Prospects and challenges for green hydrogen production and utilization in the Philippines

The Philippines is exploring different alternative sources of energy to make the country less dependent on imported fossil fuels and to reduce significantly the country's CO₂ emissions. Given the abundance of renewable energy potential in the country, green hydrogen from renewables is a promising fuel because it can be utilized as an energy carrier and can provide a source of clean and sustainable energy with no emissions. This paper aims to review the prospects and challenges for the potential use of green hydrogen in several production and utilization pathways in the Philippines. The study identified green hydrogen production routes from available renewable energy sources in the country, including geothermal, hydropower, wind, solar, biomass, and ocean. Opportunities for several utilization pathways include transportation, industry, utility, and energy storage. From the analysis, this study proposes a roadmap for a green hydrogen economy in the country by 2050, divided into three phases: I–green hydrogen as industrial feedstock, II–green hydrogen as fuel cell technology, and III–commercialization of green hydrogen. On the other hand, the analysis identified several challenges, including technical, economic, and social aspects, as well as the corresponding policy implications for the realization of a green hydrogen economy that can be applied in the Philippines and other developing countries.     

Techno-economic calculation of green hydrogen production and export from Colombia

In the present paper a techno-economic hydrogen production and transportation costs to export from Colombia to Europe and Asia were determined using the open-source Python tools, such as WindPowerLIB, PVLIB, ERA5 weather data, and the Hydrogen-2-Central (H2C) model. Calculations were performed as well for Chile, for comparison as a regional competitor. In addition, a detailed overview of Colombia's energy system and national efforts for a market ramp-up of renewable energy and hydrogen is provided. The application of the model in different scenarios shows Colombia's potential to produce green hydrogen using renewable energies. The prices estimated are 1.5 and 1.02 USD/kgH₂ for 2030 and 2050 with wind power, and 3.24 and 1.65 USD/kgH₂ for 2030 and 2050 using solar energy. Colombia can become one of the most promising hydrogen suppliers to Asian and European countries with one of the lowest prices in the production and transportation of green hydrogen.     

Hydropower for green hydrogen production in Turkey

The current study develops a hydro-based hydrogen production concept and investigates the utilization of hydroelectric power for green hydrogen production in Turkey. For the hydroelectric power potential calculations, the installed and under construction hydroelectric power plants, run-of-river systems, and reservoir dams are considered for the entire country. The potential capacities of each city are estimated based on the available official and published data by the government agencies, and some reasonable assumptions are also made for detailed analysis and assessment for a feasible hydrogen economy in the country. The results obtained here clearly show that the contribution of hydroelectric energy to hydrogen production is considerable high in promoting countries towards leadership in the field of green hydrogen production. Based on the analysis results, Turkey's hydro-based green hydrogen production potential is estimated to be 2.26 megatons. Şanlıurfa, Elazığ, Diyarbakır, Artvin, and Adana are cities with the highest green hydrogen production potential from hydroelectric power with an annual production capacity of 233.09, 204.92, 175.35, 157.28, and 140.8 kilotons, respectively. The results of this study are expected to help the policymakers to use hydropower energy for planning and developing action plan for the country and help overcome carbon-based fuel usage and its associated pollution. The main idea is to prepare hydrogen maps in detail for each region in Turkey, based on the hydro energy potential by using electrolysers. This, in turn, can be considered in the context of the current policies of the local communities and policymakers to prepare a sustainable energy roadmap for the country.     

Green hydrogen production potential for developing a hydrogen economy in Pakistan

Pakistan's energy crisis can be diminished through the use of Renewable and alternative sources of energy. Hydrogen as an energy vector is likely to replace the fossil fuels in the future owing to the political, financial and environmental factors associated with the latter. In this regard it is imperative that conscious effort is directed towards the production of hydrogen from Renewable resources. Renewable energy resources are abundantly available in Pakistan. The need to produce Hydrogen from Renewable resources in Pakistan (or any developing economy) is investigated because it is possible to store vast amount of intermittent renewable energy for later use. Thus the introduction of Hydrogen in the energy supply chain implies the start of a Pakistan Hydrogen Economy. Many nations have developed the Hydrogen Energy Roadmap, and if Pakistan has to follow suite it is only possible through the employment of Renewable energy resources. This study estimates the potential of different Renewable resources available in Pakistan i.e. Solar, Wind, Geothermal, Biomass and Municipal Solid waste. An estimate is then made for the potential of producing hydrogen from various established technologies from each of these Renewable resources. A number of reviews have been published stating the availability and usage of Renewable energy in Pakistan; however no specific study has been focused on the use of Renewable resources for developing a Hydrogen economy or a power-to-gas system in Pakistan. This study concludes that that Biomass is the most feasible feedstock for developing a Hydrogen supply chain in Pakistan with a potential to generate 6.6 million tons of Hydrogen annually, followed by Solar PV that has a generation potential of 2.8 million tons and then Municipal solid waste with a capacity of 1 million ton per annum.     

