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Solution processing of metal halide perovskites offers the potential for efficient, high-speed roll-based manufacturing of emerging optoelectronic devices such as lightweight photovoltaics and light emitting diodes at lower cost than achievable with incumbent technologies (e.g., Silicon). However, current perovskite fabrication methods are limited in their speed, uniformity, and patterning resolution, relying on subtractive postdeposition scribing for integration of modules and device arrays. Here, a method for flexographic printing of MA0.6FA0.4PbI3 at 60 m min−1, the fastest reported perovskite absorber deposition and the first report of inline drying integrated with roll-based printing, is presented. This process delivers high-resolution patterning (< 3 µm line edge roughness) and precise thickness control through rheological design of precursor inks, allowing scalably printed 50 µm features over large areas (140 cm2), while obviating damaging scribing steps. 2D scanning photoluminescence (PL) is applied to resolve correlations between ink leveling dynamics and optoelectronic quality. Integrating these highly uniform printed perovskite absorbers into n-i-p planar perovskite solar cells, photovoltaic conversion efficiency up to 20.4% (0.134 cm2), the highest performance yet reported for any roll-printed perovskite cells is achieved. This study, thus, establishes flexography as a scalable approach to deposit precisely-patterned high-quality perovskites extensible to applications in emitter and detector arrays. 相似文献
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Ke Meng Xiao Wang Qiaofei Xu Zhimin Li Zhou Liu Longlong Wu Youdi Hu Ning Liu Gang Chen 《Advanced functional materials》2019,29(35)
Metal halide perovskites have revolutionized the development of highly efficient, solution‐processable solar cells. Further advancements rely on improving perovskite film qualities through a better understanding of the underlying growth mechanism. Here, a systematic in situ grazing‐incidence X‐ray diffraction investigation is performed, facilitated by other techniques, on the sequential deposition of formamidinium lead iodide (FAPbI3)‐based perovskite films. The active chemical reaction, composition distribution, phase transition, and crystal grain orientation are all visualized following the entire perovskite formation process. Furthermore, the influences of additive ions on the crystallization speed, grain orientation, and morphology of FAPbI3‐based films, along with their photovoltaic performances, are fully evaluated and optimized, which leads to highly reproducible and efficient perovskite solar cells. The findings provide key insights into the perovskite growth mechanism and suggest the fabrication of high‐quality perovskite films for widespread optoelectronic applications. 相似文献
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喷墨打印作为一种非接触式、无需掩膜的数字印刷技术,被广泛应用于印刷电路板、光伏组件和显示器件等领域。近年来,金属卤化物钙钛矿作为一种新型的直接带隙离子型半导体材料,受到科研工作者们的广泛关注与研究。利用喷墨打印技术可以对钙钛矿墨滴的分配和沉积过程进行精确调控,为钙钛矿光电器件迈向产业化提供了一种可行的工艺路线。本文从喷墨打印的工作原理出发,分别从墨水制备和打印工艺两个角度概述了喷墨打印钙钛矿光电器件的发展进程,并分析了目前喷墨打印钙钛矿所面临的挑战。同时对基于喷墨打印技术制备钙钛矿光电器件的功能层和电极进行了总结,在此基础上对喷墨打印钙钛矿光电器件未来的发展前景和产业化探索进行了展望。 相似文献
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Haining Chen 《Advanced functional materials》2017,27(8)
Organometal halide perovskite materials have become a superstar in the photovoltaic (PV) field because of their advantageous properties, which boost the power conversion efficiency (PCE) of perovskite solar cells (PSCs) from about 3.8% to above 22% in just seven years. Most importantly, such promising achievement is mainly based on its low‐cost and solution‐processed fabrication technique. One of the most promising and famous approaches to fabricating perovskite is a two‐step sequential deposition method because precursor (e.g., PbI2) deposition is controllable, versatile, and flexible. Due to tremendous efforts, great progress has been achieved on the two‐step sequential deposition method, which helps to promote the development of PSCs. Herein, the progresses on the two‐step sequential deposition method of perovskite layers is reviewed thoroughly. At first, the reaction process and principle is introduced and discussed. Then, the research on the deposition techniques, structures, and compositions of precursors (the first step) is presented. Subsequently, the developments on the conversion techniques, conversion solutions, and growth of large crystals at the second step are introduced. Finally, four important issues on the two‐step sequential deposition method will be stated, accompanied with proposed solutions. 相似文献
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Shaofu Wang Junjun Jin Yuyang Qi Pei Liu Yu Xia Yun Jiang Rong‐Xiang He Bolei Chen Yumin Liu Xing‐Zhong Zhao 《Advanced functional materials》2020,30(7)
