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1.
Yingping Zou Bo Peng Bo Liu Yongfang Li Yuehui He Kechao Zhou Chunyue Pan 《应用聚合物科学杂志》2010,115(3):1480-1488
Three alternating conjugated copolymers of cyanosubstituted poly(p‐phenylene vinylene) (CN–PPV) with phenylene ethynylene and thienylene vinylene moieties, P1, P2, and P3, were synthesized via cross‐coupling polycondensation with Pd(PPh3)2Cl2 as a catalyst. Their structures were confirmed by 1H‐NMR, IR spectroscopy, elemental analysis, and gel permeation chromatography, and the thermal, photophysical, and electrochemical properties of the copolymers were also investigated. The incorporation of a triple bond into the CN–PPV backbone led to higher reduction potentials, which corresponded to lower lowest unoccupied molecular orbital energy levels. The three copolymers possessed broader absorption spectra, especially copolymer P3 with its polymerization units containing two thiophene rings, which showed the broadest absorption spectrum, from 300 to 710 nm. Their high electron affinities, broad absorptions, and relatively higher oxidation potentials make the copolymers potentially good electron‐acceptor material for use in photovoltaic devices. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
2.
A series of poly(p‐phenylene vinylene) (PPV) derivatives with phenylene vinylene side chains (branched PPVs), PPV0, PPV1, PPV2, and PPV3, were synthesized by the Heck coupling reaction and characterized by TGA, absorption spectra, photoluminescence (PL) spectra, and electrochemical cyclic voltammetry. The branched PPVs showed two absorption peaks in the UV–vis region, corresponding to the conjugated side chains (UV absorption) and the main chains (the visible absorption). Especially the absorption spectrum of PPV3 covers a broad wavelength range from 300 to 500 nm. Introducing the electron‐donating alkoxy substituents on the PPV main chains and increasing the content of the alkoxy groups lead to bathochromic shift of both absorption and PL spectra from PPV1 to PPV2 to PPV3. The onset oxidation potential of the branched PPVs is lower by 0.1–0.2 V than that of PPV, indicating that the electron‐donating ability of the branched PPVs enhanced in comparison with that of PPV. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
3.
Narrow‐band‐gap 2,5‐thienylene‐divinylene (ThV) units were incorporated into the poly(fluorene vinylene) backbone via a Gilch reaction as an energy trap with various feed ratios; this yielded pronounced changes in the electrochemical and optical properties of the material. The energy levels of the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of the polymers {poly(9,9‐di‐iso‐octylfluorene vinylene) [poly(fluorene vinylene‐co‐thiophene vinylene (FV))], C1, and C2 } were estimated to be ?5.53 to ?5.10 eV and ?2.98 to ?2.84 eV, respectively, by cyclic voltammetry measurements. In comparison with poly(FV), the HOMO energy levels of polymers poly(fluorene vinylene‐co‐thiophene vinylene (FV) (90 : 10) ( C1 ) and poly(fluorene vinylene‐co‐thiophene vinylene (FV) (80 : 20) ( C2 ) were significantly increased, but their LUMO energy levels were slightly decreased. The optical properties were investigated by absorption and emission spectra of the polymers. The good spectral overlap between the emission of poly(FV) and the absorption of polymers C1 and C2 revealed a sufficient energy transfer from the majority of 9,9‐di‐iso‐octylfluorene vinylene units to the minority of ThV units. The reduction of self‐absorption losses of polymers C1 and C2 due to spectral separation caused by the incorporation of ThV units could be indirectly confirmed by nonlinear optical (NLO) properties. The result of the NLO properties of the polymers showed that the third‐order NLO coefficients of poly(FV), C1, and C2 were 8.1 × 10?10, 1.35 × 10?9, and 1.51 × 10?9 esu, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
4.