Dry reforming of biogas in a pilot unit: Scale-up of catalyst synthesis and green hydrogen production

A pilot experimental unit was constructed to produce synthesis gas from the dry reforming (DR) of biogas, and its operation was monitored during reaction assays. A scale-up was performed on synthesizing a Ni granulated catalyst, supported on mesoporous silica. The catalyst activity was evaluated under processes of induced deactivation, followed by regeneration during a 90-h reaction. The reaction variables studied included the volumetric composition of the inlet gas flow to the reactor (40–70%CH₄ and 60-30%CO₂), metal content (5–20% by mass), and inlet gas flow rate (684–2844 L h^?1). The catalyst with the metal content of 20% provided the best conversions (99%CH₄ and 97%CO₂). The experimental pilot unit is capable of producing 575 L h^?1 of green H₂ from biogas. The regeneration step effectively eliminated coke from the catalyst surface, resulting in the recovery of catalytic performance.     

Reducing CO2 emissions in the iron industry with green hydrogen

The different methods of producing Green Hydrogen have been discussed in detail in this article. The implications and significance of employing green hydrogen in the steel and iron industries have been brought to light. Carbon Dioxide (CO₂) is a significant environmental gas pollutant which is released in large quantities by steel mills and other industrial facilities. It is hoped that the appropriate measures would be taken to minimize the emission of hazardous gases, such as CO₂, from each facility. The green hydrogen idea is a new technology that is being used as an alternative energy source for the sectors listed above. The most important step in reducing CO₂ emissions is to collect it and store it in a secure location. In this article, the main goal and scope is to analyse various methodologies to minimize CO₂ emissions in Iron and Steel Industries as well as compare with noble green hydrogen technology. Here, the state of art for the emission of CO₂ as well as the recommendations of Green Hydrogen Technology are emphasized which is the novelty of this article.     

Flexible production of green hydrogen and ammonia from variable solar and wind energy: Case study of Chile and Argentina

We report a techno-economic modelling for the flexible production of hydrogen and ammonia from water and optimally combined solar and wind energy. We use hourly data in four locations with world-class solar in the Atacama desert and wind in Patagonia steppes. We find that hybridization of wind and solar can reduce hydrogen production costs by a few percents, when the effect of increasing the load factor on the electrolyser overweighs the electricity cost increase. For ammonia production, the gains by hybridization can be substantially larger, because it reduces the power variability, which is costly, due to the need for intermediate storage of hydrogen between the flexible electrolyser and the less flexible ammonia synthesis unit. Our modelling reveals the crucial role in the synthesis of flexibility, which cuts the cost of variability, especially for the more variable wind power. Our estimated near-term production costs for green hydrogen, around 2 USD/kg, and green ammonia, below 500 USD/t, are encouragingly close to competitiveness against fossil-fuel alternatives.     

Exploring the feasibility of green hydrogen production using excess energy from a country-scale 100% solar-wind renewable energy system

When planning large-scale 100% renewable energy systems (RES) for the year 2050, the system capacity is usually oversized for better supply-demand matching of electrical energy since solar and wind resources are highly intermittent. This causes excessive excess energy that is typically dissipated, curtailed, or sold directly. The public literature shows a lack of studies on the feasibility of using this excess for country-scale co-generation. This study presents the first investigation of utilizing this excess to generate green hydrogen gas. The concept is demonstrated for Jordan using three solar photovoltaic (PV), wind, and hybrid PV-wind RESs, all equipped with Lithium-Ion battery energy storage systems (ESSs), for hydrogen production using a polymer electrolyte membrane (PEM) system. The results show that the PV-based system has the highest demand-supply fraction (>99%). However, the wind-based system is more favorable economically, with installed RES, ESS, and PEM capacities of only 23.88 GW, 2542 GWh, and 20.66 GW. It also shows the highest hydrogen annual production rate (172.1 × 10³ tons) and the lowest hydrogen cost (1.082 USD/kg). The three systems were a better option than selling excess energy directly, where they ensure annual incomes up to 2.68 billion USD while having payback periods of as low as 1.78 years. Furthermore, the hydrogen cost does not exceed 2.03 USD/kg, which is significantly lower than the expected cost of hydrogen (3 USD/kg) produced using energy from fossil fuel-based systems in 2050.     

