共查询到20条相似文献,搜索用时 31 毫秒
1.
An AlN buffer layer grown on (0001) sapphire substrate by molecular beam epitaxy has been studied. It is found to be made of small grains having a common [0001] axis parallel to that of the substrate. Some grains are rotated around this axis and the angle rotation can reach 20° leading to a new epitaxial relationship (0001) sap//(0001) AlN and [11 0] sap//[21 0] AlN. A model for the atomic structure of one of these grain boundaries is proposed using high resolution electron microscopy and extensive image simulation. 相似文献
2.
In this paper we examine a series of four GaN epilayers grown by MOVPE on sapphire substrates with different AlN buffer layer thicknesses. We examine the effect of the buffer layer thickness on the physical and optical properties of the samples via optical microscopy, cathodoluminescence imaging, photoluminescence, and cathodoluminescence spectroscopy. While the morphological and optical properties of all the films (excepting that with the thinnest buffer layer of 30 nm) are good, i.e. the films are smooth and the luminescence is dominated by excitonic luminescence, a number of circular island like features are observed in all the films whose density decrease with increasing buffer layer thickness. A large circular island present on the sample with the thinnest buffer layer and surrounded by cracks in the 11 0 directions, displays some interesting acceptor related luminescence. 相似文献
3.
Transmission electron microscopy is used to analyse a range of defects observed in hexagonal GaN films grown on sapphire and GaN substrates by metalorganic chemical vapour deposition. Large angle convergent beam electron diffraction is used to analyse the Burgers vectors of dislocations and to show that hollow tubes, or nanopipes, are associated with screw dislocations having Burgers vectors±c. Weak-beam electron microscopy shows that dislocations are dissociated into partials in the (0001) basal plane, but that threading segments are generally undissociated. The presence of high densities of inversion domains in GaN/sapphire films is confirmed using convergent beam electron diffraction and the atomic structure of the { } inversion domain boundary is determined by an analysis of displacement fringes seen in inclined domains. 相似文献
4.
The kinetic parameters such as crystallization activation energy, E, and the frequency factor, ν, of Li 2O–Al 2O 3–SiO 2 glass were determined by a new non-isothermal method. The method is described by the equation , where β is the heating rate and Tf is the inflection-point temperature of differential thermal analysis (DTA). The value of Tf is determined as the maximum peak temperature on derivative differential thermal analysis (DDTA) curves. Values of E and ν of Li 2O–Al 2O 3–SiO 2 glass were also determined by two existing non-isothermal methods, namely the Kissinger plot and the Ozawa plot, and compared with those determined by isothermal method. Values of E and ν determined by the proposed equation were 332 kJ/mol and 1.4×10 13 s −1, respectively. They are excellent agreement with the isothermal analysis results, 336 kJ/mol and 1.8×10 13 s −1, respectively. In contrast, both the Kissinger equation and the Ozawa equation give much higher values of E and ν. 相似文献
5.
A new family of three optical glasses of the following chemical composition with 1 mol% of Nd 3+ were prepared to examine the effects of alkali fluorides in unmixed form: , where RF=LiF, NaF and KF. On the basis of the measured values of densities and refractive indices, the dielectric constant, reflection losses, molar refraction, Nd 3+ ion concentration in glasses and several other physical properties were determined. Absorption spectra of these glasses were recorded and Judd–Ofelt intensity parameters ( Ωλ) have been calculated. Radiative lifetimes ( τR) and branching ratios ( βR) for the fluorescent levels have been determined. To understand the laser efficiency of these materials, the values of the spectroscopic quality factor ( Ω4/ Ω6) has been evaluated and it is found that glass C could be suggested as a suitable lasing material. 相似文献
6.
