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1.
Xiaoding Lou Yu Huang Xian Yang Hai Zhu Liping Heng Fan Xia 《Advanced functional materials》2020,30(10)
Surfaces with controllable liquid wettability and related functions have gained increasing attention from interfacial scientists due to the high demand of fundamental research and practical applications. Inspired by pitch plant's excellent liquid repellency, external stimuli responsive lubricant‐infused surfaces switching between slippery state and nonslippery state under external stimuli (E‐LIS) have been developed by introducing external stimuli responsive materials as substrates, lubricants, or repellent liquids. This progress report is focused on recent development of E‐LIS. First, design strategy and fabrication of E‐LIS upon external stimuli exposure, including stress, electrical field, magnetic field, and temperature, is summarized. Then, emerging interfacial applications of E‐LIS, such as microreactors, pipetting devices, fog collection devices, and so on, are highlighted. In addition, remaining challenges and future prospects are provided. 相似文献
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Inkyu Oh Christoph Keplinger Jiaxi Cui Jiehao Chen George M. Whitesides Joanna Aizenberg Yuhang Hu 《Advanced functional materials》2018,28(39)
Traditional dynamic adaptive materials rely on an atomic/molecular mechanism of phase transition to induce macroscopic switch of properties, but only a small number of these materials and a limited responsive repertoire are available. Here, liquid as the adaptive component is utilized to realize responsive functions. Paired with a porous matrix that can be put in motion by an actuated dielectric elastomer film, the uncontrolled global flow of liquid is broken down to well‐defined reconfigurable localized flow within the pores and conforms to the network deformation. A detailed theoretical and experimental study of such a dynamically actuated liquid‐infused poroelastic film is discussed. This system demonstrates its ability to generate tunable surface wettability that can precisely control droplet dynamics from complete pinning, to fast sliding, and even more complex motions such as droplet oscillation, jetting, and mixing. This system also allows for repeated and seamless switch among these different droplet manipulations. These are desired properties in many applications such as reflective display, lab‐on‐a‐chip, optical device, dynamic measurements, energy harvesting, and others. 相似文献
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Chao Chen Zhouchen Huang Lu‐An Shi Yunlong Jiao Suwan Zhu Jiawen Li Yanlei Hu Jiaru Chu Dong Wu Lei Jiang 《Advanced functional materials》2019,29(40)
Unidirectional underwater gas bubble (UGB) transport on a surface is realized by buoyant force or wettability gradient force (Fwet‐grad) derived from a tailored geography. Unfortunately, intentional control of the UGB over transport speed, direction, and routes on horizontal planar surfaces is rarely explored. Herein reported is a light‐responsive slippery lubricant‐infused porous surface (SLIPS) composed of selective lubricants and super‐hydrophobic micropillar‐arrayed Fe3O4/polydimethylsiloxane film. Upon this SLIPS, the UGB can be horizontally actuated along arbitrary directions by remotely loading/discharging unilateral near‐infrared (NIR) stimuli. The underlying mechanism is that Fwet‐grad can be generated within 1 s in the presence of a NIR‐trigger due to the photothermal effect of Fe3O4. Once the NIR‐stimuli are discharged, Fwet‐grad vanishes to break the UGB on the SLIPS. Moreover, performed are systematic parameter studies to investigate the influence of bubble volume, lubricant rheology, and Fwet‐grad on the UGB steering performance. Fundamental physics renders the achievement of antibuoyancy manipulation of the UGBs on an inclined SLIPS. Significantly, steering UGBs by horizontal SLIPS to configurate diverse patterns, as well as facilitating light‐control‐light optical shutter, is deployed. Compared with the previous slippery surfaces, light‐responsive SLIPS is more competent for manipulating UGBs with controllable transport speed, direction, and routes independent of buoyancy or geography derivative force. 相似文献