Evaluation of strategic directions for supply and demand of green hydrogen in South Korea

Currently, worldwide efforts are being made to replace fossil fuels with renewable energy to meet the goals of the Paris Agreement signed in 2015. Renewable energy, with solar and wind power as representative examples, focuses on hydrogen as a means of supplementing the intermittency in operation. Moreover, 17 advanced countries, including Australia and Europe, announced policies related to hydrogen, and Korea joined the ranks by announcing a roadmap to revitalize the hydrogen economy in 2019. As of 2020, the unit price of renewable energy in Korea is 0.1 $/kWh and 0.12 $/kWh for solar and wind power, respectively, which are more than five times higher than those of the world's best. The significant difference is due to the low utilization of power plants stemming from environmental factors. Consequently, securing the economic feasibility for the production of green hydrogen in Korea is difficult, and the evaluation of various policies is required to overcome these shortcomings. Currently, Korea's policy on renewable energy is focused on solar power, and despite the goal for a power generation of 57,483 GWh/year centered on offshore wind power by 2034, plans for utilization are lacking. By harnessing such energy, producing a percentage of the total green hydrogen required from the hydrogen economy roadmap can be realized, but securing economic feasibility may be difficult. Therefore, reinforcements in policies for the production of green hydrogen in Korea are required, and implementation of foreign policies for overseas cooperation in hydrogen production and import is necessary.     

Design of a novel flat-plate photobioreactor system for green algal hydrogen production

Some green microalgae have the ability to harness sunlight to photosynthetically produce molecular hydrogen from water. This renewable, carbon-neutral process has the additional benefit of sequestering carbon dioxide and accumulating biomass during the algal growth phase. We document the details of a novel one-litre vertical flat-plate photobioreactor that has been designed to facilitate green algal hydrogen production at the laboratory scale. Coherent, non-heating illumination is provided by a panel of cool-white light-emitting diodes. The reactor body consists of two compartments constructed from transparent polymethyl methacrylate sheets. The primary compartment holds the algal culture, which is agitated by means of a recirculating gas-lift. The secondary compartment is used to control the temperature of the system and the wavelength of radiation. The reactor is fitted with probe sensors that monitor the pH, dissolved oxygen, temperature and optical thickness of the algal culture. A membrane-inlet mass spectrometry system has been developed and incorporated into the reactor for dissolved hydrogen measurement and collection. The reactor is hydrogen-tight, modular and fully autoclaveable.     

The sustainability of green hydrogen: An uncertain proposition

Green hydrogen is increasingly considered a vital element for the long-term decarbonization of the global energy system. For regions with scarce land resources, this means importing significant volumes of green hydrogen from regions with abundance of renewable energy. In producing countries, this raises significant sustainability questions related to production and export. To assess these sustainability-related opportunities and challenges, the authors first present a review of renewable energy deployment in the electricity sector, and then extend it to the foreseeable opportunities and risks of green hydrogen production in exporting countries. The paper finds that questions of freshwater and land availability are critical from an environmental and a socio-economic point of view, and that the development of international standards for the governance of hydrogen-related projects will be crucial. These should also address potential conflicts between the deployment of renewable energy for the decarbonization of local power grids, and the export of green hydrogen.     

Review of green electricity production in Slovenia

The article presents a short review of electricity production from renewable energy sources in Slovenia. In Introduction the term of “green electricity” is defined. Comparison of structures of electricity production is presented for the years 1990 and 2003. The main part of the article presents an approximate data for technical and theoretical potentials of renewable energy sources in Slovenia. State-of-the-art regarding individual technologies of electricity production from renewable energy sources and political targets according to Directive 2001/77/EC for green electricity are also presented. At the end of the article different stimulation models are described and uniform prices and premiums for the purchase of green electrical energy are presented.     

