Estimating global production and supply costs for green hydrogen and hydrogen-based green energy commodities

Green energy commodities are expected to be central in decarbonising the global energy system. Such green energy commodities could be hydrogen or other hydrogen-based energy commodities produced from renewable energy sources (RES) such as solar or wind energy. We quantify the production cost and potentials of hydrogen and hydrogen-based energy commodities ammonia, methane, methanol, gasoline, diesel and kerosene in 113 countries. Moreover, we evaluate total supply costs to Germany, considering both pipeline-based and maritime transport. We determine production costs by optimising the investment and operation of commodity production from dedicated RES based on country-level RES potentials and country-specific weighted average costs of capital. Analysing the geographic distribution of production and supply costs, we find that production costs dominate the supply cost composition for liquid or easily liquefiable commodities, while transport costs dominate for gaseous commodities. In the case of Germany, importing green ammonia could be more cost-efficient than domestic production from locally produced or imported hydrogen. Green ammonia could be supplied to Germany from many regions worldwide at below the cost of domestic production, with costs ranging from 624 to 874 $/t NH₃ and Norway being the cheapest supplier. Ammonia production using imported hydrogen from Spain could be cost-effective if a pan-European hydrogen pipeline grid based on repurposed natural gas pipelines exists.     

Design of a novel flat-plate photobioreactor system for green algal hydrogen production

Some green microalgae have the ability to harness sunlight to photosynthetically produce molecular hydrogen from water. This renewable, carbon-neutral process has the additional benefit of sequestering carbon dioxide and accumulating biomass during the algal growth phase. We document the details of a novel one-litre vertical flat-plate photobioreactor that has been designed to facilitate green algal hydrogen production at the laboratory scale. Coherent, non-heating illumination is provided by a panel of cool-white light-emitting diodes. The reactor body consists of two compartments constructed from transparent polymethyl methacrylate sheets. The primary compartment holds the algal culture, which is agitated by means of a recirculating gas-lift. The secondary compartment is used to control the temperature of the system and the wavelength of radiation. The reactor is fitted with probe sensors that monitor the pH, dissolved oxygen, temperature and optical thickness of the algal culture. A membrane-inlet mass spectrometry system has been developed and incorporated into the reactor for dissolved hydrogen measurement and collection. The reactor is hydrogen-tight, modular and fully autoclaveable.     

Two-step thermochemical electrolysis: An approach for green hydrogen production

Electrolysis and thermochemical water splitting are approaches to produce green hydrogen that use either an electrical potential (electrolysis) or a chemical potential (thermochemical water splitting) to split water. Electrolysis is technologically mature when applied at low temperatures, but it requires large quantities of electrical energy. In contrast to electrolysis, thermochemical water splitting uses thermal energy, as thermal energy can typically be supplied at a lower unit cost than electrical energy using concentrating solar power. Thermochemical water splitting, however, typically suffers from high thermal losses at the extremely high process temperatures required, substantially increasing the total energy required. We show how, by combining electrical and chemical potentials, a novel and cost-efficient water splitting process can be envisioned that overcomes some of the challenges faced by conventional electrolysis and thermochemical water splitting. It uses a mixed ionic and electronic conducting perovskite with temperature-dependent oxygen non-stoichiometry as an anode in an electrolyzer. If solar energy is used as the primary source of all energy required in the process, the cost of the energy required to produce hydrogen could be lower than in high-temperature electrolysis by up to 7%.     

Prospects for the production of green hydrogen: Review of countries with high potential

The article provides a review of the current hydrogen production and the prospects for the development of the production of “green” hydrogen using renewable energy sources in various countries of the world that are leaders in this field. The potential of hydrogen energy in such countries and regions as Australia, the European Union, India, Canada, China, the Russian Federation, United States of America, South Korea, the Republic of South Africa, Japan and the northern countries of Africa is considered. These countries have significant potential for the production of hydrogen and “green” hydrogen, in particular through mining of fossil fuels and the use of renewable energy sources. The quantitative indicators of the production of “green” hydrogen in the future and the direction of its export are considered; the most developed hydrogen technologies in these countries are presented. The production of “green” hydrogen in most countries is the way to transition from the consumption of fossil fuels to the clean energy of the future, which will significantly improve the environmental situation, reduce greenhouse gas emissions and improve the energy independence of the regions.     