Poly(p‐phenylene vinylene) (PPV) derivatives are an important class of conjugated polymers, known for their applications as electroluminescent materials for light‐emitting devices and sensors. These derivatives are highly susceptible to photodegradation by the combined action of oxygen and light. Here, the use of various commercial polymers as protective coatings against the photodegradation of PPV derivatives was explored. Cast films of two similar PPV derivatives, poly[(2‐methoxy‐5‐n‐hexyloxy)‐p‐phenylene vinylene] and poly[2‐methoxy‐5‐(2‐ethylhexyloxy)‐p‐phenylene vinylene], were submitted to photodegradation by exposure to white light under atmospheric conditions in order to verify if the type of side chain (linear or branched) had an effect on the photodegradation. No significant differences in the photodegradation behaviour between the two polymers were noticed. The following commercial polymers were tested as protective coatings for the PPV derivative cast films: 99 and 80% hydrolysed poly(vinyl alcohol) (PVA) and starch. The best results were achieved using coatings of 99% hydrolysed PVA, which increased about 700 times the time necessary for complete degradation of the PPV derivative films. The results show the effectiveness of this coating in minimizing and, possibly, controlling the effects of the photodegradation of PPV derivative films, which can be useful in many applications, e.g. oxygen sensors. Copyright © 2009 Society of Chemical Industry 相似文献
5.
A light‐emitting partially conjugated hyperbranched polymer (2,5‐dimethoxy‐substituted hyperbranched poly(p‐phenylene vinylene), MOHPV) based on rigid fluorescent conjugated segments, 2,5‐dimethoxy‐substituted distyrylbenzene (a derivative of oligo‐poly(p‐phenylene vinylene)), and flexible non‐conjugated spacers, trioxymethylpropane, was synthesized via an A2 + B3 approach. The weight‐average molecular weight was 2.48 × 104 g mol?1. The introduction of two methoxy groups into central rings of the oligo‐poly(p‐phenylene vinylene) imparted to MOHPV better solubility in common organic solvents and processability than its analogues reported in our previous work, especially the fully conjugated hyperbranched polymers. The effect of the molar ratio of monomer A2 to monomer B3 on the molecular weight and molecular weight distribution was investigated. A single‐layer light‐emitting diode was fabricated employing MOHPV as an emitter. A double‐layer light‐emitting diode was also fabricated by doping an electron transport material, 2‐(4‐biphenylyl)‐5‐phenyl‐1,3,4‐oxadiazole, into the emitting layer and inserting a thin layer of tri(8‐hydroxyquinoline)aluminium as electron‐transporting/hole‐blocking layer. A maximum luminance of 1500 cd m?2 at 12 V and a maximum electroluminescence efficiency of 1.38 cd A?1 at 14 mA cm?3, which are approximately 43.5 and 12.9 times greater, respectively, than those of the single‐layer device, were achieved. The synthetic simplicity, excellent solubility and solution processability, and less of a propensity to aggregation make MOHPV a novel type of emitter for polymer light‐emitting displays. Copyright © 2010 Society of Chemical Industry 相似文献
6.
Kotohiro Nomura 《大分子材料与工程》2019,304(9)
Acyclic diene metathesis polymerization using ruthenium–carbene catalysts affords defect‐free, high molecular weight poly(arylene vinylene)s containing all trans olefinic double bonds. The exclusive end‐functionalization in the resultant poly(fluorene vinylene)s or poly(phenylene vinylene)s can be attained by treating the vinyl end groups using a molybdenum–alkylidene catalyst/reagent (through olefin metathesis) followed by addition of various aldehydes (Wittig‐type coupling). Some of these end‐modified conjugated materials display unique emission properties, which are different from the original ones, through an interaction (energy transfer or structural change in the excited state) between the conjugated main chain and the end groups [oligo(thiophene)s, F‐BODIPY, etc.]. Exclusive synthesis of well‐defined, all‐trans end‐functionalized oligo(2,5‐dialkoxy‐1,4‐phenylene vinylene)s [(oligo(phenylene vinylene), alkoxy = O(CH2)2OSii Pr3, up to 31 repeat units] is demonstrated by adopting a stepwise synthetic approach (olefin metathesis and the subsequent Wittig‐type cleavage). It is clearly demonstrated that their optical properties (especially the fluorescence spectra including photoluminescence quantum yields) are strongly affected by the end groups as well as the conjugation repeat units. 相似文献
7.
