The fuel cell electric vehicles: The highlight review

Transportation sector is the important sector and consumed the most fossil fuel in the world. Since COVID-19 started in 2019, this sector had become the world connector because every country relies on logistics. The transportation sector does not only deal with the human transportation but also relates to logistics. Research in every country has searched for alternative transportation to replace internal combustion engines using fossil fuel, one of the most prominent choices is fuel cells. Fuel cells can use hydrogen as fuel. Hydrogen can be fed to the fuel cells to provide electric power to drive vehicles, no greenhouse gas emission and no direct combustion required. The fuel cells have been developed widely as the 21st century energy-conservation devices for mobile, stationary, and especially vehicles. The fuel cell electric vehicles using hydrogen as fuel were also called hydrogen fuel cell vehicles or hydrogen electric vehicles. The fuel cells were misconceived by several people that they were batteries, but the fuel cells could provide electric power continuously if their fuel was provided continuously. The batteries could provide electric power as their only capacities, when all ions are released, no power could be provided. Because the fuel cell vehicles play important roles for our future transportation, the overall review for these vehicles is significantly interesting. This overall review can provide general and technical information, variety of readers; vehicle users, manufacturers, and scientists, can perceive and understand the fuel cell vehicles within this review. The readers can realize how important the fuel cell technologies are and support research around the world to drive the fuel cell vehicles to be the leading vehicles in our sustainable developing world.     

Metal hydride material requirements for automotive hydrogen storage systems

The United States Department of Energy (DOE) has published a progression of technical targets to be satisfied by on-board rechargeable hydrogen storage systems in light-duty vehicles. By combining simplified storage system and vehicle models with interpolated data from metal hydride databases, we obtain material-level requirements for metal hydrides that can be assembled into systems that satisfy the DOE targets for 2017. We assume minimal balance-of-plant components for systems with and without a hydrogen combustion loop for supplemental heating. Tank weight and volume are driven by the stringent requirements for refueling time. The resulting requirements suggest that, at least for this specific application, no current on-board rechargeable metal hydride satisfies these requirements.     

Efficiencies of hydrogen storage systems onboard fuel cell vehicles

Energy efficiency, vehicle weight, driving range, and fuel economy are compared among fuel cell vehicles (FCV) with different types of fuel storage and battery-powered electric vehicles. Three options for onboard fuel storage are examined and compared in order to evaluate the most energy efficient option of storing fuel in fuel cell vehicles: compressed hydrogen gas storage, metal hydride storage, and onboard reformer of methanol. Solar energy is considered the primary source for fair comparison of efficiencies for true zero emission vehicles. Component efficiencies are from the literature. The battery powered electric vehicle has the highest efficiency of conversion from solar energy for a driving range of 300 miles. Among the fuel cell vehicles, the most efficient is the vehicle with onboard compressed hydrogen storage. The compressed gas FCV is also the leader in four other categories: vehicle weight for a given range, driving range for a given weight, efficiency starting with fossil fuels, and miles per gallon equivalent (about equal to a hybrid electric) on urban and highway driving cycles.     

The car industry and the blow-out of the hydrogen hype

The hydrogen hype of the last decade has passed and it is now seemingly substituted by the electric vehicle hype. A technological hype can have both positive as well as negative consequences. On the one hand it attracts sponsors for technology development but on the other hand the high expectations might result in disappointment and subsequent withdrawal of the sponsors. In this paper I ask the question to what extent the car industry has created the hype and how it has done so. The industry’s role is studied through their prototyping activities and accompanying statements on market entry. I conclude that the car industry has indeed inflated the hype, especially through its public statements on market release after the turn of the millennium. Furthermore, it can be concluded that the industry has shown a double repertoire of both highly optimistic and more modest statements. It is possible that statements are used deliberately to serve the industry’s interests whenever needed. Without neglecting the positive influence of technological hype on public policy and private funding for R&D efforts, more modest promises could serve the development of sustainable mobility better. For policy makers the challenge is to remain open to different options instead of following hypes and disappointments as they come and go.     

