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1.
Above average precipitation from October 2018 through July 2019 in the Maumee River (R.) Basin resulted in 29% of cropland left fallow, providing a glimpse of potential effects from decreased nutrient application. Ongoing monitoring at 15 water-quality sites on the Maumee R. upstream from Defiance enabled comparison with 2017, which was hydrologically similar to 2019 in precipitation and streamflow. In 2019, nitrate (as nitrogen; NO3-N) for March-July was significantly less than previous years (2015–2018), but the response for phosphorus (P) was more complicated. Relative to 2017, total P (TP) was lower at 7 of 15 sites, but higher at 7, reflecting higher suspended sediment (SS). Dissolved P (DP) was generally lower, but less different than NO3; DP was higher at 3 sites. DP-P:NO3-N was generally higher in 2019, DP-P:TP was lower, and there was less TP relative to SS. Overall, less P was in the system in 2019. However smaller streams showed a large range of difference between 2019 and 2017 for all constituents, indicating variability in land management and physiography. In contrast, all constituents were lower in 2019 in larger (>5000 km2) streams, including the Maumee R. near Defiance, where the difference in NO3 (−37%) exceeded that for TP (−16%), DP (−10%), and SS (−20%). Differences in these relations among N, P, and SS indicate that P was available from legacy sources that are more difficult to distinguish during typical agricultural production years and that some material from 2019 was stored in the system upstream from the largest sites.  相似文献   

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3.
The Governments of the United States and Canada must decide in the near future if vessel and cargo transit on the Great Lakes-St. Lawrence Seaway (GL-SLS) is to be operated at capacity or the system be improved to accommodate the projected increases. Portions of the GL-SLS could approach operating capacity in the mid-1980s and options to increase capacity include extending the present 81/2 month navigation season to 11–12 months, and/or upgrading existing facilities to accommodate larger vessels. The U.S. Army Corps of Engineers is one of the few groups which has examined this issue in depth, and has concluded that it is technically and economically feasible to increase the capacity.The economic and environmental issues of the Corps proposal are discussed as viewed from a Canadian perspective. Total cost of the proposed improvements is difficult to establish because some economic costs and benefits can be identified while others are less obvious, and environmental costs and benefits have not been adequately assessed to provide the basis for a rational judgment. The major economic and environmental concerns are discussed to demonstrate the need for more information that would be required by both countries to make an equitable decision.An evaluation of the proposed improvements to the GL-SLS on the environmental resources of Canada is presented. Environmentally sensitive areas such as shorelines, wetlands, and inshore and shallow areas along the interconnecting waterways have been characterised and it is evident that a large percentage of these areas occur within Canadian waters. Furthermore, most of the major capital improvements proposed for the system are in Canada. In view of this, it is suggested that the cost-sharing arrangement between the U.S. and Canada proposed by the Corps of Engineers for improvements on the GL-SLS would not be in the best interest of Canada.  相似文献   

4.
LM3-Eutro is a high-resolution eutrophication model with several improved features lacking in historical Great Lakes models. We calibrated LM3-Eutro using a 2-year (1994-1995) dataset and performed a hindcast simulation from 1976 to 1995 to evaluate the model's ability to make predictions over an extended period of time. Results show a reasonable agreement between model output and field data over this time period. The model predicted that an annual loading of 5600 metric tons (MT) would result in a lake-wide annual total phosphorus (TP) concentration of 7.5 μg L− 1. Using best estimates of future TP loadings, LM3-Eutro forecasts suggest that Lake Michigan will remain oligotrophic and will continue to meet the 7 μg L− 1 spring TP concentration Great Lakes Water Quality Agreement objective.  相似文献   

