Interaction between water spray and smoke in a fire event in a confined and mechanically ventilated enclosure

This work deals with the interaction between water droplet flows and smoke in a fire event in a confined and ventilated enclosure. The objective is to identify the specific effect of water spray in the specific environment of a confined and ventilated enclosure. The study is based on 17 large-scale fire tests performed in one room of 165 m³ ventilated at a renewal rate of 15.4 h⁻¹. The fire source is a propane gas burner with a heat release rate of between 140 and 290 kW. The water spray system consists of two Deluge nozzles with a nozzle coefficient of 26 l/min/bar^0.5. The test parameters are the fire heat release rate, the water flow rate, from 50 to 124 l/min, and the activation time. The study focuses on three topics, the interaction of the droplets with the smoke, the droplet evaporation process and the energy transferred to the droplets. The water spray significantly modifies the smoke stratification by mixing and cooling the gas phase. The rate of droplet evaporation has been determined from the water mass balance and is of the same order of magnitude as the rate of water vapor production by the combustion reaction. Heat transfer from the smoke to the droplets has been investigated using the energy balance equation. For a fire scenario in a confined and ventilated enclosure, the energy released by the fire is mainly transferred to the walls and extracted by the ventilation network. In the event of water spray activation, a significant share, up to 65%, is transferred to the droplet flows.     

Inhibition of counterflow methane/air diffusion flame by water mist with varying mist diameter

In the present study, the effect of fine water mist on extinguishment of a methane–air counterflow diffusion flame was investigated to understand the underlying physics of fire extinguishment of highly stretched diffusion flame by water mist. Twin-fluid atomizers were used to generate polydisperse water mist of which Sauter mean diameters were 10, 20, 40, and 60 μm. When water mist is not added, the critical stretch rate at extinguishment is 439 s⁻¹ as compared to the theoretical value of 460 s⁻¹. For the case with water mist addition, when the stretch rate is small enough, almost all the water mist evaporates within the flame zone. On the other hand, for high stretch rate case, large mist droplets pass through the flame zone and can reach the stagnation plane. However, no oscillatory motion was found around the stagnation plane. Critical stretch rate at extinguishment decreases monotonously with the mass fraction of water mist independently of the mist diameter within the range of D₃₂ from 10 μm to 60 μm. On the other hand, with increase in the surface area parameter, the critical stretch rate at extinguishment decreases rapidly and becomes less sensitive at large surface area parameter, of which tendency is qualitatively in good agreement with theoretical predictions. For a constant surface area parameter, the critical stretch rate decreases with mist diameter because the mass fraction of water mist should increase in proportion to the mist diameter to keep the surface area parameter constant. When the water mist evaporates completely in the flame zone as in the present study, the mass fraction of the water mist is the dominant factor for fire extinguishment, rather than the surface area parameter. Therefore, an appropriate combination of stretch rate and water mist mass fraction should be provided to suppress effectively a given fire with a small amount of water mist.     

Extinguishing characteristics of a diffusion flame with water vapor produced from a water droplet impacting onto a heated plate

In this study, we have investigated an extinguishing method of a diffusion flame with water vapor produced from a water droplet impacting onto a headed plate, which is called as indirect fire attack. In order to clarify the extinguishing characteristics, the extinguishing experiments of a methane-air diffusion flame have been performed by using a pure water droplet with the diameter of 3.2 mm. The droplet dropped from the height of 400 mm. The wall superheat and the burner height were varied from 0 K to 330 K and from 32 mm to 102 mm, respectively. As a result, under certain wall-heat conditions, the water-vapor vortex ring is formed and visualized by the white water fog. At wall superheat of 150 K, the formation probability of the vortex ring is unity and the extinguishing probability always shows the peak values regardless of the burner height. As a result, it can be said in our study that the wall superheat of 150 K is the most effective value for the indirect extinguishing method.     