Two novel phenyl‐substituted poly(p‐phenylene vinylene) derivatives, poly{2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐1,4‐phenylenevinylene} (EDP‐PPV) and poly{2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐5‐methoxy‐1,4‐phenylenevinylene} (EDMP‐PPV), and their copolymer, poly{2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐1,4‐phenylene‐vinylene‐co‐2‐[3′,4′‐(2″‐ethylhexyloxy)(3″,7″‐dimethyloctyloxy)benzene]‐5‐methoxy‐1,4‐phenylenevinylene} (EDP‐co‐EDMP‐PPV; 4:1, 1:1, and 1:4), were successfully synthesized according to the Gilch route. The structures and properties of the monomers and the resulting conjugated polymers were characterized with 1H‐NMR, 13C‐NMR, elemental analysis, gel permeation chromatography, thermogravimetric analysis, ultraviolet–visible absorption spectroscopy, and photoluminescence and electroluminescence (EL) spectroscopy. The EL polymers possessed excellent solubility in common solvents and good thermal stability with a 5% weight loss temperature of more than 380°C. The weight‐average molecular weights and polydispersity indices of EDP‐PPV, EDMP‐PPV, and EDP‐co‐EDMP‐PPV were 1.40–2.58 × 105, and 1.19–1.52, respectively. Double‐layer light‐emitting diodes with the configuration of indium tin oxide/polymer/tris(8‐hydroxyquinoline)aluminum/Al devices were fabricated, and EDP‐co‐EDMP‐PPV (1:1) showed the highest EL performance and exhibited a maximum luminance of 1050 cd/m2 at 19.5 V. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1259–1266, 2005 相似文献
8.
Chang‐Gyu Kim Sung‐Hoon Joo Cheol Hong Cheon Mi‐Yun Jeong Soon‐Wook Cha Byung‐Hee Sohn Jung‐Il Jin 《应用聚合物科学杂志》2006,100(1):307-317
Three new soluble polyconjugated polymers, all of which emitted blue light in photoluminescence and electroluminescence, were synthesized, and their luminescence properties were studied. The polymers were poly{1,1′‐biphenyl‐4,4′‐diyl‐[1‐(4‐t‐butylphenyl)]vinylene}, poly((9,9‐dioctylfluorene‐2,7‐diyl)‐alt‐{1,4‐phenylene‐[1‐(4‐t‐butylphenyl)vinylene‐1,4‐phenylene]}) [P(DOF‐PVP)], and poly([N‐(2‐ethyl) hexylcarbazole‐3,6‐diyl]‐alt‐{1,4‐phenylene‐[1‐(4‐t‐butylphenyl)]vinylene‐1,4‐phenylene}). The last two polymers had alternating sequences of the two structural units. Among the three polymers, P(DOF‐PVP) performed best in the light‐emitting diode devices of indium–tin oxide/poly(ethylenedioxythiophene) doped with poly(styrene sulfonate) (30 nm)/polymer (150 nm)/Li:Al (100 nm). This might have been correlated with the balance in and magnitude of the mobility of the charge carriers, that is, positive holes and electrons, and also the electronic structure, that is, highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels, of the polymers. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 307–317, 2006 相似文献
9.
Zhan'ao Tan Rupei Tang Erjun Zhou Youjun He Chunhe Yang Fu Xi Yongfang Li 《应用聚合物科学杂志》2008,107(1):514-521
A copolymer of dendronized poly(p‐phenylene vinylene) (PPV), poly{2‐[3′,5′‐bis (2′‐ethylhexyloxy) bnenzyloxy]‐1,4‐phenylene vinylene}‐co‐poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐1,4‐phenylene vinylene] (BE‐co‐MEH–PPV), was synthesized with the Gilch route to improve the electroluminescence and photovoltaic properties of the dendronized PPV homopolymer. The polymer was characterized by ultraviolet–visible absorption spectroscopy, photoluminescence spectroscopy, and electrochemical cyclic voltammetry and compared with the homopolymers poly{2‐[3′, 5′‐bis(2‐ethylhexyloxy) benzyloxy‐1,4‐phenylene vinylene} (BE–PPV) and poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐1,4‐phenylenevinylene] (MEH–PPV). Polymer light‐emitting diodes based on the polymers with the configuration of indium tin oxide (ITO)/poly(3,4‐ethylene dioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS)/polymer/Ca/Al were fabricated. The electroluminescence efficiency of BE‐co‐MEH–PPV reached 1.64 cd/A, which was much higher than that of BE–PPV (0.68 cd/A) and a little higher than that of MEH–PPV (1.59 cd/A). Photovoltaic properties of the polymer were studied with the device configuration of ITO/PEDOT : PSS/polymer : [6,6J‐phenyl‐C61‐butyric acid methyl ester] (PCBM)/Mg/Al. The power conversion efficiency of the device based on the blend of BE‐co‐MEH–PPV and PCBM with a weight ratio of 1 : 3 reached 1.41% under the illumination of air mass 1.5 (AM1.5) (80 mW/cm2), and this was an improvement in comparison with 0.24% for BE–PPV and 1.32% for MEH–PPV under the same experimental conditions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
10.
