.The dynamic model was used to develop low-level control strategies aimed at guaranteeing targeted performance while keeping stack temperature derivative within safe limits to reduce stack degradation due to thermal stresses. Control strategies for both cold-start and warmed-up operations were implemented by combining feedforward and feedback approaches. Particularly, the main cold-start control action relies on the precise regulation of methane flow towards anode and post-burner via by-pass valves; this strategy is combined with a cathode air-flow adjustment to have a tight control of both stack temperature gradient and warm-up time. Results are presented to show the potentialities of the proposed model-based approach to: (i) serve as a support to control strategies development and (ii) solve the trade-off between fast SOFC cold-start and avoidance of thermal-stress caused damages.     

Analysis of the control structures for an integrated ethanol processor for proton exchange membrane fuel cell systems

The aim of this work is to investigate which would be a good preliminary plantwide control structure for the process of Hydrogen production from bioethanol to be used in a proton exchange membrane (PEM) accounting only steady-state information. The objective is to keep the process under optimal operation point, that is doing energy integration to achieve the maximum efficiency. Ethanol, produced from renewable feedstocks, feeds a fuel processor investigated for steam reforming, followed by high- and low-temperature shift reactors and preferential oxidation, which are coupled to a polymeric fuel cell. Applying steady-state simulation techniques and using thermodynamic models the performance of the complete system with two different control structures have been evaluated for the most typical perturbations. A sensitivity analysis for the key process variables together with the rigorous operability requirements for the fuel cell are taking into account for defining acceptable plantwide control structure. This is the first work showing an alternative control structure applied to this kind of process.     

Life cycle cost analysis to examine the economical feasibility of hydrogen as an alternative fuel

This study uses a life cycle costing (LCC) methodology to identify when hydrogen can become economically feasible compared to the conventional fuels and which energy policy is the most effective at fostering the penetration of hydrogen in the competitive fuel market. The target hydrogen pathways in this study are H₂ via natural gas steam reforming (NG SR), H₂ via naphtha steam reforming (Naphtha SR), H₂ via liquefied petroleum gas steam reforming (LPG SR), and H₂ via water electrolysis (WE). In addition, the conventional fuels (gasoline, diesel) are also included for the comparison with the H₂ pathways.     

Air quality and environmental impacts of alternative vehicle technologies in Ontario,Canada

This study is focused on the province-wide emissions in Ontario, Canada and urban air pollution in the city of Toronto. The life-cycle (LC) impacts of utilizing alternative fuels for transportation purposes is considered in terms of six major stressors for climate change, acidification and urban air quality. The vehicles considered are plug-in hybrid electric vehicles (PHEVs), fuel cell vehicles (FCVs) and fuel cell plug-in hybrid electric vehicles (FCPHEVs). Modeling of the penetration rates for these types of vehicles has been completed based on the maximum base-load capacity of Ontario's electricity grid to accommodate the generation of hydrogen and charging of vehicles using grid electricity. Results show that the reduction in greenhouse gas emissions from adoption of PHEVs or FCVs will exceed 3% of the current emissions from the transportation sector in Ontario while FCPHEVs may achieve almost twice this reduction. All vehicles exhibit similar impacts on the precursors for photochemical smog although the province-wide effects differ significantly.     

