共查询到19条相似文献,搜索用时 187 毫秒
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白光LED被称作第四代照明光源,有着庞大的市场。文章主要介绍了白光LED用荧光粉,特别是紫外/近紫外光激发的白光LED用荧光粉的技术现状,并指出今后的发展需要解决的问题。 相似文献
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LED用稀土Eu掺杂硅酸盐基荧光粉的研究进展 总被引:3,自引:0,他引:3
由于硅酸盐为基体的光转换材料具有原料来源丰富、工艺适应性广泛及晶体结构稳定性较高等特点,目前已成为白光发光二极管(light-emitting diode,LED)用荧光粉的研究重点之一。本文综述了近年来国内外硅酸盐基稀土荧光粉材料的研究进展,对硅酸盐基稀土荧光粉的材料体系、发光机理及发光特性的改进方面进行了分析与探讨。通过比较固相反应法和溶胶-凝胶法两种不同制备方法的优缺点,阐述了不同制备方法对白光LED质量的影响,并对硅酸盐基荧光粉的发展趋势和应用前景作了简要展望。 相似文献
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白光LED用新型红色荧光粉的组成与发光性能的关系 总被引:5,自引:0,他引:5
白光LED有望发展成为新一代绿色照明光源.荧光粉作为配套材料,其性能优劣直接影响白光LED的发光效率、亮度以及显色性等.高效红色荧光粉已经成为白光LED发展的瓶颈.概述了Eu3+激活的钨/钼酸盐、氧化钇铋和钛酸盐,Sm3+激活的锌酸锶,Pr3+和Bi3+共激活的钛酸钙,Eu2+激活的氮化物,Ce3+激活的硅锗酸盐石榴石以及Mn4+激活的多铝酸钙和Mn2+激活的硫氧化锌钙等白光LED用新型红色荧光粉的发光性能的研究进展;着重分析了它们的组成变化对荧光性能的影响;并对今后的研究提出了一些设想. 相似文献
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根据目前LED实现白光的两种主流方式:近紫光LED芯片+红/绿/蓝三基色荧光粉和蓝光LED芯片+黄色荧光粉(或+绿色/红色荧光粉),本文重点从黄色荧光粉、绿色荧光粉、红色荧光粉及蓝色荧光粉四个方面综述了利用阳离子置换实现对白光LED灯用荧光粉发光性能改善的研究进展,并对利用该方法对荧光粉的发光性能改善的研究趋势进行了展望。 相似文献
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Shih Chieh Huang Jui Kung Wu Wei-Jen Hsu Hsin Hsiung Chang Hsien Yen Hung Chi Lian Lin Hung-Yuan Su Nitin Bagkar Wei-Chih Ke Hui Tung Kuo Ru-Shi Liu 《International Journal of Applied Ceramic Technology》2009,6(4):465-469
The synthesis of cerium-doped yttrium aluminum garnet (YAG:Ce) phosphor of different sizes with uniform size distribution was carried out using solid-state reaction followed by grinding and sieving method. The effect of particle size distribution of YAG:Ce phosphors on the photoluminescence (PL) properties was investigated. The results demonstrate that the uniform size distribution and particle size affects the packaging performance in white light emitting diode (LED) applications. The YAG:Ce phosphors with different particle sizes were packaged in white LEDs using different amounts of each phosphors in order to get similar efficiency as that of commercially available YAG:Ce phosphors. It was observed that minimum amount of phosphor material is required for smaller particle size for getting the similar efficiency as that exhibited by commercially available YAG:Ce phosphors. The results are particularly interesting in view of reducing the cost of current LEDs by lowering the amount of phosphors without compromising the efficiencies of final LED package. A systematic study of YAG:Ce phosphors on the packing performance in white LEDs is reported. 相似文献
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以实验室自制SiO2粉体和商用Ce∶YAG荧光粉为玻璃原料,采用放电等离子体烧结(SPS)技术,在1 200℃保温2 min烧结得到有望用于白光LED封装的Ce∶YAG荧光玻璃。用X射线衍射仪(XRD)、荧光光谱(PL)等方法对制备获得的荧光玻璃样品进行表征。结果显示,烧结并没有破坏Ce∶YAG荧光粉的晶体结构,且荧光玻璃主体相仍为玻璃体,该荧光玻璃在460nm具有强吸收峰,在此波长激发下发射出530 nm左右的黄光。研究结果表明,本实验制备的Ce∶YAG荧光玻璃是一种具有重要应用前景的LED封装用新型荧光材料。 相似文献
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P. J. Yadav C. P. Joshi S. V. Moharil 《International Journal of Self-Propagating High-Temperature Synthesis》2012,21(1):32-37
About 50% of the world’s need for lighting is provided by artificial lighting. For over the last decade, the world has witnessed
rapid shift from conventional Hg-based lighting to LED-based solid state lighting (SSL). SSL technology extensively uses YAG:Ce3+ phosphor for production of white light emitting devices (LEDs). Part of the blue light from the (In,Ga)N LED chip is absorbed
by a thin layer of Ce3+-doped YAG and is converted into yellow light. The combination of blue and yellow gives a bright white light source with an
overall energy efficiency exceeding that of a compact fluorescent lamp. Several soft chemical routes have been explored for
synthesis of YAG but were discarded due to their complex nature, high cost for the industrialization, phase impure materials,
etc. In this paper we describe rapid one-step modified combustion synthesis of YAG:Ce3+ and related phosphors carried out at 500°C using a mixed fuel. Photoluminescence spectra of YAG:Ce3+ and LED prepared thereof are comparable with those of commercial phosphors. 相似文献
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Lung-Chien Chen Zong-Liang Tseng Wei-Wen Chang Yen Wen Lin 《Ceramics International》2018,44(4):3868-3872
This work reports warm white light-emitting diodes (WLEDs) using organic–inorganic halide perovskite materials coated YAG:Ce3+ phosphors by a liquid phase synthesis method. The perovskite MAPbBr3?xIx-coated YAG:Ce3+ phosphors have more red light contribution than YAG:Ce3+ phosphors without the perovskite coating. The chromaticity coordinate of white LED with YAG:Ce3+ remote phosphor is (x = 0.3134, y = 0.3497) 6359. However, those of MAPbBr2.5I0.5 and MAPbBr2.0I1.0-coated YAG:Ce3+ remote phosphor shift to (x = 0.4220, y = 0.3725) 2908 and (x = 0.4067, y = 0.4028) 3525, respectively. The colors of perovskite-coated samples are more red and warm. Therefore, the perovskite-coated YAG:Ce3+ method is useful for warm WLED. 相似文献
