共查询到20条相似文献,搜索用时 125 毫秒
1.
水热条件下钛酸钡粉体晶粒形成机理 总被引:15,自引:0,他引:15
以圩采用加直流电场水热法制备的BaTiO3粉体体系,测定了反应过程中外直流电场电流和反应反溶液中残 OHJ一。水热反应初期,电流随着反应温度的升高而增大,反应继续进行,电流达到极大值,然后急剧减小。反应温度越高,反应时间越长,反应后溶液里残留的OH量越少。结合粉体物相和晶粒形貌的表征,对水热条件下BaTiO3晶粒的形成机量进行了探讨。在反应初期,随着温度的升高驱物逐渐溶解,体系中导电离子数不断增多 相似文献
2.
3.
近年来,高纯超细BaTiO3粉体的制备技术发展十分迅速,它们在BaTiO3电子陶瓷的应用研究中起着日益重要的作用。尽管BaTiO3粉体的合成方法很多,但醇盐水解法有其不可解辨的优点。本文就醇盐水解法合成BaTiO3粉体的制备技术及其发展作了综合评述。 相似文献
4.
本文介绍了一种通过液相原料形式引入以草酸盐共沉淀来制备PTC粉体的新方法。即BaTiO3、Al2O3、SiO2、MnO2、Y2O3等均采用液相原料引入,然后用草酸进行共沉淀,通过灼烧制得PTC粉体。用这种粉体制得的PTC陶瓷,其晶粒均匀性和电性能都优于传统固相法制得的PTC陶瓷。 相似文献
5.
以乙酸和氢氧化钾为辅助原料,通过Ti(O^nBu)4-Ba(OAc)2水解法合成BaTiO3粉体。借助SEM、TEM、XRD和EPMA等分析手段,研究了PH值对BaTiO3粉体性能的影响。论述了合成BaTiO3的反应机理,同时探讨了PH值对其反应机理的影响。 相似文献
6.
7.
正丁醇钛—乙酸钡水解法合成BaTiO3粉体的研究 总被引:1,自引:0,他引:1
本文着重研究了Ti(O^nBa)4-Ba(DAc)2水解法合成高纯超细BaTiO3粉体的制备工艺。借助TGDTA,XRD,TEM,SEM,SAXS和ICP-AES等分析手段,研究了PH值,Ba/Ti比和(Ba/Ti)比,反应温度,浸泡处理等对BaTiO2粉体性能的影响,采用本工艺方法合成的BaTiO3粉体,纯度达99.80wt%,比表面积为68m^2/g,一次粒子平均粒径46.7nm,二次粒子粒径 相似文献
8.
基于液相化学共沉淀法合成超细BaTiO3粉末,研究了制备PTC BaTiO3陶瓷的成瓷技术。利用XRD和SEM分析手段,对制备的BaTiO3陶瓷的结构进行了表征。对于影响BaTiO3陶瓷的主要性能,如致密化、PTC效应和半导化性能的工艺参数进行了较为详细的研究和讨论。 相似文献
9.
通过对BaTiO3超细粉制备过程的探索,研究了影响化学配比及粒度的因素,提出反应过程中的PH值是影响Ba:Ti比的关键因素,反应条件,分散剂,陈化剂及煅烧温度对粒度具有决定性作用,本研究提供了一条BaTiO3超细粉制备的新途径。 相似文献
10.
超细BaTiO3粉的液相合成技术研究 总被引:7,自引:2,他引:7
把快速混合技术运用于草酸盐沉淀法,制备了超细BaTiO3颗粒。运用XRD,TEM等测试手段,研究了制备超细BaTiO3粉末前驱体的液相合成工艺条件,过程规律及相应的表面处理技术。 相似文献
11.
Ultrafine 5.5 mol% CeO2 —2 mol% YO1.5 ZrO2 powders with controllable crystallite size were synthesized by two kinds of coprecipitation methods and subsequent crystallization treatment. The amorphous gel produced by ammonia coprecipitation and hydrothermal treatment at 200°C for 3.5 h results in an ultrafine powder with a surface area of 206 m2 /g and a crystallite size of 4.8 nm. The powder produced by urea hydrolysis and calcination exhibits a purely tetragonal phase. In addition, the powders crystallized by hydrothermal treatment exhibit high packing density and can be sintered at lower temperature (,1400°C) with nearly 100% tetragonal phase achieved. 相似文献
12.
《Journal of the European Ceramic Society》2000,20(2):139-145
Ultrafine powders of ZrO2–Y2O3 solid solutions have been synthesized by hydrothermal treatment at 110°C. Zirconia gel, crystalline Y2O3 and various mineralizing solutions have been utilized as precursors for the hydrothermal synthesis. Yttria-stabilized zirconia (YSZ) with different Y2O3 content and characterized by different crystallite sizes have been produced by changing the hydrothermal treatment temperature, and the nature and concentration of the mineralizer solution. The role of mineralizer solutions on the crystallization-stabilization of zirconia gel at low temperature of hydrothermal treatment is discussed. 相似文献
13.
14.