Eco-efficiency of H2 and fuel cell buses

Urban governments are continually striving to improve air quality by making public transportation more environmentally friendly. H₂ fuel cell buses (FCBs) offer one of the best ways to reduce air pollution. FCB has high energy efficiency and lower air pollutant emissions than conventional buses (e.g. diesel bus/Compressed natural gas bus, CNGB), and H₂ is an attractive alternative energy source in the face of depleting fossil fuels and global warming. H₂ can be produced via fossil fuels and renewable sources and then stored and distributed in a variety of different ways. While many contend that H₂ and FCB are not yet commercially viable, H₂ technology has developed a great deal over recent years. This fact alone demands that governments as well as for-profit businesses take a discerning look at what H₂ and FCB have to offer in terms of both environmental and economic opportunities.In this study, environmental and economic aspects of hydrogen pathways are analyzed according to plausible production methods and capacity, and distribution options in Korea using life cycle assessment (LCA) and life cycle costing (LCC) methods. This study considers the following means of hydrogen production: naphtha steam reforming (Naphtha SR), natural gas steam reforming (NG SR), and water electrolysis (WE). Additionally, conventional fuels (Diesel and CNG) are also included as target fuel pathways in order to identify which hydrogen pathway in particular has the greatest environmental advantage over conventional fuels. This study aimed to identify whether H₂ and FCB can compete with conventional fuels used in buses in terms of the eco-efficiency method, which focuses on economic feasibility and environmental improvement.The conclusion of this study is that H₂ pathways, especially, Naphtha SR [C] and NG SR [S], are more competitive than conventional fuels from an eco-efficiency perspective. As a result, switching from conventional transportation fuel to these suggested H₂ pathways is expected to offer an economically and environmentally more eco-efficient means of transportation. Henceforth, drawing upon evidence within this report, decision-makers would be wise to invest in more cost-effective and environment-friendly fuels by constructing an optimal H₂ infrastructure.     

The analysis on energy and environmental impacts of microalgae-based fuel methanol in China

The whole life of methanol fuel, produced by microalgae biomass which is a kind of renewable energy, is evaluated by using a method of life cycle assessment (LCA). LCA has been used to identify and quantify the environment emissions and energy efficiency of the system throughout the whole life cycle, including microalgae cultivation, methanol conversion, transport, and end-use. Energy efficiency, defined as the ratio of the energy of methanol produced to the total required energy, is 1.24, the results indicate that it is plausible as an energy producing process. The environmental impact loading of microalgae-based fuel methanol is 0.187mPET₂₀₀₀ in contrast to 0.828mPET₂₀₀₀ for gasoline. The effect of photochemical ozone formation is the highest of all the calculated categorization impacts of the two fuels. Utilization of microalgae an raw material of producing methanol fuel is beneficial to both production of renewable fuels and improvement of the ecological environment. This Fuel methanol is friendly to the environment, which should take an important role in automobile industry development and gasoline fuel substitute.     

Premixed hydrogen-air combustion system for fuel cell systems

The advance of efficient hydrogen-air combustion systems has increasingly become of interest in the framework of the development of fuel cell systems, especially for the automotive sector. Therefore, compact modulating systems are required, with the additional demand of low emissions, to be integrated in a fuel cell system. A modulating combustion system based on combustion within inert porous media and an integrated heat exchanger has been developed and investigated. The system is able to handle premixed combustion of lean H₂/air mixtures at a surface load range of 1075 kW/m²-2150 kW/m², and a global equivalence ratio of ?=0.5. The special hydrogen-air mixing concept eliminates the risk of flame flashback and enables operation with very low NO_x emissions.     

Model-based control of fuel cells (2): Optimal efficiency

A dynamic PEM fuel cell model has been developed, taking into account spatial dependencies of voltage, current, material flows, and temperatures. The voltage, current, and therefore, the efficiency are dependent on the temperature and other variables, which can be optimized on the fly to achieve optimal efficiency. In this paper, we demonstrate that a model predictive controller, relying on a reduced-order approximation of the dynamic PEM fuel cell model can satisfy setpoint changes in the power demand, while at the same time, minimize fuel consumption to maximize the efficiency. The main conclusion of the paper is that by appropriate formulation of the objective function, reliable optimization of the performance of a PEM fuel cell can be performed in which the main tunable parameter is the prediction and control horizons, V and U, respectively. We have demonstrated that increased fuel efficiency can be obtained at the expense of slower responses, by increasing the values of these parameters.     

