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1.
Previous measurements in gaseous hydrocarbon and carbon-oxygen compounds in the range 0.3 ≦ Eα ≦ 2.0 MeV revealed that the Bragg additive rule failed to give molecular stopping cross sections εα from the measured atomic solid carbon stopping cross section ε(C) and diatomic εexpt(H2) or εexpt(o2). For example, when hydrogen was present in the compound, the molecular data could be fitted either by using ε(C) and an ε'(H) which was higher than 12εexpt(H2) by as much as 21%, or by using 12εexpt(H2) and another ε'(C) which was greater than ε(C) by as much as 22%. A similar difficulty has also been encountered in interpreting the stopping cross sections recently measured for C-H-F and C-H-O compounds. ε(C), εexpt(H2) and εexpt(O2) can be used to fit (CH3)2O, but it is necessary to use ε'(C) and εexpt(H2) for C2H2F2. Nevertheless, a closer examination of the stopping cross sections for eight hydrocarbon compounds reveals a correlation between the stopping cross sections of atomic hydrogen and carbon which are required to satisfy the Bragg rule, and the type of bond associated with the atomic carbon in the molecule. The stopping cross section of a carbon atom is greater when the atom is bound by a triple bond than a single bond, whereas that of a hydrogen atom is less in a triple-bond compound than in a single-bond compound. Double-bonded compounds yield a carbon stopping cross section between the single-bond and triple-bond values at lower energies and closer to the triple-bond values at higher energies.  相似文献   

2.
《Thin solid films》1987,148(3):273-278
Optical absorption coefficient and photoconductivity measurements were performed on amorphous indium selenide thin films produced by vacuum evaporation. The dependence of the absorption coefficient α on the photon energy ħω at the edge of the absorption band is well described by the relation αh̵ω = B(h̵ω - Eopt)2 where B is a quality factor and Eopt is the optical band gap. The steady state photoconductivity as a function of the temperature and light intensity is tentatively interpreted in terms of a simple kinetic model proposed by Weiser et al.  相似文献   

3.
The mean distance of surface diffusion of bismuth adatoms on mica, carbon and silicon monoxide surfaces has been determined at different temperatures by measurement of the instantaneous sticking coefficient and the nucleus density.The surface diffusion distance has been found to increase with decreasing temperature in accordance with the formula
X=12a0v0dv0a12expEa ? Ed2RT
at temperatures above 413, 373 and 383 K for mica, carbon and silicon monoxide respectively. Here X is one-half of the diffusion distance, Ea is the adsorption energy, Ed the activation energy for surface diffusion, a0 the diffusion jump distance and v0a and v0d the vibrational frequencies associated with re-evaporation and with surface diffusion respectively. Below these temperatures it has been found that the temperature dependence of the diffusion distance deviates from the above formula; this can be explained by the presence of residual gas molecules adsorbed on the surfaces.From the temperature dependence of the diffusion distance, the respective values of the pre-exponential term a0 (v0dv0a)12 and the difference of energies Ea?Ed have been estimated as 7.6 Å and 5.8 kcal mol?1 for mica, 17 Å and 3.2 kcal mol?1 for carbon and 58 Å and 1.3 kcal mol?1 for silicon monoxide.  相似文献   

4.
The Erlangen multidetector neutron facility is used in investigations of nuclear reactions and scattering processes with polarized neutrons. The dc neutron beam is produced by the D(d, n)3He reaction in the energy range of En = 9–14 MeV. Behind an iron collimator embedded in a concrete shielding, angular distributions are simultaneously measured with 22 scintillation detectors. The overall amplification of the electronics is stabilized by a small readjustment of the photomultiplier voltage of each detector on the high voltage side. The n-γ discrimination of all detectors is controlled on-line and displayed via a personal computer.  相似文献   

5.
E.L. Wolf 《Thin solid films》1975,28(2):213-217
Several recent measurements of the tunnel conductance G(V) in metal-insulator-amorphous semiconductor film junctions have shown, at V = 0, the G(0) ∝ exp (-BT-14) temperature dependence characteristic of the variable-range phonon-assisted tunnelling model of Mott. It is suggested, however, that observation of this temperature dependence for a bias V》kTe indicates failure to achieve tunnel injection and internal equilibrium in the amorphous film. At equilibrium in the low temperature case, effective electron-phonon coupling can lead to the proportionality G(V)∝ 0eV ?(E)dE where ?(E) is the energy density of states, rather than to G(V) ∝ ?(eV) as is commonly assumed.  相似文献   

6.
Many experimental and analytical equations on a rate of a fatigue crack propagation have been proposed. However, it seems that they can not fully express its complex behavior. There are still many problems remaining to be solved in order to clarify its mechanism. One of them is to clarify the relation between the rate of the crack propagation and the mechanical properties of material. In this paper, the rate of the crack propagation is analysed to clarify this problem. This analysis is based on the observation results of the fatigue crack propagation behavior previously by the authors. The analytical result is compared with the experimental one to make sure that they agree with each other. The conclusion obtained is; the rate of fatigue crack propagation is expressed by using the stress intensity factors as
dldN = {c[Y2FaEa(1?n)]} (Kmax)2(Ka)a(2?n)
. where C is a constant; E, Young's modulus; F, plastic coefficient; Y, yield stress; Kmax and Ka, maximum and amplitude of the stress intensity factor, and α and n, exponents of the Manson-Coffin's law and work-hardening.  相似文献   