A series of novel porphyrin‐grafted poly (phenylene vinylene) derivatives, Porp‐RO‐PPV, were synthesized by a simple two‐step method. These copolymers contain conjugated poly(phenylene vinylene) derivatives as polymer backbone and covalently linked porphyrin units as side chain, which were confirmed by FTIR and 1H NMR, and used for photovoltaic devices. The thermal, optical properties and sensitizing effect, and photovoltaic properties have been investigated. The emission spectra of Porp‐RO‐PPV copolymers revealed the existence of strong energy transfer from PPV backbone to porphyrin units. The energy conversion efficiency (ηe) of photovoltaic devices based on Porp‐RO‐PPV+PCBM reached 0.33% (78.2 mW/cm2, AM1.5) and porphyrin units in the copolymers showed good sensitizing effect at low concentration. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
11.
Two poly(thiazole vinylene) derivatives, poly(4‐hexylthiazole vinylene) (P4HTzV) and poly(4‐nonylthiazole vinylene) (P4NTzV), were synthesized by Pd‐catalyzed Stille coupling method. The polymers are soluble in common organic solvents such as o‐dichlorobenzene and chloroform, and possess good thermal stability. P4HTzV and P4NTzV films exhibit broad absorption bands at 400–720 nm with an optical bandgap of 1.77 eV and 1.74 eV, respectively. The HOMO (the highest occupied molecular orbital) energy levels of P4HTzV and P4NTzV are ?5.11 and ?5.12 eV, respectively, measured by cyclic voltammetry. Preliminary results of the polymer solar cells based on P4HTzV : PC61BM ([6,6]‐phenyl‐C‐61‐butyric acid methyl ester) (1 : 1, w/w) show a power conversion efficiency of 0.21% with an open‐circuit voltage of 0.55 V and a short circuit current density of 1.11 mA cm?2, under the illumination of AM1.5G, 100 mW cm?2. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
12.
The effects of platinum metal nanoparticles on a conjugated polymer were investigated by monitoring the electronic structures and measuring the electrical properties of poly(p‐phenylene vinylene) (PPV) and PPV/Pt nanocomposites films. Enhanced current density in PPV/Pt nanocomposite films was obtained by the incorporation of Pt nanoparticles into the conjugated polymer PPV. This result agrees well with our observation of an increase in the electron affinity and an increase in roughness with increasing Pt nanoparticle content. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
13.
Bo Qu Zhongliang Jiang Zhijian Chen Lixin Xiao Di Tian Chao Gao Wei Wei Qihuang Gong 《应用聚合物科学杂志》2012,124(2):1186-1192
A new soluble polythiophene copolymer with thiophene‐vinylene conjugated side chain poly[3‐(5′‐octylthienylenevinyl) thiophene]‐thiophene (POTVTh‐Th) was successfully synthesized and characterized using NMR, UV‐visible spectroscopy, etc. To study the photovoltaic property of the copolymer, photovoltaic device of ITO/PEDOT:PSS/POTVTh‐Th:[6,6]‐phenyl C61‐butyric acid methyl ester (PC61BM) (weight ratio being 1 : 1)/LiF/Al was fabricated, in which POTVTh‐Th acted as the electron donor in the active layer. Under 100 mW/cm2 AM 1.5G simulated solar emission, the open‐circuit voltage and the short‐circuit current density of the device were 0.58 V and 2.50 mA/cm2, respectively. The power conversion efficiency and the fill factor of the photovoltaic device were evaluated to be 0.42% and 0.30. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
14.