Production,storage, fuel stations of hydrogen and its utilization in automotive applications-a review

Fossil fuels are responsible for a significant portion of the emissions of greenhouse gases. As the need to find renewable and environmentally friendly energy solutions grows, the tendency is for these sources increase in the vehicle matrices, gradually. Because of this, hydrogen appears as a potential alternative to fossil fuels. Hydrogen is one of the most abundant elements on the planet and can be obtained from numerous sources, such as water, biomass, natural gas, ethanol, among others. To be used in fuel cell vehicles or in internal combustion engines, hydrogen needs to go through stages such as production, storage and distribution. All of these steps need to be feasible in terms of technology, economics and also from the environmental point of view. Therefore, the objective of this study was to review the feasibility and impacts of all stages from production to final use of hydrogen as a resource for mobility purposes. This article provides a general discussion of the path which the hydrogen goes through from its source until its usage, approaching technological, economic and environmental issues that are essential for the viability of this economy. Moreover, it also presents the main challenges and research fields that need greater engagement by researchers and political decision-makers. The results indicate that hydrogen production techniques need more development in order to be competitive. Production methods that show the best average results are hybrid production methods, followed by thermal and photonic. The main difficulty in terms of storage is to obtain a good volumetric density. The volumetric density of the current compression storage is about 5,7 wt percent capacity (wt%). Fuel cells need to achieve better results in terms of system durability (current durability is approximately 120,000 km) and costs.     

Fuel cells and odorants for hydrogen

Odorants have been proposed as a reliable, inexpensive means to enable leak detection for hydrogen systems and increase public safety. However, traditional odorants cause problems for fuel cell systems. This paper examines the use of odorants for fuel cell systems, including the hydrogen storage. Current odorants and potential odorants have negative impacts on fuel cell performance. Odorants also appear to be problematic for most of the advanced hydrogen storage options. If odorants are used, the odorants will probably need to be removed from the hydrogen prior to the storage medium. Current hydrogen detectors are more reliable than the odorant–human detection system and should provide increased safety.     

Recent challenges of hydrogen storage technologies for fuel cell vehicles

Fuel cell vehicles have a high potential to reduce both energy consumption and carbon dioxide emissions. However, due to the low density, hydrogen gas limits the amount of hydrogen stored on board. This restriction also prevents wide penetration of fuel cells. Hydrogen storage is the key technology towards the hydrogen society. Currently high-pressure tanks and liquid hydrogen tanks are used for road tests, but both technologies do not meet all the requirements of future fuel cell vehicles. This paper briefly explains the current status of conventional technologies (simple containment) such as high-pressure tank systems and cryogenic storage. Another method, hydrogen-absorbing alloy has been long investigated but it has several difficulties for the vehicle applications such as low temperature discharge characteristics and quick charge capability due to its reaction heat. We tested a new idea of combining metal hydride and high pressure. It will solve some difficulties and improve performance such as gravimetric density. This paper describes the latest material and system development.     

Effects of tank heating on hydrogen release from metal hydride system in VoltaFCEV Fuel Cell Electric Vehicle

Metal hydride (MH) storage is known as a safe storage method because it does not require complex processes like high pressure or very low temperature. However, it is necessary to use a heat exchanger due to the endothermic and exothermic reactions occurring during the charging and discharging processes of the MH tanks. The performance of the MH is adversely affected by the lack of a heat exchanger or a suitable temperature range and it causes non-stable hydrogen supply to the fuel cell systems. In this study, effect of the tank surface temperature on hydrogen flow and hydrogen consumption performance were investigated for the MH hydrogen storage system of a hydrogen Fuel Cell Electric Vehicle (FCEV). Different temperature values were arranged using an external heat circulator device and a heat exchanger inside the MH tank. The fuel cell (FC) was operated at three different power levels (200 W, 400 W, and 600 W) and its performance was determined depending on the temperature and discharge flow rate of the MH tank. When the heat exchanger temperature (HET) was set to 40 °C, the discharge performance of the MH tank increased compared to lower temperatures. For example, when the FC power was set to 200 W and the HET of the system was at 40 °C, 1600 L hydrogen was supplied to the FC and 2000 Wh electrical energy was obtained. The results show that the amount of hydrogen supplied from the MH tank decreases significantly by increasing the flow rate in the system and rapid temperature changes occur in the MH tank.     