Cs/FA/MA triple cation perovskite films have been well developed in the antisolvent dripping method, attributable to its outstanding photovoltaic and stability performances. However, a facile and effective strategy is still lacking for fabricating high‐quality large‐grain triple cation perovskite films via sequential deposition method a, which is one of the key technologies for high efficiency perovskite solar cells. To address this issue, a δ‐CsPbI3 intermediate phase growth (CsPbI3‐IPG) assisted sequential deposition method is demonstrated for the first time. The approach not only achieves incorporation of controllable cesium into (FAPbI3)1–x(MAPbBr3)x perovskite, but also enlarges the perovskite grains, manipulates the crystallization, modulates the bandgap, and improves the stability of final perovskite films. The photovoltaic performances of the devices based on these Cs/FA/MA perovskite films with various amounts of the δ‐CsPbI3 intermediate phase are investigated systematically. Benefiting from moderate cesium incorporation and intermediate phase‐assisted grain growth, the optimized Cs/FA/MA perovskite solar cells exhibit a significantly improved power conversion efficiency and operational stability of unencapsulated devices. This facile strategy provides new insights into the compositional engineering of triple or quadruple cation perovskite materials with enlarged grains and superior stability via a sequential deposition method. 相似文献
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Hung‐Yu Lin Chien‐Yu Chen Bo‐Wei Hsu Yu‐Lun Cheng Wei‐Lun Tsai Yu‐Ching Huang Cheng‐Si Tsao Hao‐Wu Lin 《Advanced functional materials》2019,29(44)
The novel growth of cesium lead halide perovskite thin films, which are prepared through thousand‐layer rapid alternative deposition, is performed by developing an active perovskite film consisting of a layer‐by‐layer structure. This method is considerably more difficult to be implemented from the solution process. The obtained thin film morphology and characteristics are distinguished from that of the traditional a few layers and two‐material codeposition. These alternative deposited perovskites are integrated with vacuum‐deposited carrier‐transporting layers and electrodes, and all vacuum‐sublimed perovskite solar cells exhibit an outstanding power conversion efficiency of 13.0%. The use of these devices for environmental light energy harvesting provides a power conversion efficiency of 33.9% under fluorescent light illumination of 1000 lux. 相似文献
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Jiujiang Chen Jian Liu Yifei Li Peng Xu Lisha Xie Yuanyuan Meng Haodong Wu Xiaofeng Shang Su Zhao Jun Pan Chuanxiao Xiao Mengjin Yang Ziyi Ge 《Advanced functional materials》2024,34(26):2314652
In recent years, perovskite solar cells have attained unprecedented advancements in power conversion efficiency, yet their commercialization remains a formidable challenge. Addressing this challenge relies on developing an affordable and scalable method for manufacturing top-notch perovskite films. This study presents an innovative strategy, employing both gas quenching technology and ultrasonic-assisted processing (UAP), to fabricate high-caliber perovskite thin films. The UAP process enhances the grain size of the perovskite film, reduces grain boundary defects, improves carrier extraction and transport, and suppresses carrier nonradiative recombination. Furthermore, it effectively reduces residual stress and mitigates lattice distortion in the perovskite crystals. Ultimately, efficient and stable inverted perovskite solar cells using FA0.87Cs0.13PbI2.7Br0.3 and FA0.85MA0.1Cs0.05PbI3 perovskite are successfully prepared. The target device achieved a power conversion efficiency of 22.32% and 24.51%, respectively. Moreover, the target devices exhibited enhanced photostability. This work provides a cost-effective and scalable method for producing high-quality perovskite films, paving the way for the commercialization of perovskite solar cells. 相似文献
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有机/无机杂化钙钛矿太阳电池因具有高光吸收系数、高转换效率以及低制备成本等优点引起了科学界的广泛关注.综述了近年来有机/无机杂化钙钛矿吸收层几种制备工艺的研究进展,重点分析了目前应用较为广泛且制备工艺相对简单的一步溶液法和两步连续沉积法的工艺条件对钙钛矿薄膜质量及太阳电池光伏性能的影响,并详细介绍了几种制备工艺存在的主要问题及其调控的研究现状.此外,对后续工艺中的有机空穴传输材料及其溶剂、添加剂对钙钛矿太阳电池稳定性的影响及其调控的研究现状进行了简要阐述.为更好地提高钙钛矿太阳电池的效率和长期稳定性,制备工艺的优化和创新是未来钙钛矿太阳电池发展的趋势. 相似文献
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Xiaojin Peng Jian Yuan Shirley Shen Mei Gao Anthony S. R. Chesman Hong Yin Jinshu Cheng Qi Zhang Dechan Angmo 《Advanced functional materials》2017,27(41)
