Thermodynamic analysis of subcooling and superheating effects of alternative refrigerants for vapour compression refrigeration cycles

This paper presents a computer‐based first law and exergy analysis applied to vapour compression refrigeration systems for determining subcooling and superheating effects of environmentally safe new refrigerants. Three refrigerants are considered: R134a, R407c and R410a. It is found that subcooling and superheating temperatures directly influence the system performance as both condenser and evaporator temperatures are affected. The thermodynamic properties of the refrigerants are formulated using artificial neural network (ANN) methodology. Six ANNs were trained to predict various properties of the three refrigerants. The training and validation of the ANNs were performed with good accuracy. The correlation coefficient obtained when unknown data were used to the networks were found to be equal or very near to 1 which is very satisfactory. Additionally, the present methodology proved to be much better than the linear multiple regression analysis. From the analysis of the results it is found that condenser and evaporator temperatures have strong effects on coefficient of performance (COP) and system irreversibility. Also both subcooling and superheating affect the system performance. This effect is similar for R134a and R407c, and different for R410a. Copyright © 2005 John Wiley & Sons, Ltd.     

Energy influence of the IHX with R22 drop-in and long-term substitutes in refrigeration plants

This work focuses on the investigation of new drop-in or long-term refrigerants for low evaporating temperatures that can be used as substitutes for HCFC-22, which is gradually being phased-out. This process is already in progress in European countries (Regulation CE-1005/2009) and has been accelerated in Article 5 Countries of the Montreal Protocol. Specifically, in this work the energy influence of the suction line/liquid line heat exchanger on the new substitute fluids is addressed from an experimental approach.The study has been based on experimental measurements in a single-stage vapour compression refrigeration plant, which has been tested in the same external conditions operating with and without an Internal Heat Exchanger (IHX). The energy influence of the IHX working with R22 and three potential substitutes for low temperature applications, the chlorine-free drop-in fluids R417B and R422A and the chlorine-free long-term substitute R404A has been analysed.From the experimental results, reductions in capacity and COP have been observed when R22 is replaced by the drop-in fluids, although the presence of an IHX can help to lessen these reductions. Furthermore, the criteria that are usually employed to determine the energy advantage or disadvantage of the use of the IHX with the new refrigerants have been tested, the results confirming that they remain valid for them.     

Performance comparison of CFCs with their substitutes using artificial neural network

In order to decrease global pollution due to chlorofluorocarbons (CFCs), the usage of HFC‐ and HC‐based refrigerants and their mixtures are considered instead of CFCs (R12, R22, and R502). This was confirmed by an international consensus (i.e. Montreal Protocol signed in 1987). This paper offers to determine coefficient of performance (COP) and total irreversibility (TI) values of vapour‐compression refrigeration system with different refrigerants and their mixtures mentioned above using artificial neural networks (ANN). In order to train the network, COPs and TIs of refrigerants and their some binary, ternary and quartet mixtures of different ratios have been calculated in a vapour‐compression refrigeration system with liquid/suction line heat exchanger. In the calculations thermodynamic properties of refrigerants have been taken from REFPROP 6.01 which was prepared based on Helmholtz energy equation of state. To achieve this, a new software has been written in FORTRAN programming language using sub‐programs of REFPROP, and all related calculations have been performed using this software using constant temperature method as reference. Scaled conjugate gradient, Pola–Ribiere conjugate gradient, and Levenberg–Marquardt learning algorithms and logistic sigmoid transfer function were used in the network. Mixing ratios of refrigerants, and evaporator temperature were used as input layer; COP and TI values were used as output layer. It is shown that R² values are about 0.9999, maximum errors for training and test data are smaller than 2 and 3%, respectively. It is concluded that, ANNs can be used for prediction of COP and TI as an accurate method in the systems. Copyright © 2004 John Wiley & Sons, Ltd.     

A comparison of the operating performance of alternative refrigerants

This paper provides a comparison of the operating performance of three alternative refrigerants for use in a vapour compression refrigeration cycle. The refrigeration capacity and COP of R401A, R290 and R134A were compared with those of R12 when used in a propriety vapour compression refrigeration unit initially designed to operate with R12. The results indicate that the performance of R134a is very similar to that of R12 justifying the claim that it is a drop in replacement for R12 but of the refrigerants tested it gave the poorest performance. When viewed in terms of green house impact however R290 showed the best performance.     