Potential of renewable hydrogen production for energy supply in Hong Kong

Hong Kong is highly vulnerable to energy and economic security due to the heavy dependence on imported fossil fuels. The combustion of fossil fuels also causes serious environmental pollution. Therefore, it is important to explore the opportunities for clean renewable energy for long-term energy supply. Hong Kong has the potential to develop clean renewable hydrogen energy to improve the environmental performance. This paper reviews the recent development of hydrogen production technologies, followed by an overview of the renewable energy sources and a discussion about potential applications for renewable hydrogen production in Hong Kong. The results show that although renewable energy resources cannot entirely satisfy the energy demand in Hong Kong, solar energy, wind power, and biomass are available renewable sources for significant hydrogen production. A system consisting of wind turbines and photovoltaic (PV) panels coupled with electrolyzers is a promising design to produce hydrogen. Biomass, especially organic waste, offers an economical, environmental-friendly way for renewable hydrogen production. The achievable hydrogen energy output would be as much as 40% of the total energy consumption in transportation.     

Exploring supply chain design and expansion planning of China's green ammonia production with an optimization-based simulation approach

Green ammonia production as an important application for propelling the upcoming hydrogen economy has not been paid much attention by China, the world's largest ammonia producer. As a result, related studies are limited. This paper explores potential supply chain design and planning strategies of green ammonia production in the next decade of China with a case study in Inner Mongolia. A hybrid optimization-based simulation approach is applied, considering traditional optimization approaches are insufficient to address uncertainties and dynamics in a long-term energy transition. Results show that the production cost of green ammonia will be at least twice that of the current level due to higher costs of hydrogen supply. Production accounts for the largest share of the total expense of green hydrogen (~80 %). The decline of electricity and electrolyser prices are key in driving down the overall costs. In addition, by-product oxygen is also considered in the model to assess its economic benefits. We found that by-product oxygen sales could partly reduce the total expense of green hydrogen (~12 % at a price of USD 85/t), but it also should be noted that the volatile price of oxygen may pose uncertainties and risks to the effectiveness of the offset. Since the case study may represent the favourable conditions in China due to the abundant renewable energy resources and large-scale ammonia industry in this region, we propose to take a moderate step towards green ammonia production, and policies should be focused on reducing the electricity price and capital investments in green hydrogen production. We assume the findings and implications are informative to planning future green ammonia production in China.     

Cost of green hydrogen: Limitations of production from a stand-alone photovoltaic system

The aim of this work is to analyse the price of renewable hydrogen production in a stand-alone photovoltaic plant. The energy studied herein is generated in a photovoltaic plant. Two dependent parameters that directly affect the price of hydrogen are analysed in detail: the price of the electricity needed to carry out its production process, and the utilisation rate of the connected electrolyser. To this end, a photovoltaic plant is dimensioned with the help of the PVsyst simulator, by means of which the hourly generation curves are obtained. A variable power electrolyser is employed to study its performance according to these photovoltaic production curves. Furthermore, the system is studied by introducing batteries capable of storing the energy left over during the day and of supplying the electrolyser when the photovoltaic power is insufficient. The selling prices calculated in the various scenarios in terms of efficiency and electricity cost are calculated. The significance of a combined analysis of these two parameters and their real impact on the final price of hydrogen is also analysed. This article aims to analyse the price of green hydrogen produced through an isolated photovoltaic system. When the hourly production is evaluated, differences are found with respect to global production that justify the importance of the variables analysed herein, which could not be determined in any other way. The behaviour of isolated production and its effects are discussed.     

How the hydrogen production from RES could change energy and fuel markets: A review of recent literature

The goal that the international community has set itself is to reduce greenhouse gas (GHG) emissions in the short/medium-term, especially in Europe that committed itself to reducing GHG emissions to 80–95% below 1990 levels by 2050. Renewable energies play a fundamental role in achieving this objective. In this context, the policies of the main industrialized countries of the world are being oriented towards increasing the shares of electricity produced from renewable energy sources (RES).In recent years, the production of renewable energy has increased considerably, but given the availability of these sources, there is a mismatch between production and demand. This raises some issues as balancing the electricity grid and, in particular, the use of surplus energy, as well as the need to strengthen the electricity network.Among the various new solutions that are being evaluated, there are: the accumulation in batteries, the use of compressed air energy storage (CAES) and the production of hydrogen that appears to be the most suitable to associate with the water storage (pumped hydro). Concerning hydrogen, a recent study highlights that the efficiencies of hydrogen storage technologies are lower compared to advanced lead acid batteries on a DC-to-DC basis, but “in contrast […] the cost of hydrogen storage is competitive with batteries and could be competitive with CAES and pumped hydro in locations that are not favourable for these technologies” (Moliner et al., 2016) [1].This shows that, once the optimal efficiency rate is reached, the technologies concerning the production of hydrogen from renewable sources will be a viable and competitive solution. But, what will be the impact on the energy and fuel markets? The production of hydrogen through electrolysis will certainly have an important economic impact, especially in the transport sector, leading to the creation of a new market and a new supply chain that will change the physiognomy of the entire energy market.     