Fire extinguishing properties of novel ferrocene/surfynol 465 dispersions

This paper reports a novel fire-extinguishing agent: an aqueous dispersion of fine ferrocene particles. In this study, the ferrocene–water–surfactant dispersions were prepared to optimize the gas-phase concentration of ferrocene, and their ability to extinguish heptane fires was examined. The fire-extinguishing efficiency was characterized by three parameters: the ferrocene concentration in the dispersion (0–175 ppm), the surfactant used, and the ferrocene particle size (d₅₀=10.4, 11.4, 21.5, and 68.8 μm). The results indicated that (1) the ferrocene (d₅₀=10.4 mm)–water–surfynol 465 dispersion is the most stable among the dispersions tested, (2) the ferrocene–water–surfynol 465 dispersions have an optimal value of ferrocene concentration regarding the extinguishing time, and (3) in the ferrocene particle size range of 10.4–21.5 μm, the minimum extinguishing time of the ferrocene–water–surfynol 465 dispersions is remarkably shorter (1.2 s) than those observed when using a conventional wet chemical agent (45 wt% aqueous solution of potassium carbonate, 12.9 s).     

Automatic fire detection in road traffic tunnels

Fire detection experiments in a road traffic tunnel were performed in the Runehamar test tunnel 5th–8th March 2007. The Runehamar test tunnel is a full profile road traffic tunnel, 1.65 km long, located outside Åndalsnes, Norway. The goal was to examinate smoke and heat detection systems to determinate what kind of principle best suited for detecting a fire in an early stage. The systems were tested during small Heptane pool fires, varying between 0.16 m² and 1 m², giving heat release rates from 0.2 MW to 2.4 MW accordingly, and one car fire of about 3–5 MW, and with wind conditions varying from 1.1 m s^?1 to 1.6 m s^?1. The size of the fires, were designed to be in the range from impossible to difficult to detect. The results were conclusive. Earliest detection of a car fire, fire starts inside, was by smoke detection given fixed limits (3000 μg m^?3). With open pool fires, or immediate flames, continues fibre optical heat detection systems was faster given the limits 3 °C/4 min.     

Effect of micro-silica loading on the mechanical and acoustic properties of cement pastes

This study aimed at investigating the role of ultra fine sand (UFS) in enhancing the mechanical and acoustic properties of cementitious pastes. The microstructural origin of these properties was also identified and compared to the conventional materials. The maximum particle size of the UFS used was 100 μm (100% passing) while 50% of the UFS had less than 20 μm in diameter. Ordinary Portland cement (OPC) was partially substituted by UFS at 1%, 2%, 3%, 4%, 5%, 7.5% and 10% by weight of binder. The blended compounds were prepared using the standard water of consistency. Test samples with dimension of 20 × 20 × 20 mm and 40 × 40 × 160 mm were cast for compression and bending strengths tests, respectively. Circular samples with diameters of about 100 and 29 mm and average thickness of about 30 mm were used for sound absorption tests. All samples were kept in molds for 24 h, and then de-molded and allowed to cure in water for 28 days. The specimens were dried at a temperature of 105 °C for 24 h in an oven before testing. It was found that as the loading of UFS increases both the compressive and bending strength increase up to about 5% UFS loading, then a decrease in these properties was observed. This can be attributed to the pozzolanic effect of UFS resulting in enhancing the chemical reaction between free lime in cement and silica producing more hydration products that makes the paste more homogeneous and dense. In addition, the dispersed UFS has improved the filling effect allowing denser packing of the paste. These dense microstructural features were captured by scanning electron microscope (SEM) examination of the 5% UFS modified compound. The results also showed that, the sound absorption and noise reduction coefficient (NRC) for modified cement paste decreases with the increase of UFS up to 5% and this may be due to the decrease in porosity. However, the NRC began to increase at UFS loadings of 7.5% and 10% due to the increase in the porosity of the compounds.     