Green hydrogen production potential for developing a hydrogen economy in Pakistan

Pakistan's energy crisis can be diminished through the use of Renewable and alternative sources of energy. Hydrogen as an energy vector is likely to replace the fossil fuels in the future owing to the political, financial and environmental factors associated with the latter. In this regard it is imperative that conscious effort is directed towards the production of hydrogen from Renewable resources. Renewable energy resources are abundantly available in Pakistan. The need to produce Hydrogen from Renewable resources in Pakistan (or any developing economy) is investigated because it is possible to store vast amount of intermittent renewable energy for later use. Thus the introduction of Hydrogen in the energy supply chain implies the start of a Pakistan Hydrogen Economy. Many nations have developed the Hydrogen Energy Roadmap, and if Pakistan has to follow suite it is only possible through the employment of Renewable energy resources. This study estimates the potential of different Renewable resources available in Pakistan i.e. Solar, Wind, Geothermal, Biomass and Municipal Solid waste. An estimate is then made for the potential of producing hydrogen from various established technologies from each of these Renewable resources. A number of reviews have been published stating the availability and usage of Renewable energy in Pakistan; however no specific study has been focused on the use of Renewable resources for developing a Hydrogen economy or a power-to-gas system in Pakistan. This study concludes that that Biomass is the most feasible feedstock for developing a Hydrogen supply chain in Pakistan with a potential to generate 6.6 million tons of Hydrogen annually, followed by Solar PV that has a generation potential of 2.8 million tons and then Municipal solid waste with a capacity of 1 million ton per annum.     

Exergy analyses of green hydrogen production methods from biogas-based electricity and sewage sludge

In this study, five models are considered for the use of biogas-based electricity and sewage sludge obtained from a municipal wastewater treatment plant for green hydrogen production. These models include alkaline, PEM, high temperature water electrolysis, alkaline hydrogen sulfide electrolysis and dark fermentation biohydrogen production processes. Energy and exergy analyses are performed on these models by applying thermodynamic procedures and the results are compared. The daily hydrogen production rates of the models are found as 594, 625.4, 868.6, 10.8 and 56.74 kg and the exergetic efficiencies of the models are calculated as 19.81, 20.66, 25.83, 24.86 and 60.54%, respectively. In terms of the exergetic efficiency, the dark fermentation biohydrogen production process is found to be superior to the other models, followed by the high temperature steam electrolysis process. This paper aims to determine the most appropriate model for a wastewater treatment plant among the considered models in terms of exergy efficiency.     

Green methods for hydrogen production

This paper discusses environmentally benign and sustainable, as green, methods for hydrogen production and categorizes them based on the driving sources and applications. Some potential sources are electrical, thermal, biochemical, photonic, electro-thermal, photo-thermal, photo-electric, photo-biochemical, and thermal-biochemical. Such forms of energy can be derived from renewable sources, nuclear energy and from energy recovery processes for hydrogen production purposes. These processes are analyzed and assessed for comparison purposes. Various case studies are presented to highlight the importance of green hydrogen production methods and systems for practical applications.     

A newly isolated green alga, Tetraspora sp. CU2551, from Thailand with efficient hydrogen production

A novel unicellular hydrogen-producing green alga was isolated from fresh water pond in Pathumthani province, Thailand. Under light microscope, this alga was identified as belonging to the genus Tetraspora. Phylogenetic analysis of 18S rRNA sequence revealed that the green alga, identified as Tetraspora sp. CU2551, is closely related to other unicellular green algal species. Tetraspora sp. CU2551 had the shortest doubling time when grown in Tris-acetate-phosphate (TAP) medium under a light intensity of 48–92 μE/m²/s and a temperature of 36 °C. Hydrogen production increased with increasing pH from 5.75 to 9.30; however, almost no production was observed at a pH of 5.25. Addition of 0.5 mM β-mercaptoethanol to the TAP medium stimulated hydrogen production about two-fold. During the hydrogen production phase, the use of TAP medium lacking both nitrogen and sulfur resulted in about 50% increase in the hydrogen production. This was in contrast to only a small increase in the production when either nitrogen or sulfur was omitted in TAP medium. The stimulation of hydrogen production by 0.5 mM β-mercaptoethanol under nitrogen- and sulfur-deprived conditions occurred only when the cells were grown at a light intensity lower than 5 μE/m²/s with no effects at higher intensities. Maximal calculated hydrogen production, 17.3–61.7 μmol/mg Chl a/h, is a very high production rate compared to other green algae and makes Tetraspora sp. CU2551 an interesting model strain for photobiological hydrogen production.     