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Directional transportation and collection of liquids and bubbles are highly desirable in human life and industrial production. As one of the most promising types of functional surfaces, the reported anisotropic slippery liquid‐infused porous surfaces (SLIPSs) demonstrate unique advantages in liquid directional transportation. However, anisotropic SLIPSs readily suffer from the depletion of lubricant when used to manipulate droplets and bubbles, which leads to unstable surface properties. Therefore, fabricating stable anisotropic slippery surfaces for the directional transportation of drops and bubbles remains a challenge. Here, stable anisotropic covalently grafted slippery surfaces are fabricated by grafting polydimethylsiloxane molecular brushes onto directional microgrooved surfaces. The fabricated surfaces show remarkable anisotropic omniphobic sliding behaviors towards droplets with different surface tensions ranging from 72.8 to 37.7 mN m?1 in air and towards bubbles underwater. Impressively, the surface maintains outstanding stability for the transportation of droplets (in air) and air bubbles (underwater) even after 240 d. Furthermore, anisotropic self‐cleaning towards various dust particles in air and directional bubble collection underwater are achieved on this surface. This stable anisotropic slippery surface has great potential for applications in the directional transportation of liquids and bubbles, microfluidic devices, directional drag reduction, directional antifouling, and beyond. 相似文献
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Namrata Raman Michael A. Welsh Yashira M. Zayas‐Gonzalez Helen E. Blackwell Sean P. Palecek David M. Lynn 《Advanced functional materials》2016,26(21):3599-3611
Many types of slippery liquid‐infused porous surfaces (‘SLIPS’) can resist adhesion and colonization by microorganisms. These ‘slippery’ materials thus offer approaches to prevent fouling on commercial and industrial surfaces. However, while SLIPS can prevent fouling on surfaces to which they are applied, they can currently do little to prevent the proliferation of non‐adherent organisms. Here, multi‐functional SLIPS are reported that address this issue and expand the potential utility of these materials. The approach is based on the release of antimicrobial agents from the porous matrices used to host the infused oil phases. It is demonstrated that SLIPS fabricated from nanoporous polymer multilayers can prevent colonization and biofilm formation by four common fungal and bacterial pathogens, and that the polymer and oil phases comprising these materials can be used to sustain the release of triclosan, a model antimicrobial agent, into surrounding media. This approach improves the inherent anti‐fouling properties of these materials and endows them with the ability to kill non‐adherent pathogens. This strategy has the potential to be general; the strategies and concepts reported here will enable the design of SLIPS with improved anti‐fouling properties and open the door to new applications of slippery liquid‐infused materials that host or release other active agents. 相似文献
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Mizuki Tenjimbayashi Ryo Togasawa Kengo Manabe Takeshi Matsubayashi Takeo Moriya Masatsugu Komine Seimei Shiratori 《Advanced functional materials》2016,26(37):6693-6702
Liquid‐infused coatings are because of their fluidity of considerable technological importance for hydrophobic materials with multifunctional properties, such as self‐healing, transmittance, and durability. However, conventional coatings absorb viscous liquid into their sponge‐like structured surface, causing uncontrollable liquid layer formation or liquid transport. In addition, a hydrophobic‐liquid‐retained surface can cause instability and lead to limitation of the hydrophobicity, optical properties, and flexibility due to liquid layer evaporation. Here, we report a strategy for controllable liquid‐layer formation on smooth surfaces (R rms < 1 nm) by π ‐electron interactions. Using this technology, superoleophilic wetting of decyltrimethoxysilane results in the design of a surface with π ‐interaction liquid adsorption, smoothness, and hydrophobicity (SPLASH), that shows extraordinary hydrophobicity (CAH = 0.75°), and stable repellence for various water‐based solutions including micrometer‐sized mist. The smoothness of the solid under a liquid layer enabled the SPLASH to exhibit stable hydrophobicity, transparency (>90%), structure damage durability and flexibility, regardless of the liquid layer thickness by bending or evaporation. Furthermore, the patterned π ‐electrons' localization on the smooth coating enables controlled liquid‐layer formation and liquid transport. This strategy may provide new insights into designing functional liquid surfaces and our designed surface with multifunctional properties could be developed for various applications. 相似文献
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Hydrophobic Materials: Liquid‐Infused Smooth Coating with Transparency,Super‐Durability,and Extraordinary Hydrophobicity (Adv. Funct. Mater. 37/2016) 
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下载免费PDF全文 Mizuki Tenjimbayashi Ryo Togasawa Kengo Manabe Takeshi Matsubayashi Takeo Moriya Masatsugu Komine Seimei Shiratori 《Advanced functional materials》2016,26(37):6674-6674