7.
A review of the published literature on fatigue crack growth suggests that power-law growth in Ti-6A1-4V is sensitive to microstnictural changes which result in variations in the fatigue mechanism. Microstnictures which promote secondary cracking along α/β interfaces display slow growth rates while microstructures which promote dimpled rupture display fast growth rates. Examples of similar effects are found in other alloy systems.Typically, the power-law growth are found in other alloy systems. It is also suggested that the power-law regime begins at ΔK ~- 13 MNm?case32, coinciding with the lower limit of striation formation on the fracture surface. The upper limit occurs at about Kmax = 1/2Kc. At higher growth rates, the Forman equation appears to be adequate.The normalized stress intensity factor, ΔK/E, required to produce a given growth rate in Ti-6A1-4V is on the order of that for other Ti-base alloys, ferritic steels, martensitic steels and aluminum alloys. Austenitic steels, which deform by planar slip are much more resistant to crack growth over much of the stress intensity range normally encountered.  相似文献   

8.
The prediction of fatigue crack growth at very low ΔK values, and in particular for the threshold region, is important in design and in many engineering applications. A simple model for cyclic crack propagation in ductile materials is discussed and the expression
dadN=21+n(1?2v)(ΔK2eff?ΔK2c,eff)4(1+n)π σ1?nycE1+n ?1+nf
developed. Here, n is the cyclic strain hardening exponent, σyc is cyclic yield, and εf is the true fracture strain. The model is successfully used in the analysis of fatigue data BS 4360-50D steel.  相似文献   

9.
10.
A method, based upon the careful investigation of the dependence of the Hall coefficient on thickness, to determine the value of the mean surface scattering length λ is presented. Hall data presented for slowly deposited cadmium sulphide thin films indicate the relationship between λ and the carrier concentration. Data are also presented to exhibit the critical dependence of λ upon substrate temperature and deposition rate. The temperature dependence of the parameter λ/μb indicates the predicted T12 relationship.  相似文献   

11.
Some optical and electrical properties of the As2Se3?xTex system (0 ≤ x ≤ 0.15) have been studied. The value of the optical gap decreases from 1.74 eV to 1.59 eV. The slope of the absorption edge changes, so that value of Eo from the relation α ~ exp (h? ωEo) exhibits a maximum value in neighbourhood of composition As2Se2.9Te0.1. The d.c. and a.c. conductivities have been studied. The value of the activation energy Eel ~ 1.8 eV is almost unchanged up to x = 0.15. The a.c. conductivity fulfils the relation б(ω) ~ ωs where s ? 1 and 1.1. at frequencies f < 1 kHz and f > 1 kHz respectively.  相似文献   

12.
The use of flexible fiber-optic bundles as lightguides for thin scintillators in a telescope is described. The telescopes will be used in the pion induced fission experiment π+6Li → 23He. The fiber-optic lightguide detector was tested, under identical condi against a conventional lightguide-detector arrangement and for α-particles of 5.5 MeV. An efficiency > 99% was obtained with a relative transmission efficiency of ~ 45% compared to the conventional lightguide arrangement.  相似文献   

13.
Thermomigration in pure lead has been observed by a material flow technique over the temperature range 595-475 K. In all circumstances the flow of material was from hot to cold. At high diffusion temperatures this flow could be described, in both single crystals and polycrystals, by a reduced heat of transport Q1 ? hf = 0.106±0.004 eV. In the temperature range 515-475 K thermomigration rates in polycrystals were found to exceed those in single crystals maintained under the same conditions. The observed increases in the polycrystal flow rates varied inversely with grain diameter and were consistent with a model of grain boundary thermomigration with an effective grain boundary heat of transport ΔE′ = 0.25 eV.While the atomic flow in grain boundaries is more sensitive to temperature gradients than is that in the volume, it is suggested that the bias in atomic movement due to the asymmetry of scattering interactions is relatively smaller in grain boundaries.  相似文献   

14.
The electromigration resistance of Al-0.5%Cu meander lines was found to increase with increasing grain size s and degree of {111} preferred orientation and with decreasing spread σ in the grain size distribution. This dependence on microstructure can be expressed in terms of the empirical quantity (sσ2)log(I111I200)3 which correlates well with the electromigration lifetime of films obtained by different deposition techniques.  相似文献   