The role of hydrogen cars in the economy of California

Hydrogen has been proposed as an alternative transportation fuel that could reduce energy consumption and eliminate tailpipe emissions when used in fuel cell vehicles (FCVs). To investigate the potential effects of hydrogen vehicles on California’s economy over the next two decades, we employed the modified Costs for Advanced Vehicles and Energy (CAVE) model and a California-specific computable general equilibrium model. Results indicate that, even in the aggressive scenario, hydrogen cars can only account for a minor fraction of the on-road fleet through 2030. Although new sales could drop sharply, conventional gasoline cars and carryover pre-2010 vehicles are still expected to dominate the on-road vehicle stock and consume the majority of transportation energy through 2030. Transportation energy consumption could decline dramatically, mainly because of the fuel economy advantage of FCVs over conventional cars. Both moderate and aggressive hydrogen scenarios are estimated to have a slightly negative influence on California’s economy. However, the negative economic impacts could be lessened as the market for hydrogen and FCVs builds up. Based on the economic optimization model, both hydrogen scenarios would have a negative economic impact on California’s oil refining sector and, as expected, a positive impact on the other directly related sectors that contribute to either hydrogen production or FCV manufacturing.     

Fuel cell vehicles: Status 2007

Within the framework of this paper, a short motivation for hydrogen as a fuel is provided and recent developments in the field of fuel cell vehicles are described. In particular, the propulsion system and its efficiency, as well as the integration of the hydrogen storage system are discussed. A fuel cell drivetrain poses certain requirements (concerning thermodynamic and engineering issues) on the operating conditions of the tank system. These limitations and their consequences are described. For this purpose, conventional and novel storage concepts will be shortly introduced and evaluated for their automotive viability and their potential impact. Eventually, GM's third generation vehicles (i.e. the HydroGen3) are presented, as well as the recent 4th generation Chevrolet Equinox Fuel Cell SUV. An outlook is given that addresses cost targets and infrastructure needs.     

Analysis of a “cluster” strategy for introducing hydrogen vehicles in Southern California

The cost and logistics of building early hydrogen refueling infrastructure are key barriers to the commercialization of fuel cell vehicles. In this paper, we explore a “cluster strategy” for introducing hydrogen vehicles and refueling infrastructure in Southern California over the next decade, to satisfy California's Zero Emission Vehicle regulation. Clustering refers to coordinated introduction of hydrogen vehicles and refueling infrastructure in a few focused geographic areas such as smaller cities (e.g. Santa Monica, Irvine) within a larger region (e.g. Los Angeles Basin). We analyze several transition scenarios for introducing hundreds to tens of thousands of vehicles and 8–42 stations, considering:     

Fuel cell vehicles: State of the art with economic and environmental concerns

Hydrogen fueled fuel cell vehicles (FCVs) will play a major role as a part of the change toward the hydrogen based energy system. When combined with the right source of energy, fuel cells have the highest potential efficiencies and lowest potential emissions of any vehicular power source. As a result, extensive work into the development of hydrogen fueled FCVs is taking place. The aim of this paper is to highlight some of the research and development work which has occurred in the past five years on fuel cell vehicle technology, with a focus on economic and environmental concerns. It is observed that the current efforts are divided up into several parts. The performance, durability, and cost of fuel cell technology continue to be improved, and some fuel cells are currently ready to be mounted on vehicles and tested. Environmental and economic assessments of the entire hydrogen supply chain, including fuel cell end-use, are being carried out by groups of researchers around the world. It is currently believed that fuel cells need at least five more years of testing and improvement before large scale commercialization can begin. Economic and environmental analyses show that FCVs will likely be both economically competitive and environmentally benign. Indeed, the transition of the transportation sector to the use of hydrogen FCVs will represent one of the biggest steps toward the hydrogen economy.     

