FeB粒度对Mo_2FeB_2基金属陶瓷硬质相形貌及力学性能的影响

以Mo、Fe、Cr、Ni和不同粒度的Fe B粉为原料,采用反应硼化烧结法制备了Mo2Fe B2基金属陶瓷。研究了Fe B粉粒度对金属陶瓷硬质相形貌及力学性能的影响。结果表明:当Fe B粉较粗时,在固相反应阶段生成的Mo2Fe B2硬质相颗粒较粗,并在随后的液相烧结过程中沿c轴优先生长,最终呈粗大的长条状;当Fe B粉较细时,固相反应进行较完全,生成的硬质相颗粒细小,其Mo含量相对较高,晶格常数c与a之间差距缩小,各向异性减小,硬质相沿c轴的生长得到抑制,最终呈细小的近等轴状。当硬质相呈近等轴状时,由于硬质相颗粒平均尺寸较小,金属陶瓷具有较高的抗弯强度和硬度;当硬质相呈长条状时,金属陶瓷具有较好的断裂韧性,其增韧机制主要为裂纹偏转和颗粒桥接。     

TiN含量对Ti(C,N)/NiCr金属陶瓷微观结构和力学性能的影响

采用粉末冶金真空烧结方法制备了Ti（C,N）／NiCr金属陶瓷．研究了TiN含量对Ti（C,N）／NiCr金属陶瓷微观结构与力学性能的影响、结果表明,TiN的加入既改变了金属陶瓷硬质相颗粒的尺寸,使其变小,也改变了硬质相颗粒的形貌,使其由圆形变为多边形;随TiN含量的增加,金属陶瓷的抗弯强度均出现先增加后降低的规律,但在较低的烧结温度下,抗弯强度在TiN含量为4％时达到最大值,而在较高的烧结温度下,抗弯强度在TiN含量为6％时达到最大值;硬度在TiN含量〈10％时变化不明显,TiN含量〉10％时硬度急剧下降;抗弯断口以穿晶解理为主要的断裂模式．     

电冶熔铸WC钢结硬质合金断裂韧度研究

对电冶熔铸钢结硬质合金DGJW30采用不同工艺进行了热处理。借助扫描电镜和能谱分析研究了电冶熔铸钢结硬质合金DGJW30的断裂韧度和断口形貌,讨论了WC钢结合金硬质相粒子的断裂机制。结果表明,钢结合金的断口包括硬质相和钢基体两部分。随着回火温度的提高,断裂韧度逐渐增加,但硬质相内部裂纹扩展降低了断裂韧度。     

二次低压烧结对Ti(C,N)基金属陶瓷组织与性能的影响

本文对真空烧结后的Ti(C,N)基金属陶瓷进行了二次低压烧结并对材料的组织和性能做了研究。研究发现,二次低压烧结后,Ti(C,N)基金属陶瓷中出现了一些白色的芯相组织,与黑色的芯相比,其Mo含量更高,而Ti含量更低。低压烧结后,金属陶瓷中的孔隙减少了,硬质相平均晶粒度从0.8μm增加到0.9μm。金属陶瓷的线收缩率从18.7%增加到20.3%;相对密度从99.19%增加到99.31%;硬度从93 HRA下降到92.8HRA;横向断裂强度从1 587 MPa增加到1 844 MPa。从断口形貌看,二次低压烧结后金属陶瓷断口中硬质相内部的微裂纹减少了,而且穿晶断裂的现象增多。     

改性碳纤维含量对Ti(C,N)基金属陶瓷组织结构和力学性能的影响

以Ti C、Ti N微米级粉末为主要原料,Ni、Co为金属粘结剂,添加改性短碳纤维(Cf)为增强相,采用无压结技术制备了Ti(C,N)基金属陶瓷,利用扫描电镜分析了Ti(C,N)基金属陶瓷的显微组织、断口形貌,通过维氏硬度法、三点弯曲法测试了Ti(C,N)基金属陶瓷的硬度和抗弯强度。结果表明:碳纤维表面镀镍后,镍磷(Ni-P)镀层表面平整致密,均匀包覆于碳纤维表面,且镀层与纤维结合紧密;添加改性碳纤维后,Ti(C,N)基金属陶瓷断裂方式以穿晶断裂为主,断面整体起伏较大,断口形貌主要表现为大量穿晶断裂留下的大块硬质相颗粒,少量沿晶断裂留下的凹坑以及小块硬质相颗粒和粘结相金属塑性变形形成的撕裂棱;Ti(C,N)基金属陶瓷组织形貌具有典型的"芯-壳"组织结构;当碳纤维添加量为4wt%时,材料抗弯强度和硬度达到最大值,分别为386.42、33.96 GPa。     