Development and environmental impact of hydrogen supply chain in Japan: Assessment by the CGE-LCA method in Japan with a discussion of the importance of biohydrogen

Hydrogen is an attractive and clean source of energy with a high energy content and environmentally friendly production using green power. Hydrogen is therefore considered to be one of the future alternatives to fossil fuels that can limit the damage done by climate change. A dynamic GTAP model with LCA method is utilized herein in this investigation to forecast the development of the hydrogen supply chain and CO₂ emissions in Japan. The supply chain incorporates six hydrogen-related industries – biohydrogen, steam reforming, electrolysis, hydrogen fuel cell vehicles (HFCV), hydrogen fuel cells (HFC), and hydrogen fueling stations.     

Process simulation and optimization for enhanced biophotolytic hydrogen production from green algae using the sulfur deprivation method

This article explores the modeling, simulation and optimization of a biophotolytic cyclic process for enhanced hydrogen production from microalgae, employing the sulfur deprivation method. To achieve sulfur deprivation, each process cycle contained two temporally separated steps of sulfur-controlled algae growth and sulfur-deprived anaerobic hydrogen production.Reaction kinetics were modeled via an empirical logistic model. Reaction times, sulfate concentrations, and medium pH levels of each cycle were controlled to optimize the rate and yield of hydrogen production. Consequently, 65% and 23% improved values were obtained, respectively, with a smaller total process time (?11%), higher ratio of algae growth-to-hydrogen production time (29% vs. 21%), buffered pH (7.8), controlled sulfate injection and intermediary algae concentrations. Two- and 15-times higher hydrogen yields were obtained for 2- and 12-times lower initial algae concentrations. The proposed method is a significant tool for the design and optimization of a process for enhanced hydrogen production from microalgae.     

Investigation of the effect of chemistry models on the numerical predictions of the supersonic combustion of hydrogen

In this numerical study, the influence of chemistry models on the predictions of supersonic combustion in a model combustor is investigated. To this end, 3D, compressible, turbulent, reacting flow calculations with a detailed chemistry model (with 37 reactions and 9 species) and the Spalart-Allmaras turbulence model have been carried out. These results are compared with earlier results obtained using single step chemistry. Hydrogen is used as the fuel and three fuel injection schemes, namely, strut, staged (i.e., strut and wall) and wall injection, are considered to evaluate the impact of the chemistry models on the flow field predictions. Predictions of the mass fractions of major species, minor species, dimensionless stagnation temperature, dimensionless static pressure rise and thrust percentage along the combustor length are presented and discussed. Overall performance metrics such as mixing efficiency and combustion efficiency are used to draw inferences on the nature (whether mixing- or kinetic-controlled) and the completeness of the combustion process. The predicted values of the dimensionless wall static pressure are compared with experimental data reported in the literature. The calculations show that multi step chemistry predicts higher and more wide spread heat release than what is predicted by single step chemistry. In addition, it is also shown that multi step chemistry predicts intricate details of the combustion process such as the ignition distance and induction distance.     