Evaluation of capillary water absorption in rendering mortars made with powdered waterproofing additives

Several additives, such as powdered stearates, oleates, silanes and silicone films, are used to avoid water absorption in renders. This paper looks at the effectiveness of six powdered waterproofing additives after 28 days of curing at: 0.00%, 0.25%, 0.50%, 1.00% and 2.00% w/w on the whole composition. The waterproofing efficiency is analyzed by capillary water absorption tests, while water immersion tests are also carried out after 20 and 90 min. Powdered silicone and sodium oleate showed the best resistance to water penetration, while metallic soaps in the form of calcium stearate and zinc stearate showed the lowest efficiency in this respect at low dosages. The results are useful for understanding the long-term durability of renders and the minimal waterproofing dosages according to the EN 998 requirements.     

Development of alpha plaster from phosphogypsum for cementitious binders

Efforts have been made to make high strength alpha plaster from phosphogypsum, a by-product of phosphoric acid industry. Phosphogypsum was autoclaved in slurry form (phosphogypsum 50% + water 50%, by wt.) in the laboratory at different steam pressures for different durations in presence of chemical admixtures. It was found that with small quantity of chemical admixture (sodium succinate/potassium citrate/sodium sulphate), alpha plaster of high strength can be produced. The optimum pressure and duration of autoclaving was found to be as 35 psi and 2.0 h, respectively. The alpha plaster was examined for making cementitious binders by admixing hydrated lime, fly ash, granulated blast furnace slag, marble dust and chemical additives with alpha plaster. Data showed that cementitious binder of compressive strength of 22.0 and 30 MPa (at 28 days of curing at 40° and 50 °C) and low water absorption was produced. DTA and SEM studies of the binder showed formation of CSH, ettringite and C₄AH₁₃ as main cementitious products to give strength.     

Suppression of sodium fires with liquid nitrogen

Sodium has unusual fire hazards, including autoignition when heated in air or exposed to liquid water. Owing to limitations of existing suppression agents for sodium pool fires, suppression using liquid nitrogen (LN₂) is examined here. Sodium pools of 5–80 g were heated in stainless steel beakers. At about 290 °C, pool surface autoignition occurred and caused a rapid pool temperature increase. Vapor phase combustion occurred when the pools reached 320–450 °C, ultimately leading to pool temperatures up to 700 °C. For suppression tests, LN₂ delivery (at 2.7 g/s) began when the fires became fully-developed, near a pool temperature of 600 °C. Liquid nitrogen was found to be an effective suppression agent. The minimum amount of LN₂ required to suppress a fully-developed sodium pool fire was found to be about three times the initial sodium pool mass.     

The effect of fuel area size on behavior of fires in a reduced-scale single-track railway tunnel

A set of experiments was carried out in a 1/9 reduced-scale single-track railway tunnel to investigate the effect of fuel area size on the temperature distribution and behavior of fires in a tunnel with natural ventilation. Methanol pool fires with four different fuel areas 0.6 × 0.3 m² (1 pan), 1.2 × 0.3 m² (2 pans), 2.4 × 0.3 m² (4 pans) and 3.6 × 0.3 m² (6 pans), were used in these experiments. Data were collected on temperatures, radiative heat flux and mass loss rates. The temperature distribution and smoke layer in the tunnel, along with overflow dimensions and radiant heat at the tunnel entrance were analyzed. The results show that as the fuel area enlarges, the fire gradually becomes ventilation-controlled and the ceiling temperature over the center of fire source declines. Burning at the central region of fire source is depressed due to lack of oxygen. This makes the temperature distribution along the tunnel ceiling change from a typical inverted V-shape to an M-shape. As observed in the experiments, a jet flame appeared at tunnel entrances and both the size and temperature of the flame increased with the enlargement of fuel area leading to a great threat to firefighters and evacuees in actual tunnel fires.     

