Hydrogen production from biological systems under different illumination conditions

Hydrogen is a natural by-product of several microbial driven biochemical reactions, mainly in anaerobic fermentation processes. In addition, certain microorganisms produce enzymes by which H₂ from water may be obtained if an outside energy source, like sunlight, is provided. Biophotolysis is a biological process which involves solar energy and algae clusters to convert water into hydrogen. Algae pigments absorb solar energy and enzymes in the cell act as catalysts to split water into hydrogen and oxygen. There are many research activities studying hydrogen production from biological systems cyanobacteria and green algae and some studies present a complete outline of the main available pathways to improve the photosynthetic H₂ production [1] and [2].Efficiency (energy produced from hydrogen divided by solar energy) of such processes can be estimated up to 10%. This value has to be increased for a large-scale hydrogen production. The effect of different artificial illumination conditions on H₂ production was studied for green algae cultures (Chlamydomonas reinhardtii). Results will be used to design a high-efficiency photobioreactor for a large-scale hydrogen production.     

A review on integrated thermochemical hydrogen production from water

Hydrogen production from water splitting is considered one of the most environmentally friendly processes for replacing fossil fuels. Among the various technologies to produce hydrogen from water splitting, thermochemical cycles using chemical reagents have the advantage of scale up compared to other specific facilities or geological conditions required. According to thermochemical processes using chemical redox reactions, 2-, 3-, 4-step thermochemical water splitting cycles can generate hydrogen more efficiently due to reducing temperatures. Increasing the number of cycles or steps of thermochemical hydrogen production could reduce the required maximum temperature of the facility. In addition, recently developed hybrid thermochemical processes combined with electricity or solar energy have been studied on a large scale because of the reduced cost of hydrogen production. Additionally, hybrid thermochemical water splitting combined with renewable energy can result in not only reducing the cost, but also increasing hydrogen production efficiency in terms of energy. As for a green energy, hydrogen production from water splitting using sustainable and renewable energy is significant to protect biological environment and human health. Additionally, hybrid thermochemical water splitting is conducive to large scale hydrogen production. This paper reviews the multi-step and highly developed hybrid thermochemical technologies to produce hydrogen from water splitting based on recently published literature to understand current research achievements.     

可再生能源制氢综合能源管理平台研究

目的   氢能是一种绿色高效的清洁能源,可以通过多种方式转化为电能、热能等加以利用。可再生能源制氢是实现碳达峰、碳中和目标的重要支撑。可再生能源制氢属于新型项目,是电力行业与化工行业的结合,系统间耦合性不强,提高能源综合利用率是可再生能源制氢的研究重点。 方法   文章介绍了当前主要的制氢工艺,对比了灰氢、蓝氢和绿氢的主要特点,阐述了风电及光伏制氢的主要系统,并提出了通过构建综合能源管理平台对可再生能源制氢各系统进行统筹管控的思路。 结果   在综合能源管理平台制定控制策略可以平衡功率,实现最优调度从而减少弃风弃光,而且还可以降低单位制氢成本。 结论   综合能源管理平台可以提高可再生能源制氢的能源综合利用率,对可再生能源制氢项目的推广起到支撑的作用,为可再生能源制氢领域的研究人员提供了重要的参考借鉴     

Large-scale decomposition of green ammonia for pure hydrogen production

It is acknowledged that Hydrogen has a decisive role to play in insuring a reliable and efficient penetration of renewable electricity in the energy mix. Nonetheless, building a sustainable Hydrogen Economy is faced with numerous challenges across the value chain. Namely, large-scale production and storage are still open issues that need to be addressed. A promising solution is to store renewable H₂ in the form of green ammonia often referred to as Power-to-Ammonia. Thus unlocking all available infrastructure for ammonia to effectively store and export hydrogen in bulk. In this value chain, the missing link is ammonia cracking to recover back hydrogen at high purities. The present work explores a technical solution to recover hydrogen from ammonia at large-scale. Through an exhaustive technoeconomic analysis, we have demonstrated the feasibility of large-scale production of pure H₂ from ammonia. The designed Ammonia-to-H₂ plant operates at a thermal efficiency of 68.5% to produce 200 MTPD of pure hydrogen at 250 bar. Furthermore, this study has established a final estimation of the Levelized Cost of Hydrogen (LCOH) from green ammonia. It was revealed that LCOH is mostly dependent on green ammonia cost, which in turn varies with renewable electricity cost.     