HR-2抗氢钢反挤球壳类锻件断口缺陷分析

由于HR-2抗氢钢棒料内存在氧化物、碳化物杂质及脆性相使得HR-2球壳的成形性能急剧降低,锻件表面产生局部裂纹。经取样分析,在断口表面观察到了较多的碳化物及氧化物颗粒。裂纹萌生周围的断口形貌出现崩碎现象,为典型的脆性断裂形貌。随着裂纹的扩展,断口形貌由崩碎的解理断面扩展到准解理面,最终在裂纹消失处发生了塑性断裂,并出现了大量规则的韧窝。     

纳米TiN改性Ti(C,N)基金属陶瓷的抗热震性能

为研究不同粘结相对纳米TiN改性Ti(C,N)基金属陶瓷抗热震性能的影响,真空烧结制备了粘结相质量分数分别为20%Ni、10%Co-10%Ni和20%Co的Ti(C,N)基金属陶瓷。采用扫描电镜研究了材料的组织,并测量了力学性能。采用压痕-急冷法主要研究了其抗热震性能,结果表明,随着温度的升高和热循环次数的增加,裂纹增长,粘结相为Ni的金属陶瓷的抗热震性优于粘结相为Co的金属陶瓷。显微照片表明,裂纹主要沿硬质相/粘结相界面及粘结相扩展。     

ZL201A铝合金低压铸造轮辐断口失效分析研究

利用铸件本体材料成分分析、力学性能分析、X射线探伤、金相检验、断口微观形貌观察等手段对ZL201A铝合金低压铸造轮辐断口进行了失效分析研究。结果表明,断口形貌显示裂纹产生于工件阳极氧化之后,零件内部组织中分布于晶界的T相和杂质相相对于基体组织韧性较差,断口是金属材料内部组织的微观薄弱部位,受外力重击时,该处首先萌生细小裂纹并迅速扩展,当外应力超过材料最小截面的破坏强度时,在最小截面处形成宏观裂纹。     

烧结温度对Ti(C,N)基金属陶瓷组织及力学性能的影响

采用真空烧结制备了Ti(C,N)-Mo-Ni金属陶瓷,利用扫描电镜(SEM)、能谱仪(EDS)和维氏硬度计研究了烧结温度对Ti(C,N)基金属陶瓷显微组织及力学性能的影响。结果表明:随着烧结温度的提高,粘结相逐渐从块状向网状转变,当烧结温度达到1450℃时,网状粘结相基本形成。1450℃是敏感烧结温度,在此温度,硬质相颗粒开始发生异常长大,且存在尖角硬质相颗粒,尖角的硬质相颗粒易发生穿晶断裂,降低材料的断裂韧性。当烧结温度高于1450℃,硬质相颗粒尺寸逐渐趋于均匀,硬质相颗粒尖角钝化。在1510℃烧结的样品具有较好的显微组织和力学性能,维氏硬度达到1700 HV30,断裂韧性KIC达到8.56 MPa·m~(1/2)。     

SiC颗粒对SiC_p/2009Al复合材料疲劳短裂纹扩展的影响

采用粉末冶金法制备15%(体积分数)SiC_p/2009Al复合材料,研究该材料的微观组织、力学性能、高周疲劳性能以及疲劳断口形貌.结果表明:在SiC_p/2009Al复合材料的疲劳短裂纹扩展阶段,SiC颗粒及其表面包覆的2009Al薄层在裂纹扩展面上形成"丘陵"状形貌,使疲劳断口的粗糙度增大,裂纹的闭合效应也随之增大:同时"丘陵"状形貌可以引发疲劳裂纹扩展路径偏析,使裂纹扩展的有效驱动力减小并使裂纹扩展路径增加;上述裂纹迟滞效应使SiC_p/2009Al复合材料在短裂纹扩展阶段具有较高的疲劳裂纹扩展抗力.     