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Designing functional interfaces to control solid/fluid interactions has emerged as an indispensable strategy for developing advanced materials and optimizing current technologies. Surfaces exhibiting special wettability offer many paradigms for regulating fluid behavior in practical applications including oil–water separation and fog harvesting. Nevertheless, the flexible manipulation of air bubbles under water still has room for further exploration. Here, it is reported that the lubricant‐infused slippery (LIS) surface with water repellency is applicable to manipulate bubbles in an aqueous environment. On the basis of the sufficient bubble adhesion, the shaped LIS tracks can be used in guiding the bubble delivery and facilitating continuous bubble distribution. Through the incorporation of an asymmetrical structure into the LIS surface, a triangle‐shaped bubble holder is capable of controlling a single bubble with ease. Moreover, the LIS surface is integrated with a H2 microbubble evolving apparatus, demonstrating a potential method for in situ capture and delivery of microbubbles. The current finding reveals the meaningful interaction between underwater bubbles and the LIS surface, providing several examples for the applications of this bubble carrier, which should shed new light on the development of bubble‐controlling interfaces. 相似文献
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Weihao Pan Qiulin Wang Jun Ma Wen Xu Jing Sun Xin Liu Jinlong Song 《Advanced functional materials》2023,33(31):2302311
Many solar-power and wind-power devices in the world urgently demand self-cleaning and de-icing surfaces to ensure stable power generation. However, existing superhydrophobic surfaces and slippery liquid-infused porous surfaces with self-cleaning and de-icing functions are difficult to apply due to various defects. Herein, a novel solid-like slippery coating (SSC) is developed by constructing a smooth epoxy resin surface embedded with oil-stored silica nanoparticles. The SSC has excellent water-slippery capability to various water-based liquids with low to super-high viscosity, excellent durability and robustness, high hardness, strong adhesive strength to substrate, good optical transparency, and easy fabrication processes. This SSC also has remarkable non-sticking, self-cleaning, and de-icing performances, showing promising practical applications in solar and wind power. 相似文献
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Alexander B. Tesler Lucia H. Prado Marat M. Khusniyarov Ingo Thievessen Anca Mazare Lena Fischer Sannakaisa Virtanen Wolfgang H. Goldmann Patrik Schmuki 《Advanced functional materials》2021,31(27):2101090
Wetting is a surface phenomenon that commonly occurs in nature and has an enormous influence on human life. Slippery liquid-infused porous surfaces have recently been developed to support the growing demand for anti-fouling coatings. While short-chain fluorinated compounds, commonly used to reduce the surface energy of substrates, are banned due to environmental toxicity, silane-based compounds are expensive and barely scalable. In this sense, silicone-based chemistry may match the gap as a real alternative. However, the grafting approaches demonstrated so far suffered from either slow binding kinetics or are applied under harsh conditions. Here, it is demonstrated that polydimethylsiloxanes graft to virtually any substrate when illuminated by UV light serving simultaneously as a reducing surface energy agent and infusing lubricant. This procedure is applied on metals, metal oxides, and ceramics of various surface morphologies. The proposed approach is simple, fast, scalable, environmentally friendly, and of low-cost, yet forms stable lubricant-infused slippery surfaces by a one-pot process. Due to the biocompatibility of silicone-based compounds, the process is examined on plain medically applicable substrates such as scalpel blades and glass lenses that display enhanced corrosion resistance, reduced friction through incision, and repel blood staining and bacterial adhesion without deteriorating their mechanical and optical characteristics. 相似文献
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Mengchun Wu Benhua Ma Tiezheng Pan Shanshan Chen Junqi Sun 《Advanced functional materials》2016,26(4):569-576