Clean fuel options with hydrogen for sea transportation: A life cycle approach

In this study, two potential fuels, namely hydrogen and ammonia, are alternatively proposed to replace heavy fuel oils in the engines of sea transportation vehicles. A comparative life cycle assessments of different types of sea transportation vehicles are performed to investigate the impacts of fuel switching on the environment. The entire transport life cycle is considered in the life cycle analyses consisting of production of freight ship and tanker; operation of freight ship and tanker; construction and land use of port; operation, maintenance and disposal of port; production and transportation of these clean fuels. Various environmental impact categories, such as global warming, marine sediment ecotoxicity, marine aquatic ecotoxicity, acidification and ozone layer depletion are selected in order to examine the diverse effects of switching to clean fuels in maritime transportation. As a carbon-free fuel for marine vehicle engines, ammonia and hydrogen, yield considerably lower global warming impact during the operation. Furthermore, numerous production methods of alternative fuels are evaluated to comparatively show environmentally benign options. The results of this study demonstrate that if ammonia is even partially utilized in the engines of ocean tankers as dual fuel (with heavy fuel oils), overall life cycle greenhouse gas emissions per tonne-kilometer can be decreased about 27% whereas it can be decreased by about 40% when hydrogen is used as dual fuel.     

Exergetic assessment of solar hydrogen production methods

Hydrogen is a sustainable fuel option and one of the potential solutions for the current energy and environmental problems. Its eco-friendly production is really crucial for better environment and sustainable development. In this paper, various types of hydrogen production methods namely solar thermal (high temperature and low temperature), photovoltaic, photoelecrtolysis, biophotolysis etc are discussed. A brief study of various hydrogen production processes have been carried out. Various solar-based hydrogen production processes are assessed and compared for their merits and demerits in terms of exergy efficiency and sustainability factor. For a case study the exergy efficiency of hydrogen production process and the hydrogen system is discussed in terms of sustainability.     

Potential of green ammonia production in India

The threat of climate change is forcing the world to decarbonize all economic sectors. Ammonia primarily used for fertilizer production and a potential, ‘hydrogen carrier’ currently accounts for ~27% of global hydrogen consumption and ~1% of global greenhouse gas emissions. In this analysis, we assess the techno-economic potential of ammonia production using onshore wind, open-field photovoltaic and batteries for both domestic usage and export scenarios in India, which is currently one of the world's largest producer and importer of ammonia. Our results reveal that India's potential can comfortably satisfy global ammonia demand with lowest ammonia costs of 723 EUR/t_NH3 and 765 EUR/t_NH3 for the domestic and export scenario, respectively. To compete with conventional ammonia production a carbon tax of 224–335 €/t_CO2 would be required. Finally, costs of shipping liquid hydrogen and the ‘hydrogen carrier’ ammonia are similar here giving other economic, environmental and safety factors higher relevance.     

Evaluation of DCX converters for off-grid photovoltaic-based green hydrogen production

Photovoltaic (PV) to electrolyzer power systems are an attractive research topic since the PV produced power can be optimized by skipping power conversion into AC and producing a direct DC-DC interface. Existing DC-DC power conversion systems to directly interface the PV generation and Hydrogen (H₂) electrolyzer are mainly based in interleaved structures or multi-resonant converters. Soft-switching characteristics are also suitable for these conversion topologies and DCX converters are then serious candidates to be used. DCX provides an isolated high efficiency solution but the DCX-based two-stage converter topology must be optimized in order to obtain better efficiency and energy yield. In this work a detailed comparison of DCX topologies is given for a PV to H₂ application. The proposed optimized system is validated through simulation in a multi-string electrolysis system, showing the relevance of the solution for this application. The proposed approach reaches a global maximum efficiency of 98.2%.     

Biocatalyzed hydrogen production in a continuous flow microbial fuel cell with a gas phase cathode

A single liquid chamber microbial fuel cell (MFC) with a gas-collection compartment was continuously operated under electrically assisted conditions for hydrogen production. Graphite felt was used for anode construction, while the cathode was made of Pd/Pt coated Toray carbon fiber paper with a catalyst loading of 0.5 mg cm⁻². To achieve hydrogen production, the MFC was connected to a power supply and operated at voltages in a range of 0.5–1.3 V. Either acetate or glucose was used as a source of carbon. At an acetate load of 1.67 g (L_A d)⁻¹, the volumetric rate of hydrogen production reached 0.98 L_STP (L_A d)⁻¹ when a voltage of 1.16 V was applied. This corresponded to a hydrogen yield of 2 mol (mol-acetate)⁻¹ with a 50% conversion efficiency. Throughout the experiment, MFC efficiency was adversely affected by the metabolic activity of methanogenic microorganisms, which competed with exoelectrogenic microorganisms for the carbon source and consumed part of the hydrogen produced at the cathode.     