Green methods for hydrogen production

This paper discusses environmentally benign and sustainable, as green, methods for hydrogen production and categorizes them based on the driving sources and applications. Some potential sources are electrical, thermal, biochemical, photonic, electro-thermal, photo-thermal, photo-electric, photo-biochemical, and thermal-biochemical. Such forms of energy can be derived from renewable sources, nuclear energy and from energy recovery processes for hydrogen production purposes. These processes are analyzed and assessed for comparison purposes. Various case studies are presented to highlight the importance of green hydrogen production methods and systems for practical applications.     

Clean hydrogen generation and storage strategies via CO2 utilization into chemicals and fuels: A review

Hydrogen becomes one of the most clean energy sources. The major issues on hydrogen are lack of practical clean and high‐temperature processes and possible practical storage of clean hydrogen. An energy intensive of clean hydrogen storage via chemical and liquid fuel production route is the current demand. This article reviewed the most recent research for hydrogen (H₂) production by using several methods, such as thermochemical process, thermal decomposition, biological approaches, electrolysis, and photocatalytic method. H₂ storage types, including physical and chemical approaches, were also reviewed. The produced H₂ was stored as valuable chemicals and fuels via CO₂ hydrogenation reaction. Reactor designs are the illustrated number of design ranging from the fixed bed to the continuous stirred tank reactor. Catalyst type, catalytic system, and the related mechanism of CO₂ hydrogenation reaction to form alcohol, alkanes, and carboxylic acid were also discussed in detail.     

Political,economic and environmental impacts of biomass-based hydrogen

The purpose of this study is to assess the political, economic and environmental impacts of producing hydrogen from biomass. Hydrogen is a promising renewable fuel for transportation and domestic applications. Hydrogen is a secondary form of energy that has to be manufactured like electricity. The promise of hydrogen as an energy carrier that can provide pollution-free, carbon-free power and fuels for buildings, industry, and transport makes it a potentially critical player in our energy future. Currently, most hydrogen is derived from non-renewable resources by steam reforming in which fossil fuels, primarily natural gas, but could in principle be generated from renewable resources such as biomass by gasification. Hydrogen production from fossil fuels is not renewable and produces at least the same amount of CO₂ as the direct combustion of the fossil fuel. The production of hydrogen from biomass has several advantages compared to that of fossil fuels. The major problem in utilization of hydrogen gas as a fuel is its unavailability in nature and the need for inexpensive production methods. Hydrogen production using steam reforming methane is the most economical method among the current commercial processes. These processes use non-renewable energy sources to produce hydrogen and are not sustainable. It is believed that in the future biomass can become an important sustainable source of hydrogen. Several studies have shown that the cost of producing hydrogen from biomass is strongly dependent on the cost of the feedstock. Biomass, in particular, could be a low-cost option for some countries. Therefore, a cost-effective energy-production process could be achieved in which agricultural wastes and various other biomasses are recycled to produce hydrogen economically. Policy interest in moving towards a hydrogen-based economy is rising, largely because converting hydrogen into useable energy can be more efficient than fossil fuels and has the virtue of only producing water as the by-product of the process. Achieving large-scale changes to develop a sustained hydrogen economy requires a large amount of planning and cooperation at national and international alike levels.     

Biohydrogen production: An outlook on methods,constraints, economic analysis and future prospect

Utilization of hydrogen as fuel lights into various technological, economic and ecological challenges. High production cost and low yield are main drawbacks of commercial hydrogen production methods. Hydrogen production by biological methods helps to overcome these issues owing to its merit such as cost-effective, non-pollutant, recyclability and efficiency in energy conversion. Research has been conducted in utilizing cyanobacteria and algal species for producing biohydrogen utilizing solar light and other sources. Developments have been made for improving biohydrogen productivity through genetic and metabolic engineering. This review outlines the importance of biohydrogen and the constraints in producing biohydrogen in detail. Biohydrogen production can be facilitated using photolysis, fermentation and electrochemical processes. Bioreactors can be used effectively with specific designs and configuration for increasing productivity. The challenges faced during biological production and methods to overcome those demerits are also included for bringing the uncharted principles for producing biohydrogen in an efficient method.     

A state of the art review on biomass processing and conversion technologies to produce hydrogen and its recovery via membrane separation

Hydrogen is a zero-emission green fuel containing sufficient energy potentially suitable for electricity generation. Currently, large quantities of hydrogen are produced using classical fossil fuels. Nevertheless, the finite quantities of these resources have compelled the global community to look into using more sustainable and environmentally friendly resources such as bio-based waste. There are several approaches, to convert biomass to hydrogen, among which the thermochemical and biological processes are considered as the most important ones. The aim of this review paper is twofold, namely, (a) to evaluate hydrogen production and biomass processing methods to give a better insight into their potential merits and identify gaps for sustainable hydrogen generation, and (b) to evaluate current and future opportunities in membrane technology for hydrogen separation and purification from biomass processing. By fulfilling these gaps, the objectives of economical, sustainable, and environmentally-friendly resources for hydrogen production and separation can be recommended.     