The governing equations for plane waves in generally nonlinear isotropic elastic solids are a system of 6 × 6 hyperbolic conversation laws. For the half-space Riemann problem in which the initial conditions at t = 0, x > 0 and the boundary conditions at x = 0, t > 0 are constant, the system is equivalent to 3 × 3 system in the full-space Riemann problem. It is further reduced to a 2 × 2 system due to the fact that one of the characteristic wave speeds is linearly degenerate. For hyperelastic materials for which there exists a potential W whose gradients provide the strains, the wave curves near an isolated umbilic point are represented by the potential of the form which contains two parameters k and m. The classification of the geometry of wave curves depends on the values of k and m and can be classified into five cases. The potential function considered here is equivalent to
considered by Schaeffer and Shearer where a and b are parameters. The classification presented here seems to provide simpler algebraic expressions. It also renders more refined classification as shown in the paper. 相似文献
7.
The dynamic fracture toughness K1d and J1d, arrest toughness K1a and Charpy V-notched impact toughness (CVN) of a pipeline steel, X70, were studied at different temperatures. It was found that fracture toughness was strongly affected by temperature and loading rate. The fracture toughness decreases with decreasing temperature from 213 to193 K and increasing loading rate from
to
. At constant temperatures, only increasing loading rate can induce the transition from ductile to brittle. There exists a fracture transition caused by loading rate. Through thermal activation analysis, a quantitative relationship has been derived: . It can describe the fracture process at different temperatures and loading rates. At a loading rate of
, the relationship can predict arrest toughness well. It provides the possibility of measuring arrest toughness with small size specimen. An empirical equation has been derived: CVN=4.84×10 6T−2.8K1d( K1a), which correlates K1d and K1a with CVN in one equation. This means that we can calculate K1d and K1a when we get CVN. 相似文献
8.
This paper gives the formulation and solution of near-tip fields of mode- I cracks growing quasi-statically in compressible elastic perfectly plastic materials. As Poisson's ratio v tends to
, the solution approaches the solution of crack growth in incompressible elastic perfectly plastic materials. The rate of crack opening is determined as , where β = 5.454 for V = o.3. The evaluation of fracturing based on the criterion of the near-tip opening is discussed. 相似文献
9.
CaCu 3 Ti 4 O 12– x CaTiO 3 ceramics ( x=0,0.1,0.2,0.3,0.4 and 0.5) was studied by X-ray diffraction, scanning electron microscope and dielectric measurements. It was indicated that some CaTiO 3 entered the boundaries of CaCu 3 Ti 4 O 12 grains and/or subgrains. Dielectric measurement showed that the addition of CaTiO 3 lowered the dielectric loss remarkably, especially at low frequencies, while the giant dielectric constant still remained. At room temperature, the dissipation factor of the x=0.5 sample was decreased to 0.02 over the frequency range from 50 to 2000 Hz, and the dielectric constant was kept to be 4000. We explain this phenomenon in terms of internal barrier layer capacitance model by using the impedance spectroscopy analysis. 相似文献
10.
The surface of carbon fibres prepared from polyacrylonitrile (PAN) precursor have been continuously treated by means of a cold plasma. The interlaminar shear strength of carbon fibre reinforced epoxy composites containing fibres so treated was increased from about 60 MPa to 100 MPa. There are four possible mechanisms for this increase: 1. (1) Higher reactivity between fibre surface and matrix as a result of an increase of groups on the fibre surface.2. (2) The surface constitution was changed by the plasma treatment so as to improve the wetting properties of fibre surface. The contact angle θ between water and the carbon fibre was decreased from 75° to 61°. 3. (3) Electron micrographs of the surface of carbon fibre show that the surface striations and surface roughness were changed increasingly on fibre surfaces after plasma etching. This increases the interfacial adhesion and the effect of mechanical interlocking. 4. (4) The strength of the carbon fibre was decreased very little (about 1·6%) by this surface treatment method.
Analysis of fracture morphology by scanning electron microscopy (SEM) indicates that debonding and fibre pull-out between fibre and matrix do not occur in the treated carbon fibre reinforced epoxy composite. These results all show that adhesion between fibre and matrix is very strong. In addition, the plasma treatment technology is very simple and the cost is low. This treatment process produces no environmental pollution and has promising future for engineering applications. 相似文献
11.