Inkjet printing (IJP) technology, adapted from home and office printing, has proven to be an essential research tool and industrial manufacturing technique in a wide range of printed electronic technologies, including optoelectronics. Its primary advantage over other deposition methods is the low‐cost and maskless on‐demand patterning, which offers unmatched freedom‐of‐design. Additional benefits include the efficient use of materials, contactless high‐resolution deposition, and scalability, enabling rapid translation of learning from small‐scale, laboratory‐based research into large‐scale industrial roll‐to‐roll manufacturing. In the development of organic solar cells (OSCs), IJP has enabled the printing of many of the multiple functional layers which comprise the complete cell as part of an additive printing scheme. Although IJP is only recently employed in perovskite solar cell (PeSC) fabrication, it is already showing great promise and is anticipated to find broader application with this class of materials. As OSCs and PeSCs share many common functional materials and device architectures, this review presents a progress report on the IJP of OSCs and PeSCs in order to facilitate knowledge transfer between the two technologies, with critical analyses of the challenges and opportunities also presented. 相似文献
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Zhi Xing Suyu Lin Xiangchuan Meng Ting Hu Dengxue Li Baojin Fan Yongjie Cui Fengyu Li Xiaotian Hu Yiwang Chen 《Advanced functional materials》2021,31(50):2107726
Homogeneity and stability of flexible perovskite solar cells (PSCs) are significant for the commercial feasibility in upscaling fabrication. Concretely, the mismatching between bottom interface and perovskite precursor ink can cause uncontrollable crystallization and undesired dangling bonds during the printing process. Herein, methylammonium acetate, serving as ink assistant (IAS) can effectively avoid the micron-scale defects of perovskite film. The in situ optical microscope is applied to prove the IAS can inhibit the colloidal aggregation and induce more adequate crystallization growth, thus avoiding the micron-scale defects of pinholes and intergranular cracking. Concurrently, 4-chlorobenzenesulfonic acid is introduced into the electrode surface as a passivation layer to restore the deep traps at perovskite interface in nano-scale. Finally, the target flexible devices (1.01 cm2) deliver a superior efficiency of 18.12% with improved air atmosphere stability. This multi-scale defect repair strategy provides an integrated design concept of homogeneity and stability for scalable and flexible PSCs. 相似文献
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Xinxin Lian Ye Xu Wei Fu Rui Meng Quanxing Ma Chunyu Xu Ming Luo Ying Hu Junchao Han Hao Min Anurag Krishna Yifan Chen Huawei Zhou Xueling Zhang Cong Chen Jin Chang Can Li Yifeng Chen Zhiqiang Feng Zhen Li Guangzheng Zuo Jifan Gao Hong Zhang Xiaoliang Mo Junhao Chu 《Advanced functional materials》2024,34(37):2402061
A facile and eco-friendly dimethyl sulfoxide-mediated solution aging (DMSA) treatment is presented to control the crystallization dynamics of methylammonium (MA)-free wide-bandgap (WBG) perovskite films, enhancing film quality, and morphology for high-performance tandem solar cells. The comprehensive structural, morphological, and characterization analyses reveal that the DMSA treatment significantly enhances composition and morphology homogeneity while suppressing halide segregation. Consequently, opaque, and semi-transparent MA-free WBG perovskite solar cells (PSCs) exhibit remarkable power conversion efficiencies (PCEs) of 18.28% and 17.61%, respectively. Notably, the unencapsulated DMSA-treated devices maintain 95% of the initial PCE after 900 h of continuous operation at 55 °C ± 5 °C. Furthermore, stacking semi-transparent DMSA-treated PSCs as top cells in a 4T tandem configuration, along with silicon heterojunction (SHJ), lead–tin (Pb–Sn) alloyed PSCs, and organic photovoltaics (OPV) as bottom cells, yields impressive PCEs of 28.09%, 26.09%, and 25.28%, respectively, for the fabricated tandem cells. This innovative approach opens new avenues for enhancing the photo-stability and photovoltaic performance of perovskite-based tandem solar cells. 相似文献
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Daiyu Li Deyi Zhang Kwang-Soo Lim Yue Hu Yaoguang Rong Anyi Mei Nam-Gyu Park Hongwei Han 《Advanced functional materials》2021,31(12):2008621
Power conversion efficiency of perovskite solar cells (PSCs) has been boosted to 25.5% among the highest efficiency for single-junction solar cells, making PSCs extremely promising to realize industrial production and commercialization. Scaling up PSCs to fabricate efficient perovskite solar modules (PSMs) is the fundamental for applications. Here, present progresses on scaling up PSCs are reviewed. The structure design for PSMs is discussed. Various scalable methods and related morphology control strategies for large-area uniform perovskite films are summarized. Potential charge transport materials and electrode materials together with their scalable methods for low-cost, efficient, and stable PSMs are also summarized. Besides, current attempts on encapsulation for improving stability and reducing lead leakage are introduced, and the calculated cost and environment influence of PSMs are also outlined. 相似文献