Comparison of thermochemical,electrolytic, photoelectrolytic and photochemical solar-to-hydrogen production technologies

Hydrogen produced from solar energy is one of the most promising solar energy technologies that can significantly contribute to a sustainable energy supply in the future. This paper discusses the unique advantages of using solar energy over other forms of energy to produce hydrogen. Then it examines the latest research and development progress of various solar-to-hydrogen production technologies based on thermal, electrical, and photon energy. Comparisons are made to include water splitting methods, solar energy forms, energy efficiency, basic components needed by the processes, and engineering systems, among others. The definitions of overall solar-to-hydrogen production efficiencies and the categorization criteria for various methods are examined and discussed. The examined methods include thermochemical water splitting, water electrolysis, photoelectrochemical, and photochemical methods, among others. It is concluded that large production scales are more suitable for thermochemical cycles in order to minimize the energy losses caused by high temperature requirements or multiple chemical reactions and auxiliary processes. Water electrolysis powered by solar generated electricity is currently more mature than other technologies. The solar-to-electricity conversion efficiency is the main limitation in the improvement of the overall hydrogen production efficiency. By comparison, solar powered electrolysis, photoelectrochemical and photochemical technologies can be more advantageous for hydrogen fueling stations because fewer processes are needed, external power sources can be avoided, and extra hydrogen distribution systems can be avoided as well. The narrow wavelength ranges of photosensitive materials limit the efficiencies of solar photovoltaic panels, photoelectrodes, and photocatalysts, hence limit the solar-to-hydrogen efficiencies of solar based water electrolysis, photoelectrochemical and photochemical technologies. Extension of the working wavelength of the materials is an important future research direction to improve the solar-to-hydrogen efficiency.     

Hydrogen from solar energy,a clean energy carrier from a sustainable source of energy

Solar energy is going to play a crucial role in the future energy scenario of the world that conducts interests to solar-to-hydrogen as a means of achieving a clean energy carrier. Hydrogen is a sustainable energy carrier, capable of substituting fossil fuels and decreasing carbon dioxide (CO₂) emission to save the world from global warming. Hydrogen production from ubiquitous sustainable solar energy and an abundantly available water is an environmentally friendly solution for globally increasing energy demands and ensures long-term energy security. Among various solar hydrogen production routes, this study concentrates on solar thermolysis, solar thermal hydrogen via electrolysis, thermochemical water splitting, fossil fuels decarbonization, and photovoltaic-based hydrogen production with special focus on the concentrated photovoltaic (CPV) system. Energy management and thermodynamic analysis of CPV-based hydrogen production as the near-term sustainable option are developed. The capability of three electrolysis systems including alkaline water electrolysis (AWE), polymer electrolyte membrane electrolysis, and solid oxide electrolysis for coupling to solar systems for H₂ production is discussed. Since the cost of solar hydrogen has a very large range because of the various employed technologies, the challenges, pros and cons of the different methods, and the commercialization processes are also noticed. Among three electrolysis technologies considered for postulated solar hydrogen economy, AWE is found the most mature to integrate with the CPV system. Although substantial progresses have been made in solar hydrogen production technologies, the review indicates that these systems require further maturation to emulate the produced grid-based hydrogen.     

Effects of nanofluids on the photovoltaic thermal system for hydrogen production via electrolysis process

In this study the photovoltaic hybrid thermal system has been fabricated for an effective increase in production of electric output. Further the PV/T system also designed to produce the hydrogen from the water through electrolysis process. Several studies reported drastic reduction in the electric output due to high cell temperatures. Nevertheless, these effects are reduced by introduction of the nanoparticles. This study also examines the nanofluids MWCNT and Fe₂O₃ as the passive cooling agent for higher electric output production without any major energy loss. The nanoparticles are dispersed in the water at the optimum fashions to increase the thermal and electrical efficiency of the system. Both MWCNT and Fe₂O₃ nanofluids were passed to the hybrid system at the flow rate of 0.0075 kg/s and 0.01 kg/s. The highest electrical output and thermal efficiency has been obtained at 12.30 P.M. With regard to the production of hydrogen, the maximum productions were observed from 12.15 P.M. to 13.00 P.M.. Implementation of this method compensates the energy loss with superior electrical output compared to previous conventional method. By compelling the results, 0.01 kg/s subjected to be efficient on the electricity production and the hydrogen generation. Further, employing the electrolyzer as the attached to the hybrid system produces the hydrogen, which can be stored for future use as the promising source of energy.     