Applications of sewage sludge ash and nano-SiO2 to manufacture tile as construction material

In this study, various portions of potter’s clay and porcelain clay were replaced with incinerated sewage sludge ash (ISSA) to manufacture sludge ash tile specimens. We used these tiles to investigate the effect of introducing nano-SiO₂ particles as strengthening additives in the clay–ISSA materials. Percentages of ISSA in the porcelain or potter’s clay-based materials ranged from 0% to 50%, and fractions of nano-SiO₂ additives range from 0% to 3%. Tile specimens were manufactured from the different clay–ISSA–additive mixtures and sintered at kiln temperatures of 1000 °C and 1100 °C. Mechanical tests were performed to measure shrinkage, water absorption, abrasion, and bending strength. The sample microstructure was investigated using scanning electron microscopy (SEM). Chemical compositions of the tile specimens were characterized with X-ray diffraction. Results indicate that water absorption of porcelain and potter’s clay-based tiles was reduced when samples were fired at the higher kiln temperature, dropping to less than 12% in porcelain tiles at a kiln temperature of 1100 °C. Kiln temperature appeared to have less influence on the tiles made from potter’s clay. With the addition of nano-SiO₂ additive, the bending strengths of both types of tiles were increased, with the strengthening effect more pronounced in potter’s clay tiles when compared to porcelain clay tiles.     

Experimental study of the effect of water spray on the spread of smoldering in Indonesian peat fires

Peatland fires remain a major contributor of environmental problems in Indonesia. Several studies on peat fire suppression have been conducted with multiple methods, such as quarrying, water spray, artificial rain, and foam spray. This research is focused on laboratory scaled experiments of Indonesian peat smoldering fire behaviour and suppression by a water mist system. The peat used in this work was obtained from two different locations, namely Papua and South Sumatra, Indonesia. During the suppression tests, the intensity of the water mist spray was varied by changing the distance between the nozzle and the peat surface. Meanwhile, the time periods of spray were 15 min (short period of suppression) and approximately 2 h for full suppression until the peat fire was extinguished. The peat temperature and the total mass lost during the smoldering reaction were recorded to get the burning rate ratio for each sample. The spread rate of the smoldering process was identified by the changes in the local temperatures of the peat bed. The results show that the spread rate of the smoldering combustion front was affected by particle size and permeability of peat material. The short duration of water suppression failed to extinguish the peat fires. A re-ignition phenomenon was identified due to the persistence of stored heat in the core of the peat. In addition, the total water required to fully suppress both peat fires is about 6 L/kg peat.     

Modeling of fire suppression by fuel cooling

Fire suppression with water spray was investigated, focusing on cases where fuel cooling is the dominant suppression mechanism, with the aim to add a specific suppression model addressing this mechanism in Fire Dynamics Simulator (FDS), which already involves a suppression model addressing effects related to flame cooling. A series of experiments was selected, involving round pools of either 25 or 35 cm diameter and using both diesel and fuel oil, in a well-ventilated room. The fire suppression system is designed with four nozzles delivering a total flow rate of 25 l/min and injecting droplets with mean Sauter diameter 112 μm. Among the 74 tests conducted in various conditions, 12 cases with early spray activation were especially considered, as suppression was observed to require a longer time to cool the fuel surface below the ignition temperature. This was quantified with fuel surface temperature measurements and flame video recordings in particular. A model was introduced simulating the reduction of the pyrolysis rate during the water spray application, in relation to the decrease of the fuel local temperature. The numerical implementation uses the free-burn step of the fire to identify the relationship between pyrolysis rate and fuel surface temperature, assuming that the same relationship is kept during the fire suppression step. As expected, numerical simulations reproduced a sharp HRR decrease following the spray activation in all tests and the suppression was predicted in all cases where it was observed experimentally. One specific case involving a water flow rate reduced such that it is too weak to allow complete suppression was successfully simulated. Indeed, the simulation showed a reduced HRR but a fire not yet suppressed. However, most of the tests showed an under-estimated duration before fire suppression (discrepancy up to 26 s for a spray activation lasting 73 s), which demonstrates the need for model improvement. In particular the simulation of the surface temperature should require a dedicated attention. Finally, when spray activation occurred in hotter environments, probably requiring a combination of fuel cooling and flame cooling effects, fire suppression was predicted but with an over-estimated duration. These results show the need for further modeling efforts to combine in a satisfactory manner the flame cooling model of FDS and the present suggested model for fuel cooling.     