Design of a hybrid electric fuel cell power train for an urban bus

With the requirements for reducing emissions and improving fuel economy, new markets have become attractive for automotive companies that are developing electric, hybrid, and plug-in vehicles using new technologies candidates to be implemented in the next generations of vehicles. Most of all, hybrid vehicles are attracting interest due to great potential to achieve higher fuel economy and a longer range with respect to pure electric mode but often this solution is not petroleum free. Within a national project CNR TAE Institute is involved in the development of a zero emission hybrid electric city bus based on PEM fuel cell technology able to increase the range at least 30% with respect to the same vehicle in pure electric configuration. Design, control and preliminary results are reported in this paper.     

Model-based fault detection of hybrid fuel cell and photovoltaic direct current power sources

Hybrid DC power sources which consist of fuel cells, photovoltaic and lithium-ion batteries provide clean, high efficiency power supply. This hybrid DC power sources can be used in many applications. In this work, a model-based fault detection methodology for this hybrid DC power sources is presented. Firstly, the dynamic models of fuel cells, photovoltaic and lithium-ion batteries are built. The state space model of hybrid DC power sources is obtained by linearizing these dynamic models in operation points. Based on this state space model the fault detection methodology is proposed. Simulation results show that model-based fault detection methodology can find the fault on line, improve the generation time and avoid permanent damage to the equipment.     

Life-cycle assessment of diesel, natural gas and hydrogen fuel cell bus transportation systems

The Sustainable Transport Energy Programme (STEP) is an initiative of the Government of Western Australia, to explore hydrogen fuel cell technology as an alternative to the existing diesel and natural gas public transit infrastructure in Perth. This project includes three buses manufactured by DaimlerChrysler with Ballard fuel cell power sources operating in regular service alongside the existing natural gas and diesel bus fleets. The life-cycle assessment (LCA) of the fuel cell bus trial in Perth determines the overall environmental footprint and energy demand by studying all phases of the complete transportation system, including the hydrogen infrastructure, bus manufacturing, operation, and end-of-life disposal. The LCAs of the existing diesel and natural gas transportation systems are developed in parallel. The findings show that the trial is competitive with the diesel and natural gas bus systems in terms of global warming potential and eutrophication. Emissions that contribute to acidification and photochemical ozone are greater for the fuel cell buses. Scenario analysis quantifies the improvements that can be expected in future generations of fuel cell vehicles and shows that a reduction of greater than 50% is achievable in the greenhouse gas, photochemical ozone creation and primary energy demand impact categories.     

The dynamics of the stationary fuel cell standardisation framework

Standardisation efforts for stationary fuel cell systems (FCS) have been carried out over the last twenty years on different international, European and national platforms. These efforts have resulted in an active standardisation landscape with a variety of cross-cutting, application-oriented and technology-oriented standards published and under development. In principle, standards ease the market introduction of these systems, but careful coordination and harmonisation between the platforms is necessary to avoid conflicting technical specifications. This paper describes the state-of-the-art of the standardisation platforms and activities for stationary fuel cell applications and assesses the interaction between the different platforms and activities. The bottom-up feeding and top-down transposition of standards and the active involvement of national standardisation organisations in regional and international standardisation activities continues to add to a coherent standardisation framework for stationary fuel cells.     

Comparative economic and environmental benefits of ownership of both new and used light duty hydrogen fuel cell vehicles in Japan

We present a novel study of the differential total costs of ownership and marginal cost of life cycle emissions abatement for owners of both new and used light duty fuel cell and internal combustion engine vehicles in Japan. We find the emergence of used FCVs in the fleet significantly improves the economic and emissions savings over ICEVs. The cumulative life cycle GHG emissions reductions rapidly increase when FCVs exceed 55%–70% of total LDVs. Life cycle emissions in the vehicle fleet increase 40% if hydrogen is produced from SMR with CCS rather than from solar or wind based electrolysis. Fuel cell cost and electrolyser efficiency are key factors in achieving benefits. Finally, if the early time growth of FCVs to 2030 can be maintained near 50% the government 2050 emissions reduction target of 80% reduction from a 2013 base can be achieved.     

