VN12合金在钒氮微合金化钢中的应用研究

本文主要介绍了在济钢２０ＭｎＳｉＶ、１６ＭｎＶ钢中,加入钒铁合金ＶＦｅ（５１．６％Ｖ）及美国钒公司提供的专利产品富氮钒合金ＶＮ１２（８０％Ｖ,１２％Ｎ）的对比试验,研究了钒、氮复合微合金化对钢的力学性能的影响,分析了采用钒铁及富氮钒合金微合金化时,钢中钒含量的差别及其经济性。     

高氮钒微合金化钢筋的应用研究

主要介绍在２０ＭｎＳｉＶ钢中,加入钒铁ＶＦｅ（５１．６％Ｖ）及美国钒公司的专利产品富氮钒合金ＶＮ１２（８０％Ｖ,１２％Ｎ）的对比试验,研究了钒、氮复合微合金化对钢筋的性能的影响,分析了采用钒铁及富氮钒合金微合金化时,钢筋中钒含量的节约及其技术经济性。     

钒氮微合金化钢筋的研究

研究了在２０ＭｎＳｉ钢中添加高氮钒合金Ｎｉｔｒｏｖａｎ１２对钢的力学性能的影响。结果表明,在钒含量相同的情况下,与８０ＦｅＶ相比,添加Ｎｉｔｒｏｖａｎ１２的钢,抗张强度可提高１３５ＭＰａ,屈服强度可提高１１７．５ＭＰａ;在保持强度相同或相近的情况下,添加Ｎｉｔｒｏｖａｎ１２的钢可节约３３．３％以上的钒。钢中添加Ｎｉｔｒｏｖａｎ１２合金,充分利用了廉价的氮元素,促进了Ｖ（Ｃ,Ｎ）的析出,南昌市了Ｖ的     

经济型建筑用Ⅲ级钢筋的研究

研究了在２０ＭｎＳｉ钢中添加高氮钒合金Ｎｉｔｒｏｖａｎ１２对钢的力学性能的影响。结果表明，在钒含量相同的情况下，添加Ｎｉｔｒｏｖａｎ１２的钢，抗拉强度可提高１３５ＭＰａ，屈服强度可提高１１７．５ＭＰａ；在保持强度相同或相近的情况下，添加Ｎｉｔｒｏｖａｎ１２的钢可节约３３．３％以上的钒。钢中添加Ｎｉｔｒｏｖａｎ１２合金，充分利用了廉价的氮元素，促进了Ｖ（Ｃ，Ｎ）的析出，提高了钒的沉淀强化效果。研制出     

VN合金在非调质钢中的应用

简要介绍了ＶＮ合金在Ｆ３５ＭｎＶＮ钢中应用,对钒、氮的作用和钢水增氮方法进行了研究。结果表明,为发挥钒的作用,应增加含钒非调质钢中氮的含量;加氮的最好办法是采用ＶＮ合金。     

(C+N)复合强化的Fe-Cr-Mn(W,V)钢高温性能的研究

研究了用于核反应推低放射性结构材料Ｆｅ－Ｃｒ－Ｍｎ（Ｗ,Ｖ）奥氏体钢。通过（Ｃ＋Ｎ）复合强化有效地提高Ｆｅ－１２％Ｃｒ０１５％Ｍｎ（Ｗ,Ｖ）钢高温强度和蠕变断裂寿命,并改善高温塑性。在温度６７３Ｋ以下,合金比ＳＵＳ３１６钢和ＪＰＣＡＳ钢强度和塑性优良。合金强度和塑性与形变的相互关系是和合金形变组织变化;密切相关。对６７３Ｋ以上塑性降低的原因进行断口和显微组织分析,控制晶界碳化物粗化是进一步提高高温     

氮含量对Cr18Mn18N无磁不锈钢力学性能、磁导率和组织的影响

探讨了Ｃｒ１８Ｍｎ１８Ｎ无磁不锈钢中氮含量对钢的力学性能、磁导性能以及组织状态的影响，研究结果表明，Ｃｒ１８Ｍｎ１８Ｎ钢中氮含量大于０．３１％时，组织才为全奥氏体状态，该钢氮含量的最佳区间为０．４％￣０．６％。     