The performance of a triple pressure level absorption cycle (TPLAC) with working fluids based on the absorbent DMEU and the refrigerants R22, R32, R124, R125, R134a and R152a

This paper compares the performance of a single-stage triple pressure level (TPL) absorption cycle with different refrigerant–absorbent pairs. Four HFC refrigerants namely: R32, R125, R134a and R152a which are alternative to HCFC, such as R22 and R124, in combination with the absorbent dimethylethylenurea (DMEU) were considered. The highest coefficient of performance (COP) and the lowest circulation ratio (f), were found as a function of the generator temperature for a given evaporating and cooling water temperatures. The sensitivity of the COP and f for evaporator and cooling water temperatures changes at the maximum COP for the best three working fluids were also examined. It was obtained that the preferable pair is R124–DMEU and among working fluids based on HFC the preferable pair is the R125–DMEU.     

Numerical analysis of an air condenser working with the refrigerant fluid R407C

As CFC (clorofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants which have been used as refrigerants in a vapour compression refrigeration system were know to provide a principal cause to ozone depletion and global warming, production and use of these refrigerants have been restricted. Therefore, new alternative refrigerants should be searched for, which fit to the requirements in an air conditioner or a heat pump, and refrigerant mixtures which are composed of HFC (hydrofluorocarbon) refrigerants having zero ODP (ozone depletion potential) are now being suggested as drop-in or mid-term replacement. However also these refrigerants, as the CFC and HCFC refrigerants, present a greenhouse effect.The zeotropic mixture designated as R407C (R32/R125/R134a 23/25/52% in mass) represents a substitute of the HCFC22 for high evaporation temperature applications as the air-conditioning.Aim of the paper is a numerical–experimental analysis for an air condenser working with the non azeotropic mixture R407C in steady-state conditions. A homogeneous model for the condensing refrigerant is considered to forecast the performances of the condenser; this model is capable of predicting the distributions of the refrigerant temperature, the velocity, the void fraction, the tube wall temperature and the air temperature along the test condenser. Obviously in the refrigerant de-superheating phase the numerical analysis becomes very simple. A comparison with the measurements on an air condenser mounted in an air channel linked to a vapour compression plant is discussed. The results show that the simplified model provides a reasonable estimation of the steady-state response and that this model is useful to design purposes.     

Thermoeconomic optimization of subcooled and superheated vapor compression refrigeration cycle

An exergy-based thermoeconomic optimization application is applied to a subcooled and superheated vapor compression refrigeration system. The advantage of using the exergy method of thermoeconomic optimization is that various elements of the system—i.e., condenser, evaporator, subcooling and superheating heat exchangers—can be optimized on their own. The application consists of determining the optimum heat exchanger areas with the corresponding optimum subcooling and superheating temperatures. A cost function is specified for the optimum conditions. All calculations are made for three refrigerants: R22, R134a, and R407c. Thermodynamic properties of refrigerants are formulated using the Artificial Neural Network methodology.     

Neural networks—a new approach to model vapour‐compression heat pumps

The aim of this paper is to model the steady‐state performance of a vapour‐compression liquid heat pump with the use of neural networks. The model uses a generalized radial basis function (GRBF) neural network. Its input vector consists only of parameters that are easily measurable, i.e. the chilled water outlet temperature from the evaporator, the cooling water inlet temperature to the condenser and the evaporator capacity. The model then predicts relevant performance parameters of the heat pump, especially the coefficient of performance (COP). Models are developed for three different refrigerants, namely LPG, R22 and R290. It is found that not every model achieves the same accuracy. Predicted COP values, when LPG or R22 are used as refrigerant, are usually accurate to within 2 per cent, whereas many predictions for R290 deviate more than ±10 per cent. Copyright © 2001 John Wiley & Sons, Ltd.     

A comparative study of water as a refrigerant with some current refrigerants

Water as a refrigerant (R718) is compared with some current natural (R717 and R290) and synthetic refrigerants (R134a, R12, R22, and R152a) regarding environmental issues including ozone depletion potential (ODP) and global warming potential (GWP), safety (toxicity and flammability), operating cost, refrigeration capacity and coefficient of performance (COP). A computer code simulating a simple vapour compression cycle was developed to calculate COPs, pressure ratios, outlet temperatures of the refrigerants from the compressor, and evaporator temperatures above which water theoretically yields better COPs than the other refrigerants investigated. The main difference of this study from other similar studies is that both evaporator temperature and condenser temperature are changed as changing parameters, but the temperature lift, which is the temperature difference between condenser and evaporator, are held constant and the irreversibility during the compression process is also taken into consideration by taking the isentropic efficiency different from 100%. It is found that for evaporator temperatures above 20°C and small temperature lift (5 K), R718 gives the highest COP assuming exactly the same cycle parameters. For medium temperature lifts (20–25 K), this evaporator temperature is above 35°C, whereas for even greater temperature lifts it decreases again. Furthermore, with increased values of polytropic efficiency, R718 can maintain higher COPs over other refrigerants, at lower evaporator temperatures. Copyright © 2005 John Wiley & Sons, Ltd.     