Ti(C,N)_w/Ti(C,N)基金属陶瓷的组织与力学性能研究

采用Ti(C,N)晶须和颗粒复合粉末(Ti(C,N)w+Ti(C,N)p)制备Ti(C,N)w/Ti(C,N)基金属陶瓷。研究了复合粉末对金属陶瓷组织及性能的影响。结果表明,Ti(C,N)w的加入,金属陶瓷的各项力学性能都得到了提高。组织表现为环形相结构特征,与Ti(C,N)基金属陶瓷相比,双层环形相结构所占比例增大,且尺寸加厚。烧结组织中Ti(C,N)w的长径比大于临界长径比,在强化金属陶瓷方面起着重要的作用。环形相使Ti(C,N)w与基体界面结合紧密,增韧机制主要表现为裂纹桥联和裂纹偏转,拔出效应不明显。     

(Ti,W,Ta)(C,N)_p/Ti(C,N)基金属陶瓷的组织与性能

采用自制的多元复式碳氮化物陶瓷粉末 ((Ti,W,Ta) (C,N) p)制备 (Ti,W,Ta) (C,N) p/Ti(C,N)基金属陶瓷。研究了 (Ti,W,Ta) (C,N) p 粉末的组织结构特征及其加入对金属陶瓷的组织及性能的影响。结果表明 ,多元复式碳氮化物粉末的晶格常数与元素的固溶度有很好的对应关系 ,调整粉末中元素的固溶度可控制粉末的晶格常数 ,进而控制材料的性能。 Ti(C,N)基金属陶瓷中 (Ti,W,Ta) (C,N) p 粉末的加入 ,有利于重金属元素 W和 Ta向粘结相中扩散 ,从而降低了硬质相在粘结相中的溶解度 ,阻碍了晶粒长大。(Ti,W,Ta) (C,N) p/Ti(C,N)基金属陶瓷各项性能指标优于 Ti(C,N)基金属陶瓷和国外对应的金属陶瓷牌号 CT5 2 5的产品。强化机制主要表现为细晶强化与固溶强化。     

Effects of NiTi additions on the microstructure and mechanical properties of Ti(C,N)-based cermets

X-ray diffractometer (XRD) and scanning electron microscope (SEM) were used to observe and investigate the microstructure and fracture morphology of Ti(C,N)-based cermets added with NiTi alloy powder. A new ceramic phase is found with the structure of gray core, black inner rim, noncontinuous white inner rim and continuous gray outer rim. The fracture toughness and the transverse rupture strength have a distinct trend to increase with the increase of NiTi powder content in Ti(C,N)-based cermets, while the hardness has the opposite trend. Grain refinement and the increase of metallic phase are the dominant strengthening and toughening mechanisms. Additionally, the crack deflection and bridging may play an active role in improving the properties, as well as the special structure of large metallic binder containing many small ceramic particles. In cermets with a higher content of NiTi powder, the microcrack and the crack closure effect induced by martensitic transformation are advantageous to the mechanical properties.     

Effect of submicron Ti(C,N) on the microstructure and the mechanical properties of Ti(C,N)-based cermets

There is an increased industry demand for Ti(C,N)-based cermets with improved material properties. One of the parameters which are supposed to influence these properties is the mean particle size of the Ti(C,N) powder used. In this study the effects of a newly developed submicron Ti(C,N) powder grade on the properties of Ti(C,N)-based cermets, including hardness, toughness and microstructure were investigated. The cermets showed only small differences with respect to outgassing upon sintering (investigated by MS-EGA) as well as shrinkage (dilatometry). Cermet formulations with submicron Ti(C,N) could be sintered under identical conditions as with fine Ti(C,N), yielding completely dense bodies of A00 porosity. From SEM and XRD investigations it was found that submicron Ti(C,N) powders cause accelerated diffusion and homogenisation of the microstructure leading to a substantially increased amount of outer rim phase, a higher amount of inverse grains and substantially finer and less Ti(C,N) cores. Upon using submicron Ti(C,N), hardness (HV10) is increased and in one grade the fracture toughness (Palmqvist–Shetty) is increased as well.     

陶瓷相原始粉末粒度对Ti（C，N）基金属陶瓷组织和性能的影响

采用粉末冶金法制备了超细晶Ti（ C, N）基金属陶瓷和纳米改性Ti（ C, N）基金属陶瓷试样和刀具。研究了陶瓷相粉末粒度对Ti（ C, N）基金属陶瓷显微组织、力学性能及其刀具耐磨损性能的影响。结果表明,超细晶Ti（ C, N）基金属陶瓷和纳米改性Ti（ C, N）基金属陶瓷的硬质相均具有黑芯/灰壳和白芯/灰壳两种显微结构。超细晶Ti（ C, N）基金属陶瓷中白芯/灰壳结构硬质相晶粒较多,而纳米改性Ti（ C, N）基金属陶瓷中硬质相晶粒主要为黑芯/灰壳结构。与超细晶Ti（ C, N）基金属陶瓷相比,纳米改性Ti（ C, N）基金属陶瓷具有较高的抗弯强度和断裂韧度以及较低的硬度和孔隙度。纳米改性Ti（ C, N）基金属陶瓷刀具具有较长的使用寿命,约为超细晶Ti（ C, N）基金属陶瓷刀具使用寿命的2．3倍。     