A review of hydrogen as a compression ignition engine fuel

Diesel fuelled engines emit higher levels of carbon dioxide and other harmful air pollutants (such as noxious gases and particulates) per litre of fuel than gasoline engines. This fact, combined with the recent diesel emission scandal and the rumours of more widespread cheating by automotive manufacturers have initiated a long discussion about the future and sustainability of diesel engines.Improving the compression ignition engine is a direct way of going green. Reducing the harmful emissions can be achieved by future developments in the engine technology but also the implementation of alternative fuels. Hydrogen is a renewable, high-efficient and clean fuel that can potentially save the future of diesel-type engines. The evolution of high-efficiency renewable hydrogen production methods is the most important path for the start of a new hydrogen era for the compression ignition engine that can improve its sustainability and maximum efficiency.This paper provides a detailed overview of hydrogen as a fuel for compression ignition engines. A comprehensive review of the past and recent research activities on the topic is documented. The review focuses on the in-cylinder combustion of hydrogen either as a primary fuel or in dual fuel operation. The effects of injection strategies, compression ratio and exhaust gas recirculation on the combustion and emission characteristics of the hydrogen fuelled engine are fully analysed. The main limitations, challenges and perspectives are presented.     

Systematic planning to optimize investments in hydrogen infrastructure deployment

The introduction of hydrogen infrastructure and fuel cell vehicles (FCVs) to gradually replace gasoline internal combustion engine vehicles can provide environment and energy security benefits. The deployment of hydrogen fueling infrastructure to support the demonstration and commercialization of FCVs remains a critical barrier to transitioning to hydrogen as a transportation fuel. This study utilizes an engineering methodology referred to as the Spatially and Temporally Resolved Energy and Environment Tool (STREET) to demonstrate how systematic planning can optimize early investments in hydrogen infrastructure in a way that supports and encourages growth in the deployment of FCVs while ensuring that the associated environment and energy security benefits are fully realized. Specifically, a case study is performed for the City of Irvine, California – a target area for FCV deployment – to determine the optimized number and location of hydrogen fueling stations required to provide a bridge to FCV commercialization, the preferred rollout strategy for those stations, and the environmental impact associated with three near-term scenarios for hydrogen production and distribution associated with local and regional sources of hydrogen available to the City. Furthermore, because the State of California has adopted legislation imposing environmental standards for hydrogen production, results of the environmental impact assessment for hydrogen production and distribution scenarios are measured against the California standards. The results show that significantly fewer hydrogen fueling stations are required to provide comparable service to the existing gasoline infrastructure, and that key community statistics are needed to inform the preferred rollout strategy for the stations. Well-to-wheel (WTW) greenhouse gas (GHG) emissions, urban criteria pollutants, energy use, and water use associated with hydrogen and FCVs can be significantly reduced in comparison to the average parc of gasoline vehicles regardless of whether hydrogen is produced and distributed with an emphasis on conventional resources (e.g., natural gas), or on local, renewable resources. An emphasis on local renewable resources to produce hydrogen further reduces emissions, energy use, and water use associated with hydrogen and FCVs compared to an emphasis on conventional resources. All three hydrogen production and distribution scenarios considered in the study meet California's standards for well-to-wheel GHG emissions, and well-to-tank emissions of urban ROG and NO_X. Two of the three scenarios also meet California's standard that 33% of hydrogen must be produced from renewable feedstocks. Overall, systematic planning optimizes both the economic and environmental impact associated with the deployment of hydrogen infrastructure and FCVs.     