Green hydrogen production potential for Turkey with solar energy

The current study develops a hydrogen map concept where renewable energy sources are considered for green hydrogen production and specifically investigates the solar energy-based hydrogen production potential in Turkey. For all cities in the country, the available onshore and offshore potentials for solar energy are considered for green hydrogen production. The vacant areas are calculated after deducting the occupied areas based on the available governmental data. Abundant solar energy as a key renewable energy source is exploited by photovoltaic cells. To obtain the hydrogen generation potential, monocrystalline and polycrystalline type solar cells are considered, and the generated renewable electricity is directed to electrolysers. For this purpose, alkaline, proton exchange membrane (PEM), and solid oxide electrolysers (SOEs) are considered to obtain the green hydrogen. The total hydrogen production potential for Turkey is estimated to be between 415.48 and 427.22 Million tons (Mt) depending on the type of electrolyser. The results show that Erzurum, Konya, Sivas, and Van are found to be the highest hydrogen production potentials. The main idea is to prepare hydrogen map in detail for each city in Turkey, based on the solar energy potential. This, in turn, can be considered in the context of the current policies of the local communities and policy-makers to supply the required energy of each country.     

Economics of hydrogen energy of green transition in the world and Russia.Part I

Recently, the theme of the “green transition”, in which the economic and commercial prospects of the hydrogen industry play a leading role, in the global energy industry has attracted special attention from business, government and scientific circles in many countries, which is associated with its predicted impact, incl. due to the climate agenda, to the economic, technological and geopolitical redistribution of the energy map of the world at the global and regional levels. Some slowdown in the “green transition” is expected due to the need to overcome the global energy crisis in the next two or three years, which may turn out to be more serious than the crisis of the 1970s of the last century which will require eliminating the shortage of traditional non-renewable energy resources in the near future. Nevertheless, the “green transition”, in which hydrogen accents are intensifying, continues to be implemented, which will have a serious impact on the system of international and international economic relations in the world. Thanks to the financial support of the state and business, modern technologies of the entire hydrogen energy chain are actively developing, hydrogen markets are being formed in the conditions of inter-fuel competition, as well as hydrogen energy command centers at the global, regional, country and corporate levels.     

Transition to renewable energy systems with hydrogen as an energy carrier

Unlike the present energy system based on fossil fuels, an energy system based on renewable energy sources with hydrogen and electricity as energy carriers would be sustainable. However, the renewable energy sources in general have less emergy than the fossil fuels, and their carriers have lower net emergy. Because of that they would not be able to support continuous economic growth, and would eventually result in some kind of a steady-state economy. An early transition to renewable energy sources may prove to be beneficial in the long term, i.e., it may result in a steady state at a higher level than in the case of a transition that starts later. Once the economy starts declining it will not be able to afford transition to a more expensive energy system, and transition would only accelerate the decline. Similarly, if a transition is too fast it may weaken and drain economy too much and may result in a lower steady state. If a transition is too slow, global economy may be weakened by the problems related to utilization of fossil fuels (such as global warming and its consequences) before transition is completed and the result again would be a lower steady state. Therefore, there must be an optimal transition rate; however, its determination would require very complex models and constant monitoring and adjustment of parameters.     

Development of an optimization model for the feasibility analysis of hydrogen application as energy storage system in microgrids

Hydrogen can be used as an Energy Storage System (ESS) in a microgrid allowing to store surplus generation of variable renewable sources for later use. Research in the area mainly refers to the sizing of the components, however few studies evaluate the optimal technology selection and operation of microgrids using hydrogen as ESS. In this work, a model to determines optimal selection and to dispatch of Distributed Energy Resources (DER) allowing to evaluate the viability of hydrogen application as ESS in a microgrid is developed. The model is implemented in GAMS, using mixed integer linear programming, and applied in a hypothetical microgrid using as input data load profiles and commercial data available in literature. The results indicate the economical and environmental benefits of DER adoption, but the currently high investment costs make it infeasible to adopt hydrogen into a microgrid. However, when considering environmental costs and market prospects, the adoption of this technology became a good alternative, improving the energy management and reducing the total annual cost of the microgrid by 14.1%.