5.
Increased human population growth, reduction of phosphorus (P) loading, and the invasion of dreissenid mussels may have changed the spatial pattern and relationships between the nearshore and the offshore seston and nutrient concentrations in the eastern basin of Lake Erie over the past 30 years. We compared seston characteristics, nutrient concentrations, and phytoplankton nutrient status between nearshore and offshore zones in years before (1973–1985) and after (1990–2003) the dreissenid invasion. In 1973 (the only pre-dreissenid year nearshore data was collected), chlorophyll a (chla) and nutrient concentrations were higher nearshore than offshore. In post-dreissenid years, nearshore chla concentrations became significantly lower than the offshore, while carbon (C):chla ratios became higher, which was related to mussel grazing and possibly photoacclimation. Phosphorus deficiency in the phytoplankton increased over the 30-year period, and in the post-dreissenid years was less acute in the nearshore than offshore. Mean water column irradiance became higher in the nearshore relative to the offshore in the post-dreissenid years. The nutrient changes and phytoplankton physiology were consistent with the expected effects of nutrient cycling by mussels and diminished demand by phytoplankton despite increased demand from benthic algae in the nearshore. This basin-scale study suggests that dreissenid mussel invasion can be associated with alterations in the spatial pattern of water column properties in large lakes even on open coasts with vigorous circulation and exchange.  相似文献   

6.
Recent surface-water surveys suggest that high nutrient concentrations and nuisance algae remain issues in the St. Lawrence River Area of Concern (AOC) at Cornwall, Ontario, specifically in the tributaries and nearshore zones of Lake St. Francis (LSF). In particular, it is unclear whether management actions designed to reduce nutrient inputs, first implemented in the 1990s as part of the Remedial Action Plan for the AOC, have reduced algal production or influenced assemblage composition. To address this issue, a paleolimnological approach was used to provide a historical context for the present-day nutrient concentrations and to quantify the extent of change in water quality in LSF since the early 1990s. A sediment core was collected near the north shore of LSF and was examined for changes in the concentrations and compositions of fossil diatoms and pigments, as well as stable isotope (δ15N and δ13C) values. Analyses of diatom and pigment concentrations indicated that overall algal abundance has risen in the last few decades, including trends of increasing occurrences of potentially toxic cyanobacteria, despite ongoing remediation efforts. Temporal patterns of stable isotope signatures in the core suggest a steady increase in nutrient influx since the mid-20th century, with the post-1990 increase in algal production likely attributable to recent inputs associated with land-use changes in local contributing watersheds. These patterns suggest that the AOC delisting goals for the LSF tributaries will not be reached without a drastic change in land management practices.  相似文献   

7.
Fluctuations in total nitrogen and phosphorus concentrations and in the N/P ratio (i.e. in terms of mass) were measured at the entry and exit of the Sahela Reservoir (Morocco) throughout an annual cycle. Particulate N and P concentrations in sedimenting particles in the reservoir itself were also measured. The results obtained showed that the spring floods were a major source of N and P inputs, this being especially pronounced for phosphorus that was present mainly in particulate form. In all the compartments of the reservoir analysed, the N/P ratios were high (means between 81 and 314), especially in summer (the only season when the reservoir was emptied) when the supply of P was apparently limited by the drought. However, the values of this ratio in the sedimenting particles remained lower (mean = 21), at levels characteristic of natural communities. This implies that the reservoir's biological communities preferentially store phosphorus, no doubt to maximise their activity in an environment where a large proportion of this element is not bioavailable. Furthermore, it appeared that the quantity of particulate N and P sequestrated by the sediments and the total quantities of N and P leaving the reservoir were greater than the inputs of these nutrients, underlining the importance of lateral and internal nutrient supplies. One spot measurement, made in a single month, showed that nutrient release activity from the sediments was in fact quite considerable.  相似文献   