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Perovskite solar cell has emerged as a promising candidate in flexible electronics due to its high mechanical flexibil-ity,excellent optoelectronic properties,light weight and low cost.With the rapid development of the device structure and mater-ials processing,the flexible perovskite solar cells (FPSCs) deliver 21.1％ power conversion efficiency.This review introduces the latest developments in the efficiency and stability of FPSCs,including flexible substrates,carrier transport layers,perovskite films and electrodes.Some suggestions on how to further improve the efficiency,environmental and mechanical stability of FPSCs are provided.Specifically,we considered that to elevate the performance of FPSCs,it is crucial to substantially improve film quality of each functional layer,develop more boost encapsulation approach and explore flexible transparent electrodes with high conductivity,transmittance,low cost and expandable processability. 相似文献
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Perovskite Solar Cells: Passivated Perovskite Crystallization via g‐C3N4 for High‐Performance Solar Cells (Adv. Funct. Mater. 7/2018) 
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下载免费PDF全文 Lu‐Lu Jiang Zhao‐Kui Wang Meng Li Cong‐Cong Zhang Qing‐Qing Ye Ke‐Hao Hu Ding‐Ze Lu Peng‐Fei Fang Liang‐Sheng Liao 《Advanced functional materials》2018,28(7)
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Lu‐Lu Jiang Zhao‐Kui Wang Meng Li Cong‐Cong Zhang Qing‐Qing Ye Ke‐Hao Hu Ding‐Ze Lu Peng‐Fei Fang Liang‐Sheng Liao 《Advanced functional materials》2018,28(7)
Organometallic halide perovskite films with good surface morphology and large grain size are desirable for obtaining high‐performance photovoltaic devices. However, defects and related trap sites are generated inevitably at grain boundaries and on surfaces of solution‐processed polycrystalline perovskite films. Seeking facial and efficient methods to passivate the perovskite film for minimizing defect density is necessary for further improving the photovoltaic performance. Here, a convenient strategy is developed to improve perovskite crystallization by incorporating a 2D polymeric material of graphitic carbon nitride (g‐C3N4) into the perovskite layer. The addition of g‐C3N4 results in improved crystalline quality of perovskite film with large grain size by retarding the crystallization rate, and reduced intrinsic defect density by passivating charge recombination centers around the grain boundaries. In addition, g‐C3N4 doping increases the film conductivity of perovskite layer, which is beneficial for charge transport in perovskite light‐absorption layer. Consequently, a champion device with a maximum power conversion efficiency of 19.49% is approached owing to a remarkable improvement in fill factor from 0.65 to 0.74. This finding demonstrates a simple method to passivate the perovskite film by controlling the crystallization and reducing the defect density. 相似文献
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Jing Zhang Xiangang Hu Hui Li Kangyu Ji Bowei Li Xueping Liu Yuren Xiang Pengxiang Hou Chang Liu Zhiheng Wu Yonglong Shen Samuel D. Stranks S. Ravi P. Silva Hui-Ming Cheng Wei Zhang 《Advanced functional materials》2021,31(37):2104396
The unprecedented advancement in power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) has rendered them a promising game-changer in photovoltaics. However, unsatisfactory environmental stability and high manufacturing cost of window electrodes are bottlenecks impeding their commercialization. Here, a strategy is introduced to address these bottlenecks by replacing the costly indium tin oxide (ITO) window electrodes via a simple transfer technique with single-walled carbon nanotubes (SWCNTs) films, which are made of earth-abundant elements with superior chemical and environmental stability. The resultant devices exhibit PCEs of ≈19% on rigid substrates, which is the highest value reported to date for ITO-free PSCs. The facile approach for SWCNTs also enables application in flexible PSCs (f-PSCs), delivering a PCE of ≈18% with superior mechanical robustness over their ITO-based counterparts due to the excellent mechanical properties of SWCNTs. The SWCNT-based PSCs also deliver satisfactory performances on large-area (1 cm2 active area in this work). Furthermore, these SWCNT-based PSCs can retain over 80% of original PCEs after exposure to air over 700 h while ITO-based devices only sustain ≈60% of initial PCEs. This work paves a promising way to accelerate the commercialization of ITO-free PSCs with reduced material cost and prolonged lifetimes. 相似文献