Jiaguo Yu Guohong Wang Bei Cheng Minghua Zhou 《Applied catalysis. B, Environmental》2007,69(3-4):171-180
Bimodal nanocrystalline mesoporous TiO2 powders with high photocatalytic activity were prepared by a hydrothermal method using tetrabutylorthotitanate (TiO(C4H9)4, TBOT) as precursor. The as-prepared TiO2 powders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) and N2 adsorption–desorption measurements. The photocatalytic activity of the as-prepared TiO2 powders was evaluated by the photocatalytic degradation of acetone (CH3COCH3) under UV-light irradiation at room temperature in air. The effects of hydrothermal temperature and time on the microstructures and photocatalytic activity of the TiO2 powders were investigated and discussed. It was found that hydrothermal treatment enhanced the phase transformation of the TiO2 powders from amorphous to anatase and crystallization of anatase. All TiO2 powders after hydrothermal treatment showed bimodal pore-size distributions in the mesoporous region: one was intra-aggregated pores with maximum pore diameters of ca. 4–8 nm and the other with inter-aggregated pores with maximum pore diameters of ca. 45–50 nm. With increasing hydrothermal temperature and time, the average crystallite size and average pore size increased, in contrast, the Brunauer-Emmett-Teller (BET) specific surface areas, pore volumes and porosity steadily decreased. An optimal hydrothermal condition (180 °C for 10 h) was determined. The photocatalytic activity of the prepared TiO2 powders under optimal hydrothermal conditions was more than three times higher than that of Degussa P25. 相似文献
15.
The primary ultrafine carbon powders were prepared by sol–gel supercritical fluid drying method using different starting materials. After heat-treatment at 1100 and 2600°C, respectively, the ultrafine carbon powders were obtained. The properties of primary ultrafine carbon powders and their annealed products were characterized by TEM, XRD, Raman spectra and nitrogen adsorption. The results reveal that starting materials have influence on the structure of ultrafine carbon powders. 相似文献
16.
A Mg2SiO4:Eu3+ nanopowder was synthesized by a polyacrylamide gel method. In this route, the gelation of the solution is achieved by the formation of a polymer network which provides a structural framework for the growth of particles. The densification of the powders was also studied. An amorphous nanopowder was synthesized and crystallized to Mg2SiO4 after heat-treatment via a solid-state reaction at a relatively low temperature of about 700 °C. The powders prepared by the polyacrylamide gel method showed better sinterability than the powders synthesized by the conventional sol–gel method. The relative density of the sample was 97% at 1500 °C. 相似文献
17.
《Ceramics International》2015,41(4):5445-5453
Calcium silicates have proven to be potential candidates for biomedical applications because of their osteogenic properties. Sol–gel methods are typically used for the preparation of calcium silicate powders. However, in the sol–gel route, an acid or base and ethanol are used to catalyze the precursors. From the perspective of green chemistry, it is better to avoid the use of organic solvents. The objective of this study was to prepare calcium silicate powders using a green synthesis route (hydrothermal method) without organic solvents. The powders were also prepared via the sol–gel process using tetraethoxysilane (TEOS) and calcium nitrate as the raw materials for the purpose of comparison. The powders were sintered at temperatures ranging from 600 to 1000 °C after the application of both methods. To understand the feasibility of using the resulting materials in medical applications for bone repair, the powders were mixed with water to form cements. The results indicated that the powder composition was not significantly affected by the different techniques but was dependent on the Ca:Si ratio of the precursors and on the sintering temperature. The different techniques produced no differences in powder morphology. In addition, the setting times of the powder-derived cements were found to be independent of the sintering temperature and synthesis technique, but it was affected by the Ca:Si ratio of the precursors. The mechanical strength of the cements was similar. These encouraging results suggest that the hydrothermal method is a potentially beneficial alternative to the sol–gel route for the production of calcium silicate powders. 相似文献
18.
实验以β环糊精(β-CD)为造孔剂,采用水热法制备了高比表面积介孔TiO2纳米粉体.利用BET、XRD、N2 ad-sorption-sorption等方法对样品进行了测试.考察了水热温度、水热时间、焙烧温度、造孔剂添加量等因素对材料的比表面积及其光催化性能的影响.实验结果表明:当体系的水热温度180℃、水热时间8h、... 相似文献
19.
Hydrothermal Synthesis of Spherical Perovskite Oxide Powders Using Spherical Gel Powders 总被引:2,自引:0,他引:2
Jae Young Choi Chong Hee Kim Do Kyung Kim 《Journal of the American Ceramic Society》1998,81(5):1353-1356
Spherical perovskite oxide powders, composed of fine particulates, were prepared by using spherical gel powders under hydrothermal conditions. Spherical PbTiO3 , BaTiO3 , and SrTiO3 powders were synthesized from spherical TiO2 gel powders, and spherical PbZrO3 powder from spherical ZrO2 gel powder. Spherical Pb(Zr0.5 , Ti0.5 )O3 and Ba(Zr0.5 ,Ti0.5 )O3 powders were prepared from spherical ZrTiO4 gel powders. Lead acetate trihydrate, barium hydroxide octahydrate, and strontium hydroxide octahydrate were used as the sources of A-site ions in each perovskite oxide (ABO3 ). The spherical TiO2 and ZrO2 gel powders were prepared by thermal hydrolysis of titanium tetrachloride and zirconium oxychloride, respectively, and spherical ZrTiO4 gel powder by thermal hydrolysis of a mixture of them in alcohol-water mixed solvent. During the hydrothermal treatment, the spherical gel powders retained their spherical shape to produce spherical perovskite oxide powders, composed of nanometer-sized particulates. 相似文献