8.
Lake Erie western basin (WB) cyanobacterial blooms are a yearly summer occurrence; however, blooms have also been reported in the offshore waters of the central basin (CB), and very little is known about what drives these blooms or their potential for cyanobacterial toxins. Cyanobacteria Index was quantified using MODIS and MERIS data for the CB between 2003 and 2017, and water samples were collected between 2013 and 2017. The goals were to 1) quantify cyanobacteria, 2) determine environmental drivers of CB blooms, and 3) determine the potential for cyanobacterial toxins in the CB. Dolichospermum (Anabaena) occurred in the CB during July before the onset of the WB bloom, and then in August and September, the cyanobacteria community shifted towards Microcystis. The largest Dolichospermum blooms (2003, 2012, 2013, and 2015) were associated with reduced water clarity (Secchi disk depth?<?4?m), whereas large CB Microcystis blooms (2011 and 2015) were associated with large WB blooms. Dolichospermum blooms occurred in high nitrate concentrations (>20?μmol/L) and high nitrogen-to?phosphorus ratios (>100), which indicate nutrient concentrations or ratios did not select for Dolichospermum. Additionally, the sxtA gene, but not mcyE or microcystins, were detected in the CB during July 2016 and 2017. The mcyE gene and microcystins were detected in the CB during August 2016 and 2017. The results indicate the CB's potential for cyanotoxins shifts from saxitoxins to microcystins throughout the summer. Continued monitoring of cyanobacteria and multiple cyanobacterial toxins is recommended to ensure safe drinking water for CB coastal communities.  相似文献   

9.
为了解拉林河流域地下水中稀土元素(REE)的地球化学特征,通过稀土元素质量浓度测试和北美页岩(NASC)归一化分析研究区域地下水系统中稀土元素的质量浓度和分异特征,利用软件PHREEQC模拟计算研究稀土元素沿流向的形态分布特征。结果表明:拉林河流域地下水中稀土元素总质量浓度(ΣREE)较低,范围为0.030~2.649μg/L(均值0.328μg/L);轻稀土元素(LREE)相对亏损,而重稀土元素(HREE)相对富集,具有显著Eu正异常和轻度Ce负异常;地下水中稀土元素主要以LnCO_3~+和Ln(CO)3))2~-形态存在;随径流距离增加,地下水中ΣREE质量浓度明显下降,Eu正异常程度增大,LnCO_3~+和Ln(CO_3)_2~-形态质量浓度分别呈下降和上升趋势,稀土元素形成二碳酸配合物是造成重稀土元素相对富集的主要原因。  相似文献   

10.
While the four‐dimensional nature of river ecosystems has been recognized for nearly two decades, the role of lateral complexity has rarely been factored into studies of zooplankton ecology. We examined the importance of hydrologic retention areas (slackwaters) near islands and embayments of the St. Lawrence River for densities, fecundity, and diel migration of planktonic microcrustaceans. Densities of cladocera and copepods (nauplii and adult stages of cyclopoids and calanoids) were sampled from surface and deeper layers both at night (2100–0100 h, near the new moon) and during the day (1000–1400 h) for channel (deep‐fast), offshore (shallow‐slower), and inshore (shallow‐stagnant) habitats. Average zooplankton densities increased laterally from the main channel into the slackwaters with the exception of calanoid copepods, which peaked in the intermediate depths and flows of the offshore habitats. Although the ratio of males to females for the calanoid Eurytemora affinis and the cladoceran Bosmina spp. did not differ among habitats, a greater percentage of ovigerous cladoceran females were present in slackwaters than in channel habitats. Densities of microcrustaceans were generally greater during the night than day, suggesting diel vertical migration. By demonstrating both lateral and diel differences in the spatial distribution of riverine zooplankton, we refute the view of large rivers as well‐mixed homogenous systems. To the contrary, the two non‐random patterns that we document imply that there is an abiotic template that at least microcrustacean potamoplankton can exploit. In turn this suggests more research into the ecological significance of the pelagic structure of other large rivers like the St. Lawrence is justified. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
Phosphorus (P) losses from agricultural soils are a growing economic and water-quality concern in the Lake Erie watershed. While recent studies have explored edge-of-field and watershed P losses related to land-use and agricultural management, the potential for soils developed from contrasting parent materials to retain or release P to runoff has not been examined. A field-based study comparing eight agricultural fields in contrasting glacial landscapes (hummocky coarse-textured till-plain, lacustrine and fine-textured till-plain) showed distinct physical and geochemical soil properties influencing inorganic P (Pi) partitioning throughout the soil profile between the two regions. Fields located on the coarse-textured till-plain in mid-western Ontario, Canada had alkaline calcareous soils with the highest Total-Pi concentrations and the majority of soil Pi stored in an acid-soluble pool (up to 91%). In contrast, loosely to moderately soluble Pi concentrations were higher in soils of the lacustrine and fine-textured till-plain in southwestern Ontario, northeast Indiana and northwestern Ohio, US. Overall, soils on the lacustrine and fine-textured till-plain had a greater shrink swell-capacity, likely creating preferential flow to minimize Pi interaction with the more acidic, lower carbonate and lower sorption capacity soils. These differences in soil Pi retention and transport pathways demonstrate that in addition to management, the natural landscape may exert a significant control on how Pi is mobilized throughout the Lake Erie watershed. Further, results indicate that careful consideration of region-specific hydrology and soil biogeochemistry may be required when designing appropriate management strategies to minimize Pi losses across the lower Great Lakes region.  相似文献   