Investigation of the effect of superheating on the performance of a refrigeration system using low temperature different refrigerant blends in porous media

A comparative experimental investigation on the effect of superheating of R‐22, R‐404A, R‐407C, and R‐422A as low‐temperature refrigerant blends on the performance of a vapor compression refrigeration system is conducted. Empty and porous evaporators with porosities of (40%, 43%, and 45%) are used during the tests, to predict good alternatives to the refrigerant R‐22, which has high ozone depletion potential and high global warming potential. Condensation, evaporation temperatures, degree of subcool are kept constants at 40°C, ?26°C, and 6°C (±0.5°C), respectively. The effect of superheating on the compressor discharge temperature, evaporating pressure drop, evaporating capacity, volumetric refrigeration capacity and coefficient of performance (COP) of these refrigerants has been analyzed. Refrigerants, R‐422A and R‐404A showed greater performances than that of R‐22. The percentages of increase in evaporation capacities of R‐407c, R‐22, R‐404A, and R‐422A are approximately 144%, 168%, 146.3%, and 161.5%, respectively, when changing the degrees of superheat from 6°C to 16°C and changing the porosity from empty evaporator to 40%. The percentages of increase in COP are approximately 319%, 320%, 312%, and 350%, respectively. The percentages of increase in evaporation capacities of R‐422A and R‐404A when compared with R‐22 under the same conditions are 18.6% and 8.8%, respectively, while the percentages of increase in COP when compared with R‐22 are 17% and 12%, respectively.     

Performance prediction of a refrigerating machine using R‐407C: the effect of the circulating composition on system performance

This article presents a steady‐state model of a vapour compression refrigerating machine using a ternary refrigerant mixture R‐407C. When using a zeotropic mixture in a refrigerant cycle, the circulating composition does not agree with the composition of the original charged mixture. It is mainly due to the temperature glide and the vapour–liquid slip ratio. As a result of the composition shift and its magnitude, the system performance changes depending on the system design, especially the presence of liquid receiving vessels. In this paper, a method that predicts the circulating composition has been associated to a refrigerating machine model. The results obtained with this model show an enrichment in the most volatile components of about 1% for the circulating composition, which is sufficient to decrease the system performance by about 3%. Factors affecting the overall performance have been investigated. The results show a very strong performance dependence on the refrigerant charge. The COP can decrease by 25% when the refrigerant charge is insufficient. An initial charged composition variation of 2% involves variations of the cooling capacity of about 5%. Furthermore, our model was employed to compare the performance for both R‐22 and R‐407C. The cooling capacity for R‐22 is slightly greater in comparison to R‐407C and the COP is almost constant. Copyright © 2002 John Wiley & Sons, Ltd.     

Thermo‐economic optimization of superheating and sub‐cooling heat exchangers in vapor‐compressed refrigeration system

In this study, superheating and sub‐cooling heat exchangers in vapor‐compressed refrigeration system are analyzed from thermodynamics and economical (refrigeration system operation cost, investment cost) viewpoints. Using four different refrigerants (R22, R502, R134a and R404a), the temperature of condenser at the interval of (35–55°C) and temperature of evaporator at the interval of (?10 to 10°C) have been obtained from the calculation process. The second law analysis (analysis of irreversibility) of a refrigeration system is carried out and then the whole system is optimized thermo‐economically. As a result of calculations, optimum superheating and sub‐cooling temperatures of heat exchanger (superheating, sub‐cooling) areas corresponding to these temperatures are obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

Thermodynamic analysis of R422 series refrigerants as alternative refrigerants to HCFC22 in a vapour compression refrigeration system

In the present study, the first and second law analysis of R422 series refrigerants (R422A, R422B, R422C and R422D) is presented as an alternative to HCFC22. A computational model, developed in engineering equation solver software, is employed for comparing the performance of these refrigerants in vapour compression refrigeration cycle. The thermodynamic properties of the R422 series refrigerants are computed using Refprop version 7.0. The parameters computed are volumetric cooling capacity (VCC), compressor discharge temperature, coefficient of performance (COP), exergetic efficiency and efficiency defects in system components. The results indicate that VCC, COP and exergetic efficiency for HCFC22 are higher in comparison with R422A, R422B, R422C and R422D. The efficiency defects in the condenser are largest followed by throttle valve, compressor and evaporator. Thus, the design improvement of condenser is of utmost importance to reduce the overall irreversibility and improve the system performance. Copyright © 2009 John Wiley & Sons, Ltd.     