Spread and burning behavior of continuous spill fires

Spill fire experiments with continuous discharge on a fireproof glass sheet were conducted to improve the understanding of spill fire spread and burning. Ethanol was used as the fuel and the discharge rate was varied from 2.8 mL/s to 7.6 mL/s. Three ignition conditions were used in the experiments; no ignition, instantaneous ignition and delayed ignition. The spread rate, regression rate, penetrated thermal radiation and the temperature of the bottom glass were analyzed. The experiments clearly show the entire spread process for spill fires. Further, the regression rate of spill fires at the quasi-steady burning was lower than that of pool fires and the ratio of the spill fires’ regression rate to the pool fires’ regression rate was found to be approximately 0.89. With respect to the radiative penetration and the heat conduction between the fuel layer and the glass, a regression rate expression for spill fires was developed based on some modifications on existing expressions for pool fires. In addition, a complete phenomenological model for spill fires was developed by combining the characteristics of spread and burning. The model was verified by the experimental data and found to predict the spread process for spill fires with reasonable accuracy.     

Spectral radiation intensities of a turbulent buoyant ethylene flame: CFD-aided tomographic inversion

Radiation heat transfer has been found to dominate fire spread in large-scale fires. The radiation heat loss of buoyant turbulent fires is coupled with fluid mechanics, combustion processes, and soot/gas concentrations. Deconvolution of these combined phenomena can facilitate the development of combustion and radiation models for use in predictive fire modeling. Therefore, in this work, line-of-sight spectral radiation intensities have been measured from a buoyant turbulent pool-fire-like ethylene diffusion flame. In an attempt to be representative of practical turbulent fires, a burner of 15.2 cm in diameter was used. Temporal measurements of radiation intensity were obtained with a fast (400 Hz) mid-infrared spectrometer at a horizontal plane located at half a burner diameter above the burner. Measurement statistics, including mean, root mean square (RMS), probability density function (PDF) of line of sight intensity, and intermittency are reported herein for wavelengths dominated by soot and CO₂ radiation. The data show that radiation is affected by large-scale vortical motions, resulting in varying flame intermittency in the radial direction. Radial distributions of local scalar properties (temperature and soot volume fraction) were calculated through tomographic inversion, using measured data at multiple soot radiation wavelengths. The inversion technique was coupled with the results of a computational fluid dynamics (CFD) fire simulation code. CFD results were used to construct PDFs and spatial correlations for the scalars of interest. The estimated scalars are shown to be consistent with values from the literature, and mean and RMS radiation intensities computed from these scalars are in good agreement with measurements.     

Simulation of water mist suppression of small scale methanol liquid pool fires

The focus of this paper is on numerical modeling of methanol liquid pool fires and the suppression of these fires using water mist. A mathematical model is first developed to describe the evaporation and burning of liquid methanol. The complete set of unsteady, compressible Navier–Stokes equations are solved along with an Eulerian sectional water mist model. Heat transfer into the liquid pool and the metal container through conduction, convection and radiation are modeled by solving a modified form of the energy equation. Clausius–Clapeyron relationships are invoked to model the evaporation rate of a two-dimensional pool of pure liquid methanol.The interaction of water mist with pulsating fires stabilized above a liquid methanol pool and steady fires stabilized by a strong co-flowing air jet are simulated. Time-dependent heat release/absorption profiles indicate the location where the water droplets evaporate and absorb energy. The relative contribution of the various suppression mechanisms such as oxygen dilution, radiation and thermal cooling is investigated. Parametric studies are performed to determine the effect of mist density, injection velocity and droplet diameter on entrainment and suppression of pool fires. These results are reported in terms of reduction in peak temperature, effect on burning rate and changes in overall heat release rate. Numerical simulations indicate that small droplet diameters exhibit smaller characteristic time for decrease of relative velocity with respect to the gas phase, and therefore entrain more rapidly into the diffusion flame than larger droplet. Hence for the co-flow injection case, smaller diameter droplets produce maximum flame suppression for a fixed amount of water mist.     