Colored cotton fabrics with satisfactory color fastness as well as durable antibacterial and self‐healing superhydrophobic properties are fabricated via a convenient solution‐dipping method that involves the sequential deposition of branched poly(ethylenimine) (PEI), silver nanoparticles (AgNPs), and fluorinated decyl polyhedral oligomeric silsesquioxane (F‐POSS) on cotton fabrics. The deposited AgNPs with tunable surface plasmon resonance endow the cotton fabrics with abundant color and and antibacterial ability. However, in general, water‐soluble AgNPs cannot be firmly deposited onto cotton fabrics to endure the laundering process. The integration of self‐healing superhydrophobicity into the cotton fabrics by depositing F‐POSS/AgNP/PEI films significantly enhances the color fastness of the AgNPs against laundry and mechanical abrasion, while retaining the antibacterial property of the AgNPs. The F‐POSS/AgNP/PEI‐coated cotton fabric accommodates an abundance of F‐POSS, which autonomically migrates to the cotton surface to repetitively restore its damaged superhydrophobicity. The self‐healing superhydrophobicity of the F‐POSS/AgNPs/PEI‐coated cotton fabric guarantees long‐term protection of the underlying AgNPs against laundry and abrasion and allows the cotton fabric to be cleaned by simple rinsing with water. 相似文献
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In this paper, we first investigate the effect of mobility via the random waypoint (RWP) mobility model on the performance of nonaccess point (non‐AP) or AP large intelligent surfaces (LISs). The theoretical average bit error probability (ABEP) for each of these LISs under mobility is formulated. The presented formulation is complicated to solve; hence, the trapezoidal approximation is employed. Simulation results serve to validate the ABEP. Second, we investigate a two‐way relaying (TWR) network assisted by non‐AP or AP LISs. A network with two source/destination nodes with a single relay node employing decode‐and‐forward placed between these nodes is considered. The transmission interval is broken into two transmission phases. In the first phase, the two source nodes transmit information blocks to the relay node assisted by LISs. On receiving these information blocks, the relay node decodes the two information blocks and encodes these into a single information block via the use of network coding. In the second phase, the relay node forwards the network‐coded information block to the destination nodes assisted by LISs, where the intended information block is decoded via network coding. The theoretical ABEP is formulated for the proposed non‐AP and AP LIS‐assisted TWR schemes and is validated by simulation results. RWP mobility is also demonstrated for the proposed TWR schemes. 相似文献
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Shanghua Li Richard Furberg Muhammet S. Toprak Björn Palm Mamoun Muhammed 《Advanced functional materials》2008,18(15):2215-2220
World energy crisis has triggered more attention to energy saving and energy conversion systems. Enhanced surfaces for boiling are among the applications of great interest since they can improve the energy efficiency of heat pumping equipment (i.e., air conditioners, heat pumps, refrigeration machines). Methods that are used to make the state‐of‐the‐art enhanced surfaces are often based on complicated mechanical machine tools, are quite material‐consuming and give limited enhancement of the boiling heat transfer. Here, we present a new approach to fabricate enhanced surfaces by using a simple electrodeposition method with in‐situ grown dynamic gas bubble templates. As a result, a well‐ordered 3D macro‐porous metallic surface layer with nanostructured porosity is obtained. Since the structure is built based on the dynamic bubbles, it is perfect for the bubble generation applications such as nucleate boiling. At heat flux of 1 W cm‐2, the heat transfer coefficient is enhanced over 17 times compared to a plain reference surface. It's estimated that such an effective boiling surface would improve the energy efficiency of many heat pumping machines with 10–30%. The extraordinary boiling performance is explained based on the structure characteristics. 相似文献
16.
Yun Ho Kim Dong Ki Yoon Hyeon Su Jeong Jung Hyun Kim Eun Kyoung Yoon Hee‐Tae Jung 《Advanced functional materials》2009,19(18):3008-3013
A novel fabrication method is developed for the preparation of superhydrophobic surfaces. The procedure uses focal conic structures of semi‐fluorinated smectic liquid crystals (LCs) whose periodic toric focal conic domains (TFCDs) are prepared on a surface modified substrate. Reactive ion etching (RIE) on the periodic TFCD surface leads to a superhydrophobic surface with a water contact angle of ～160° and a sliding angle of ～2° for a 10 µL water droplet. The results show that this phenomenon is due to the development of a dual‐scale surface roughness arising from the nanoscale protuberance caused by applying the RIE process to the top of the microscale TFCD arrays. The unique surface behavior is further verified by demonstrating that RIE on a flat lamellar liquid crystal film, in which the director is aligned parallel with surface, results in a relatively low hydrophobicity as compared to when periodic TFCDs are subjected to REI. The observations made in this publication suggest that a new approach exists for selecting potential candidates of superhydrophic surface formation based on spontaneous self‐assembly in smectic liquid‐crystalline materials. 相似文献
17.