Comparative assessment of environment-friendly alternatives to R134a in domestic refrigerators

In the present work, the possibility of using R152a and hydrocarbon refrigerants (such as R290, R1270, R600a, and R600) as alternatives to R134a in domestic refrigerators has been assessed theoretically. The refrigerants are assessed over wider range condensing and evaporator temperatures. The assessment was done with standard parameters such as pressure ratio, volumetric cooling capacity (VCC), coefficient of performance (COP), compressor input power, compressor discharge temperature, and total equivalent warming impact (TEWI). The results obtained showed that pure hydrocarbon refrigerants are not suitable to be used as alternatives to R134a due to its mismatch in VCC. R152a has approximately the same VCC with about 9% higher COP and lower values of operating pressure and compressor input power. The discharge temperature of R152a was higher than that of R134a by about 14–26 K. TEWI of R152a was about 7% lower than that of R134a. The reported results proved that R152a is an energy-efficient and environment-friendly alternative to phase out R134a in domestic refrigerators.     

Effect of saturation‐temperature on the performance of a vapour‐compression refrigeration‐cycle working on different refrigerants using exergy method

In this study, the behaviour of a vapour‐compression refrigeration cycle, for different refrigerants such as NH₃, R‐12, R‐22 and HFC‐134a was investigated using the exergy method. The cooling load of the plant and the saturation‐temperature of the cold chamber were held constant, whereas the saturation‐temperatures of the evaporator and the condenser were varied from 303 to 313 K and 258 to 248 K, respectively. The irreversibility rates (or exergy destruction rates) of sub‐regions for the whole cycle, using energy and exergy analysis, were determined for each refrigerant. The effects of changes in the saturation‐temperature in the condenser and evaporator on the irreversibility rate of the cycle were obtained for each refrigerant. The relations between the total irreversibility rate of the plant and the irreversibility rate of the condenser and the evaporator were determined for different values of saturation temperatures of the condenser and the evaporator. The COP of the cycle and the rational efficiency were determined for each of the refrigerants and compared with each other. Among the refrigerants used, R‐12 was found to be the most economical refrigerant as compared with the others. Copyright © 2005 John Wiley & Sons, Ltd.     

Considerations about evaporator thermal design in a vapour compression liquid chiller. Experimental analysis with HFC fluids (R134a and R407C)

In this paper, the predicted performance of a shell‐and‐tube (1‐2) evaporator installed in a vapour compression liquid chiller is analysed. The classical thermal design methods are applied to the evaporator performance with two HFC refrigerants, a pure fluid (R134a) and a zeotropic blend with an appreciable glide (R407C). From the experimental results obtained it is possible to discuss the validation of the simplificatory assumptions usually taken, evaluating the resulting error introduced due to the no consideration of pressure drops and temperature glide (in the case of zeotropic blends) at the evaporator. Concluding that is not possible to consider the behaviour of a zeotropic refrigerant as a pure refrigerant, rejecting the glide. Whereas the assumption of no pressure drops in evaporator, leads to an error of about 5% in cooling capacity calculation. Copyright © 2004 John Wiley & Sons, Ltd.     

Analysis of pinch point in liquid–vapour heat exchanger of R134a–DMAC vapour absorption refrigeration system

R134a (1,1,1,2 tetrafluro ethane)–DMAC (N,N Dimethyl Acetamide) vapour absorption refrigeration system can be used for sub-zero temperature applications and in industries where ammonia is forbidden. But it needs rectification of vapour from generator and draining of residual R134a–DMAC liquid from evaporator. As such, owing to the comparatively low ratio of latent heat of vapourisation to vapour specific heat of R134a, liquid vapour heat exchanger (LVHX) is required and the residual liquid further enhances its prominence in sub-cooling the incoming condensate to improve COP. In this paper LVHX is analyzed in detail by varying operating parameters like rectifier efficiency and evaporation and generator temperatures. Heat capacity rate of the cold stream (vapour and residual liquid) changes continuously due to the progressive phase change of the residual liquid. Depending on the rectifier efficiency, the maximum temperature difference shifts from one end of LVHX to the other, while at certain efficiencies it occurs within the heat exchanger indicating that normal design procedure would lead to its design oversize. The importance of LVHX increases with a decrease in both rectifier efficiency and evaporator temperature.     