12.
研究黄河内蒙古段十大孔兑(以下简称十大孔兑)流域土地利用变化,对于区域生态环境建设和水土保持效果评价有重要意义。根据1980年、1998年、2010年3期遥感影像解译的土地利用数据,采用土地利用动态变化和土地利用转移矩阵,系统分析了十大孔兑流域1980年以来的土地利用变化时空特征。结果表明:研究区以耕地、草地和未利用地为主要土地利用类型,1980年以来草地面积逐渐增加,未利用地面积逐渐减少,1998年-2010年较1980年-1998年的土地利用变化幅度和变化速度提高。1980年-1998年和1998年-2010年,土地利用转移方向主要是未利用地向低、中覆盖草地转化,低覆盖草地向中、高覆盖草地转化,中覆盖草地向高覆盖草地转化,该转化主要分布在流域的上中游,以流域东部和西部最明显。1980年-1998年间低覆盖草地向中、高覆盖草地转化比例较高,1998年-2010年间未利用地向低、中覆盖草地转化比例较高。分析认为,1980年以来十大孔兑流域城镇化水平提高,林草水保措施力度增强、成效显著,区域生态环境改善,特别是国家实施"退耕还林(草)"生态修复政策后,生态环境改善效果更为突出。  相似文献   

13.
This paper examines the tributary monitoring network currently in place for sampling the amount of phosphorus entering the U.S. Great Lakes, focusing on the challenges faced by the agencies and organizations responsible for maintaining the network. The tributaries that are monitored vary in terms of flow, the size and terrain of the watershed being drained, and patterns of land use. Data generated by this network are used by researchers to compute lake-wide phosphorus loads. In this work, the primary drivers and challenges associated with operating an effective phosphorus tributary monitoring program were investigated through interviews with stakeholders responsible for managing a portion of the existing network. Based on these interviews, the authors identify three recommendations that policy makers interested in maintaining an effective phosphorus monitoring network in the Great Lakes should consider. The first is to provide states with incentives to support the long-term monitoring that is required to estimate phosphorus loads in tributaries to the Great Lakes; currently, most states design their programs to meet the requirements of the Clean Water Act, which results in patterns of sampling that are not necessarily useful for computing loads. The second recommendation is to facilitate the creation of a monitoring protocol that generates enough samples to identify trends and quantify loads at a level of certainty necessary for use in statistical models and load control programs. Finally, funding mechanisms capable of supporting long-term monitoring programs need to be established, with programs in Michigan and Minnesota serving as potential models.  相似文献   

14.
Extensive efforts are underway to reduce phosphorus (P) export from the Lake Erie watershed. On the Canadian side, the Thames River is the largest tributary source of P to Lake Erie’s western basin. However, the role of dams in retaining and modifying riverine P loading to the lake has not been comprehensively evaluated. We assessed whether Fanshawe Reservoir, the largest dam reservoir on the Thames River, acts as a source or sink of P, using year-round discharge and water chemistry data collected in 2018 and 2019. We also determined how in-reservoir processes alter P speciation by comparing the dissolved reactive P to total P ratio (DRP:TP) in upstream and downstream loads. Annually, Fanshawe Reservoir was a net sink for P, retaining 25% (36 tonnes) and 47% (91 tonnes) of TP in 2018 and 2019, respectively. Seasonally, the reservoir oscillated between a source and sink of P. Net P release occurred during the spring of 2018 and the summers of 2018 and 2019, driven by internal P loading and hypolimnetic discharge from the dam. The reservoir did not exert a strong influence on DRP:TP annually, but ratio increases occurred during both summers, concurrent with water column stratification. Our analysis demonstrates that Fanshawe Reservoir is not only an important P sink on the Thames River, but also modulates the timing and speciation of P loads. We therefore propose that the potential of using existing dam reservoirs to attenuate downstream P loads should be more thoroughly explored alongside source based P mitigation strategies.  相似文献   