We present a systematic study of the sub-band gap optical absorption coefficients (h ν) in the range 1.2–6 eV vs. deposition-temperature ( Ts from 27 to 450°C) films deposited on silica by 13.6 MHz magnetron sputtering of an Al target with 53 and 72% N 2 in the reactive mixture. X-ray diffraction, infrared absorption and Raman diffusion are also presented, mainly on films deposited on Si in the same run to help in the characterisation of the films. All signals are specific of AlN polycrystalline films, which are of better quality when deposited with 72% N 2. The lowest sub-band gap optical absorption around 5×10 2 cm −1 is obtained for deposition on silica at Ts=300°C with 72% N 2 and is close to that of heteroepitaxial films deposited on sapphire. 相似文献
12.
The temperature dependence of luminescence from a long-lasting phosphor (LLP), SrAl 2O 4 : Eu 2+,Dy 3+, exposed to ionizing radiation has been measured to understand the LLP luminescence mechanism. Evaluation of the decay constants of the LLP exposed to -, β- or γ-rays at temperatures from 200 to 390 K showed that the decay constant is divided into four components ranging from 10 −4 to 10 −1 s −1 with activation energies of 0.02–0.35 eV. Total luminous intensity from the LLP with changing irradiation temperature has its maximum value around the room temperature. Irradiation at elevated temperature (390 K) has the total luminescence pattern with monotonous decrease as temperature rises. As a result of evaluating the temperature dependence of luminescence, the luminescence mechanism is considered as follows:
Author Keywords: Radiation detection; Long-lasting phosphor; Luminescence; Temperature dependence; Fade-out effect 相似文献
13.
Raman spectroscopy has been used to investigate the domain structures in bismuth-layered-structured ferroelectrics (BLSFs). In Bi 4Ti 3O 12 single crystal, the lowest frequency mode (soft mode) at 30 cm −1 appears exclusively for the xx polarization configuration ( xpolar axis). We found that the polarization dependence of the Raman signal exhibits spatial symmetries that reflect the presence of different domain variants present in Bi 4Ti 3O 12. This highly anisotropic character of the soft mode shares with other BLSFs such as Bi 3.25La 0.75Ti 3O 12 and SrBi 2Ta 2O 9, which demonstrate the usefulness of the soft-mode spectroscopy for the study of ferroelectric domain structures in BLSFs. We also applied Raman spectroscopy to in situ observation of domain structures in Bi 4Ti 3O 12 under applied electric field. 相似文献
14.
AlN films were prepared by CVD using aluminum halide (AlCl 3) and aluminum alkyl ((CH 3)3Al) precursors. The appropriate deposition conditions to obtain polycrystalline AlN films using A1C1 3 precursor were found at T dep = 1173 K, P tot = 66.6 Pa and N 2/NH 3 = 0.75. It was found that AlN films of different crystallinity can be obtained from (CH 3) 3Al precursor at T de = 973-1023 K, P tot = 1.99 kPa, only under a H 2 atmosphere. AlN films can be grown highly oriented in the (210) direction on amorphous quartz substrates depending on their thicknesses. The 0.1 -0.2 μm thick AlN films were transparent and their refractive indexes were about 1.4-1.6. 相似文献
15.
Simple formulas for direct pair production are derived from the general equation for deeply inelastic lepton scattering. Applications to energy loss by ultrarelativistic muons are discussed. For muons above the critical energy, Ecμ 200 GeV, where the radiative effects of direct pair production and bremsstrahlung are dominant, the expressions for energy losses are considerably simplified when quoted in terms of the fractional energy loss per radiation length. The differential probability for direct pair production in a thickness x of material of radiation length X0 for an incident lepton of energy E, mass M, can be expressed as where ν is the energy of the produced pair, υ is the fractional energy loss, υ = ν/ E, me is the electron mass and the variable z is defined by For indicent muons, this simple expression agrees very well with the exact calculation to within 30% over the entire range of υ, for E 1 TeV. At higher energies complete screening occurs, and the agreement is further improved, to better than 15% (except for the range 0.005 ≤ υ ≤ 0.01 where it is 25%). The integral of this expression gives the energy loss due to direct pair production by muons (complete screening) which is accurate to 10%: . 相似文献
16.