Hydrogen production through renewable and non-renewable energy processes and their impact on climate change

The urbanization and increase in the human population has significantly influenced the global energy demands. The utilization of non-renewable fossil fuel-based energy infrastructure involves air pollution, global warming due to CO₂ emissions, greenhouse gas emissions, acid rains, diminishing energy resources, and environmental degradation leading to climate change due to global warming. These factors demand the exploration of alternative energy sources based on renewable sources. Hydrogen, an efficient energy carrier, has emerged as an alternative fuel to meet energy demands and green hydrogen production with zero carbon emission has gained scientific attraction in recent years. This review is focused on the production of hydrogen from renewable sources such as biomass, solar, wind, geothermal, and algae and conventional non-renewable sources including natural gas, coal, nuclear and thermochemical processes. Moreover, the cost analysis for hydrogen production from each source of energy is discussed. Finally, the impact of these hydrogen production processes on the environment and their implications are summarized.     

Exergetic assessment of solar hydrogen production methods

Hydrogen is a sustainable fuel option and one of the potential solutions for the current energy and environmental problems. Its eco-friendly production is really crucial for better environment and sustainable development. In this paper, various types of hydrogen production methods namely solar thermal (high temperature and low temperature), photovoltaic, photoelecrtolysis, biophotolysis etc are discussed. A brief study of various hydrogen production processes have been carried out. Various solar-based hydrogen production processes are assessed and compared for their merits and demerits in terms of exergy efficiency and sustainability factor. For a case study the exergy efficiency of hydrogen production process and the hydrogen system is discussed in terms of sustainability.     

Potential importance of hydrogen as a future solution to environmental and transportation problems

Air pollution is a serious public health problem throughout the world, especially in industrialized and developing countries. In industrialized and developing countries, motor vehicle emissions are major contributors to urban air quality. Hydrogen is one of the clean fuel options for reducing motor vehicle emissions. Hydrogen is not an energy source. It is not a primary energy existing freely in nature. Hydrogen is a secondary form of energy that has to be manufactured like electricity. It is an energy carrier. Hydrogen has a strategic importance in the pursuit of a low-emission, environment-benign, cleaner and more sustainable energy system. Combustion product of hydrogen is clean, which consists of water and a little amount of nitrogen oxides. Hydrogen has very special properties as a transportation fuel, including a rapid burning speed, a high effective octane number, and no toxicity or ozone-forming potential. It has much wider limits of flammability in air than methane and gasoline. Hydrogen has become the dominant transport fuel, and is produced centrally from a mixture of clean coal and fossil fuels (with C-sequestration), nuclear power, and large-scale renewables. Large-scale hydrogen production is probable on the longer time scale. In the current and medium term the production options for hydrogen are first based on distributed hydrogen production from electrolysis of water and reforming of natural gas and coal. Each of centralized hydrogen production methods scenarios could produce 40 million tons per year of hydrogen. Hydrogen production using steam reforming of methane is the most economical method among the current commercial processes. In this method, natural gas feedstock costs generally contribute approximately 52–68% to the final hydrogen price for larger plants, and 40% for smaller plants, with remaining expenses composed of capital charges. The hydrogen production cost from natural gas via steam reforming of methane varies from about 1.25 US$/kg for large systems to about 3.50 US$/kg for small systems with a natural gas price of 6 US$/GJ. Hydrogen is cheap by using solar energy or by water electrolysis where electricity is cheap, etc.     

Development and environmental impact of hydrogen supply chain in Japan: Assessment by the CGE-LCA method in Japan with a discussion of the importance of biohydrogen

Hydrogen is an attractive and clean source of energy with a high energy content and environmentally friendly production using green power. Hydrogen is therefore considered to be one of the future alternatives to fossil fuels that can limit the damage done by climate change. A dynamic GTAP model with LCA method is utilized herein in this investigation to forecast the development of the hydrogen supply chain and CO₂ emissions in Japan. The supply chain incorporates six hydrogen-related industries – biohydrogen, steam reforming, electrolysis, hydrogen fuel cell vehicles (HFCV), hydrogen fuel cells (HFC), and hydrogen fueling stations.     