15.
为探明涡河中下游水质状况,基于2016年12月至2017年9月涡河中下游4次监测的浮游植物和水质数据,利用物种优势度和多样性指数对浮游植物的时空分布特征进行定量分析。结果表明:涡河中下游的浮游植物主要表现出种类分布不均匀、不同河段差异性大等特点;涡河中下游共发现浮游植物7门89属种,以绿藻门和硅藻门为主;浮游植物的优势类群随季节变化较大,4次采样共发现16个优势物种,4个季节中绿藻门的优势种类均为最多;浮游植物Shannon-Wiener多样性指数水质评价等级显示涡河中下游整体污染程度呈转好趋势;冗余度分析表明环境因子对浮游植物时空分布总体变异的解释度为60.02%;温度、电导率和总磷是影响涡河中下游浮游植物时空分布的主要环境因子。  相似文献   

16.
The round goby (Neogobius melanostomus) is increasingly being reported in tributaries of the Laurentian Great Lakes where these fish have been shown to adversely impact native stream biota. Determining the characteristics and distribution of invaded streams are the first steps toward effective round goby management. We sampled 30 tributaries in the Great Lakes basin and characterized each in terms of nine physical reach-scale attributes. Round goby were detected in 14 streams where abundances ranged from 4% to 53% of the fish sampled in each stream. Round goby was the single most abundant fish species sampled, constituting 14% of all fish encountered across all sites, and 30% of individuals in round goby-present sites. Round goby-present sites were larger, had lower channel slopes, less large wood, and less canopy cover than round goby-absent sites, suggesting that these attributes may promote round goby establishment. Mottled sculpin, cyprinids, brook stickleback, white sucker and rainbow trout were associated with goby absence while centrarchids, percids, yellow bullhead, and mud minnow were associated round goby presence. Collectively these results demonstrate that round goby are widespread in eastern Michigan tributaries to the Great Lakes, present in streams with a range of physical habitat characteristics, and that round goby presence is associated with certain fish species.  相似文献   

17.
We analyzed lower water column redox-sensitive and bio-relevant (Al, Fe, Mn) micronutrient data between 2018 and 2019 to assess spatial and seasonal variability within Lake of the Woods (LoW) as they relate to continued eutrophication and water quality issues. The sediment–water interface represents a dynamic linkage between the sediment and overlying water column, dominated by diffusive flux and particulate resuspension. The complexity of LoW basins, shoreline extent, and underlying geology (situated on both the Canadian Shield and Glacial Lake Agassiz Lakebed sediments) creates variable water quality conditions, with cyanobacterial and harmful algal blooms (cHABs) particularly prevalent in the southern basins. We used a multivariate approach to differentiate basins within LoW, to better understand potential mechanisms underlying eutrophication and cHAB development. A unique signature of redox-sensitive metals was observed above the lakebed suggesting differential impacts of diffusive flux and resuspension dynamics, with significantly different micronutrient signatures between locations on vs off the Canadian Shield. The basins on the Glacial Lake Agassiz lakebed including Big Traverse, Little Traverse, Morson and Bishop were statistically comparable (p > 0.05), and significantly different from those on the Canadian Shield (p < 0.05). Correlations between bio-relevant element vanadium (element potentially used in nitrogen fixation) and chlorophyll-a), suggest potential elemental drivers of cyanobacterial ecology in LoW. An integration of multi-disciplinary research may serve to better address water quality issues as they relate to underlying geology and improve monitoring programs into the future to further delineate the physical-biogeochemical processes differentially impacting basins within LoW.  相似文献   