Fire tests to evaluate CPVC pipe sprinkler systems without fire resistance barriers

Nine full-scale fire tests were conducted to assess the adequacy of exposed chlorinated poly vinyl chloride (CPVC) pipe and fitting sprinkler systems installed in light hazard occupancies. The tests were conducted in an enclosure using six different types of automatic sprinklers including QREC pendent and sidewall sprinklers, a pendent residential sprinkler, and a sidewall residential sprinkler. Two types of fires, fast growing and slow growing, were used as test fires.The sprinkler in each test was operated with the normal operation pressure until the test fire was almost completely suppressed. Next, to assess the integrity of piping systems after fire exposure, the water pressure was increased to 12.1 bar and maintained for 10 min and then were visually inspected for any leakage while hydrostatic pressure was maintained at 12.1 bar. No leakage was detected in any of the tests.The results of the tests indicate that sprinkler systems based on exposed CPVC pipe and fittings can be safely installed in light hazard occupancies and will provide adequate protection when installed to all the relevant standards.     

Study of high performance autoclaved shell-aggregate from propylene oxide sludge

This study focuses on the comprehensive utilization of propylene oxide sludge (POS). High performance propylene oxide sludge aggregate (POSA), whose main hydrated phase is tobermorite, was prepared by the hydrothermal synthesis of POS and silica materials under the condition of 180 °C saturated steam. The factors affecting the performance of the aggregate were investigated systematically by orthogonal experiments, thus aggregate with cylinder compressive strength between 6.14 and 13.52 MPa, bulk density between 882 and 1163 kg/m³, apparent density between 1515 and 1916 kg/m³, 1 h water absorption rate between 4% and 14%, 24 h water absorption rate between 11% and 19%, the mass loss of freezing and thawing between 1.63% and 3.92% was achieved. By single-factor analysis, it was shown that cylinder compressive strength and specific strength of propylene oxide sludge shell-aggregate (POSS-A) increases by 21.3% and 13.9%, respectively, in contrast to the POSA with no shell. At the same time, 1 h water absorption rate and 24 h water absorption rate decreases by 57% and 20%, respectively. The compressive strength of the concrete with POSS-A as coarse aggregate reaches 80 MPa, which is 8.1% higher than that of the crushed stone concrete. In addition, the density gets lowered by 17%. The HVEP results of analysis of the aggregate imply that heavy metals are solidified inside aggregate and the POSA thus fabricated is non-hazardous for construction use.     

Preparation of eco-friendly construction bricks from hematite tailings

With the objective of reducing the negative impacts on environment and utilizing the secondary resource of tailings, the possibility of making construction bricks by using the hematite tailings from western Hubei province of China was investigated. Besides hematite tailings, the additives of clay and fly ash were added to the raw materials to improve the brick quality. Through the process of mixing, forming, drying and firing, the bricks were produced. The optimum conditions were found to be that the hematite tailings content were as high as 84%, forming water content and forming pressure were respectively in the range of 12.5–15% and 20–25 MPa, and the suitable firing temperature was ranged from 980 to 1030 °C for 2 h. Under these conditions, the mechanical strength and water absorption of the reddish fired specimens were 20.03–22.92 MPa and 16.54–17.93%, respectively, and the other physical properties and durability were well conformed to Chinese Fired Common Bricks Standard (GB/T5101-2003). The phases and morphologies of the green tailings and fired specimen were characterized by XRD and SEM. The results showed that the main mineral phases of the product were hematite, quartz, anorthite and tridymite, which were principally responsible for the mechanical strength of bricks.