15.
16.
The ionic conductivity of pyrochlores A1+α(Ta1+αW1?α)O6 was investigated for A = Na and T1. The thallium compounds are rather good conductors (0.34 ≤ ΔE ≤ 0.40 eV and 5 10?8cm)?1σ25°C ≤ 5.5 10?5cm)?1); the sodium oxides are poor conductors (0.76 eV ≤ ΔE ≤ 1.48 eV and 10?7cm)?1σ500K ≤ 10?5cm)?1). The differences between these two classes of pyrochlores are explained in terms of structure. New non-stoechiometric oxides T112+x(M30+xW3?x)O90, with M = Ta, Nb, and 0 ≤ x ≤ 3, were isolated. They are, like pyrochlores, characterized by an intersecting tunnel structure, which is an intergrowth of pyrochlore and A2M7O18 structures. These oxides show ionic conduction properties which are very close to those of pyrochlores: the tantalum oxides are better conductors (0.30 eV ≤ ΔE ≤ 0.37 eV ; 3.6 10?7cm)?1σ25°C ≤ 1.4 10?6cm)?1) than the niobium oxides (0.36 eV ≤ ΔE ≤ 0.42 eV ; 10?7cm)?1σ25°C ≤ 3.8 10?7cm)?1). The evolution ofionic conduction properties of all these compounds is discussed.  相似文献   

17.
L. Żdanowicz  T. Kwiecień 《Vacuum》1977,27(4):409-412
The transmission of vacuum deposited Cd3As2 films has been measured in the spectral range 0.6–15 ωm. The absorption coefficient α has been calculated from the data for crystalline films obtained at substrate temperature Ts = 440 K and also for amorphous films obtained on substrates at Ts = 300?393 K. The position of the low-energy absorption edge in the spectral range 0.1–0.3 eV is discussed and the value Δgopt = 0.06 eV for indirect transion ΓΓ15 is obtained for crystalline films. For amorphous films, a shift of the minimum absorption edge to ΔEgopt ? 0.4?0.5 eV was observed. For higher energies two direct transitions have been established: the first at E1 = 0.9 eV in the photon energy range 0.9–1.2 eV.and the second at E2 = 1.2?1.3 eV in the photon energy range 1.3?1.6 eV. The last value is in good agreement with the value calculated by Lin Chung and with reflectivity data; it corresponds to the transition Γ15 → X1 in the hypothetical band model of Lin Chung. Differences in the reflective index values for crystalline and amorphous Cd3 As2 are also discussed.  相似文献   

18.
An equation governing the prior to failure crack propagation is proposed. For a rate-sensitive solid containing two-dimensional crack and subject to the tensile mode of fracture the differential equations are integrated numerically for the loads increasing monotonically in time. The resulting integral curves gs = σ(l) and l= l(t), i.e. load vs crack length and length vs time, indicate that the growth of cracks in the subcritical range is strongly rate dependent.The fatigue growth, viewed as a sequence of slow growth periods, is simulated on EAI 380 analogue computer. The fourth power law proposed by Paris is confirmed only within certain range of high-cycle fatigue propagation and for a rate-insensitive solid. Otherwise, that is for a more pronounced rate dependency induced by viscosity of a solid and/or in the proximity of the final instability point the growth is markedly enhanced. For sufficiently small ratios of the applied stress intensity range ΔK to the toughness Kc, the suggested fatigue growth law consists of two terms, i.e.
dldn=l1124ΔKKc4 +Cf?1ΔKKc2, l1=πK2c8Y2
First term is the familiar Paris expression while the second one accounts for the rate-dependent contribution; f denotes frequency and Y is the yield strength. Rate-sensitivity C is defined by eq. (1.13).  相似文献   

19.
Surface-cracked specimens of several thicknesses of 7075-T651 and 7075-T6 aluminum were tested in uniaxial tension. For thicknesses t less than 0.25 in., the gross fracture stress σf of 7075-T651 Al was empirically related to flaw size by the following expression:
δfσult = 1 + S(aφ2.t?12
where σult is the ultimate strength, a the crack depth, φ a function of crack shape, and S a proportionality constant equal to ?1.7 in.?12. For 0.25-in. thick 7075-T651 aluminum, σf was found to obey this relationship only when aφ2 is less than 0.065 in.; for larger flaws, such that 0.065 < aφ2 < 0.11, σf is better predicted by Irwin's surface-crack equation with an apparent KIC value of 32.2 ksi-in.12.Fracture data for thin sections of 2014-T6 and 2014-T651 Al tested at ?423°F are analyzed in terms of the empirical relationship above and are found to be in good agreement. For these alloys, S has a value of ?2.6 in.?12.Applicability of the empirical relationship and Irwin's surface-crack analysis to the fracture of thin sections is discussed in terms of crack size, section thickness, and plastic zone size.  相似文献   

20.
A miniaturised UHF (430 MHz) ac-biased SQUID magnetometer operating at 4.2 K has been designed in which the first stage amplification is provided by a liquid helium cooled GaAs FET amplifier. The magnetometer, which uses in situ varactor tuning for the SQUID tank circuit and FETAmp has a signal energy sensitivity (figure of merit) ? 1.3 × 10?3JHz?1 ( 1 × 10?5 Φ0 Hz?12 flux sensitivity) in flux lock. The system operates in full flux lock over a frequency range from dc to 5 MHz.  相似文献   

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