Chunliang Lu Haiqiao Wang Xiaochen Wang Yongfang Li Teng Oiu Lifan He Xiaoyu Li 《应用聚合物科学杂志》2010,117(1):517-523
Via A2 + B4 and A2 + B3 [where A2 is 1,4‐distyrylol‐2,5‐butoxybenzene, B3 is 1,1,1‐tris‐(p‐tosyloxymethyl)‐propane, and B4 is pentaerythritol tetra(methyl benzene sulfonate)] approaches, we synthesized two kinds of partially conjugated hyperbranched polymers, hyperbranched polymer with 3 arms (HP1) and hyperbranched polymer with 4 arms (HP2), which had rigid conjugated segments [oligo‐poly(phenylene vinylene)] and flexible, nonconjugated spacers arranged alternately through ether bonds in the skeleton. The conjugated segments were modified by pendant butoxy groups, which imparted the resulting polymers with excellent solubility in common organic solvents and excellent film‐forming abilities. Fourier transform infrared and nuclear magnetic resonance spectroscopy were used to identify the structure of the monomers and polymers. Thermal property investigations showed that two polymers both had good thermal stability with their decomposition temperatures in the range 396–405°C and high glass‐transition temperatures, which are of benefit to the fabrication of high‐performance light‐emitting devices. The photophysical properties were studied, and the relative photoluminescence quantum efficiencies of HP1 and HP2 in dilute chloroform solution amounted to 56.8 and 49.3%, respectively. A brief light‐emitting diode device with a configuration of indium tin oxide/HP1/Ca/Al was fabricated, and its electroluminescence performance was studied. The brightness of the device reached an optimistic maximum of 190 cd/m2 at 8.2 V. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
15.
A series of conjugated (poly{N‐(2‐ethylhexyl)‐3,6‐carbazole–vinylene‐alt‐[(2,5‐bisphenyl)‐1,3,4‐oxadiazole]}) and nonconjugated (poly{N‐(2‐ethylhexyl)‐3,6‐carbazole–vinylene‐alt‐[(2,5‐bisphenol)‐1,3,4‐oxadiazole]}) and poly{9,9‐dihexyl‐2,7‐fluorene–vinylene‐alt‐[(2,5‐bisphenol)‐1,3,4‐oxadiazole]}) polymers containing oxadiazole and carbazole or fluorene moieties in the polymer backbone were synthesized with a multiple‐step procedure. The properties of the polymers, including the photophysical and electrochemical characteristics, could be fine‐tuned by adjustment of the components or structures in the polymer chains. The polymers were used to examine the hole‐injection/transport behavior as hole‐injection/hole‐transport layers in double‐layer indium tin oxide (ITO)/polymer/aluminum tris(8‐hydroxyquinoline)/LiF/Al devices by the determination of their energy levels. The effects of the polymers in these devices on the charge‐transport behavior were compared with a control device fabricated with poly(ethylenedioxythiophene) (PEDOT)–poly(styrene sulfonate) (PSS). Devices containing the synthesized polymers showed comparable adhesion to the ITO anode and good hole‐injection/transport performance. In addition, they exhibited higher electroluminescence over an identical range of current densities than the control device. This was attributed to the prevention of radiative exciton quenching caused by the PEDOT–PSS interfaces and the improvement of electron/exciton blocking due to the higher electron affinity of the synthesized polymers. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
16.
Conjugated polymers have been the subject of many studies because of their widespread applications in electronic and optoelectronic devices. Poly(p‐phenylene vinylene) is a leading semiconducting polymer in optical applications. This work is focused on the development of thin films of poly(p‐phenylene vinylene) by spin coating and their characterization with Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy to understand their changes. An empirical model has been developed to show the effect of the variables—the spin speed, polymer concentration, and spin time—on the film thickness. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
17.
Synthesis and characterization of alternating copolymers containing bipyridine and phenylene vinylene for fluorescent chemosensors
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Alternating copolymers containing bipyridine and phenylene vinylene were synthesized through a Wittig condensation reaction of their corresponding diphosphonium salts and dialdehydes. The molecular weights of the resulting polymers were relatively low because of the low solubility in the reaction solvents. The optical properties of the polymers were substantially affected by the repeating units of phenylene vinylene. The absorption spectra of the copolymers in the solid state exhibited a bathochromic shift compared to those carried out in solution. The effective conjugation length could be extended with the addition of Cu2+, Ni2+, and Zn2+ ions into the polymer solutions in a 1 : 1 ratio of the bipyridine to the phenylene vinylene units. All of the polymer solutions behaved as a turn‐off fluorescent chemosensor upon the addition of a variety of the metal ions. The sensing behavior to various metal ions revealed that the polymers were highly sensitive to the Cu2+, Ni2+, and Zn2+ ions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42795. 相似文献
18.