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Mengting He Jiannan Jia Junjie Zhao Xvsheng Qiao Jincheng Du Xianping Fan 《Ceramics International》2021,47(3):2963-2980
Solid state lighting, including phosphor converted light-emitting diodes (LEDs) and laser diodes (LDs), have released high demand to develop thermally stable phosphors. For this purpose, inorganic glass-ceramics (GCs) embedded with phosphor particles can act as competitive candidates. They are superior to traditional phosphors or resin/silica composites through successfully overcoming thermal aging and color temperature drifting problems and simultaneously maintaining high luminescent efficiencies. Inorganic GC phosphors can be classified into devitrified glass-ceramics, PiG (Phosphor-in-Glass) and sintered glass-ceramics. This review summarized the recent progress on LED/LD GC phosphors from the aspects of design principles, synthesis methods, microstructure-property relationships and their application studies. In addition, some challenging issues (e.g., crystallization behavior of luminous phase in glass, corrosion behavior of phosphor by glass matrix) are also discussed in detail. Significant issues of glass-ceramics packed LED/LD, such as luminescence efficiency, chromaticity, correlated color temperature and color gamut, are sorted out as well. Potential research directions are further suggested for not only developing new glass-ceramic phosphors but feeding upon various practical application. 相似文献
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Avital Wagner Barak Ratzker Sergey Kalabukhov Maxim Sokol Nachum Frage 《Journal of the European Ceramic Society》2019,39(4):1436-1442
Transparent cerium-doped yttrium aluminum garnet (Ce:YAG) phosphors are promising candidates for high-power white light emitting diode applications. In the present study, Ce:YAG powder was synthesized by a co-precipitation method and highly transparent ceramics were fabricated by spark plasma sintering. The effects of temperature and pressure, as well as post-sintering treatments (annealing or hot isostatic pressing), on residual porosity were studied by electron and confocal laser microscopy. Correlation between residual porosity characteristics (pore size and volume fraction) and optical properties (in-line transmittance and photoluminescence intensity) of the luminescent transparent ceramics was established. 相似文献
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《Ceramics International》2023,49(12):19606-19614
The main focus of laser lighting research has been on perfectly combining fluorescent conversion materials with laser light sources to improve luminous efficiency (LE). In this paper, the high refractive index, high transmittance and low sintering temperature of tellurite glass is combined with the thermal stability and mechanical strength of germanate glass,which is innovatively used as a matrix for phosphor-in-glass (PiG). The use of high valent ions as modifiers reduces the diffusion and mobility of ions to reduce the erosion of phosphors and protect the luminescent performance of phosphors. By changing Ge/Te ratio, the glass maintains 80% transmittance, and the refractive index decreases from 1.97 to 1.83 matching that of the YAG phosphor. The increase in GeO2 improves the thermal stability and mechanical strength of the glass, thereby improving the fluorescence intensity (approximately 1.6%) at 473 K and the luminous flux by up to 12.8%. The best PiG sample had a LE of 230 lm/W and excellent internal quantum efficiency (IQE) of 85.3%, achieving high levels of luminescence. Adding different phosphor contents can achieve the role of adjusting the correlated color temperature (4500–6000 K), and the color coordinates (0.322, 0.330) are close to the ideal white light. These results show that tellurite-germanate glass can be used as a good carrier for fluorescence conversion materials, which brings a new direction for the exploration of glass matrix. 相似文献
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采用直径10in积分球结合CCD(Charge Coupled Device)探测器测试系统,在蓝色半导体发光二极管激发下,对Ce3 掺杂的Y3Al5O12(YAG)玻璃陶瓷的荧光光谱进行表征,实现了以荧光发射特性绝对评价为目的的绝对光谱功率分布测定,为白色LED(Light Emitting Diode)荧光材料发射特性的精确测定提供了一种准确方法。荧光测试系统经标准卤素灯定标,辅助卤素灯校正积分球内环境变化,解析出样品发光的绝对光谱功率分布,并进一步计算出光量子数分布,求得荧光量子产率。实验结果表明,YAG高效玻璃陶瓷片的荧光量子产率高达33.7%,为新型高效LED照明发光材料的研制提供了新的标准和比照。 相似文献