18.
We conducted a 2-year, multi-gear survey in the lower St. Louis River, which includes the Duluth-Superior harbor, an international shipping port and non-native species invasion “hotspot.” Our objectives were to quantify the contribution of non-native species to the overall fish assemblage and assess their spatial distribution and abundance. We captured 10 non-native fishes; none, however, were first detections. Non-native fishes composed roughly one quarter of the total species richness, were found in 84% of samples, and composed 15% of the total abundance. The spatial distribution and abundance of non-native fishes was dependent on gear selection (and thereby habitat selection), sampling location, and abundance measure (individuals or biomass). We used a recently published non-native species establishment framework to integrate catch data from the different gears. Viewed in the context of this framework, we identified only two non-native fishes, Eurasian ruffe (Gymnocephalus cernuus) and round goby (Neogobius melanostomus), as both widespread and abundant, whereas we identified three as localized and rare. Moreover, the time since first detection of non-native fishes was not predictive of their frequency of occurrence across the study area, underscoring the importance of environmental and biological factors in controlling fish establishment success. Although non-native fishes constitute a considerable portion of the trawl catch in the river channel, from a multi-gear system-wide perspective, native fishes collectively make up the majority of the fish biomass and abundance in the lower St. Louis River.  相似文献   

19.
Signs of increasing oligotrophication have been apparent in the open waters of both Lake Huron and Lake Michigan in recent years. Spring total phosphorus (TP) and the relative percentage of particulate phosphorus have declined in both lakes; spring TP concentrations in Lake Huron are now slightly lower than those in Lake Superior, while those in Lake Michigan are higher by only about 1 μg P/L. Furthermore, spring soluble silica concentrations have increased significantly in both lakes, consistent with decreases in productivity. Transparencies in Lakes Huron and Michigan have increased, and in most regions are currently roughly equivalent to those seen in Lake Superior. Seasonality of chlorophyll, as estimated by SeaWiFS satellite imagery, has been dramatically reduced in Lake Huron and Lake Michigan, with the spring bloom largely absent from both lakes and instead a seasonal maximum occurring in autumn, as is the case in Lake Superior. As of 2006, the loss of cladocerans and the increased importance of calanoids, in particular Limnocalanus, have resulted in crustacean zooplankton communities in Lake Huron and Lake Michigan closely resembling that in Lake Superior in size and structure. Decreases in Diporeia in offshore waters have resulted in abundances of non-dreissenid benthos communities in these lakes that approach those of Lake Superior. These changes have resulted in a distinct convergence of the trophic state and lower food web in the three lakes, with Lake Huron more oligotrophic than Lake Superior by some measures.  相似文献   

20.
We report dissolved CO2, CH4 and N2O concentrations in two large East African lakes, Edward (surface area 2,325 km2, average depth of 37 m) and George (surface area 273 km2, average depth of 2 m). Lake George showed modest seasonal and spatial variations, and lower partial pressure of CO2 (pCO2) (26 ± 16 ppm, mean ± standard deviation), CH4 (234 ± 208 nmol/L) and N2O saturation levels (%N2O) (80 ± 9 %) than Lake Edward (404 ± 145 ppm, 357 ± 483 nmol/L, 139 ± 222 %). Surface waters in both lakes were over-saturated in CH4, and Lake George was under-saturated in CO2 while Lake Edward was slightly over-saturated in CO2. This difference was related to higher phytoplankton biomass in Lake George than Lake Edward, with average chlorophyll-a concentrations of 177 ± 125 and 18 ± 25 µg/L, respectively. Permanent high cyanobacterial biomass in Lake George led to uniform dissolved CO2, CH4 and N2O concentrations. In surface waters of Lake Edward, spatial variations of pCO2, CH4 and N2O were related to bottom depth, and locally (in particular in Katwe Bay) also related to the inputs of water from Lake George via the Kazinga Channel, a 40-km natural channel connecting the lakes. Short-term mixing events related to storms increased CO2, CH4 and N2O content in surface waters, in particular for CH4 and N2O. This indicates that mixing events in response to storms can create ‘hot moments’ for CH4 and N2O emissions to the atmosphere in tropical lakes, given the weaker vertical density gradients compared to higher latitude systems.  相似文献   

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