氮在非调质钢中的作用

了氮在非调质钢中所起的有益作用。在Ｎｂ,Ｖ,Ｔｉ三咱微合金化元素中,钒有较高的溶解度,钒有较高的溶解度,是非调质钢最常用也是最有效的强化元素。钒在钢中通过形成细小析出相起细化晶粒和沉淀强化作用。与碳相比,氮与钒有更强的亲和力,且氮化物更稳定,因此,氮对控制钒的析出起更重要的作用。大量研究结果表明,非调质钢中增氮改变了钒在相间的分布,促进Ｖ（Ｃ,Ｎ）析出,使析出相的颗粒尺寸明显减小。因而氮增强了非调     

V-N微合金化钢筋中钒的析出行为

研究了氮对含钒微合金化钢筋中钒的析出行为的影响。实验结果表明：低氮钒钢中,大部分钒固溶于铁素体基体,比例高达565,只有35．5％钒形成V（C,N）;高氮钒钢中,70％的钒析出形成V（C,N）,只有20％的钒因溶于基体,钢氮还减小了V（C,N）颗粒尺寸,明显增加细小V（C,N）析出相的体积分数。     

铁铝合金的磁性

本文根据Ｆｅ－Ａｌ合金中Ａｌ含量的变化导致其结构的变化，分别介绍了６％Ａｌ－Ｆｅ，（８－１０）％Ａｌ－Ｆｅ，１２％Ａｌ－Ｆｅ，１４％Ａｌ－Ｆｅ，１６％Ａｌ－Ｆｅ，（１２－１６）％Ａｌ－Ｆｅ－Ｍ（Ｍ＝Ｍｏ，Ｍｎ，Ｃｒ，Ｚｒ，Ｔａ，Ｃｅ）Ｆｅ－Ｓｉ－Ａｌ等合金的磁性能。     

VN合金在大规格角钢生产中的应用研究

大规格角钢主要用于铁塔制造和建筑结构中。唐钢过去用16Mn钢生产Q345级别角钢，因供轧化学成分范围较窄，供轧率偏低。通过加入V-Fe合金及VN合金进行微合金化，设计了16Mnv(N)钢种生产角钢，使角钢综合性能有显著提高。分析比较了16Mn、16MnV及16MnV(N)角钢的性能，认为在大规格高强度角钢生产中，用VN合金进行微合金化，其效果是最佳的。     

氮化钒合金在400MPa级钢筋中的应用

介绍了攀钢采用氮化钒合金化与钒铁合金化生产400MPa级含钒钢筋(20MnSiVⅢ级钢筋)的对比试验结果,研究了钒、氮微合金化对钢筋的性能和组织的影响,探讨了氮化钒的强化机理,比较了使用两种合金的生产成本。     

VN合金化对20MnSiV钢筋钢组织的影响

对比研究了VN合金化和Fe-V合金化的20MnSiV钢筋钢的显微组织和钒析出物。结果表明：用VN合金化的20MnSiV钢筋钢的铁素体量较多,珠光体量较少;钒析出物的量明显较多。顶计用vN合金生产的20MnSiV钢筋钢将具有较高的屈服强度和较低的冲击转变温度。     

钒氮微合金化高强度钢的研究及应用

根据国内外对钒氮合金微合金化技术的研究现状，综述了钒氮微合金化在高强度钢中的强化机制，并概述了钒氮微合金在高强度钢中的研究开发、应用状况。     

增氮对钒微合金钢组织和性能的影响

 通过对不同钒、氮质量分数的试验钢进行热模拟压缩试验和实验室轧制试验,用OM、SEM和TEM分析试验钢的显微组织,研究增氮对钒微合金钢组织和性能的影响。结果表明,普通钒微合金钢为板条贝氏体＋粒状贝氏体组织,增加氮质量分数,可促进晶内铁素体相变,得到针状铁素体组织,使M/A组织细化且弥散分布,改善韧性;而增加钒质量分数,可以增加析出强化作用,提高强度,但组织形态无明显变化,不能提高韧性。增氮钢中的钒在奥氏体内以VN析出,低氮钢内的钒在铁素体内以VC的形式析出,奥氏体-铁素体、VC-铁素体和VN-铁素体的平面点阵错配度分别为6.72%、3.89% 和 1.55%,在奥氏体内析出的VN可以作为铁素体的优先形核位置,促进晶内铁素体相变。     

Influence of nitrogen on hot ductility of steels and its relationship to problem of transverse cracking

