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采用扩展的Hückel方法与格林函数方法,分析了双Au电极作用下C60富勒稀分子的电子结构与电子输运特性。结果表明,C60富勒稀分子与Au电极“接触”后,其分子轨道能级发生了较大的变化,HOMO,LUMO间的能隙显著减小;C60与Au电极之间的结合既有共价键的成分,又有离子键的成分;C60富勒稀分子的电压-电导率曲线以及伏安曲线表现出了微妙的量子特性。 相似文献
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在工业测控系统中,经常需要对电动机的转速进行检测和控制。本文介绍了光电传感器实施电机转速测量的方法、基本原理.并用STC12C5A60S2和光电码盘配合M/T测速法来检测电动机转速,完成了一种基于STC12C5A60S2的电机测速表的系统设计。本文系统分析了系统的组成及工作原理,设计了电机测速表的硬件电路和软件编程,硬件系统包括光电传感器、脉冲信号处理和显示等相关模块,并运用汇编与c混合编程进行软件设计。该测速系统方便、稳定、可靠,具有较大的应用价值。 相似文献
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微波反射光电导衰退法是一种非接触式的半导体材料少子寿命表征手段,本文用微波反射光电导衰减法测试了台面InGaAs光电器件制备中各单项工艺(刻蚀、腐蚀、硫化)中InCaAs样品的少子寿命分布,结果表明,离子刻蚀使得样品少子寿命降低,非均匀性增大,而湿法腐蚀能够在一定程度上修复离子刻蚀带来的损伤,损伤区域中心的少子寿命增大,寿命分布也更加均匀,硫化钝化能够进一步提高损伤区域少子的寿命,却使寿命分布均匀性变差。可见,微波反射光电导衰减法可以简单无损地得到样品少子寿命分布,对工艺改进具有重要的指导意义。 相似文献
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微波反射光电导衰退法是一种非接触式的半导体材料少子寿命表征手段,本文用微波反射光电导衰减法测试了台面InGaAs光电器件制备中各单项工艺(刻蚀、腐蚀、硫化)中InCaAs样品的少子寿命分布,结果表明,离子刻蚀使得样品少子寿命降低,非均匀性增大,而湿法腐蚀能够在一定程度上修复离子刻蚀带来的损伤,损伤区域中心的少子寿命增大,寿命分布也更加均匀,硫化钝化能够进一步提高损伤区域少子的寿命,却使寿命分布均匀性变差。可见,微波反射光电导衰减法可以简单无损地得到样品少子寿命分布,对工艺改进具有重要的指导意义。 相似文献
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光刻胶在光电产品中的应用及发展简述 总被引:1,自引:0,他引:1
进入90年代后,随着微电子信息技术的发展,微电子信息产业愈来愈受到人们的重视,发展速度之快。几乎超过人们的预料。与其相配套的世界电子化学品平均年增长率也保持在8%以上。是传统化工行业中发展最快的部门之一。预计到2005年。世界电子化学品的市场规模将超过300亿美元。 相似文献
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微波反射光电导衰退法是一种非接触式的半导体材料少子寿命表征手段,本文用微波反射光电导衰减法测试了台面InGaAs光电器件制备中各单项工艺(刻蚀、腐蚀、硫化)中InCaAs样品的少子寿命分布,结果表明,离子刻蚀使得样品少子寿命降低,非均匀性增大,而湿法腐蚀能够在一定程度上修复离子刻蚀带来的损伤,损伤区域中心的少子寿命增大,寿命分布也更加均匀,硫化钝化能够进一步提高损伤区域少子的寿命,却使寿命分布均匀性变差.可见,微波反射光电导衰减法可以简单无损地得到样品少子寿命分布,对工艺改进具有重要的指导意义. 相似文献
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研究了非故意掺杂和掺Si的n型GaN外延材料持续光电导的光淬灭。实验发现非故意掺杂GaN的持续光电导淬灭程度远大于掺Si的n型GaN;撤去淬灭光后前者的持续光电导几乎没有变化,后者的却有明显减小;稍后再次加淬灭光前者的持续光电导无变化,而后者的有明显增加。我们认为两者持续光电导的形成都与空穴陷阱有关,用空穴陷阱模型解释了非故意掺杂GaN持续光电导的形成以及淬灭;认为掺Si的n型GaN的持续光电导是电子陷阱(杂质能级)和空穴陷阱共同作用的结果,并且在持续光电导发生的不同阶段其中一种陷阱的作用占主要地位。 相似文献
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研究了金属有机物化学气相外延 (MOVPE)方法生长的非故意掺杂的立方相 Ga N的持续光电导效应 .在六方相 Ga N中普遍认为持续光电导效应与黄光发射有关 ,而实验则显示在立方 Ga N中 ,持续光电导效应与其中的六方相 Ga N夹杂有关系 ,而与黄光发射没有关系 .文中提出 ,立方相 Ga N与其中的六方相 Ga N夹杂之间的势垒引起的空间载流子分离是导致持续光电导现象的物理原因 .通过建立势垒限制复合模型 ,解释了立方相 Ga N的持续光电导现象的物理过程 ,并对光电导衰减过程的动力学作了分析 .对实验数据拟合的结果证明以上的模型和推导是与实验相符的 . 相似文献
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Semi-insulating GaAs doped with different amounts of Cr and oxygen has been characterized by extrinsic photocon-ductivity
spectra at room temperature. The shape of the spectrum depends on the amount of Cr and oxygen dopant. It is interpreted by
the two-level model which assumes the lattice relaxation effect at the Cr and oxygen-related levels. The height of the photoconductivity