Chao Li Mathew Boban Sarah A. Snyder Sai P. R. Kobaku Gibum Kwon Geeta Mehta Anish Tuteja 《Advanced functional materials》2016,26(33):6121-6131
In this work, a facile methodology is discussed, involving fluoro‐silanization followed by oxygen plasma etching, for the fabrication of surfaces with extreme wettabilities, i.e., surfaces that display all four possible combinations of wettabilities with water and different oils: hydrophobic–oleophilic, hydrophilic–oleophobic, omniphobic, and omniphilic. Open‐channel, paper‐based microfluidic devices fabricated using these surfaces with extreme wettabilities allow for the localization, manipulation, and transport of virtually all high‐ and low‐surface tension liquids. This in turn expands the utility of paper‐based microfluidic devices to a range of applications never before considered. These include, as demonstrated here, continuous oil–water separation, liquid–liquid extraction, open‐channel microfluidic emulsification, microparticle fabrication, and precise measurement of mixtures' composition. Finally, the biocompatibility of the developed microfluidic devices and their utility for cell patterning are demonstrated. 相似文献
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Anton Grigoryev Yuri Roiter Ihor Tokarev Igor Luzinov Sergiy Minko 《Advanced functional materials》2013,23(7):870-877
An efficient strategy to produce forests of aligned nanowires and nail‐like micrometer‐sized structures, whose density can be tuned in a broad range, is reported in this study. It relies on a combination of two template‐assisted nanofabrication/patterning methods: electrochemical growth of metal nanowires in nanoporous sacrificial templates and partial masking of a surface with a self‐assembled colloidal monolayer. A great potential of this novel approach, termed here colloidal occlusion template method, is demonstrated on the example of the fabrication of omniphobic surfaces comprised of nickel micronails whose density is varied to approach highest possible contact angles. After chemical modification to reduce their surface tension, these microstructures with reentrant geometry support the non‐wetting Cassie state for both high‐surface‐tension water and low‐surface‐tension hexadecane. In particular, superhydrophobic behavior (contact angles exceeding 150°) is found for water, while oleophobicity (contact angles approaching 110°) is observed for hexadecane. The proposed approach can be exploited for the fabrication of a large variety of supported high‐aspect‐ratio nano/microstructures in applications where a surface density of features has to be several orders of magnitude lower than can be obtained with conventional template methods. 相似文献
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Pu Guo Zubin Wang Liping Heng Yuqi Zhang Xuan Wang Lei Jiang 《Advanced functional materials》2019,29(11)
Smart manipulation of liquid/bubble transport has garnered widespread attention due to its potential applications in many fields. Designing a responsive surface has emerged as an effective strategy for achieving controllable transport of liquids/bubbles. However, it is still challenging to fabricate stable amphibious responsive surfaces that can be used for the smart manipulation of liquid in air and bubbles underwater. Here, amphibious slippery surfaces are fabricated using magnetically responsive soft poly(dimethylsiloxane) doped with iron powder and silicone oil. The slippery gel surface retains its magnetic responsiveness and demonstrates strong affinity for bubbles underwater but shows small and switching resistance forces with the water droplets in air and bubbles underwater, which is the key factor for achieving the controllable transport of liquids/bubbles. On the slippery gel surface, the sliding behaviors of water droplets and bubbles can be reversibly controlled by alternately applying/removing an external magnetic field. Notably, compared with slippery liquid‐infused porous surfaces, the slippery gel surface demonstrates outstanding stability, whether in air or underwater, even after 100 cycles of alternately applying/removing the magnetic field. This surface shows potential applications in gas/liquid microreactors, gas–liquid mixed fluid transportation, bubble/droplet manipulation, etc. 相似文献