Exergy analysis of an integrated fuel processor and fuel cell (FP–FC) system

Fuel cells have great application potential as stationary power plants, as power sources in transportation, and as portable power generators for electronic devices. Most fuel cells currently being developed for use in vehicles and as portable power generators require hydrogen as a fuel. Chemical storage of hydrogen in liquid fuels is considered to be one of the most advantageous options for supplying hydrogen to the cell. In this case a fuel processor is needed to convert the liquid fuel into a hydrogen-rich stream. This paper presents a second-law analysis of an integrated fuel processor and fuel cell system. The following primary fuels are considered: methanol, ethanol, octane, ammonia, and methane. The maximum amount of electrical work and corresponding heat effects produced from these fuels are evaluated. An exergy analysis is performed for a methanol processor integrated with a proton exchange membrane fuel cell, for use as a portable power generator. The integrated FP–FC system, which can produce 100 W of electricity, is simulated with a computer model using the flow-sheeting program Aspen Plus. The influence of various operating conditions on the system efficiency is investigated, such as the methanol concentration in the feed, the temperature in the reformer and in the fuel cell, as well as the fuel cell efficiency. Finally, it is shown that the calculated overall exergetic efficiency of the FP–FC system is higher than that of typical combustion engines and rechargeable batteries.     

Analysis of the control strategies for fuel saving in the hydrogen fuel cell vehicles

A hydrogen fuel cell vehicle requires fuel cells, batteries, supercapacitors, controllers and smart control units with their control strategies. The controller ensures that a control strategy predicated on the data taken from the traction motor and energy storage systems is created. The smart control unit compares the fuel cell nominal output power with the vehicle power demand, calculates the parameters and continually adjusts the variables. The control strategies that can be developed for these units will enable us to overcome the technological challenges for hydrogen fuel cell vehicles in the near future. This study presents the best hydrogen fuel cell vehicle configurations and control strategies for safe, low cost and high efficiency by comparing control strategies in the literature for fuel economy.     

Environmental life cycle feasibility assessment of hydrogen as an automotive fuel in Western Australia

A life cycle assessment has been undertaken in order to determine the environmental feasibility of hydrogen as an automotive fuel in Western Australia. The criterion for environmental feasibility has been defined as having life cycle impacts equal to or lower than those of petrol. Two hydrogen production methods have been analysed. The first is steam methane reforming (SMR), which uses natural gas (methane) as a feedstock. The second method analysed is alkaline electrolysis (AE), a mature technology that uses water as a feedstock. The life cycle emissions and impacts were assessed per kilometre of vehicle travel.     

Energy system analysis of the fuel cell buses operated in the project: Clean Urban Transport for Europe

During the project Clean Urban Transport for Europe (CUTE), which ended in May 2006, 27 fuel cell buses were operated in nine European cities. In this paper key performance parameters from the operation of the fuel cell buses in the project are reported, the energy system of the bus is analysed and drive cycle tests in five cities are presented and analysed. The focus of the paper is on fuel consumption and optimisation potential but experiences of, and recommendations for, evaluation in large demonstration projects are also presented. The results show that although the total fuel cell system efficiency was found to be high (36–41%), the fuel consumption was higher for the fuel cell buses than for diesel buses. Since the CUTE buses were a pre-commercial generation of fuel cell buses, with standard auxiliaries and extensive reliability measures, large fuel consumption reduction is possible. Suggestions on how to increase the efficiency is presented in this paper. Minimising the reliability measures would decrease fuel consumption by about 20% and lowering the weight by 2 tonnes would decrease fuel consumption by another 10%. Hybridisation in combination with using electrical auxiliaries could save an additional 5–10% or more.