hump around 0.9 eV depends on the concentration ratio of Cr to oxygen; the larger the ratio is, the higher the hump is. 相似文献
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Cu diffusion was carried out in p-InP at 300°C for one hour followed by 600°C for one minute. High photoconductivity (Iph/Id = 2.6 × 105 at 200K) was observed in this sample. Information about Cu related deep levels was obtained from dark conductivity, photoconductivity
and its spectral response. A Cu related photoluminescence (PL) band was observed at 1.216 eV and its line-shape and line-width
analysis carried out. The configuration coordinate diagram of the band was calculated and showed small lattice relaxation.
In n-InP Cu diffusion at 650°C for two hours resulted in two PL bands at 1.20 and 1.01 eV. The former was similar to the 1.216
eV band in p-InP. The PL of the 1.01 eV band was also studied in detail and the corresponding configuration coordinate diagram
derived. The parameters of the Cu related bands obtained from the line-shape and line-width analysis are compared with those
reported due to Mn and Fe in InP. 相似文献
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通过分析体全息光栅的读取过程,得到光折变晶体Cu:KNSBN的光电导在入射光强为5×104W/m2时的典型值为σph=3.01×10-10A·m-2。实验得到光电导与入射光强是指数约为b=0.8的亚线性关系,从而得到满陷阱与空陷阱之密度比的定量表示式为(CCu+/CCu2+)=αIb-1。在观测的波长范围内,b随着波长缩短而增大。 相似文献
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Ruofei Jia Xiaofeng Wu Wei Deng Xiujuan Zhang Liming Huang Kaifeng Niu Lifeng Chi Jiansheng Jie 《Advanced functional materials》2019,29(45)
Persistent photoconductivity (PPC) in organic phototransistors provides an opportunity and broad prospects to achieve many emerging applications in optoelectronic devices. However, a fundamental understanding of PPC behavior is still a key challenge impeding its practical applications. In this study, for the first time, a mechanism for electron trapping is presented in oxygen‐induced deep levels in organic semiconductors for the clarification of PPC behavior with solid evidence. Both theoretical simulation and experimental investigation unveil that oxygen in air atmosphere plays a decisive role in determining the PPC behavior. Oxygen molecules can induce deep defect levels in the energy bandgap of organic semiconductors, which will act as deep traps for photogenerated electrons. The trapped electrons will be maintained in the traps and undergo a very slow releasing process after light illumination, thus leading to a noticeable PPC behavior for the organic phototransistors. The proposed mechanism shows good universality and can be applicable to a host of organic semiconductors for explaining the PPC behaviors. This work reveals the significant role of oxygen in PPC behavior and also provides guidelines for controlling the unique PPC behavior toward device applications. 相似文献