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Highly regioregular (RR) poly(3‐hexylthiophene)s PHTs are known to exhibit excellent electrical properties in comparison to chemically identical but regiorandom (rr) PHTs. In this study, distinct RR (97% and 55%)‐graded PHTs are subjected to solution blending to spontaneously separate the high‐RR PHT chains from the low‐RR PHT media and develop highly conjugated nanodomains in both solution and film. In the spun‐cast blend films, the rr PHT matrix imparts sufficient deformability of the channel layer required for stretchable organic thin‐film transistors (OTFTs), compared to neat RR PHTs and blends with a deformable polymer. OTFTs including RR PHT/rr PHT blend films show excellent hole mobility (µ) values up to 0.13 cm2 V?1 s?1, surpassing that of the best RR PHT films (0.026 cm2 V?1 s?1) fabricated by ultrasound solution pretreatment. Furthermore, a 50% stretched RR PHT/rr PHT film maintains ≈55% of its µ value at no strain, while RR PHT films show a sudden decrease in µ even at 10% stretch. The simple blending approach imparts deformability to π‐conjugated polymer films for application in stretchable OTFTs. 相似文献
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Printed Electronics: Room‐Temperature Printing of Organic Thin‐Film Transistors with π‐Junction Gold Nanoparticles (Adv. Funct. Mater. 31/2014)
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Takeo Minari Yuki Kanehara Chuan Liu Kenji Sakamoto Takeshi Yasuda Asuka Yaguchi Shigemi Tsukada Kei Kashizaki Masayuki Kanehara 《Advanced functional materials》2014,24(31):4869-4869
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Transparent Displays: Skin‐Like Oxide Thin‐Film Transistors for Transparent Displays (Adv. Funct. Mater. 34/2016)
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Han Eol Lee Seungjun Kim Jongbeom Ko Hye‐In Yeom Chun‐Won Byun Seung Hyun Lee Daniel J. Joe Tae‐Hong Im Sang‐Hee Ko Park Keon Jae Lee 《Advanced functional materials》2016,26(34):6319-6319
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Liquid‐Crystalline Semiconductors: Tailoring Morphology and Structure of Inkjet‐Printed Liquid‐Crystalline Semiconductor/Insulating Polymer Blends for High‐Stability Organic Transistors (Adv. Funct. Mater. 18/2016)
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Donghoon Kwak Hyun Ho Choi Boseok Kang Do Hwan Kim Wi Hyoung Lee Kilwon Cho 《Advanced functional materials》2016,26(18):3180-3180
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Thin‐Film Transistors: Synthesis of Ultrathin,Homogeneous Copolymer Dielectrics to Control the Threshold Voltage of Organic Thin‐Film Transistors (Adv. Funct. Mater. 36/2016)
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Kwanyong Pak Hyejeong Seong Junhwan Choi Wan Sik Hwang Sung Gap Im 《Advanced functional materials》2016,26(36):6672-6672
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Ito‐Free Flexible Electronics: Screen‐Printed Poly(3,4‐Ethylenedioxythiophene):Poly(Styrenesulfonate) Grids as ITO‐Free Anodes for Flexible Organic Light‐Emitting Diodes (Adv. Funct. Mater. 11/2018)
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Lu Zhou Mengjie Yu Xiaolian Chen Shuhong Nie Wen‐Yong Lai Wenming Su Zheng Cui Wei Huang 《Advanced functional materials》2018,28(11)
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Stretchable Displays: Stretchable Active Matrix Inorganic Light‐Emitting Diode Display Enabled by Overlay‐Aligned Roll‐Transfer Printing (Adv. Funct. Mater. 11/2017)
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Minwoo Choi Bongkyun Jang Wonho Lee Seonwoo Lee Tae Woong Kim Hak‐Joo Lee Jae‐Hyun Kim Jong‐Hyun Ahn 《Advanced functional materials》2017,27(11)
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Wearable Electronics: Metal/Polymer Based Stretchable Antenna for Constant Frequency Far‐Field Communication in Wearable Electronics (Adv. Funct. Mater. 42/2015)
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Aftab M. Hussain Farhan A. Ghaffar Sung I. Park John A. Rogers Atif Shamim Muhammad M. Hussain 《Advanced functional materials》2015,25(42):6557-6557