Hydrogen release from a metal hydride tank with phase change material jacket and coiled-tube heat exchanger

Hydrogen fuel cells are received increasingly wide attention in order to develop green ships and reduce greenhouse gas emissions in the field of waterway transportation. Metal hydrides (MHs) can be used to store hydrogen for green ships due to their high volumetric storage capacity and safety. Various measures should be considered in the design and manufacture process of the MH reactor to strengthen its performance of heat and mass transfer and obtain an acceptable hydrogen storage capacity. In this work, LaNi₅ hydride is used as the hydrogen storage material and packed in the reactor. A basic axisymmetric numerical model for the hydrogen storage system without a heat exchanger has been developed and proved to be effective through the comparison between its simulation results and the published data during dehydriding. A hybrid heat exchanger, which is consisted of a phase change material (PCM) jacket and a coiled-tube, has been applied into the hydrogen storage system to relieve the thermal effect of MH in the dehydriding process on system performance. Effects of the heat transfer coefficient between the circulating heating water in the coil-tube and the MH bed, the temperature of circulating heating water and the pressure at the outlet on the dehydriding performance have been investigated. Based on parametric study, the relationships among the average dehydriding rate, the heat transfer coefficient, the heating water temperature and the outlet pressure have been found and fitted as simple equations. These fitted equations can be considered as a reference, which provides an important method to effectively control the dehydriding rate in order to satisfy the fuel requirement of the power unit and ensure the safe navigation of green ships in the future.     

可再生能源发电制绿氢和氢能储运技术现状与发展分析

氢能已纳入我国能源发展战略。绿氢作为一种绿色二次能源,能够助推实现“双碳”目标。氢气制备和储运是氢能产业链的关键环节。重点阐述了电解水制绿氢和氢能储运的技术类型与发展现状,并对其应用前景和发展趋势进行了分析;提出氢气生产成本和储运方式是限制氢大规模部署的主要技术瓶颈;最后为传统电力企业进入绿氢制备和储运产业提供了一些思考和建议。     

Integrated biological hydrogen production

Biological systems offer a variety of ways by which to generate renewable energy. Among them, unicellular green algae have the ability to capture the visible portion of sunlight and store the energy as hydrogen (H₂). They hold promise in generating a renewable fuel from nature's most plentiful resources, sunlight and water. Anoxygenic photosynthetic bacteria have the ability of capturing the near infrared emission of sunlight to produce hydrogen while consuming small organic acids. Dark anaerobic fermentative bacteria consume carbohydrates, thus generating H₂ and small organic acids. Whereas efforts are under way to develop each of these individual systems, little effort has been undertaken to combine and integrate these various processes for increased efficiency and greater yields. This work addresses the development of an integrated biological hydrogen production process based on unicellular green algae, which are driven by the visible portion of the solar spectrum, coupled with purple photosynthetic bacteria, which are driven by the near infrared portion of the spectrum. Specific methods have been tested for the cocultivation and production of H₂ by the two different biological systems. Thus, a two-dimensional integration of photobiological H₂ production has been achieved, resulting in better solar irradiance utilization (visible and infrared) and integration of nutrient utilization for the cost-effective production of substantial amounts of hydrogen gas. Approaches are discussed for the cocultivation and coproduction of hydrogen in green algae and purple photosynthetic bacteria entailing broad utilization of the solar spectrum. The possibility to improve efficiency even further is discussed, with dark anaerobic fermentations of the photosynthetic biomass, enhancing the H₂ production process and providing a recursive link in the system to regenerate some of the original nutrients.     

Analysis of the yield and production cost of large-scale electrolytic hydrogen from different solar technologies and under several Moroccan climate zones

The objective of this paper is to conduct an analysis of the green hydrogen production by the mean of water electrolysis from different solar energy systems and under different climate conditions in Morocco. To this end, simulation of four solar power plants configurations -with a nominal capacity of 100 MW_e from different technologies (fixed PV, 1 axis tracking PV, 2 axis tracking PV, and Stirling Dish) coupled with a PEM electrolyzer has been done. For the sake of precision, 3 years average of high quality meteorological data measured in-situ and at 5 different locations were used as simulation inputs. To have an idea about the potential of Morocco in the green hydrogen production market, we benchmarked the simulation results against the ones from Almeria, Spain and Stellenbosch, South Africa. Results show that for almost all sites, the 1 axis tracking PV system is the optimal technology -from techno-economic aspect-for green Hydrogen production in Morocco, even though the 2 axis tracking PV systems can generate the highest amounts of hydrogen (~4500 Tons/year), the fixed PV has the lowest LCOH₂ (5.8 $/Kg) and the Stirling Dish is the most efficient one (~12%). Besides, Morocco can be considered as a very competitive country for green hydrogen production (especially for PV technology) with an LCO_H2 of 5.57 $/Kg, against 5,96$/Kg in Southern Spain and 6,51$/Kg for south Africa.