Raman scattering spectra have been investigated to evaluate the local structure of lithiated oxides used as electrode materials for lithium-ion batteries. We report the analysis of the vibrational spectra of ordered spinel phases including the partially delithiated λ-Li 0.5Mn 2O 4 ( SG), the partial charge-ordered LiMn 2O 4 orthorhombic form ( Fddd SG) and the LiNi 0.5Mn 1.5O 4 substituted oxide ( P4 132 SG). Analysis of spectroscopic data is performed using the classical factor group theory and the vibration features are compared with those of the ordered lithium ferrite -LiFe 5O 8 and the normal spinels LiMn 2O 4 and LiNi 0.5Mn 1.5O 4 ( Fd3 m SG), and the inverse spinel LiNiVO 4. 相似文献
17.
While an antiferroelectric liquid crystal (AFLC) with dimeric molecules which take a bent molecular structure may show the phase transition from the isotropic liquid to the chiral smectic-C AFLC ( ) phase via the nematic (N) phase, it has not been obvious yet why the and N phases may coexist in the phase sequence of the dimeric AFLC medium. In this study, the molecular alignment structures of the N and the SmC A phases of an achiral dimeric LC were researched in detail with a polarized Fourier transform infrared spectroscopy (FT-IR). The domain structure with two orientational directions is formed both in the SmC A and N phase, and the occupation ratio of two types of domain does not change in the phase transition. Since their alignment structures are basically same except for the existence of layer structure, their phases may coexist in the phase sequence of the dimeric AFLC. 相似文献
18.
Silicon nitride thin films have been deposited on InP-based structures at both room and high temperatures in an RF-inductively coupled plasma enhanced chemical vapor deposition (ICP-PECVD) equipment. Metal insulating semiconductor (MIS) diodes have been widely investigated using either SiH 4+NH 3 or SiH 4+N 2 gas phase. I–V measurements conducted on these diodes reveal high resistivity and breakdown electric field even at low deposition temperature (50°C). Double channel (DC) High electron mobility transistors (HEMTs) have been passivated by SiN x films deposited at room temperature using SiH 4+NH 3 precursors. Passivated devices exhibit a very low drift over a 45 h period of stress under high gate-drain electric field. 相似文献
19.
Laser spectroscopic as well as mass-spectrometric techniques were employed to examine the deposition chemistry in the catalytic chemical vapor deposition processes of the SiH 4/NH 3 system. The absolute densities of NH, NH 2 and SiH 3 radicals were measured under various conditions. The densities of the stable products, H 2 and N 2, as well as those of the reactants, NH 3 and SiH 4, were also measured. The NH 2 density is always higher than that of NH and both densities decrease by the addition of SiH 4. The SiH 3 density increases nonlinearly with the increase in the SiH 4 pressure. The SiH 3 density was found to be much higher than that of NH 2 under near practical deposition conditions to fabricate Si 3N 4 films (an NH 3 to SiH 4 flow-rate ratio of 50:1, a total pressure of 20 Pa and a catalyzer temperature of 2300 K). No aminosilane molecules were identified, suggesting that the contribution of aminosilyl radicals to the film deposition is minor. Thus, NH 2 and SiH 3 must be the major deposition species to form Si 3N 4. 相似文献
20.
A technique to measure the complex index of refraction of thin solid films in the visible and near-UV range with a spectral photometer using polarized light is introduced. The complex index of refraction of amorphous silicon (oxy)nitride films deposited in a glow discharge with different gas flow ratios of NH 3:SiH 4 and N 2O:SiH 4 at 270°C was measured as a function of wavelength. The real part of the index of refraction at 632.8 nm of the films investigated varies from 1.5 to 2.5. The results could be confirmed by scanning ellipsometry. 相似文献
|