A zero ODP replacement for R12 in a centrifugal compressor: an experimental study using R134a

It is well believed that the hydrofluorocarbons (HFCs) and their mixtures are the most promising candidates to substitute the conventional refrigerants, chlorofluorocarbons (CFCs) and HCFCs which contain chlorine atoms in the molecule. This substitution is necessary for the harmful action of CFCs and of HCFCs toward atmospheric ozone layer damage because the disruption of ozone has been attributed to chlorine. For this reason they must be replaced by more environment‐friendly refrigerants, as the new family, designated as HFCs, that are chlorine free. Centrifugal compressors differ from positive displacement compressors in two major respects: high vapour volume flow for a given physical size and lower pressure ratio. They are particularly suited to applications where differences between evaporator and condenser temperatures are low. The preferred properties for fluids used in centrifugal compressors differ in certain important aspects from those preferred for fluids used in positive displacement units. In particular centrifugal compressors typically utilize fluids such as CFC114, CFC113, CFC12 and CFC11 for which many potential candidate replacements exist; however, for CFC12, HFC134a is the most suitable replacement. A comparison of the refrigerants HFC134a and CFC12 has been carried out and the results from the tests, using data from a refrigerating plant operating with a centrifugal compressor are reported. The chilled water cooling plant, with a refrigerating capacity of 6500 kW is made up of a centrifugal two‐stage compressor, a condenser linked to a cooling tower, an economizer and a flooded evaporator. Experimental results show that a lower coefficient of performance is found when R134a is used as substitute for R12; the difference between the COP values decreases rising the compression ratio. Copyright © 2002 John Wiley & Sons, Ltd.     

Performance assessment of a direct expansion air conditioner working with R407C as an R22 alternative

This paper presents an experimental investigation of a direct expansion air conditioner working with R407C as an R22 alternative. Experiments are conducted on a vapor compression refrigeration system using air as a secondary fluid through both the evaporator and the condenser. The influences of the evaporator air inlet temperature (20–32 °C), the evaporator air flow rate (250–700 m³/h) and the evaporator air humidity ratio (9 and 14.5 g_wv/kg_a) at the condenser air temperature and volume flow rate of 35 °C and 850 m³/h, respectively on the system performance are investigated. Experimental results revealed that the evaporator air inlet temperature has pronounced effects on the air exit temperatures, pressures of the evaporator and the condenser, cooling capacity, condenser heat load, compressor pressure ratio and the COP of both refrigerants at humidity ratios of 9 and 14.5 g_wv/kg_a. Significant effects of the evaporator air flow rate are also gathered on the preceding parameters at the same values of mentioned-humidity ratios. The best performance, in terms of operating parameters as well as COP, can be accomplished using R22 compared to R407C. The inlet humidity ratio affects dramatically the performance of vapor compression system using R22 and R407C. The raising up humidity ratio from 9 to 14.5 g_wv/kg_a leads to an augmentation in the average cooling capacity by 29.4% and 38.5% and an enhancement in the average COP by 30% and 24.1% for R22 and R407C, respectively.     

Optimization of multistage vapour compression systems using genetic algorithms. Part 1: Vapour compression system model

The vapour compression cycle is the most common type of refrigeration cycle in use today. Most vapour compression systems are simple, having only four major components: a compressor, a condenser, an expansion device and an evaporator. Multistage vapour compression systems are more complex with, for example, extra compressors, aftercoolers, intercoolers, flash tanks and liquid‐to‐suction heat exchangers. The study performed here considers 121 different configurations operating at condensing and evaporating temperatures that range from ?50 to 50°C. The refrigerants used are ammonia, R‐22, R‐134a, R‐152a and R‐123. The basis of comparison for the systems is multistage effectiveness. Multistage effectiveness is a novel term defined as the ratio of the coefficient of performance of a multistage system to the collective coefficient of performance of an equivalent group of basic single‐stage systems operating at the same cooling capacities and evaporating and condensing temperatures. Equivalency here is defined on the basis of achieving the same cooling capacity at their respective temperatures as dictated by the multistage systems. The vapour compression system model presented here was put through genetic optimization with interesting results. Copyright © 2001 John Wiley & Sons, Ltd.