Arne Palmaerts Thomas J. Cleij Dirk Vanderzande Almantas Pivrikas Niyazi Serdar Sariciftci 《Polymer》2009,50(21):5007-6388
Considerable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers, i.e. poly(p-fluoranthene vinylene) (PFV) and its derivatives. This route is illustrated with three examples, i.e. unsubstituted PFV and functionalized hexyl-PFV and dodecyl-PFV. All polymers have been synthesized via the dithiocarbamate precursor route. Solubility was introduced by incorporation of alkyl side chains, which leads to a significantly enhanced purity and processability as compared to unsubstituted PFV. Under the applied electrochemical conditions PFV-type polymers demonstrate typical n-type behavior. Additional CELIV mobility measurements on dodecyl-PFV reveal an excellent electron mobility, μe = 1.4 × 10−4 cm2/Vs. Hence, poly(p-fluoranthene vinylene) and its derivatives are promising n-type materials for organic optoelectronic applications. 相似文献
19.
Sunitha M. Shivashankar Vishnumurthy K. Anantapadmanabha Airody Vasudeva Adhikari 《Polymer Engineering and Science》2013,53(6):1347-1356
In this communication we report synthesis of three new donor‐acceptor (D–A) type conjugated polymers carrying 1,3,4‐oxadiazole moiety and thiophene unit with different side groups at its 3,4 positions (4‐methoxybenzyl:P1, 3‐methylbenzyl:P2 and 4‐nitrobenzyl:P3) through polycondensation route using a series of newly synthesized monomers. The structures of new monomers and polymers were confirmed by NMR, FTIR spectroscopic methods followed by elemental analysis. Further, molecular weight and thermal stability were determined using gel permeation chromatography and thermogravimetric analysis. The linear optical and electrochemical properties of polymers were investigated by UV–vis absorption, fluorescence spectroscopic, and cyclic voltammetric studies. The polymers P1–P3 were found to be thermally stable and their electrochemical band gaps were determined to be 1.98, 2.14, and 2.18 eV respectively. Further their nonlinear optical properties were investigated by Z‐scan method using 532 nm, 7 ns laser pulses. The results reveal that they possess good optical limiting behavior due to effective three‐photon absorption (3PA) with absorption coefficient 2.5 × 10?24 m?3W2, 1.6 × 10?24 m?3W2, and 1.0 × 10?24 m?3W2. POLYM. ENG. SCI., 2013. © 2013 Society of Plastics Engineers 相似文献
20.
Synthesis and evaluation of properties of poly(p‐phenylenevinylene) based 1,3,4‐oxadiazole systems for optoelectronics and nonlinear optical applications
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Nimisha Kaippamangalath Unnikrishnan Gopalakrishnapanicker 《Polymer International》2016,65(10):1221-1231
Two new π‐conjugated polymers, namely poly(p‐phenylenevinylene‐1,3,4‐oxadiazole) (PPVO) and poly(p‐(nitro‐phenylene)vinylene‐1,3,4‐oxadiazole) (PNPVO), were synthesized and characterized. The Gilch polymerization technique, using dihalo derivatives of 1,3,4‐oxadiazoles, was employed to synthesize them under mild reaction conditions. The macromolecules exhibit good solubility in dimethylformamide, formamide and dimethyl sulfoxide and thus effectively address the insolubility issues associated with many oxadiazole derivatives for device fabrication. They show bright luminescence in the blue‐green region of the electromagnetic spectrum and have optical band gaps suited for an emissive layer in organic light‐emitting devices. PPVO and PNPPO show good non‐linear optical responses also in solution phase, with third‐order nonlinear susceptibilities of the order of 10?12esu. Interestingly, they exhibit good antimicrobial characteristics under examination with Escherichia coli and Staphylococcus. The results prove that these macromolecules are ideal materials to use as emissive layers in various light‐emitting devices and NLO applications. The excellent antimicrobial activity can be utilized for their applications in clinical and healthcare areas. © 2016 Society of Chemical Industry 相似文献