Effect of VC addition on the microstructure and properties of Ti（C,N）-based nano cermets

In this paper, Ti(C,N)-based nano cermets were prepared by nano particles, and the effect of VC addition on the microstructure and properties of Ti(C,N)-based nano cermets was investigated. The results showed that there existed black-core grayish-rim structure as well as gray-core grayish-rim structure in VC-doped Ti(C,N)-based nano cermets. With the increase of VC addition, the number of gray cores increased, the lattice parameter of Ti(C,N) phase increased, the grain size decreased, the hardness and fracture toughness of Ti(C,N)-based nano cermets were enhanced, and nearly full densification could be achieved. However, excessive addition of VC to 1 wt% resulted in slight decrease in hardness and fracture toughness. Some deep dimples were found in the fracture surface of cermets with VC addition, which corresponded to ductile fracture.     

EFFECT OF Mo AND Mo2C ON THE MICROSTRUCTURE AND PROPERTIES OF THE CERMETS BASED ON Ti（C,N）

Effect of Mo and Mo2 C on the microstructure and properties of Ti（C,N）-based cermets was investigated in this article. The results have indicated that the weight percentage of Mo from 5 to 10 can reduce Ti（C,N） grain diameter and thickness of the rim, and Ti（C,N） grain can be wetted by Ni-Cu-Mo liquid so as to get small contiguity of Ti（C,N） grain. In that way, the transverse rupture strength of Ti（C,N）-based cermets has reached 1800-1900 MPa; the fracture toughness has been due to 16-18 MPa.m1/2. But 15 wt pct Mo was not more effective on Ti（C,N）-based cermets, because the thickness of the rim becomes larger. In the circumstance of Mo2 C, 5 wt pct Mo2 C was good for microstructure and properties of Ti（C,N）-based cermets, but 11 wt pct Mo2C has resulted in larger contiguity of Ti（C,N） grain and big Ti（C,N） grain diameter so as to reduce transverse rupture strength and fracture toughness. So that, the effect of Mo on Ti（C,N）-based cermets is better than Mo2C.     

Erosion-corrosion behavior of Ti(C,N)-based cermets containing different secondary carbides

The present work investigated the effects of secondary carbides (Mo₂C\WC\TaC\NbC) on the erosion-corrosion behavior of Ti(C,N)-based cermets. The results indicate that the erosion-corrosion resistance of Ti(C,N)-based cermets is enhanced in the order of NbC, TaC, WC and Mo2C addition. The contribution of erosion to the erosion-corrosion of Ti(C,N)-based cermets is much more significant than that of corrosion, and it increases with the decreased mechanical properties. The synergistic effect plays a dominant role in the degradation of Ti(C,N)-based cermets in erosion-corrosion conditions. There are two modes to ceramic phase degradation in erosion conditions: large ceramic grains are prone to deterioration through crack initiation and propagation → grain fracture → fragment removal; finer ceramic grains trend to be pulled out after the deterioration of binder and interface. The binder loss is determined by the corrosion resistance of binder, the erosion resistance of binder and the erosion resistance of ceramic phase.     

Microstructure and fracture toughness of Ti(C0.7N0.3)-WC-Ni cermets

Mo₂C is normally added to improve the wettability between Ti(C,N) and Ni in Ti(C,N)-based cermets. Due to the increasing price of Mo₂C, much attention has been paid to Ti(C,N)-based cermets with WC addition. In this paper, effect of WC content on the microstructure and properties of Ti(C_0.7N_0.3)-xWC-15wt.%Ni cermets free of Mo₂C was studied. The experimental results show that the microstructure is refined obviously with the increase of WC content. The fracture toughness decreases with the increase of WC content when WC content is 10-25 wt.%, and increases when WC content varies from 25 wt.% to 30 wt.%.     

原始粉末粒度组合对Ti(C,N)基金属陶瓷组织和性能的影响

采用粉末冶金方法制备了Ti(C,N)基金属陶瓷,研究了TiC和TiN在不同粒度组合下,Ti(C,N)基金属陶瓷的组织和性能。利用SEM、XRD等分析手段对所制备的金属陶瓷进行分析。结果表明,采用微米级TiC和纳米级TiN粒度组合得到的Ti(C,N)基金属陶瓷综合力学性能最好。其抗弯强度达到了1 052.8 MPa,断裂韧性达到了9.3 MPa·m1/2。