Abstract

The present review examines the influence of nitrogen on the hot ductility of steels, with particular relevance to the problem of transverse cracking during continuous casting. Nitrogen itself is not detrimental to hot ductility, but when it is present with aluminium or microalloying additions, ductility can be adversely affected through the formation of nitrides or carbonitrides. The addition of aluminium to low nitrogen C–Mn steels (0·005%N)impairs ductility during casting at an acid soluble level as low as 0·02%Al. This arises because segregation of aluminium to the grain boundaries occurs on solidification, and the temperature cycling that takes place when the strand is cooled encourages AlN precipitation. However, for low nitrogen, high strength low alloy (HSLA) steels with carbon levels in the peritectic range 0·08–0·17%C, transverse cracking is not generally encountered until the aluminium level is >0·04%. Higher nitrogen levels are likely to cause problems even at very low aluminium levels, as precipitation of AlN is controlled by the product of the aluminium and nitrogen contents. The microalloying additions vanadium and niobium are detrimental to ductility but, of the two elements, niobium is more damaging, as it gives finer precipitation. Increasing the nitrogen level has a more pronounced influence on ductility in vanadium containing steels, since vanadium forms a nitride while niobium forms Nb (CN), which is mainly carbon based. Nevertheless, the product of vanadium and nitrogen contents has to approach 1·2 × 10^-3, for example 0·1%V and 0·012%N, before ductility deteriorates to that normally given by a niobium containing steel with 0·03%Nb and 0·005%N. When small titanium additions are made to low nitrogen C–Mn–Al steels (0·005%N), the best ductility is likely to be given by a high Ti/N ratio of 4–5 : 1; the excess titanium in solution encourages growth of the TiN particles. For high nitrogen steels (0·01%N), a low titanium level (0·01%)is recommended to limit the volume fraction of TiN particles. A low soluble aluminium level is also needed to prevent the excess nitrogen from combining to form AlN. For C–Mn–Nb–Al steels, similar recommendations can be made with regard to adding titanium. However, the presence of niobium and aluminium appears to have little influence on ductility, since these elements coarsen the titanium containing precipitates.     

Low carbon manganese steels microalloyed with vanadium and nitrogen

With the objective of studying the effect of vanadium and nitrogen microalloying on microstructure and strength of low carbon steels with different manganese contents, three series of low carbon steels (0.1% C) with manganese content (between 0.8 and 3.5%), vanadium content (up to 0.17%) and nitrogen content (up to 0.025%) have been designed and investigated in the hot forging condition using a preheating and finish forging temperatures of 1200 and 950°C, respectively. Steels with a manganese content up to 2.3% revealed ferrite-pearlite structures, whereas higher manganese contents from 2.7 to 3.5% resulted in the formation of bainitic structures. A pronounced effect of manganese on the mechanical properties of steels was detected at lower manganese contents < 1.5%, due to solid solution and grain refining effects, and higher manganese contents > 2.3, due to bainite formation. Manganese content in the range of 1.5-2.3% had less pronounced effect due to solely solid solution hardening. Vanadium microalloying effectively increased the strength of steels through solely precipitation strengthening or both precipitation strengthening and grain refining effect. The effectiveness of vanadium was greatly enhanced by increasing the nitrogen content. The grain refinement of vanadium-nitrogen microalloying seems to be due to inhibition of austenite grain growth as a result of precipitation of vanadium nitride in austenite during forging. Precipitation strengthening of these steels is achieved by precipitation of vanadium carbide and nitride in ferrite or bainite. Nitrogen enhanced the precipitation strengthening of vanadium microalloyed steels which could be attributed to the finer vanadium nitride dispersion precipitates compared with vanadium carbide. Up to 70% of the total nitrogen content of steel precipitates as vanadium nitride which could be achieved with V/N ratio of about 6-7. Microalloying of low carbon-manganese steels (0.1% C and 1.8% Mn) with 0.15% vanadium and 0.025% nitrogen was found to be effective in attaining high levels of yield and ultimate tensile strengths of 835 and 940 N/mm², respectively in the forging condition.     

钒氮微合金化技术在HSLA钢中的应用

含钒钢中增氮，促进了碳氧化钒的析出，增强了钒的沉淀强化作用，大幅度提高钢的强度。因此，氮是含钒钢一种经济有效的合金化元素。通过充分利用廉价的氮元素，钒氮微合金化钢在保证相同的强度水平下，可节约钒的用量，降低钢的成本。V－N微合金化技术在高强度钢筋、结构钢板带及型钢、无缝钢管、非调质钢、高碳钢钱棒材以及高速工具钢等产品中获得了广泛应用。