Deployment of fuel cell vehicles in China: Greenhouse gas emission reductions from converting the heavy-duty truck fleet from diesel and natural gas to hydrogen

Hydrogen fuel cells, as an energy source for heavy duty vehicles, are gaining attention as a potential carbon mitigation strategy. Here we calculate the greenhouse gas (GHG) emissions of the Chinese heavy-duty truck fleet under four hydrogen fuel cell heavy-duty truck penetration scenarios from 2020 through 2050. We introduce Aggressive, Moderate, Conservative and No Fuel Cell Vehicle (No FCV) scenarios. Under these four scenarios, the market share of heavy-duty trucks powered by fuel cells will reach 100%, 50%, 20% and 0%, respectively, in 2050. We go beyond previous studies which compared differences in GHG emissions from different hydrogen production pathways. We now combine an analysis of the carbon intensity of various hydrogen production pathways with predictions of the future hydrogen supply structure in China along with various penetration rates of heavy-duty fuel cell vehicles. We calculate the associated carbon intensity per vehicle kilometer travelled of the hydrogen used in heavy-duty trucks in each scenario, providing a practical application of our research. Our results indicate that if China relies only on fuel economy improvements, with the projected increase in vehicle miles travelled, the GHG emissions of the heavy-duty truck fleet will continue to increase and will remain almost unchanged after 2025. The Aggressive, Moderate and Conservative FCV Scenarios will achieve 63%, 30% and 12% reductions, respectively, in GHG emissions in 2050 from the heavy duty truck fleet compared to the No FCV Scenario. Additional reductions are possible if the current source of hydrogen from fossil fuels was displaced with increased use of hydrogen from water electrolysis using non-fossil generated electricity.     

Fuel economy of hydrogen fuel cell vehicles

On the basis of on-road energy consumption, fuel economy (FE) of hydrogen fuel cell light-duty vehicles is projected to be 2.5–2.7 times the fuel economy of the conventional gasoline internal combustion engine vehicles (ICEV) on the same platforms. Even with a less efficient but higher power density 0.6 V per cell than the base case 0.7 V per cell at the rated power point, the hydrogen fuel cell vehicles are projected to offer essentially the same fuel economy multiplier. The key to obtaining high fuel economy as measured on standardized urban and highway drive schedules lies in maintaining high efficiency of the fuel cell (FC) system at low loads. To achieve this, besides a high performance fuel cell stack, low parasitic losses in the air management system (i.e., turndown and part load efficiencies of the compressor–expander module) are critical.     

Wind energy and the hydrogen economy—review of the technology

The hydrogen economy is an inevitable energy system of the future where the available energy sources (preferably the renewable ones) will be used to generate hydrogen and electricity as energy carriers, which are capable of satisfying all the energy needs of human civilization. The transition to a hydrogen economy may have already begun. This paper presents a review of hydrogen energy technologies, namely technologies for hydrogen production, storage, distribution, and utilization. Possibilities for utilization of wind energy to generate hydrogen are discussed in parallel with possibilities to use hydrogen to enhance wind power competitiveness.     

Silicon Fuel: A hydrogen storage material

Considerable effort is focused on developing alternative approaches to generating and storing energy to reduce the world's reliance on fossil fuels. Hydrogen offers one such alternative, which is zero-emission at the point of use when used to supply a fuel cell to generate electricity. However, the availability of hydrogen by methods that are both cost-effective and environmentally friendly remains a significant challenge.The formulation presented in this work, which we call Silicon Fuel, contains 90% silicon and can generate high hydrogen yields of 70% or more in just a few minutes. This means that the dry material effectively has a hydrogen content of at least 9 wt% and a realistic specific energy of at least 1.5 kWh/kg if the hydrogen supplies a fuel cell with 50% efficiency. As the hydrogen can be generated in a commercially useful time frame, it is suitable for applications such as automotive refuelling, where consumers expect to be able to refuel their vehicle within a few minutes.