A modified steam-methane-reformation reaction for hydrogen production

Hydrogen is mostly produced by the Steam Methane Reforming (SMR) reaction which adds many tonnes of carbon emissions to the environment for each tonne of hydrogen. A modified scheme for carbon-emission free production of hydrogen, which involves sodium hydroxide, methane and steam, has been explored here. The modification of the SMR reaction isCH₄ + 2NaOH + H₂O = Na₂CO₃ + 4H₂The modified reaction has several advantages: it does not require catalysis, the temperature of reaction is considerably reduced and the products are industrially important. By this process, we can produce hydrogen without any carbon dioxide emission as shown in this theoretical and experimental study. The reaction has been studied in the temperature range of 873-1073 K in an open configuration for 30 min and at various methane and constant water vapor flow. It is determined that at a methane flow rate of 25 ml/min the reaction is 98% complete at 873 K.     

Enhanced polyhydroxybutyrate production through incorporation of a hydrogen fuel cell and electro-fermentation system

The integration of a hydrogen fuel cell with an electro-fermentation system represents a novel approach for improving polyhydroxybutyrate (PHB) accumulation in Ralstonia eutropha H16, using a sustainable energy source. In this study, electro-fermentation noticeably affected cell growth, biomass production, substrate consumption, and PHB accumulation. Final residual biomass concentrations and maximum specific growth rates were enhanced by supplying a 10-mA electric current. Furthermore, a remarkable enhancement in PHB content (30% higher than control) was achieved by redox-mediated electro-fermentation with a 10 mA electric current, upon the addition of a redox mediator. Two-stage cultivation limited the growth suppression caused by redox-mediated electro-fermentation, and also increased the maximum PHB productivity of the system. The additional electrons supplied upon supplementation of the redox mediator accelerated the glycolytic pathway and redox cycling of NADH/NAD⁺, led to a spontaneous boost for adenosine triphosphate (ATP) generation, and further facilitated the biosynthesis of PHB.     

Potential methods for geothermal-based hydrogen production

In this study, four potential methods are identified for geothermal-based hydrogen production, namely, (i) directly from the geothermal steam, (ii) through conventional water electrolysis using the electricity generated from geothermal power plant, (iii) using both geothermal heat and electricity for high temperature steam electrolysis and/or hybrid processes, (iv) using the heat available from geothermal resource in thermochemical processes to disassociate water into hydrogen and oxygen. Here we focus on relatively low-temperature thermochemical and hybrid cycles, due to their greater application possibility, and examine them as a potential option for hydrogen production using geothermal heat. We also present a brief thermodynamic analysis to assess their performance through energy and exergy efficiencies for comparison purposes. The results show that these cycles have good potential and become attractive due to the overall system efficiencies over 50%. The copper–chlorine cycle is identified as a highly promising cycle for geothermal hydrogen production. Furthermore, three types of industrial electrolysis methods, which are generally considered for hydrogen production currently, are also discussed and compared with the above mentioned cycles.     

Life cycle assessment of various hydrogen production methods

A comprehensive life cycle assessment (LCA) is reported for five methods of hydrogen production, namely steam reforming of natural gas, coal gasification, water electrolysis via wind and solar electrolysis, and thermochemical water splitting with a Cu–Cl cycle. Carbon dioxide equivalent emissions and energy equivalents of each method are quantified and compared. A case study is presented for a hydrogen fueling station in Toronto, Canada, and nearby hydrogen resources close to the fueling station. In terms of carbon dioxide equivalent emissions, thermochemical water splitting with the Cu–Cl cycle is found to be advantageous over the other methods, followed by wind and solar electrolysis. In terms of hydrogen production capacities, natural gas steam reforming, coal gasification and thermochemical water splitting with the Cu–Cl cycle methods are found to be advantageous over the renewable energy methods.